RSC – Chem. Sci. latest articles- Shedding a new light on quadrupolar 1,4-dihydropyrrolo[3,2-b]pyrroles: impact of electron-deficient scaffolds over emission November 29, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC07275H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bartosz Szymański, Smruti Ranjan Sahoo, Olena Valulyuk, Rashid Valiev, Ruslan Ramazanov, Piotr Łaski, Katarzyna N. Jarzembska, Radoslaw Kaminski, Mohammad Bagher Teimouri, Glib Baryshnikov, Daniel T GrykoIn this work, we disclose a series of […]Bartosz Szymański
- Valorization systems of electrocatalytic nitrate/nitrite conversion for energy supply and valuable product synthesis November 29, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05936K, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yi Feng, Jin-Tao Ren, Ming-Lei Sun, Zhong-Yong YuanThe excessive accumulation of nitrate/nitrite (NOx-) in surface and groundwater has severely disrupted global nitrogen cycle and jeopardized public health. The electrochemical conversion of NOx- to […]Yi Feng
- Total Biosynthesis of Cotylenin Diterpene Glycosides as 14-3-3 Protein-Protein Interaction Stabilizers November 28, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05963H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhenhua Zhenhua Guan, Nanyu Yao, Wenling Yuan, Fengli Li, Yang Xiao, Mewlude Rehmutulla, Yuhan Xie, Chunmei Chen, Hucheng Zhu, Yuan Zhou, Qingyi Tong, Zheng Xiang, Ying Ye, Yonghui ZhangCotylenins (CNs) are bioactive fungal […]Zhenhua Zhenhua Guan
- Vanadium-regulated nickel phosphide nanosheets for electrocatalytic sulfion upgrading and hydrogen production November 28, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06804A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rui-Qing Li, Xiaojun Wang, Shuixiang Xie, Songyun Guo, Zhe Cao, Zhenhao Yan, Wei Zhang, Xiaoyu WanElectrochemical sulfion oxidation reaction (SOR) is highly desirable to treat sulfion-rich wastewater and achieve energy-saving hydrogen production when […]Rui-Qing Li
- SHARC meets TEQUILA: Mixed Quantum-Classical Dynamics on a Quantum Computer using a Hybrid Quantum-Classical Algorithm November 28, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04987J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Eduarda Sangiogo Gil, Markus Oppel, Jakob S Kottmann, Leticia GonzálezRecent developments in quantum computing are highly promising, particularly in the realm of quantum chemistry. Due to the noisy nature of currently available quantum […]Eduarda Sangiogo Gil
- Constrained TACC3 peptidomimetics for a non-canonical protein–protein interface elucidate allosteric communication in Aurora-A kinase November 28, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06100D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Diana Gimenez, Martin Walko, Jennifer A. Miles, Richard Bayliss, Megan H. Wright, Andrew J. WilsonRational design is used to optimize peptidomimetic inhibitors of the TACC3/Aurora-A kinase interaction.To cite this article before page numbers […]Diana Gimenez
- Beyond Chemical Structures: Lessons and Guiding Principles for the Next Generation of Molecular Databases November 28, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04064C, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Timo Sommer, Cian Clarke, Max Garcia-MelchorDatabases of molecules and materials are indispensable for advancing chemical research, especially when enriched with electronic structure information from quantum chemistry methods like density functional theory. In this perspective, […]Timo Sommer
- A flexible and scalable synthesis of 4′-thionucleosides November 27, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05679E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Callum Lucas, Ethan Fung, Matthew Nodwell, Steven Silverman, Bara Singh, Louis-Charles Campeau, Robert BrittonA short, de novo synthesis of purine- and pyrimidine-substituted 4′-thionucleosides is reported. The scalability of this process as well as […]Callum Lucas
- The role of responsive MRI probes in the past and the future of molecular imaging November 27, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04849K, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ping Yue, Thavasilingam Nagendraraj, Gaoji Wang, Ziyi Jin, Goran AngelovskiThis Perspective provides an overview of the recent progress in the field of bioresponsive MRI probes, highlighting the richness in research approaches and achievements in […]Ping Yue
- Charge-Transfer Mediated J-aggregation in Red Emitting Ultra-Small-Single-Benzenic Meta-Fluorophore Crystal November 27, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06851C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mrinal Mandal, Sukumar Mardanya, Arijit Saha, Manjeev Singh, Swarnali Ghosh, Tanmay Chatterjee, Ramen Patra, Surojit Bhunia, Saptarshi Mandal, Soumen Mukherjee, Rahul Debnath Debnath, Chilla Malla Reddy, Mousumi Das, Prasun K. MandalRed emission in […]Mrinal Mandal
