RSC – Chem. Commun. latest articles
- Bromide-mediated Selective Electrocatalytic Oxidation of Ethylene to Ethylene Glycol by Non-Precious Metal Catalyst Sn-NiSb₂O₆ June 26, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02630J, CommunicationXianglan Li, Rong Cheng, Ruifan Zhou, Yaojie Luo, Quanhua Zhang, Xiaobing Guo, Zihua DengThis study addresses fossil fuel dependency and carbon emissions in traditional ethylene glycol synthesis by developing a bromine-mediated indirect electrocatalytic oxidation strategy for ethylene using Sn-NiSb₂O₆ catalyst. At 500 mA...The content of this RSS Feed (c) […]Xianglan Li
- An Esterase-Sensitive Persulfide/Hydrogen Sulfide Generating Fluorogenic Probe Enhances Antioxidant Response June 26, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC01523E, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bharat Choudhary, Akshi Vashishta, Ankan Ghosh, Rachit Agarwal, Harinath ChakrapaniHydrogen sulfide (H2S) and sulfane sulfur species such as persulfides and polysulfides protect the cells from oxidative stress and are central to the endogenous antioxidant […]Bharat Choudhary
- C-H Functionalisation of [2.2]Paracyclophane under Copper catalysis June 26, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02283E, CommunicationKun Zhou, Rui-Rui Wu, Xin-Rou Zhong, Jun Pu, Xin Yang, Kai Liu, Yue Wang, Dan-Qian Xu, Shao-Jie LouThe direct C-H functionalisation of [2.2]paracyclophane (PCP) by forging diverse C-C bonds is appealing, yet has remained underexplored. Herein, we describe a copper-catalysed non-directed C–H arylation and alkenylation of PCP...The content of […]Kun Zhou
- Triplex formation-mediated fluorescence sensing of single bulge nucleotide-containing double-stranded RNAs by thiazole orange base surrogate-carrying PNAs June 26, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02960K, CommunicationTianxue Han, Yusuke Sato, Eriks Rozners, Seiichi NishizawaFluorescence sensing of single bulge-containing double-stranded RNAs was achieved by triplex forming peptide nucleic acid (PNA) carrying a thiazole orange (TO) base surrogate, where the TO base surrogate facing the...The content of this RSS Feed (c) The Royal Society of ChemistryTianxue Han
- Low temperature atomic layer deposition of boron nitride using the in-situ decomposition of ammonium carbamate June 26, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02613J, CommunicationAna Álvarez-Yenes, Victor Koroteev, Maxim R. Ryzikov, Maxim Ilin, Svetlana Kozlova, Mato KnezHere, we report on a new atomic layer deposition (ALD) process for the growth of amorphous boron nitride thin films at low temperatures (100-275°C) using carbamic acid, a highly reactive...The content of this RSS Feed (c) The […]Ana Álvarez-Yenes
- A pillar[5]arene- and calix[4]pyrrole-based supramolecular polymer for selective removal of naphthols from water June 25, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02575C, CommunicationDeniz Memis, Saide Akin, Abdullah AydoganHeteroditopic host-guest architectures composed of pillar[5]arene-calix[4]pyrrole and alkylnitrile-carboxylate units were used to construct an ABCD type supramolecular polymer and subsequently fabricate a xerogel. The final system was then utilized to...The content of this RSS Feed (c) The Royal Society of ChemistryDeniz Memis
- Environment-sensitive fluorescent tryptophan analogues via indole C-2 alkenylation reactions June 25, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02114F, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Valeria K Burianova, Liyao Zeng, Abigail W Thom, Niamh C Radcliffe-Kennedy, Steven Magennis, Andrew SutherlandA modular synthetic strategy for the preparation of intrinsically fluorescent unnatural α-amino acids by C-2 oxidation and alkenylation of a […]Valeria K Burianova
- Vacancy engineering of TiO2 with low Pt content for efficient hydrogen generation June 25, 2025Chem. Commun., 2025, Advance ArticleDOI: 10.1039/D5CC02554K, CommunicationJianyang Gao, Yuanzong Shen, Jinxiao Gao, Liantao Xin, Weiping Xiao, Guangrui Xu, Dehong Chen, Lei Wang, Fusheng Liu, Zexing WuAn ultrafast (70 s) microwave quasi-solid approach is applied to design black TiO2-supported low content Pt (Pt/TiO2). The metal–support interactions of Pt and TiO2 endow the prepared catalyst with exceptional […]Jianyang Gao
- Polyoxometalate photocatalysts: solar-driven activation of small molecules for energy conversion and greenhouse gas valorization June 25, 2025Chem. Commun., 2025, Advance ArticleDOI: 10.1039/D5CC01494H, Highlight Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yinghao Wang, Geqian Fang, Vitaly V. Ordomsky, Andrei Y. KhodakovPolyoxometalate photocatalysts with tunable electronic structure drive CO2, H2O, CH4, N2 conversion, enhancing sustainability via charge dynamics and active sites.To cite this article before page […]Yinghao Wang
- Melt quenched synthesis of a manganese ZIF glass June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02342D, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luis Leon-Alcaide, Alberto Fernández-Alarcón, Joaquin Calbo, David A. Keen, Guillermo Minguez EspallargasIn this work we expand the family of ZIFs capable of being melt-quenched into a vitreous phase with the first Mn-based glass. This […]Luis Leon-Alcaide
