RSC – CrystEngComm latest articles- Chiral-Driven Formation of Hybrid Cyanurates with Large Birefringence November 20, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01123F, PaperYue Zhao, Chun-Li Hu, Peng-Fei Chen, Ming-Zhi Zhang, Jiang-Gao MaoUltraviolet (UV) birefringent crystals have important applications in polarizers, optical isolators and optical information processing. Crystals with large birefringence can enhance the modulation ability of light and realize the miniaturization...The content of this RSS Feed (c) The Royal Society of ChemistryYue Zhao
- Structure features of a supramolecular organic framework self-assembled from a chiral natural compound November 20, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01008F, CommunicationKenika Khotchasanthong, Yupa Pootaeng-On, Kanok-on Rayanil, Mongkol Sukwattanasinitt, Sakchai Laksee, Kittipong ChainokWe present an intriguing instance of a supramolecular-organic framework (SOF) self-assembling from a chiral naturally occurring lanostane compound extracted from the Thai plant Miliusa Sessilis. Intermolecular hydrogen bonding and van...The content of this RSS Feed (c) The Royal Society […]Kenika Khotchasanthong
- Thiadiazole-based 3D Covalent Organic Framework for Efficient Anhydrous Proton Conduction November 20, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00995A, PaperYaoyao Pan, Zhen Shan, Ziya Liu, Jian Su, Gen ZhangThe design and synthesis of three-dimensional (3D) covalent organic frameworks (COFs) with exceptional stability and high proton conductivity are critical for advancing high-temperature fuel cells but remain significant challenges. In...The content of this RSS Feed (c) The Royal Society of ChemistryYaoyao Pan
- Boosted oxygen vacancy in ZnO-Co3O4 composite by copper doping for Bisphenol A abatement by persulfate November 20, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00971A, PaperLei Bai, Hui Yan , Jiao Wang, Qihang Wu, Guiling Wang, Yi Huang, Bentian ZhangThough the surface leaching and ion exchange, nest-like Cu-Co3O4 and Cu-ZnO-Co3O4 composites were obtained from the solid ZIF-67 and hollow ZIF-8-ZIF-67, respectively. The investigation suggested that the ratio of the...The content of this RSS Feed (c) […]Lei Bai
- Controlling the architecture of Au/Pt core–shell nanocubes via platinum growth mode November 20, 2024CrystEngComm, 2024, Advance ArticleDOI: 10.1039/D4CE00823E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Imke Maack, Kevin Oldenburg, Katharina Al-ShameryThe nanocrystal surface architectures of cubic bimetallic plasmonic gold antenna-platinum reactor systems for photocatalysis can be controlled via the choice of the reduction agent in nanoparticle synthesis under otherwise identical […]Imke Maack
- Versatile copper(II) discrete and polymeric coordination compounds with (pyridine-2-yl)methylenenicotinohydrazide and azelaic acid November 19, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01021C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Monica Benito, Ghodrat Mahmoudi, Elies Molins, Ennio Zangrando, Masoumeh Servati Gargari, Rosa Maria Gomila, Antonio Frontera, Damir SafinIn this contribution, a series of copper(II) discrete and polymeric coordination compounds, namely [Cu3L2(aze)2]n∙nH2O (1∙nH2O), [CuL2]∙H2O (2∙H2O) and […]Monica Benito
- Syntheses and properties of pH-directed two types of cobalt-lanthanoid heterometallic complexes constructed from 2,5-dichlorobenzoate and 1,10-phenanthroline November 19, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00886C, PaperYue Shen, Jiuzeng Jin, Zhen-Yu Yang, Jie Zhao, Binqiu Liu, Ju-Wen ZhangBy adjusting the pH values, two types of heterometallic complexes originated from the same raw materials but with different structures and colors have been successfully designed and constructed. Eleven 3d-4f...The content of this RSS Feed (c) The Royal Society […]Yue Shen
- On the nature and interplay of Hg···O/S spodium-bonding and O···S chalcogen-bonding in one-dimensional phenylmercury(II) 3-alkoxycyclobutene-1,2-dione-4-thiolate coordination polymers November 19, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00879K, PaperAparna Kushwaha, Devyani Srivastava, Gabriele Kociok-Köhn, Sarfaraz Ahmed, Edward R. T. Tiekink, Abhinav KumarTwo one-dimensional coordination polymers, PhHg(3-alkoxycyclobutene-1,2-dione-4-thiolate), for alkoxy = OMe and OEt, have been synthesised, characterised spectroscopically, crystallographically and through computational chemistry techniques. Both species exhibit intermolecular Hg···O σ-hole spodium-bonding as...The content of this RSS Feed (c) The […]Aparna Kushwaha
