RSC – CrystEngComm latest articles- Structural Variety in Calcium Metal-Organic Frameworks with a Tetratopic Carboxylate Ligand March 30, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00145E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Baiwen Zhao, Guy James Clarkson, Jie Liu, Thi-Huong Le, Jérome Marrot, Franck Millange, Michel Frigoli, Richard I WaltonThe solvothermal synthesis of three new calcium-based metal-organic frameworks (MOFs) employing the tetratopic carboxylate ligand, 4,4',4'',4'''-(naphthalene-2,3,6,7-tetrayl)tetrabenzoate (NTTB) is […]Baiwen Zhao
- The role of alkali metal cations in construction of heterometallic NiII polymeric cyclopropane-1,1-dicarboxylates March 30, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01319K, PaperEkaterina N. Zorina-Tikhonova, Anna K. Matiukhina, Alexander Korlyukov, Alexander S Goloveshkin, Konstantin Andreevich Babeshkin, Eugeny V. Alexandrov, N. N. Efimov, Mikhail A. Kiskin, Igor EremenkoThe new NiII coordination compounds with cyclopropane-1,1-dicarboxylic acid (H2cpdc) dianions were synthesized {[Na2Ni(cpdc)2(H2O)6]∙4H2O}n (1), {[K6Ni3(cpdc)6(H2O)10]∙8H2O]}n (2), {[Rb6Ni3(cpdc)6(H2O)12]∙5.5H2O}n (3), [Cs2Ni(cpdc)2(H2O)8]n (4). All complexes contain mononuclear bischelate fragments […]Ekaterina N. Zorina-Tikhonova
- The Benefit of Coupling Droplet Microfluidics and Multiphoton Optical Microscopy to study the Crystallization of Polymorphic Substances: a case study with Ortho-aminobenzoic Acid. March 30, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01289E, PaperHugo Cercel, Clement Brandel, Romain Rac, Charline J.J. Gérard, Clément Pinètre, Stephane Veesler, Nadine Candoni, Romain Grossier, Valerie DuprayA new crystallization platform coupling droplet-based microfluidics with a two photon and second harmonic generation microscope operating with a femtosecond pulsed wave laser of tunable wavelength is presented. The present...The content of […]Hugo Cercel
- Incipient Fault Diagnosis Method for Silicon Single Crystal Growth Assisted by Deep Learning March 29, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00101C, Paperyuyu Liu, Ding Liu, Jun Chao Ren, ShiHai WuIn this study, an accurate diagnostic classification algorithm based on a deep belief network and entropy value (C-DBN-E) incorporating signal decomposition, entropy theory and deep belief network (DBN) network is...The content of this RSS Feed (c) The Royal Society of Chemistryyuyu Liu
- Two Zinc(II)-Based coordination polymers as Luminescent Sensors for detecting Salicylaldehyde with High Sensitivity and Selectivity March 28, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01236D, PaperRuo-Tong Gang, Wen-Jing Zhang, Hai-Jun Yu, Zhen-Hui Li, Yi-Long Li, Xue-Wu Wu, Mingguang Chen, Shu-Man Gao, Feng ShaoTwo zinc (II)-based coordination polymers namely, {[Zn2L2(bmib)]·DMA}n (1) and {[ZnL(bipd)]}n (2). (H2L= 5-{(anthracen-9-ylmethyl)amino}isophthalic acid, bmib= 1,4-bis(2-methyl-imidazol-1-yl)butane, bipd= 3,5-bi-1H-imidazol-1-ylpyridine, DMA= N,N-dimethylacetamide), were synthesized by hydrothermal method. Single-crystal X-ray diffraction analysis showed...The content of this […]Ruo-Tong Gang
- Crystallization-induced highly efficient phosphorescence in metal-free organic phosphors March 27, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01323A, PaperHui Xiao, Huili Ma, Jingyi Wang, Zhongfu An, Zhiyong GuoRoom-temperature phosphorescence (RTP) emissions of metal-free organic materials have garnered considerable research attention from the fields of organic electronics and bioelectronics. However, achieving ultralong phosphorescence lifetimes and high quantum efficiencies...The content of this RSS Feed (c) The Royal Society of ChemistryHui Xiao
- The growth of Cs3Cu2Br5 and CsCu2Br3 single crystals by cooling crystallization for scintillator application March 26, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00109A, PaperBenlan Zeng, Yongning Liu, Sirui Bao, Chencai Wang, Run Xu, Jinkun Liu, Yan ZhuCopper halide perovskite materials have been studied extensively for use in radiation detection in recent years because of their excellent properties. However, there are few researches on copper bromide perovskite...The content of this RSS Feed (c) The […]Benlan Zeng
- Different Thermal and Solubility Properties with Identical Crystal Structure - Case of Lenalidomide Hydrate March 26, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE00798K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qi Zhang, Yitong Zhu, Yisheng Xu, Huaiyu Yang, Wei Li, Xiangyang ZhangIdentification of polymorphism of medicine is critical for pharmaceutical properties. The different thermal properties and solubilities indicate different polymorphs. However, in the case of […]Qi Zhang
- Calculating and analyzing the relationship between thermal conductivity and microstructure in rare-earth doped fluoride crystals March 26, 2025CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D4CE01308E, PaperKexin Liu, Dapeng Jiang, Gang Bian, Liangbi SuThe calculation of phonon scattering coefficients is used to study the influence of different structures on glass-like thermal conductivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]Kexin Liu
- Growth and Characterization of 2-inch (-102) Plane β-Ga2O3 Crystal by Edge-defined Film-fed Grown Method March 25, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01282H, PaperJin Zhang, Boyang Chen, Zhucheng Li, Yiyuan Liu, Yue Dong, Bowen Yu, Zhitai Jia, Xutang Tao, Wenxiang Muβ-Ga2O3, with its exceptional performance, is highly favored in the application of vertical structure devices. However, its low symmetry and anisotropy present a series of challenges in the wet etching...The content of this […]Jin Zhang
