RSC – Chem. Commun. latest articles
- Supramolecularly Modulated Carbon-Centered Radicals: Toward Selective Oxidation from Benzyl Alcohol to Aldehyde April 18, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01240B, CommunicationXingchen Tang, Shan Mei, Jiang-Fei Xu, Xi ZhangThe reactivity of ketyl radicals and benzoyl radicals, two key intermediates of photo-induced oxidation of benzyl alcohol, can be stabilized by the host-guest interaction of radicals with cucurbit[7]uril. As a...The content of this RSS Feed (c) The Royal Society of ChemistryXingchen Tang
- Unprecedented ROP of quinazolinones to polyacylamidines by cesium catalyst April 18, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00491D, CommunicationTarun K. Panda, Shweta Sagar, Priyanku Nath, Ajitaro Devadkar , Himadri Karmakar, Aranya Ray, Alok SarkarUnprecedented ring-opening polymerization of quinazolinones to produce novel polyacylamidines, led by a unique cooperation between the cesium metal center and the imino-phosphanamidinate ligand. Morphological studies revealed the formation of a...The content of this RSS […]Tarun K. Panda
- Precise Prostate Cancer Diagnosis with Fluorescent Nanoprobes for Detecting PSA and PSMA in Serum April 18, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00670D, CommunicationMingyi Ouyang, Ming Jia, Zixuan Chang, Yinian Wang, Keyi Wang, Xiaonan Gao, Bo TangThe novel Au-Se bonded nanoprobes were designed for concurrent detection of PSA and PSMA in serum samples, aiming to enhance the early diagnosis of prostate cancer. The probe demonstrates robust...The content of this RSS Feed (c) […]Mingyi Ouyang
- Bulk ferromagnetism in cleavable van der Waals telluride NbFeTe2 April 18, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01160K, CommunicationAnna V. Stepanova, Andrei Mironov, Alexey Bogach, Andrey Azarevich, Igor A Presniakov, Alexey V. Sobolev, Denis A. Pankratov, Vladimir Zayakhanov, Sergey Starchikov, Valeriy Verchenko, Andrei V ShevelkovA van der Waals telluride, NbFeTe2, has been synthesized using chemical vapor transport reactions. The optimized synthetic conditions yield high-quality single crystals with […]Anna V. Stepanova
- Nickel-catalyzed C(sp2)–C(sp3) coupling via photoactive electron donor–acceptor complexes April 18, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC00217B, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Salman Alsharif, Chen Zhu, Xiushan Liu, Shao-Chi Lee, Huifeng Yue, Magnus RuepingWe have developed a novel Ni-catalyzed reductive cross-coupling reaction of aryl bromides and alkyl iodides via a photoactive electron donor–acceptor (EDA) complex.To cite […]Salman Alsharif
- Gram‐scale synthesis small-sized PtM intermetallics as high-performance catalysts for the hydrogen evolution reaction April 18, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00849A, CommunicationBentian Zhang, Lijie Zhang, Han Yang, Mengtao Shan, Lei Bai, Zirong Li, Ming SunPt-based intermetallics exhibit excellent activity in electrocatalysis. However, their controlled syntheses remain difficult. Herein, carbon-supported PtM (M= Fe, Co, Ni, Zn and Mn) intermetallics with small size (3 nm) were...The content of this RSS Feed (c) […]Bentian Zhang
- Z-selective dimerization of terminal alkynes by a (PNNP)FeII complex April 18, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC00469H, CommunicationJeremiah E. Stevens, Justin D. Miller, Matthew C. Fitzsimmons, Curtis E. Moore, Christine M. ThomasA (PNNP)FeII complex is shown to catalyze the dimerization of terminal alkynes via a metal–ligand cooperative mechanism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Jeremiah E. Stevens
- A Two Carbon homologation of Friedel-Crafts alkylation enabled by Photochemical Alkene Stitching: Modular assembly of Cyclolignans April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00957F, CommunicationSoumitra Maity, Shyamal Pramanik, Apurba SamantaHerein we report an efficient two-carbon homologated variant of Friedel-crafts alkylation via photochemical radical alkene stitching. Readily available feedstock alkenes are used as bridges between photogenerated alkyl radicals and arenes,...The content of this RSS Feed (c) The Royal Society of ChemistrySoumitra Maity
- Organic Hole Transport Materials for High Performance PbS Quantum Dot Solar Cells April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01194E, CommunicationLi Zhang, Shunqiang Wang, Yi Shi, Jiazi Xu, Shuang Cao, Zijian Deng, Yong Chen, Junjie Zhang, Xichuan Yang, Zhen Meng, Quli Fan, Bin SunWe developed a triazatruxene-based hole transport material (HTM), 3Ka-DBT-3Ka, aiming to enhance band alignment and augment charge generation and collection in devices, alternative for 1,2-ethanedithiol (EDT). […]Li Zhang
- An NIR-II-emitting type-I photosensitizer for efficient hypoxic tumor phototheranostics April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00431K, CommunicationQi Wang, Ruoqing Wang, Xiaoyuan Wang, Mingxuan Fu, Yicong Gao, Jianfeng Feng, Renyong Geng, Zhen Yuan, Quli Fan, Feng LuA small molecule-based NIR-II type-I photosensitizer (IT-IC) with strong push-pull effect and well plane π-conjugated structure was synthesized. IT-IC NPs exhibited strong light absorption, outstanding NIR-II fluorescence emission, excellent photothermal...The […]Qi Wang
