RSC – Chem. Sci. latest articles
- Alkali metal salts of 1,2,3-benzodiazaborines: Platforms for late-stage N-functionalization and metal complexation Tháng 4 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01395J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leonie Wüst, Lea Scheuring, Tim Wellnitz, Krzysztof Radacki, Holger BraunschweigThe standard procedure for the preparation of benzoid 1,2,3-diazaborines (DABs) is the condensation of 2-formylphenyl boronic acid with a hydrazine. The choice of hydrazine […]Leonie Wüst
- Photoinduced carbonylative annulation access to β-lactams Tháng 4 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02418H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuanrui Wang, Xin Qi, Zhipeng Bao, Xiao-Feng WuIn radical carbonylation chemistry, orderly and sequential construction of C-C and C-N bonds with CO can effectively approach amide units and quickly incorporate a wide range […]Yuanrui Wang
- Enabling uniform lithiation in solid-state synthesis by preventing pre-matured surface grain coarsening through grain boundary engineering Tháng 4 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00271K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yifan Wu, Xincan Cai, Weiyi Lin, Yingdong Deng, Qing Zhang, Haoyuan Li, Pu Yan, Guohui Zhong, Jin XieSolid-state calcination profoundly influences the structural integrity and electrochemical performance of polycrystalline layered oxide cathode materials […]Yifan Wu
- Critical issues and optimization strategies of vanadium dioxide-based cathodes towards high-performance aqueous Zn-ion batteries Tháng 4 24, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01889G, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Botao Wan, Yajiang Wang, Xiudong Chen, Changchao Zhan, Huixiong Jiang, Jin-Hang Liu, Yun Gao, Xiaoduo Jiang, Xiaohua Cao, Hang Zhang, Shi-Xue Dou, Yao XiaoAqueous zinc-ion batteries (AZIBs) are gaining significant attention due to […]Botao Wan
- Affinity peptide ligands: new tools for chasing non-canonical N-phosphoproteome Tháng 4 24, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01557J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.He Wang, Xiaoyu Zhang, Dongdong Wang, Qianqian Jiang, Yue Sun, Baofeng Zhao, Zhen Liang, Guangyan Qing, Bo Jiang, Lihua Zhang, Yukui ZhangThis work proposed an organic solvent- and metal-free N-phosphorylation enrichment strategy based […]He Wang
- α-N-Phthalimido-Oxy Isobutyrate-Mediated Deoxygenative Arylation: Total Synthesis of Alanenses A and B Tháng 4 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00341E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Young Eum Hyun, Jeonguk Kweon, Thi Hieu Linh Phan, Dongwook Kim, Sunkyu HanInspired by our biosynthetic hypothesis for alanense A, we developed two distinct methods for the deoxygenative arylation of α-N-phthalimido-oxy isobutyrate (NPIB), […]Young Eum Hyun
- Single-Molecule Nanopore Sensing of Proline cis/trans Amide Isomers Tháng 4 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01156F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Luca Iesu, Mariam Sai, Vladimir Torbeev, Bruno Kieffer, Juan Pelta, Benjamin CressiotMolecules known as stereoisomers possess identical numbers and types of atoms, which are oriented differently in space. Cis-trans isomerization of proline, a […]Luca Iesu
- Correction: Advanced fabrication techniques for polymer–metal nanocomposite films: state-of-the-art innovations in energy and electronic applications Tháng 4 24, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC90087E, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Tayyab, Liu Zizhe, Sajid Rauf, Zixuan Xu, R. U. R. Sagar, Faisal Faiz, Zuhra Tayyab, Rashid Ur Rehman, Muhammad Imran, Anjam Waheed, Rida Javed, A. Surulinathan, Zulakha Zafar, Xian-Zhu Fu, Jing-Li LuoTo cite […]Muhammad Tayyab
- Icosahedron kernel defect in Pt1Agx series of bimetallic nanoclusters enhances photocatalytic hydrogen evolution Tháng 4 24, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01735A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dong Tan, Tengfei Ding, Kaidong Shen, Chang Xu, Shan Jin, Daqiao Hu, Song Sun, Manzhou ZhuThe novel Pt1Ag11 nanocluster with a defect-containing icosahedral kernel displayed excellent catalytic performance in the photocatalytic hydrogen evolution […]Dong Tan
- An overlooked cyclase plays a central role in the biosynthesis of indole diterpenes Tháng 4 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02009C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rosannah Cameron, Daniel Berry, Alistair T. Richardson, Luke J. Stevenson, Yonathan Lukito, Kelly Styles, Natasha S. L. Nipper, Rose May McLellan, Emily ParkerIndole diterpenes (IDTs) are a large class of highly complex fungal […]Rosannah Cameron