- Reassessing the role and lifetime of Qx in the energy transfer dynamics of Chlorophyll a November 27, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06441K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Erika Keil, Ajeet Kumar, Lena Bäuml, Sebastian Reiter, Erling Thyrhaug, Simone Moser, Christopher D.P. Duffy, Regina de Vivie-Riedle, Jürgen HauerChlorophylls are photoactive molecular building blocks essential to most photosynthetic systems. They have comparatively […]Erika Keil
- Regulation of STING G-quadruplex for rescuing cellular senescence and Aβ phagocytic capacity of microglia November 27, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04453C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Heying Yuan, Jie Yang, Geng Qin, Yue Sun, Chuanqi Zhao, Chunyu Wang, Jinsong Ren, Xiaogang QuAlzheimer's disease (AD), as the most common form of dementia, has suffered millions of people worldwide and the […]Heying Yuan
- Efficient construction of high-quality sulfonated porous aromatic frameworks by optimizing swelling state of porous structure November 27, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05329J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lulu Yang, zhen zhan, Lin Zhao, Chengxin Zhang, Shaolei Wang, Wei Hu, Guangshan ZhuConventional post-modification methods usually face the fundamental challenge of balancing the high content of functional groups and large surface area […]Lulu Yang
- Modulating built-in electric field via Br induced partial phase transition for robust alkaline freshwater and seawater electrolysis November 27, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06673A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lei Jin, Hui Xu, Kun Wang, Yang Liu, Xingyue Qian, Haiqun Chen, Guangyu HeThe Br induces a partial phase transition, which exhibits the strongest BEF. The negatively charged PO43− layer can protect NiOOH […]Lei Jin
- Suppressing non-radiative relaxation in a NIR single photon emitter: the impact of deuteration and temperature November 27, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05517A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Krishna Mishra, Zehua Wu, Christian Erker, Klaus Müllen, Thomas BaschéDeuteration suppresses the weakly temperature dependent internal conversion (IC) and turns dibenzoterrylene molecules into bright single photon emitters, in agreement with the predictions of […]Krishna Mishra
- pH-mediated manipulation of the histidine brace in LPMOs and generation of a tri-anionic variant, investigated by EPR, ENDOR, ESEEM and HYSCORE spectroscopy November 26, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04794J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julia Haak, Ole Golten, Morten Sørlie, Vincent G. H. Eijsink, George E. CutsailA lytic polysaccharide monooxygenase's ligands and their electronic influences are revealed by advanced electron paramagnetic resonance spectroscopies.To cite this article before […]Julia Haak
- Ni-Catalyzed Asymmetric Decarboxylation for the Construction of Carbocycles with Contiguous Quaternary Carbon Stereocenters November 26, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06849A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yicheng He, Biwei Yan, Cheng Ma, Shaofei Ni, Wusheng GuoThe first Ni-catalyzed asymmetric decarboxylative strategy for the construction of carbocycles with contiguous quaternary all-carbon stereocenters is reported. The key to the success of […]Yicheng He
- Slow magnetic relaxation and strong magnetic coupling in the nitroxyl radical complexes of Lanthanide(III) with diamagnetic ground state (Ln = Lu, Eu) November 26, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05035E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Sorace, Alexey A. Dmitriev, Mauro Perfetti, Kira E. VostrikovaRadical lanthanide complexes are appealing platforms to investigate the possibility to engineer strong magnetic couplings between the two magnetic centers by exploiting the strongly […]Lorenzo Sorace
- Oleylammonium Fluoride Passivated Blue-Emitting 2D CsPbBr3 Nanoplates with Near-Unity Photoluminescence Quantum Yield: Safeguarding against Threats by External Perturbations November 26, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05565A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arghya Sen, Abhijit Dutta, Abir Lal Bose, Pratik SenQuantum-confined, two-dimensional (2D) CsPbBr3 (CPB) nanoplatelets (NPLs) have emerged as exceptional candidates for next-generation blue LEDs and display technology applications. However, their large surface-to-volume ratio […]Arghya Sen
- An elastic siderophore synthetase and rubbery substrates assemble multimeric linear and macrocyclic hydroxamic acid metal chelators November 25, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04888A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kate P Nolan, Callum A Rosser, James Liam Wood, Josep Font, Athavan Sresutharsan, Joseph Wang, Todd E Markham, Renae Ryan, Rachel CoddThe trihydroxamic acid bacterial siderophore desferrioxamine B (DFOB, 1) produced by the […]Kate P Nolan
- Shedding a new light on quadrupolar 1,4-dihydropyrrolo[3,2-b]pyrroles: impact of electron-deficient scaffolds over emission November 29, 2024