- Layered BaV6O16·3H2O@GO as a High Performance Cathode Material for Calcium Ion Batteries April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00988F, CommunicationLixiao Xiang, Wen-Hua Yang, Yuanhao Wang, Xiang Sun, Jie Xu, Derang Cao, Qiang Li, Hongsen Li, Xia WangThe lack of suitable cathode materials has hampered the further development of calcium-ion batteries (CIBs). A novel composite cathode material, namely BaV6O16·3H2O@GO was fabricated, which delivers a high specific capacity...The content of […]Lixiao Xiang
- Pure separation of acetylene based on a sulfonic acid and amino group functionalized Zn-MOF April 17, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC00863D, CommunicationYu-Xin Deng, Guo-Ping Yang, Yao-Yu WangZn-MOF 1 was synthesized by the dual-ligand strategy and had 1D channels functionalized by sulfonic acid and amino groups. Upon activation, the coordinated water of 1 was removed and the pore environment of 1a was optimized for C2H2 purification.To cite this article before page […]Yu-Xin Deng
- Recent advances in electrosynthesis of H2O2 via two-electron oxygen reduction reaction April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01476F, Highlight Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ao Yu, Shengwen Liu, Yang YangThe electrosynthesis of hydrogen peroxide (H2O2) via a selective two-electron oxygen reduction reaction (2e- ORR) presents a green and low-energy-consumption alternative to the traditional, energy-intensive anthraquinone process. This review […]Ao Yu
- Electron-insulating Li2O protection layer endowing Li-Cu-Zn ternary alloy composite anode with high performance April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00933A, CommunicationLinyun Yi, Zihao Wang, Xiaoxiao Chen, Jianxiong Xing, Hao Huang, Chaohui Wei, Qiang Zhao, Aijun Zhou, Jingze LiWe report a electron-insulating layer of Li2O nanoparticles passivated Li-rich Li-Cu-Zn ternary alloy as advanced Li anode. The insulating layer ensures Li deposition below the top protective layer and inhibit...The content of […]Linyun Yi
- A p-block dopant enables energy-efficient hydrogen production from biomass April 17, 2024Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC00140K, CommunicationWenxian Liu, Jiawei Tang, Chao Kong, Ruilian Yin, Wei Guo, Jiale Dai, Fangfang Wu, Wenhui Shi, Xiehong CaoHerein, we develop innovative p-block Bi-doped Co3O4 nanoflakes (Bi-Co3O4 NFAs) on nickel foam, which exhibit excellent electrocatalytic activity for both glucose oxidation (GOR) and H2 evolution reactions (HER).To cite this article before […]Wenxian Liu
- Enabling wide temperature battery operation with hybrid lithium electrolytes April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01110D, CommunicationSpencer A. Langevin, Tanner Hamann, Courtney McHale, Jesse KoWe demonstrate that an ionic liquid 1-ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide combined with propylene carbon- ate yields a hybrid electrolyte with a wide operational temperature window (–20 °C to 60 °C). When integrated...The content of this RSS Feed (c) The Royal Society of ChemistrySpencer A. Langevin
- Organocatalytic Access to 3-Pyridylphosphonates from Vinyl Phosphonates and Aldehydes April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00131A, CommunicationRam Subhawan Verma, Anil Kumar Khatana, Deepika Verma, Bhoopendra TiwariThe preparation of 3-phosphorylated pyridines has remained the most challenging compared to the corresponding 2- or 4-functionalized pyridines. Herein, an unprecedented amino-organocatalyzed direct synthesis of 3-pyridylphosphonates from vinylphosphonates and aldehydes...The content of this RSS Feed (c) The Royal Society of […]Ram Subhawan Verma
- Fluorescence monitoring of refluxed tyrosinase by endoplasmic reticulum-localized enzymatic activity-based sensing April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00662C, CommunicationDunji Shu, Wenzhi Xie, Huihong Liu, Jingjing Li, Jinglong Jiao, Guo-Jiang Mao, Sheng Yang, Kai ZhangA tyrosinase-activatable fluorescence probe with endoplasmic reticulum targetability was proposed for the first time. It can ratiometrically fluoresce to monitor the refluxed tyrosinase into the endoplasmic reticulum.The content of this RSS Feed (c) The […]Dunji Shu
- Integrating recombinase polymerase amplification with CRISPR/Cas9-initiated nicking-rolling circle amplification in Staphylococcus aureus assay April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC00238E, CommunicationJianguo Xu, Tong Zhou, Danni Xue, Zhuqi Sui, Haidong Yang, Xinyue Yuan, Qi WangWe integrate recombinase polymerase amplification (RPA) with CRISPR/Cas9-initiated nicking rolling circle amplification (CRISPR/Cas9-nRCA) for detecting Staphylococcus aureus. This approach utilizes a unique dimeric G-triplex structure, demonstrating firstly enhanced ThT fluorescence...The content of this RSS Feed (c) […]Jianguo Xu
- Chemical Control of CRISPR/Cpf1 Editing via Orthogonal Activation and Deactivation of Crosslinked crRNA April 17, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC01106F, CommunicationCui-Lian Lin, Wen-Da Chen, Li Liu, Liang ChengThrough the integration of CRISPR/Cpf1 with optogenetics and a reduction-responsive motif, we have developed a photoactivatable cross-linked crRNA that enables precise genome editing upon light exposure. This system also allows...The content of this RSS Feed (c) The Royal Society of ChemistryCui-Lian Lin
- Supramolecularly Modulated Carbon-Centered Radicals: Toward Selective Oxidation from Benzyl Alcohol to Aldehyde April 18, 2024