CrystEngComm

RSC – CrystEngComm latest articles

• Synthesis, Characterization, and Green to Orange Luminescence Properties of Copper(I) Complexes with 3-bdppmapy Ligand-Containing Phenanthroline and Its Derivatives February 20, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01324G, PaperQiong-Hua Jin, Wen-Long Mou, Sijie Fan, Wang Ying-Long, Guo Wang, Fu-Zhen Hu, Guo Gui-Xiong, Zhong-feng Li, Hong-Liang Han, Xiu-Lan Xin, Jian-Ming Liu, Yuping YangThis paper presents the successful synthesis of eight Cu(I) complexes 1-8, [Cu(phen)(3-bdppmapy)]BF4·CH3OH (1), [Cu(phen)(3-bdppmapy)]ClO4·CH3OH (2), [Cu(phen)(3 bdppmapy)]I (- 3), [Cu(phen)(3-bdppmapy)]CF3SO3(4), [Cu(2,3-f)(3-bdppmapy)]BF4·CH3OH (5), [Cu(2,3-f)(3-bdppmapy)]ClO4·CH3OH (6), [Cu(2,3-f)(3-bdppmapy)]I·2CH3OH (7), [Cu(2,3-f)(3-bdppmapy)]CF3SO3·CH3OH […]
  Qiong-Hua Jin
• Polytypism phenomenon in GaN nanocrystals grown on van der Waals surface February 20, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01154F, PaperYan Maidebura, Vladimir Mansurov, Timur Malin, Ivan Aleksandrov, Konstantin Zhuravlev, Béla PéczThe polytypism phenomenon in the growth of nanostructures reveals new properties and opportunities for bandgap engineering by enabling controlled formation of different phases of the same material with distinct crystalline...The content of this RSS Feed (c) The Royal Society […]
  Yan Maidebura
• UiO66-NH2@In2O3 heterostructures for improved photocatalytic CO2 reduction February 20, 2025
  CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D5CE00106D, PaperBolin Ma, Guanghui Chen, Lingling Zhou, Chengyang Ni, Xinyu Sun, Lei Zhang, Xinguo Xi, Lanqin Tang, Yong ZhouUiO66-NH2@In2O3 heterojunctions exhibit enhanced photocatalytic CO2 reduction, leveraging efficient charge separation and visible-light harvesting for sustainable catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content […]
  Bolin Ma
• Tb-TATAB crytalline organic framework material based on triazine tricarboxylic acid ligand: photophysical properties and fluorescence sensing application February 19, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01294A, PaperYuan Liu, Jinlong Li, Na Zhang, Yue Zhao, Qing-Lin Guan, Yongheng Xing, Fengying BaiA Tb-MOF complex based on triazine tricarboxylic acid ligands (2, 4, 6-tri (4-carboxylaniline)-1, 3, 5-triazine (H3TATAB) was constructed by the reaction of rare earth metal Tb(Ⅲ) and H3TATAB. The complex...The content of this RSS Feed (c) The […]
  Yuan Liu
• Microinjection assistant synthesis of Pt-Pd hollow nanoparticles for enhanced methanol oxidation reaction February 19, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00080G, PaperDan Zhao, Pan Zeng, Xinyu Wang, Fuquan Wang, Huiting Wu, Yujia Zhai, Dandan Men, Yiqiang Sun, Wenshan Qu, Haijian LiA large-scale synthesis for electrocatalysts with controllable composition and surface atomic structure is crucial for practical application. Herein, Pt-Pd hollow nanoparticles (HNs) were prepared by a facile microinjection strategy. Due...The content […]
  Dan Zhao
• Triazole-derivatived ligands-directed diverse structures and polyaniline-assisted capacitive performances of two new Anderson-type [AlMo6(OH)6O18]3--based metal-organic complexes February 19, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00049A, PaperZhi-fei Zu, Juju Liang, Zhihan Chang, Yuchun Lin, Xiuli WangTwo new polyoxometalate-based metal-organic complexes (POMOCs), namely, H{Zn2(Hpytty)2[AlMo6(OH)6O18](H2O)8}⸱6H2O (1), H{Zn2(Hpyttz)2[AlMo6(OH)6O18](H2O)8}⸱6H2O (2) , (H2pytty = 3-(pyrazin-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl, H2pyttz = 3-(pyrid-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl), were obtained under hydrothermal condition using different N-rich triazole-derivatived ligands and their...The content of this RSS Feed (c) The Royal Society of Chemistry
  Zhi-fei Zu
