RSC – Chem. Sci. latest articles
- β-Terrecyclene synthase constructs the quadrane backbone in terrecyclic acid biosynthesis Tháng Tư 24, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01208A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yongxiang Song, Wengui Wang, Jiafan Yang, De-Wei Gao, John M Billingsley, Songtao Wang, Yiguang Zhu, Junfeng Wang, Jianhua Ju, Yan Yan, Yi TangQuadrane sesquiterpenes featuring a distinctive tricyclic skeleton exhibit potent antimicrobial and […]Yongxiang Song
- Electrochemical Stereoselective Synthesis of Polysubstituted 1,4-dicarbonyl Z-Alkenes via Three-Component Coupling of Sulfoxonium Ylides, Alkynes with Water Tháng Tư 24, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01141D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hao-Ran Li, Yi-An Ran, Yu-Yi Zhu, Weisi Guo, Shao-Fei Ni, Li-Rong Wen, Ming Li, Lin-Bao ZhangThe first straightforward strategy for the synthesis of 1,4-dicarbonyl Z-alkenes has been developed via an electrochemical cross-coupling reaction […]Hao-Ran Li
- Enantioconvergent Synthesis of Chiral Fluorenols from Racemic Secondary Alcohols via Pd(II)/Chiral Norbornene Cooperative Catalysis Tháng Tư 24, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01004C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bo Ding, Qilin Xue, Han Wei, Jiangwei Chen, Ze-Shui Liu, Hong-Gang Cheng, Hengjiang Cong, Jianting Tang, Qianghui ZhouAn efficient protocol for the asymmetric synthesis of fluorenols has been developed through an enantioconvergent process […]Bo Ding
- Directed Evolution of Escherichia coli Surface-displayed Vitreoscilla Hemoglobin as an Artificial Metalloenzyme for the Synthesis of 5-Imino-1,2,4-thiadiazoles Tháng Tư 24, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00005F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yaning Xu, Fengxi Li, Hanqing Xie, Yuyang Liu, Weiwei Han, Junhao Wu, Lei Cheng, Chunyu Wang, Zhengqiang Li, Lei WangArtificial metalloenzymes (ArMs) are constructed by anchoring organometallic catalysts to an evolvable protein scaffold. […]Yaning Xu
- Metal-free Platforms for Molecular Thin Films as High-performance Supercapacitors Tháng Tư 24, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00611A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ritu Gupta, Ankur Malik, Kusum Kumari, Saurabh Kumar Singh, Vincent Vivier, Prakash Chandra MondalControlling chemical functionalization and achieving stable electrode-molecule interfaces for high-performance electrochemical energy storage applications remains a challenging task. Herein, we […]Ritu Gupta
- Azole reagents enabled ligation of peptide acyl pyrazoles for chemical protein synthesis Tháng Tư 24, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D3SC06697E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Peisi Liao, Chunmao HeNative chemical ligation (NCL) has been playing an increasingly important role in chemical protein synthesis (CPS), more efficient ligation methods that circumvent the requirement of peptidyl thioester and thiol additive—which...The […]Peisi Liao
- Contracted porphyrins and calixpyrroles: synthetic challenges and ring-contraction effects Tháng Tư 23, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC02028F, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Keita Watanabe, Narendra Nath Pati, Yasuhide InokumaRing-contracted porphyrin analogues, such as subporphyrins and calix[3]pyrroles, have recently attracted considerable attention not only as challenging synthetic targets but also as functional macrocyclic compounds. Although canonical porphyrins […]Keita Watanabe
- Nickel/Photoredox-Catalyzed Three-Component Silylacylation of Acrylates via Chlorine Photoelimination Tháng Tư 23, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC02164A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yejin Koo, Sungwoo HongThe extensive utility of organosilicon compounds across a wide range of disciplines has sparked significant interest in their efficient synthesis. Although catalytic 1,2-silyldifunctionalization of alkenes provides a promising method for...The […]Yejin Koo
- Materials Discovery with Extreme Properties via Reinforcement Learning-Guided Combinatorial Chemistry Tháng Tư 23, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D3SC05281H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hyunseung Kim, Haeyeon Choi, Dongju Kang, Won Bo Lee, Jonggeol NaThe goal of most materials discovery is to discover materials that are superior to those currently known. Fundamentally, this is close to extrapolation, […]Hyunseung Kim
- De-epimerizing DyKAT of β-Lactones Generated by Isothiourea-Catalysed Enantioselective [2+2] Cycloaddition Tháng Tư 23, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01410C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Aífe Conboy, Alister S. Goodfellow, Kevin Kasten, Joanne Dunne, David Bradford Cordes, Michael Buehl, Andrew D SmithModerate diastereoselectivity (typically 70:30 dr) is observed in the isothiourea-catalysed [2+2]-cycloaddition of C(1)-ammonium enolates with pyrazol-4,5-diones to […]Aífe Conboy