- Switching Mesoionic Carbene-Organocatalysis from Radical to Ionic Pathway through Base-Controlled Formation of Breslow Intermediates versus Breslow Enolates Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08229J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jie Jiao, Zengyu Zhang, Guangyin Lu, Shiqing Huang, Yajing Bian, Fan Gao, Guy Bertrand, Xiaoyu YanN-Heterocyclic carbene (NHC) organocatalysis has experienced significant advancements. Two distinct reaction pathways have been developed, ionic and radical, […]Jie Jiao
- Catalytic Alkoxysilylation of C–H bonds with tert-Butyl-Substituted Alkoxysilyldiazenes Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02059J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lamine Saadi, Loïc Valade, Clément ChauvierOrganoalkoxysilanes (e.g. R–SiMe3-n(OR’)n, 1 ≤ n ≤ 3 with R=alkyl or aryl) have found various applications in synthetic chemistry and materials science because the silicon-bound alkoxy groups provide […]Lamine Saadi
- Tandem Reaction-Powered Near-Infrared Fluorescent Molecular Reporter for Real-Time Imaging of Lung Diseases Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01488C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yan Hu, Hongshuai Zhang, Yiteng Ding, Weirui Chen, Changqie Pan, Longwei He, Dan Cheng, Lin YuanDiabetes and its complications have drawn growing research attention due to their detrimental effects on human health. Although […]Yan Hu
- Mechanism-Guided Descriptor for Hydrogen Evolution Reaction in 2D Ordered Double Transition-Metal Carbide MXenes Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08725A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Junmei Du, Yifan Yan, Jiao Chen, Xiumei Li, Chunsheng Guo, Yuanzheng Chen, Hongyan WangSelecting effective catalysts for the hydrogen evolution reaction (HER) among MXenes remains a complex challenge. While machine learning (ML) paired […]Junmei Du
- Water-Accelerated Photooxidation and Degradation of Lignin Linkages Mediated by Plasmonic Catalysts Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08401B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juhee Ha, Jiwon Kang, Suk Hyun Lim, Dae Won Cho, Kwang-Im Oh, Youngsoo KimThe selective oxidation and degradation of lignin are crucial for realizing its potential as a biofuel or petroleum substitute. Despite […]Juhee Ha
- Towards Site-specific Manipulation in Cysteine-mediated Redox Signaling Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02016F, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing YangCysteine sulfenic acid (SOH) modifications are pivotal in redox signaling, yet establishing their causal biological roles remains challenging due to methodological limitations. Traditional approaches often lack precision or disrupt non-redox...The content of this […]Jing Yang
- Hydrogen Production via Photocatalytic Ammonia Decomposition Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01834J, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qijun Pei, Yongyu Wang, Khai Chen Tan, Jianping Guo, Teng He, Ping ChenAmmonia, as a carbon-free fuel and promising hydrogen carrier, has attracted significant attention in the context of a net-zero-emission scenario. Photocatalytic […]Qijun Pei
- Stomata biosilica and equisetum photosynthesis: ionic tomography insight using PDMPO silicaphilic probe Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07973F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Victor V Volkov, Graham Hickman, Carole Celia PerryConfocal microscopy using silicaphilic molecular probes is a promising approach to identify the ionic character of silica interfaces. Using ab initio and density functional theory we […]Victor V Volkov
- Post-coordination of Ru(II) Controlled Regioselective B(4)–H Acylmethylation of o-Carboranes with Sulfoxonium Ylides Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01576F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hou-Ji Cao, Jia-Xin Li, Jia-Hui Yan, Miao-Xin Liu, Qianyi Zhao, Jie Zhang, Ju Zhang, Hong YanDespite significant progress in the B–H functionalization of carboranes, the development of cost-effective catalytic systems devoid of noble […]Hou-Ji Cao
- Vacuum evaporation-assisted reaction: sustainable solution for application of rare earth-based halide solid-state electrolytes Tháng 4 23, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00003C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhichao Zeng, Xiaomeng Shi, Hongtu Zhang, Yaping DuAll-solid-state lithium-ion batteries (ASLIBs) are important and promising electric energy storage devices with high stabilities and energy densities. As burgeoning key materials in ASLIBs, rare earth […]Zhichao Zeng
- Alkali metal salts of 1,2,3-benzodiazaborines: Platforms for late-stage N-functionalization and metal complexation Tháng 4 24, 2025