RSC – Chem. Commun. latest articles- Supramolecular Palladium Complexes Based on Guanidinium Pillar[5]arene for Cancer Therapy October 3, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04312J, CommunicationYafei Wen, Xiaojiao Di, Zelong Chen, Xuxu Zhang, Zhichao Pei, Yuxin PeiThe supramolecular palladium complex G-Pd, formed via self-assembly of Pd-complex of guanidinium pillar[5]arene with Pd²⁺, was used to encapsulate doxorubicin to G-Pd@DOX. The nanoparticles exhibit responsiveness to glutathione, controlled drug...The content of this RSS Feed (c) The Royal […]Yafei Wen
- Hydroxylation boosted low-overpotential CO2 reduction to ethylene for Cu/PTFE electrode October 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03845B, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yifeng Wang, Haoliang Huang, Shengjie Zhang, Hao Zhang, Linjuan Zhang, Chao Jing, Jian-Qiang WangWe observed that Cu/PTFE catalyst for CO2 reduction reaction generated high coverage of *OH which facilitates both the activation of CO2 […]Yifeng Wang
- Elucidation of the photoluminescence mechanism and determination of configuration content of arabinose isomer solution by fluorescence analysis October 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04323E, CommunicationQing Zhou, Jun Wang, Xiao-Ping Lei, chuchu Li, Qingfeng Wu, Jing Zhi SunA fluorescence method has been successfully constructed to accurately measure the D/L-Arb configuration content in optical isomers, and its application in ion detection has been expanded, which has greater sensitivity...The content of this RSS Feed (c) The […]Qing Zhou
- Influence of Alkyl Chain Fluorination Proportion on the Photovoltaic Performance of Non-Fullerene Acceptors October 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04224G, CommunicationShuai Liu, Tongzi Li, Xiaoli Zhou, Wenting Liang, Shenbo Zhu, Wenzhao Xiong, Yongjie Cui, Huawei Hu, Yiwang ChenThree non-fullerene acceptors (NFAs) with varying alkyl chain sizes and lengths but constant fluorine atoms were synthesized. BO-17F and HD-17F, with optimal fluorination, exhibit improved molecular packing and morphology, achieving...The content of […]Shuai Liu
- CRISPR-Cas12a Detection of DNA Glycosylases via DNA Modification Switching October 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04180A, CommunicationYouxian Li, Xiaoquan Yang, Yi Dong, Jiaqi Wang, Chaoxing LiuA programmable CRISPR-Cas12a system for selective detection of various DNA glycosylases is described. By temporarily inactivating Cas12a through the introduction of specific DNA modifications in the complementary DNA strand of...The content of this RSS Feed (c) The Royal Society of […]Youxian Li
- Modulating the photolysis of aryl azides in supramolecular host to develop photoactivatable fluorophores October 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03907F, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xujun Qiu, Eric Pohl, Andre Jung, Qianyu Cai, Haopu Su, Olaf Fuhr, Ute Schepers, Stefan BräsePhotolysis of aryl azides is a convenient method to approach more functionalized systems in chemical biology. Here,we present a […]Xujun Qiu
- Reversible Uncompetitive Inhibition of Metal-Organic Framework Nanozymes: Specific Colorimetric Assay of Methidathion without Enzymes October 2, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04417G, CommunicationHaiying Chen, Xin Zhang, Weimin Gao, Baojian Huang, Lei HanFe-based metal-organic framework (Fe-MOF) nanozyme with MIL-88B(Fe) structure was facilely prepared by ultrasonic method. Its oxidase-like activity could be specifically inhibited by methidathion, which conformed to a reversible uncompetitive inhibition...The content of this RSS Feed (c) The Royal Society of […]Haiying Chen
- Visualizing Back Electron Transfer in Eosin Y Photoredox Catalysis October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04463K, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kai Gu, Wenqiao Zhou, Chunming LiuBack electron transfer (BET) in eosin Y (EY) photoredox catalysis was visualized via the fluorescence of single EYs. Commonly used quenchers, alkyl bromides and tertiary amine, were studied. BET […]Kai Gu
- Characterizing excited-state intramolecular proton transfer in 3-hydroxyflavone with ultrafast transient infrared spectroscopy October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03427A, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Valerie Winkler, Joseph FournierVibrational dynamics associated with excited-state intramolecular proton transfer in 3-hydroxyflavone and 3-hydroxy-2-(thiophen-2-yl)chromen-4-one are characterized with ultrafast transient infrared spectroscopy. The spectroscopic data reveal rapid (Valerie Winkler
- Harnessing Benzotriazoles as Sustainable Ligands in Metal-Catalyzed Coupling Reactions October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04450A, Feature ArticleAkhilesh K. Verma, Manvi Sharma, Deepika Thakur, Nidhi .Coupling reactions play a crucial role in drug development enabling the rapid expansion of structure-activity relationships (SAR) during the drug discovery programs to identify a clinical candidate and simplify subsequent...The content of this RSS Feed (c) The Royal Society of […]Akhilesh K. Verma
