RSC – Chem. Commun. latest articles
- Collaborative manipulation strategy to enhance sodium ion storage capability of Prussian white cathodes May 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01027B, CommunicationZhibin Zhang, Yuan Gao, Jing Gao, Wenyan Si, Xiaolin Sun, Fuhua Zhao, Yuan Zhang, Zhonghua Zhang, Depeng Song, Jianfei WuCollaboratively manipulating strategy of proper heat treatment and self-customized hydrofluoroether-based electrolyte design has been proposed for boosting sodium-ion storge kinetics of Prussian white cathodes. Improved cubic phase stability and electrolyte-cathode...The […]Zhibin Zhang
- In situ construction A-site high-entropy Perovskite with interfacial CeO2 for high performance IT-SOFC air-electrode May 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00995A, CommunicationXuelong Li, Shuaihang Chen, Qian Yang, Fengyang Yu, Yunhe Zhang, Lina Su, Jianhua Liu, Li LiDeveloping intermediate-temperature solid oxide fuel cell (IT-SOFC) is one of the most promising ways for achieving carbon neutrality, but its air-electrode is restricted by the conflict between the sluggish catalytic...The content of this RSS […]Xuelong Li
- Lewis Base Adducts of NpCl4 May 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01560F, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lauren Marie Lopez, Madeleine Uible, Suzanne Cathleen Bart, Matthias ZellerNp(IV) Lewis base adducts were prepared by ligand substitution of NpCl4(DME)2. Using acetonitrile and pyridine, NpCl4(MeCN)4 (1) and NpCl4(pyr)4 (2), were isolated, respectively. Addition of […]Lauren Marie Lopez
- Cooperative heterometallic catalysts: balancing activity and control in PCL-block-PLA copolymer synthesis May 1, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC01664E, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maisarah Abdul Rahman, Thomas J. Neal, Jennifer A. GardenHeterometallic “ate” complexes show enhanced activities in ε-caprolactone/lactide polymerisation giving well-defined diblock copolymers, yet also enhance transesterification under certain conditions.To cite this article before page numbers […]Maisarah Abdul Rahman
- Colloidal synthesis of metallodielectric Janus matchsticks May 1, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC00488D, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yijiang Mu, Wendi Duan, Yuxuan Dai, Patrick A. Sullivan, Leila F. Deravi, Yufeng Wang, Daeyeon LeeMetallodielectric Janus matchsticks with variable aspect ratios are synthesized through a scalable approach that uses silica growth and functionalization […]Yijiang Mu
- Chronicles of plutonium peroxides: spectroscopic characterization of a new peroxo compound of Pu(IV) May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01186D, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Julien Margate, Simon Bayle, Thomas Dumas, Elodie Dalodière, Christelle Tamain, Denis Menut, Paul Estevenon, Philippe Moisy, Sergey Nikitenko, Matthieu VirotAlthough hydrogen peroxide (H2O2) has been highly used in nuclear chemistry for more than 75 […]Julien Margate
- Photocatalytic α-arylation of cyclic ketones by a thermally activated delayed fluorescence molecule May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01287A, CommunicationBaishanal Mandal, Sourav Mandal, Supriya Halder, Debashis AdhikariThe α-arylation of cyclic ketones via organophotocatalytic route has been described utilizing a thermally activated delayed fluorescence (TADF) molecule, PXZ-TRZ. A plethora of cyclic ketones spanning cyclohexanone, cyclopentanone and even...The content of this RSS Feed (c) The Royal Society of ChemistryBaishanal Mandal
- A superior zinc-air battery performance achieved by CoO/Fe3O4 heterostructured nanosheets May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01343C, CommunicationXue Long, Wei Tang, Chunsheng Li, Zhi-Yong Ma, Liu Kaiyi, Yi Li, Yazhou Chen, Yan Sun, Zehui Yang, Fang LuoCoO/Fe3O4 nanosheets exhibit a superior rechargeable zinc air battery (ZAB) performance of 276 mW cm-2 and stability within 600 h. The all-solid-state ZAB also affords a high power density of...The […]Xue Long
- Exploration of the polymorphic solid-state landscape of an amide-linked organic cage using computation and automation May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01407C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Caitlin Elise Shields, Thomas Fellowes, Anna Grace Slater, Andrew Cooper, Keith G Andrews, Filip Tomasz SzczypińskiOrganic cages can possess complex, functionalised internal cavities that make them promising candidates for synthetic enzyme mimics. Conformationally flexible […]Caitlin Elise Shields
- Substrate-controlled divergent remote C-H and N-H polyfluoroarylation of 2-aminopyrimidines with polyfluoroarenes via Pd(II)/Pd(0) catalysis May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01518E, CommunicationAnimesh Das, Biplab MajiSubstrate-controlled product divergence in the reaction of 2-aminopyrimidines with polyfluoroarenes under palladium catalysis is demonstrated for the first time. The reaction of secondary N-alkylpyrimidine-2-amines with polyfluoroarenes leads to C5-H polyfluoroarylation...The content of this RSS Feed (c) The Royal Society of ChemistryAnimesh Das
- Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01005A, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shintaro Kamio, Masaaki Nakamoto, Takehiro Yamagishi, Martin Oestreich, Hiroto YoshidaSilylation of aryl and alkenyl triflates is found to occur readily with silylboronic esters as a silicon source under copper catalysis. The silyl moieties are […]Shintaro Kamio
- Guest-induced narcissistic self-sorting in water via imine formation May 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01239A, CommunicationBingda Li, Bin Sun, Shuai Fang, Yixin Chen, Hao LiTwo anionic tetrahedral cages were self-assembled as the only observable products in weakly basic water via imine condensation. The success of high-yielding formation of the cages in water relies on...The content of this RSS Feed (c) The Royal Society of […]Bingda Li
- An extremely electron poor Au(III) trication bearing acetonitrile ligands April 30, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC00818A, CommunicationLachlan Barwise, Lachlan J. Moon, Bibidh Dhakal, Conor F. Hogan, Keith F. White, Jason L. DuttonTaking advantage of the weak Au(III)–F bond, fluoride abstraction from a bis-fluorido Au(III) cation in MeCN furnishes a bis-acetonitrile complex representing the most electron poor Au(III) coordination complex known.To cite this article before page […]Lachlan Barwise
- Forceless spontaneous delamination of high-aspect ratio fluorohectorite into monolayer nanosheets in chloroform April 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00475B, CommunicationKamonnart Imwiset, Volodymyr Dudko, Paul Markus, Georg Papastavrou, Josef Breu, Makoto OgawaOne-dimensional dissolution of a layered compound in a nonpolar organic solvent is reported for the first time. A high-aspect ratio fluorohectorite modified with a double chain cationic surfactant (dioctadecyldimethylammonium) showed...The content of this RSS Feed (c) The Royal […]Kamonnart Imwiset
- Oxalic acid as a dual C1 surrogate for heterogeneous palladium-catalyzed tandem four-component quinazolinone synthesis April 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01084A, CommunicationSheetal Nag, Poonam Sharma, Ashish Kumar, Navneet Sharma, Kousik Giri, Pralay DasHerein, a heterogeneous Pd/C-catalyzed direct one-step four-component double carbonylative approach for cascade synthesis of 2-aryl quinazolinones has been reported for first time starting from 2-iodoaniline derivatives and aryl iodides. The...The content of this RSS Feed (c) The Royal […]Sheetal Nag
- Optical Discrimination of Terpenes in Citrus Peels with a Host:Guest Sensing Array April 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01309C, CommunicationJunyi Chen, Jose L. Moreno, Wen Zhang, Lucas J. Gibson-Elias, Ria Lian, Saba Najafi, Haofei Zhang, Wenwan Zhong, Richard James HooleyA simple aqueous host:guest sensing array can selectively discriminate between different types of citrus varietal from peel extract samples. It can also distinguish between identical citrus samples at varying […]Junyi Chen
- Uncovering tetrazoles as building blocks for constructing discrete and polymeric assemblies April 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01616E, Feature ArticleSoumya Dey, Medha Aggarwal, Debsena Chakraborty, Partha Sarathi MukherjeeMetal-organic self-assembly with flexible moieties is a budding field of research due to the possibility of the formation of unique architectures. Tetrazole, characterised by four nitrogen atoms in a five-member...The content of this RSS Feed (c) The Royal Society of […]Soumya Dey
- Uniform Colloidal Synthesis of Highly Branched Chiral Gold Nanoparticles April 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00869C, CommunicationQing Song, Bing LiuWe present a uniform colloidal synthesis of highly branched gold nanoparticles (GNPs) including nanospheres, nanoplatelets and nanorods by cysteine-assisted seeded growth. The highly branched GNPs show blackbody-like absorption and chirality...The content of this RSS Feed (c) The Royal Society of ChemistryQing Song
- Metal-organic framework/Nb4C3Tx MXene composites for ultrasensitive detection of dopamine April 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00694A, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Purna K Boruah, Nidhi Sharma, Manash Ranjan Das, Ryo Ohtani, Benjamin Le Ouay, Masaaki OhbaComposites were prepared by combining several metal-organic frameworks in presence of exfoliated Nb4C3Tx MXenes. An easy, in-situ growth approach led […]Purna K Boruah
- O2 Reduction via Concerted-Proton Electron Transfer by a V(III) Aquo on a Polyoxovanadate-alkoxide Cluster April 29, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01331J, CommunicationShannon E Cooney, Eric Schreiber, Baela M Ferrigno, Ellen MatsonWe report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [nOct4N][V6O6(OH2)(OMe)12] via concerted proton-electron transfer. Oxygen reduction is compared between bridging and terminal O-H bonds revealing similar mechanisms, providing...The content of this RSS Feed (c) The Royal Society of […]Shannon E Cooney
- Collaborative manipulation strategy to enhance sodium ion storage capability of Prussian white cathodes May 2, 2024