- Hydro- and Chloroelementation Reactions Across an Iron–Carbon Bond Using Heavy Group 15 Reagents June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC03258J, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Joseph A. Zurakowski, Mitchell MacEachern, Connor Durfy, Paul D Boyle, Saurabh Chitnis, Marcus W. DroverDiaminostibines ({Sb}–H) react across the iron–carbon bond of a tucked-in iron diphosphine complex, resulting in hydrostibinated iron hydride [{Cp*-SbR2}Fe–H] complexes. […]Joseph A. Zurakowski
- Carbazole-Embedded Cyclodimer adopting Helical Conformation and Metal-ion Sensing June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC03179F, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sabapathi Gokulnath, Athira Naniyil, Arun Kumar, Aathira EdwinAn unprecedented formation of carbazole-embedded decaphyrin through acid-catalyzed condensation of appropriate coupling partners is reported. Single crystal X-ray diffraction analysis revealed that the macrocycle adopted a ‘figure-of-eight’ […]Sabapathi Gokulnath
- Linear-light controlled reverse electron transfer in a 3-D pyromelliticdiimide-based photo-/thermochromic cadmium(II) coordination polymer June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02865E, CommunicationKuixiang Li, Jin Qin, Pengfei Hao, Yi Xu, Shimin Zhang, Junju Shen, Yunlong FuThe implementation of linear-light controlled reverse electron transfer (ET) of photo-/thermo-induced chromic materials is of great importance for practical applications but remains a challenging task. In this work, a novel...The content of this RSS Feed (c) […]Kuixiang Li
- Air-processed efficient and pure green perovskite LEDs based on PVP-modified NiOX interface layer June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02585K, CommunicationJingyi Ding, Shuai Yang, Jibo Tang, Hailong Wang, Qingqian Wang, Yiman Zhang, Yangming Hu, Wenjun Zhang, Xiaobo He, Hongxing XuPerovskite light-emitting diodes (PeLEDs) have suffered moisture instability, hindering the commercialization of PeLEDs. In this study, by employing PVP-modified NiOX films, quality of perovskite films was improved with reduced trap...The […]Jingyi Ding
- In-situ Oxidizable Directing Group-Enabled Enantioselective Synthesis of Chiral Platform Ferrocene Formaldehydes June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02611C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Devendra Parganiha, Ashwini Dilip Dhumale, Yagya Dutt Upadhyay, Vishal Choudhary, Svastik Jaiswal, Raushan Kumar Jha, Sangit KumarHerein, we have developed an efficient oxidatively removable directing group approach, enabling a highly enantioselective PdII catalyzed C-H […]Devendra Parganiha
- Cycloaddition of Bicyclo [1.1.0] butanes with Enamides for the Efficient Synthesis of 2-amino-bicyclo[2.1.1]hexanes June 24, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02908B, CommunicationYanren Zhu, Shaoxiong Yang, Huiyu Chen, Fang Zhang, Enfan Pu, Piaopiao Jiang, Yi Jin, Hongbin Zhang, Jingbo ChenHere, we develop a mild and scalable approach for the synthesis of 2-amino-bicyclo[2.1.1] hexanes via Lewis acid-catalyzed (3+2) cycloaddition of bicyclo[1.1.0]butanes (BCBs) with enamides. The practicality of this methodology has...The content of […]Yanren Zhu
- Controlling the photoluminescence chromaticity of emissive copper nanoclusters via ligand engineering June 24, 2025Chem. Commun., 2025, Advance ArticleDOI: 10.1039/D5CC02621K, CommunicationMengfan Chang, Ying Xu, Ying Lv, Haizhu Yu, Hao Li, Xi Kang, Manzhou ZhuThis work manipulated the photoluminescence chromaticity of emissive copper nanoclusters by regulating the electron-donating capability of their peripheral ligands.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Mengfan Chang
- Powering the extreme: rising world of batteries that could operate at ultra-low temperatures June 24, 2025Chem. Commun., 2025, Advance ArticleDOI: 10.1039/D5CC02279G, Feature Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sung-Kwang Jung, Jyotirekha Dutta, Surendra K. Martha, Martin Byung-Guk Jun, Vilas G. PolRechargeable lithium-ion batteries and sodium-ion batteries significantly underperform at ultra-low temperatures, limiting their applicability in critical fields such as aerospace, polar […]Sung-Kwang Jung
- Current status and enhancement strategies for Bi-based materials in nickel bismuth batteries June 23, 2025Chem. Commun., 2025, Advance ArticleDOI: 10.1039/D5CC01954K, HighlightKun Yang, Haoxian Zhu, Lei Zhang, Wei Li, Li SunThis review systematically summarizes the recent advances in Bi-based anode materials. Various enhancement approaches are comprehensively discussed. This review concludes with critical perspectives on future research directions.To cite this article before page numbers are assigned, use the DOI form of […]Kun Yang
- Light‐switchable divergent C–H activation and cross‐coupling of cyclic ethers with aromatic aldehydes June 23, 2025Chem. Commun., 2025, Accepted ManuscriptDOI: 10.1039/D5CC02025E, CommunicationXumao Yang, Quansheng Mou, Mingxin LiuDivergent coupling reactions of cyclic ethers provide a powerful strategy for accessing high‐value small molecules. We report a metal‐free, light‐regulated divergent method for C–H functionalization of cyclic ethers with aromatic...The content of this RSS Feed (c) The Royal Society of ChemistryXumao Yang
- Bromide-mediated Selective Electrocatalytic Oxidation of Ethylene to Ethylene Glycol by Non-Precious Metal Catalyst Sn-NiSb₂O₆ June 26, 2025