- Recent advances on COF-based single-atom and dual-atom sites for oxygen catalysis October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03535F, HighlightXinru Yan, Ning Liu, Wencai Liu, Jiajun Zeng, Cong Liu, Shufen Chen, Yuhua Yang, Xuchun Gui, Guowei Yang, Dingshan Yu, Zhiping ZengCovalent organic frameworks (COFs) have emerged as promising platforms for the construction of single-atom and dual-atom catalysts (SACs and DACs), owing to their well-defined structures, tunable pore sizes, […]Xinru Yan
- Electron-donor-acceptor (EDA) complex-driven regioselective vicinal and oxidative geminal functionalization of alkynes† October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04610B, CommunicationDinabandhu Barik, Nikita Chakraborty, Ashish Kumar Sahoo, Hirendra Nath Dhara, Bhisma K PatelA visible-light-initiated electron-donor-acceptor (EDA) complex-driven regioselective vicinal and oxidative geminal thiosulfonylation of alkynes is presented. Organic thiosulfonates act as an acceptor, producing either sulfonyl (RSO2•) or thiyl (RS•) radical under...The content of this RSS Feed (c) The […]Dinabandhu Barik
- Revealing the Structural Influence Mechanism of Intrinsic Potassium/Calcium Elements on Bio-waste-derived Hard Carbon for Sodium-ion Batteries October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03546A, CommunicationYinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiangxi He, Xingqiao Wu, Shulei ChouThe waste gourd shell enriched with ash-forming elements is selected as raw materials in this paper, discovering that the K and Ca compounds in the precursor not only exhibit the...The content of […]Yinghao Zhang
- A simple method to modulate the selectivity of aryl azide photolysis using cucurbit[8]uril October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04209C, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xujun Qiu, Qianyu Cai, Eric Pohl, Andre Jung, Haopu Su, Olaf Fuhr, Ute Schepers, Stefan BräsePhotolysis of aryl azides typically involves multiple reaction pathways. This study designed and synthesized an aryl azide rotamer with […]Xujun Qiu
- Biomimetic light-harvesting antennas via the self-assembly of chemically programmed chlorophylls October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04363D, Feature ArticleShogo Matsubara, Sunao Shoji, Hitoshi TamiakiThe photosynthetic pigment “chlorophyll” possesses attractive photophysical properties, including efficient sunlight absorption, photoexcited energy transfer, and charge separation, which are advantageous for applications in photo- and electro-functional materials such as...The content of this RSS Feed (c) The Royal Society of ChemistryShogo Matsubara
- PdPt/SrTiO3:Al-catalysed redox-selective photoreduction of unsaturated carboxylic acids using minimal electron-donor and water October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03791J, CommunicationShogo Mori, Farzaneh Soleymani Movahed, Sha Xue, Yuji Sakai, Daling Lu, Takashi Hisatomi, Kazunari Domen, Susumu SaitoWe developed a semiconductor photocatalyst, Pd-Pt alloy nanoparticle-loaded, Al-doped SrTiO3 (PdPt/STO:Al), for photoreduction of unsaturated carboxylic acids. By the cooperative STO:Al surface and Pd-Pt alloy nanoparticle, the catalyst dispersed in...The content of this […]Shogo Mori
- Electrochemical Stereoselective Borylation of Morita–Baylis–Hillman Adducts to Functionalized Allylic Boronates October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04187A, CommunicationJagadeesh Reddy Thondur, Duddu Savaraiah Sharada, Satyanarayana GeduHerein, we disclose a highly efficient and facile electrochemical borylation of Morita−Baylis−Hillman adducts without using any metal catalyst. This methodology demonstrates excellent regio- and stereo-selectivity, leading to a wide range...The content of this RSS Feed (c) The Royal Society of ChemistryJagadeesh Reddy Thondur
- Flexible, shape-editable wood-based functional materials with acetal linkages October 1, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03522D, CommunicationYi Tan, Kaili Wang, Shanshan Gong, Hui Chen, Youming Dong, Qiang Gao, Chengguo Liu, Jianzhang LiA flexible, shape-editable transparent wood (ATW) composite containing acetal linkages were prepared through free radical polymerization and addition reaction between vinyl ether bonds and hydroxyl groups simultaneously. In this system,...The content of this RSS […]Yi Tan
- Phosphination of Aryl/Alkyl Bromides via Mn-Mediated Reductive C-P Coupling September 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04750H, CommunicationLikun Dong, Bing Zhong, Yu-Shan Zhang, Jin-Dong Yang, Jin-Pei ChengMn-mediated reductive cross-coupling of organic bromides with 2-bromo-1,3,2-diazaphospholene was developed for efficient construction of C-P bonds under mild conditions. Mechanistic studies suggested bromides are activated by in situ formed bis-diazaphospholene...The content of this RSS Feed (c) The Royal Society of […]Likun Dong
- Brønsted Acid-mediated Thiazole Synthesis From Sulfoxonium Ylides September 30, 2024Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC03905J, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joe Leslie Smy, Roxanne Ifill, Storm Hassell-HartA Brønsted acid-mediated insertion of thioureas/thioamides into sulfoxonium ylides to synthesise 40 thiazoles (34-95% yields) under mild, metal-free conditions is described. This process is scalable, substrate-tolerant (including both […]Joe Leslie Smy
- Supramolecular Palladium Complexes Based on Guanidinium Pillar[5]arene for Cancer Therapy October 3, 2024