- Biosynthesis of the Bacterial Antibiotic 3,7-Dihydroxytropolone through Enzymatic Salvaging of Catabolic Shunt Products Tháng Tư 23, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01715C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lars Höing, Sven T. Sowa, Marina Toplak, Jakob Klaus Reinhardt, Roman P Jakob, Timm Maier, Markus A. Lill, Robin TeufelThe non-benzenoid aromatic tropone ring is a structural motif of numerous microbial and plant […]Lars Höing
- Visualizing partial solvation at the air–water interface Tháng Tư 23, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01311E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kenneth D. Judd, Sean W. Parsons, Dmitry B. Eremin, Valery V. Fokin, Jahan M. DawlatyTo understand the solvation environment at the air–water interface, we use an azide vibrational reporter. The probe is sensitive […]Kenneth D. Judd
- A single hydrogen bond that tunes flavin redox reactivity and activates it for modification Tháng Tư 23, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01642D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Debarati Das, Anne-Frances MillerA hydrogen bond from a conserved histidine tunes flavin reactivity in favour of a catalytically critical anionic semiquinone state (front). However it also favours an electronically similar anionic methide intermediate […]Debarati Das
- Redox regulation of Ni hydroxides with controllable phase composition towards biomass-derived polyols electro-refinery Tháng Tư 22, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01221F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi Tang, Zhuxin Gui, Yingshuai Jia, Xianping Liao, Tianlan Yan, Boxu Gao, Wenbiao Zhang, Li Chen, Qingsheng Gao, Yahong ZhangElectrocatalytic refinery from biomass-derived glycerol (GLY) to formic acid (FA), one of the most […]Yi Tang
- Highly intense NIR emissive Cu4Pt2 bimetallic clusters featuring Pt(I)-Cu4-Pt(I) sandwich kernel Tháng Tư 22, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01022A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rui-Ru Zhong, Mo Xie, Cui-Zhou Luan, Lin-Mei Zhang , De-Bo Hao, Shang-Fu Yuan, Tao WuMetal nanoclusters (NCs) capable of near-infrared (NIR) photoluminescence (PL) are gaining increasing interest for their potential applications in bioimaging, […]Rui-Ru Zhong
- Viologen-based solution-processable ionic porous polymers for electrochromic applications Tháng Tư 22, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01408A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hongya Miao, Ling Chen, Fangfang Xing, Huijie Li, Thomas Baumgartner, Xiaoming HeA series of N-arylated viologens with terminal aldehyde groups has been synthesized. The new building blocks were successfully used to construct solution-processible, […]Hongya Miao
- Understanding Electrochemical Interfaces through Comparing Experimental and Computational Charge Density-Potential Curves Tháng Tư 22, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00746H, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nandita Mohandas, Sumit Bawari, Jani J.T. Shibuya, Soumya Ghosh, Jagannath Mondal, Tharangattu N. Narayanan, Angel CuestaElectrode-electrolyte interfaces play a decisive role in electrochemical charge accumulation and transfer processes. Theoretical modelling of these interfaces is […]Nandita Mohandas
- Optoelectronic insights of lead-free layered halide perovskites Tháng Tư 22, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01429D, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vishwadeepa Hazra, Arnab Mandal, Sayan BhattacharyyaTwo-dimensional organic-inorganic halide perovskites have emerged as promising candidates for a multitude of optoelectronic technologies, owing to their versatile structure and electronic properties. The optical and electronic properties are […]Vishwadeepa Hazra
- 1,5-Hydrogen Atom Transfer of α-Iminyl Radical Cations: A New Platform for Relay Annulation towards Pyridine Derivatives and Axially Chiral Heterobiaryls Tháng Tư 22, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01858C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu-Qiang Zhou, Kui-Cheng He, Wei-Hao Zheng, Jing-Fang Lv, Shi-Mei He, Ning Yu, Yun-Bo Yang, Lv-Yan Liu, Kun Jiang, Ye WeiThe exploitation of new reactive species and novel transformation modes for their synthetic applications […]Yu-Qiang Zhou
- Photo-Thermal Synergistic CO2 Hydrogenation towards CO over PtRh Bimetal-Decorated GaN Nanowires/Si Tháng Tư 22, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01530D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jinglin Li, Bowen Sheng, Liang Qiu, Jiajia Yang, Ping Wang, Yixin Li, Tianqi Yu, Hu Pan, Ying Li, Muhan Li, Lei Zhu, Xinqiang Wang, Zhen Huang, Baowen ZhouPhoto-thermal-synergistic hydrogenation is a promising strategy […]Jinglin Li
- β-Terrecyclene synthase constructs the quadrane backbone in terrecyclic acid biosynthesis Tháng Tư 24, 2024