• Ionization treatment of pyrazolo[4,3-c]pyrazole derivatives to achieve the low sensitivity of high-energy materials February 19, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01286K, PaperLei Shi, Bangxiang Liu, Pengfei Wang, Bingcheng Hu, Chengguo Sun, yang du, Chao Gao, chong zhangLow mechanical sensitivity is an evaluation index for the development of safe and stable high-energy materials. Herein, 3,6-Dinitropyrazolo[4,3-c]pyrazole (DNPP) and its ionic salts 1-4 with a fused-ring backbone were synthesized...The content of this RSS Feed […]
  Lei Shi
• Visualization of level-3 latent fingerprints by surfactant-free CsPbBr3 MCs with Pb(OH)2 as a passivation layer and an anchored bridge February 19, 2025
  CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D4CE01004C, PaperGuoxin Zhuang, Yujing Li, Xiaodi Chu, Xianghui Lai, Zhiyu Liang, Xiaohui Lin, Yonglin Wen, Guosong Lin, Zhechong Zheng, Chonghui LiWe report surfactant-free, core–shell structured CsPbBr3 MCs featuring a Pb(OH)2 layer on their surface, which replaces the organic passivation layer and facilitates amino acid binding via hydrogen bonds for high-quality PL […]
  Guoxin Zhuang
• On the pK of crystal surfaces: molecular modeling of crystallite protonation, local reorganization, and solute dissociation February 19, 2025
  CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D4CE01292E, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Patrick Duchstein, Moritz Macht, Dirk ZahnWe demonstrate the application of the ‘instantaneous pK’ approach to the molecular dynamics simulation of crystallite models exposed to an acidic solvent environment.To cite this article before page numbers are […]
  Patrick Duchstein
• Mononuclear complexes of dysprosium(III) with 2,6-diacetylpyridine bis(isonicotinoylhydrazone): synthesis, crystal structure, magnetic properties† February 19, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00066A, PaperVyacheslav Kopotkov, Leokadiya Zorina, Sergey Vladimirovich Simonov, Denis V. Korchagin, Michael V. Zhidkov, Alexey I Dmitriev, Ghodrat Mahmoudi, Eduard YagubskiiFour discrete mononuclear Dy(III) coordination compounds with the pentadentate N3O2 equatorial ligand 2,6-diacetylpyridine-bis(isonicotinoylhydrazone) (H2dapin) in different charge states, containing the strong-field ligands Ph3PO and Cy3PO at the apical positions have...The content […]
  Vyacheslav Kopotkov
• Enhanced Luminescence in 1D Corrugated Lead Bromides via Reduced Flexibility of Trivalent Cations February 19, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00003C, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chang-Chun Fan, Zi-Han Fang, Shulin Jiao, Jing-Xue Yu, Cheng-Dong Liu, Wei Wang, Ming-Liang Jin, Bei-Dou Liang, Xiang-Bin HanHybrid metal halides (HMPs) have attracted considerable attention from researchers exploring broad-band luminescence materials due to their low […]
  Chang-Chun Fan
• A photoluminescent second-order nonlinear optical molecular crystal with cold crystallization February 18, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01322K, CommunicationXin Shen, Jun-Chao Qi, Hang Peng, Zhang-Tian Xia, Yong-Ju Bai, Hui-Ping Chen, Zhen-Yu Wang, Tian-En Yang, Yan Qin, Wei-Qiang LiaoCold crystallization occurs commonly in polymers but is rarely found in small molecular crystals. Here, we report the first photoluminescent second-order nonlinear optical molecular crystal with cold crystallization, which shows...The content […]
  Xin Shen
• Understanding the stability of amorphous form of darifenacin February 18, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01257G, PaperPrzemysław Nowak, Anna Pietrzak, Marta K DudekDarifenacin (DAR) is a benzofuran derivative used in the treatment of an overactive bladder. In a neat solid phase it shows a propensity to exist in an amorphous form (DAR-A),...The content of this RSS Feed (c) The Royal Society of Chemistry
  Przemysław Nowak