- Synthesis of dual state emissive twisted donor-acceptor fluorophores: tunable fluorescence and self-reversible mechanofluorochromism March 25, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01317D, PaperSasikala Ravi, R Rameshbabu Priyadharsan, Subramanian Karthikeyan, Mehboobali Pannippara, Abdullah G. Al-Sehemi, Dohyun Moon, Savarimuthu Philip AnthonyExploring new organic solid-state fluorescent molecules with tunable and switchable fluorescence are of fundamental importance for understanding structure-property relationship and developing efficient materials for device applications. Herein, we have designed...The content of this RSS […]Sasikala Ravi
- Synergistic Crucible Design and Thermal-Flow Management for Enhanced 4-Inch AlN Single Crystal PVT Growth: A Combined Numerical and Experimental Investigation March 25, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00214A, PaperWenliang Li, QianLing Liu, Jun Tan, Guangze He, Yingmin Wang, Zhenhua Sun, Baikui Li, Honglei WuHigh-quality, large-diameter aluminum nitride (AlN) single crystals are essential for advanced electronic and optoelectronic applications. However, their physical vapor transport (PVT) growth remains challenging due to complex thermal-flow dynamics and...The content of this RSS Feed […]Wenliang Li
- A new silver-thiolate nanocluster synthesized utilizing pure-inorganic polyoxoniobate as a starting template and its variable-temperature fluorescence property March 25, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00195A, PaperLi Zeng, Ya-Ting Lin, Li-Hao Hong, Yan-Qiong Sun, Jianping Xie, Shou-Tian Zheng, Xin-Xiong LiIn the past, the synthesis of polyoxometalates (POMs)-templated silver nanoclusters typically relied on the use of organic salts of POMs as starting templates, thereby limiting the solvent selectivity in the...The content of this RSS Feed (c) The […]Li Zeng
- A study of the effect regularity of caprolactam on the crystallisation of ammonium sulphate in aqueous solution March 25, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01288G, Paperzhang meiqi, Xiang Sun, Xiaoyu Ma, Xunqiu WangThe crystal size of ammonium sulphate, a by-product of caprolactam production, is generally less than 1 mm. In order to increase the crystal size, a detailed study of the crystallisation...The content of this RSS Feed (c) The Royal Society of Chemistryzhang meiqi
- Preparation, Characterization, and Evaluation of the Co-amorphous System of Dasatinib to Improve its Pharmaceutical Attributes March 25, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00064E, PaperRahul B Chavan, Shovik Ray, Pritam Kundu, Sai Adiseshu Dupakuntla, Sanjeev Giri, Ponnusankar Sivasankaran, Gowthamarajan Kuppusamy, Sheetal Kumar Jain, Ranadeep BokalialSynthesizing co-amorphous system is one of the most promising approaches to enhance the solubility, and dissolution rate of pharmaceuticals and improve their oral bioavailability. Here, we screen eleven co-formers to...The […]Rahul B Chavan
- A flexible molecular organic crystal with π–π bonding for the highly selective recognition of hydrogen isotopes March 21, 2025CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D5CE00221D, PaperMin Lei, Lisha Jiang, Chunhui Wang, Jianxin Song, Wei Liu, Jie QiuASP-101, a fluorescent molecular organic crystal formed via π–π stacking, hydrogen bonding, and van der Waals forces, can detect trace H2O in D2O through solvent-exchange-induced fluorescence changes.To cite this article before page numbers are assigned, use the DOI form […]Min Lei
- Structures and band gaps of lead-free dabconium-containing hybrid alkali-metal halide perovskites March 21, 2025CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D4CE00907J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hendrik J. van der Poll, Rudolph Erasmus, Melanie RademeyerOne- or three-dimensional structures may be formed for dabconium-containing hybrid alkali-metal halide perovskites, depending on the sum of radii of the metal and halide ions, with the […]Hendrik J. van der Poll
- Fabrication of an efficient bifunctional acid catalyst based on MIL-88B(Fe) for solvent-free ring-opening of epoxides with alcohols March 21, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01072H, PaperMahdiyeh-Sadat Hosseini, Alireza Abbasi, Peyman Ghorbani, Majid Masteri-FarahaniA new bifunctional heterogeneous acid catalyst with both Lewis and Brønsted acid sites was successfully synthesized via the post-synthetic modification (PSM) method. To this end, a stable metal-organic framework (MOF),...The content of this RSS Feed (c) The Royal Society of ChemistryMahdiyeh-Sadat Hosseini
- Bright electrospun white Y2Zr2O7: Tm3+/Dy3+ nanotubes with excellent thermal quenching resistance and ultralow color shift March 21, 2025CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00133A, PaperShanshan Cong, Hongquan Yu, Zhichao Ren, Jiashi sun, Xiangping Li, Sai Xu, Baojiu ChenWhite LEDs are environmentally friendly light sources that have received extensive attention. The combination of an ultraviolet chip and three-color phosphors is the main method used to obtain white LED...The content of this RSS Feed (c) The […]Shanshan Cong
- What drives porosity in aluminosilicate zeolites? March 20, 2025CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D5CE00034C, Highlight Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dries Vandenabeele, Anjul Rais, Christine Kirschhock, Eric BreynaertPhase selection, and thus porosity, in aluminiumsilicate zeolites is driven by competition between water and framework elements to coordinate with extra-framework cations.To cite this article before page numbers […]Dries Vandenabeele
- Structural Variety in Calcium Metal-Organic Frameworks with a Tetratopic Carboxylate Ligand March 30, 2025