• Covalent Organic-Inorganic Layered 2D CdCl2(n-hexylamine)2 and Not Cd2S2(n-hexylamine) February 18, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00011D, PaperPavithra Parthiban, Urmila Makhija, Rachit Pratham, Diptikanta Swain, Angshuman NagThe organic ammonium cations (A+) and the inorganic [PbX4]2- (X: Cl, Br, I) anions bind to each other through electrostatic interactions forming the layered two-dimensional (2D) A2PbX4 hybrid perovskites. So,...The content of this RSS Feed (c) The Royal Society of Chemistry
  Pavithra Parthiban
• Second-harmonic generation in OP-GaAs0.75P0.25 heteroepitaxially grown from the vapor phase February 18, 2025
  CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D4CE01304B, CommunicationLi Wang, Shivashankar R. Vangala, Stefan Popien, Marcus Beutler, J. Matthew Mann, Vladimir L. Tassev, Edlef Büttner, Valentin PetrovTop view of an orientation-patterned GaAs0.75P0.25 sample with a domain width of 62 μm used for second-harmonic generation at 5500 nm, containing only about four quasi-phase matching periods.To cite this article before […]
  Li Wang
• Synergistic Effect of Built-in and Polarized Electric Fields in BiFeO3/BiOI Heterojunctions for Efficient Photocatalysis February 17, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D5CE00041F, PaperJiangwen Bai, Jiamin Li, Jinmeng Xiang, Chongfeng GuoThe built-in electric field (IEF) between two components of heterojunction has been proven to be capable of efficiently separating photogenerated carriers in photocatalysis. However, the rapid charge accumulation near the...The content of this RSS Feed (c) The Royal Society of Chemistry
  Jiangwen Bai
• Hydrogen bonding of H2O2 molecules in crystal structures of alkali metal and tetraethylammonium nitrate peroxosolvates February 17, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01109K, PaperAlexander G. Medvedev, Elena Mel'nik, Alexey A. Mikhaylov, Mayorov S. Nikita, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V Prikhodchenko, Andrei V. ChurakovPeroxosolvates of nitrates remain a poorly studied class of compounds among the crystalline adducts of hydrogen peroxide and salts of inorganic acids. Herein, we report the synthesis, crystal structures, […]
  Alexander G. Medvedev
• Cd(II) complexes of 9-anthracenyl-4′-benzoate and 4-pyridyl vinyl arenes: effect of steric hindrance on the solid-state photoreactivity February 17, 2025
  CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D4CE01221F, PaperK. Mohamed Yusuf Baig, Goutam Kumar KoleThe effect of steric hindrance on the crystal packing and solid-state photoreactivity of four Cd(II) complexes of 9-anthracenyl-4′-benzoate and 4-pyridyl-vinyl-arene ligands have been demonstrated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed […]
  K. Mohamed Yusuf Baig
• Pharmaceutical Salts of Venetoclax with Dicarboxylic and Sulfonic Acids: Solid-state Characterization and Dissolution Performance February 15, 2025
  CrystEngComm, 2025, Accepted ManuscriptDOI: 10.1039/D4CE01121J, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tereza Havlůjová, Erika Hriňová, Eliška Zmeškalová, Monika Kučeráková, Ludek Ridvan, Miroslav SoosThis study focuses on enhancing the aqueous dissolution of venetoclax through salt formation. Venetoclax, a BCS Class IV B-cell lymphoma-2-selective inhibitor, exhibits very low […]
  Tereza Havlůjová
• Synthesis, crystal growth and phase formation in the K–(Yb,Tm,Ho)–Mo–O system February 13, 2025
  CrystEngComm, 2025, Advance ArticleDOI: 10.1039/D5CE00021A, PaperVictor V. Maltsev, Elena A. Volkova, Elizaveta V. Koporulina, Nikolai N. Kuzmin, Anna I. Jiliaeva, Galina V. Kiriukhina, Daniil A. NaprasnikovIn this paper, we discuss the phase formation, solid-state synthesis and growth of K(Yb,Tm,Ho)(MoO4)2 and (Yb,Tm,Ho)2Mo3O12 crystals from high-temperature melts in the K–(Yb,Tm,Ho)–Mo–O system.To cite this article before page numbers […]
  Victor V. Maltsev