- Complexes of N-Chloroquinuclidinium with Chloride: Strong Halogen Bonding via Chlorine Atoms November 19, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01053A, CommunicationMaison Hardin, Matthias Zeller, Sergiy RosokhaCrystallization of N-chlorosaccharin with quinuclidine (QN) produced QN-Cl+ cations showing a covalent bond between chlorine and a tertiary nitrogen atom. Strong (supramolecular) halogen bonds between the QN-Cl+ and Cl- anions...The content of this RSS Feed (c) The Royal Society of ChemistryMaison Hardin
- Correction: Improving the grindability of rice husk-based green silica through pyrolysis process optimization employing the Taguchi method and response surface methodology November 19, 2024CrystEngComm, 2024, Advance ArticleDOI: 10.1039/D4CE90125H, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shengwang Yuan, Zichao Ma, Yihao Hou, Shichao Niu, Li Lekai, Xuanting Liu, Shuo Wang, Zihe Xu, Yunhai MaTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Shengwang Yuan
- Structural landscape studies of aminopyridinium hypodiphosphates: dehydration and polymorphism in 4‑aminopyridinium salts November 19, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01048E, PaperDaria Budzikur-Maciąg, Vasyl Kinzhybalo, Katarzyna ŚlepokuraA series of 4-aminopyridinium (4ap) hypodiphosphates has been synthesized and characterized by variable temperature (VT) optical microscopy, thermogravimetry (TGA-DSC) and X-ray diffraction techniques (SC-XRD, PXRD, VT µ-PXRD). Anhydrous salts (4apH)(H3P2O6)...The content of this RSS Feed (c) The Royal Society of ChemistryDaria Budzikur-Maciąg
- Direct fluorine- and sulfur-targeted postsynthetic modification in a porous organic polymer-based ammonia adsorbent November 18, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01025F, CommunicationEunjin Jo, Yeonwoo Park, Suin Jo, Jongsik Park, Seyoung Koo, Dong Won KangPostsynthetic modification of porous organic polymers (POPs) facilitates their use to remove toxic gases, such as NH3. This study conducted a fluorine- and sulfur-targeted postsynthetic modification of POPs to enhance...The content of this RSS Feed (c) The Royal […]Eunjin Jo
- 3,5-Dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine as insensitive and thermostable energetic melt-castable materials November 18, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01036A, CommunicationDangyue Yin, Boqian Yang, Hongyu Lv, Siwei Song, Yi Wang, Qinghua ZhangA trifluoropropyl functionalized energetic compound, viz. 3,5-dinitro-1-(3,3,3-trifluoropropyl)-1H-pyrazol-4-amine (TFDNPA) was designed and synthesized, which exhibited the potential TNT replacement as an energetic melt-castable carrier in aluminized explosives formulation due to excellent...The content of this RSS Feed (c) The Royal Society […]Dangyue Yin
- Template-directed crystallization of carbamazepine form II from palmitic acid melt – a key to understand mechanically-induced polymorphism of carbamazepine November 15, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00906A, PaperEvgeniy A. Losev, Daria Zheltikova, Valeri A. Drebushchak, Elena BoldyrevaHeating a single crystal of carbamazepine (III) (the thermodynamically stable form) in contact with solid palmitic acid resulted in melting of palmitic acid and the growth of the crystals of...The content of this RSS Feed (c) The Royal Society of ChemistryEvgeniy A. Losev
- A family of luminescent heterometallic coordination polymers based on lanthanide(III) ions and 6-methyl-2-oxonicotinate: near-infrared/visible emitters and colour fine-tuning November 15, 2024CrystEngComm, 2024, Advance ArticleDOI: 10.1039/D4CE00881B, PaperLaura Razquin-Bobillo, Jose Angel García, Ricardo Hernández, Antonio Rodríguez-Diéguez, Javier CepedaA family of Ln-based water-soluble coordination polymers with a 6-methyl-2-oxonicotinate ligand presents good photoluminescence properties in both media. A compound containing three mixed metal ions emits white light with a high quantum yield.To cite this article before page numbers are […]Laura Razquin-Bobillo
- Flexible hybrid capacitors based on NiMoS@NiCo-LDH composites at variable work conditions November 15, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00760C, PaperQi He, Wei Jia, Xiang Wu, Jinghai LiuIt is well known that the morphology and structure of electrode materials seriously affect the whole performance of the devices. Thereinto, transition metal sulfides are desirable cathode materials for supercapacitor...The content of this RSS Feed (c) The Royal Society of ChemistryQi He
- Ni-MoO2 heterostructure Encapsulated in mesoporous Silica microtubes: A Structured Hydrogenation Catalyst with Enhanced Activity for Reduction of 4-nitrophenol November 14, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01044B, PaperYiran Sun, Mintong Guo, Suping Han, Jingli Xu, Xue-Bo Yin, Min ZhangMetallic Ni catalysts often suffer from serious aggregation and poor stability during the process of catalysis. In this work, core−shell nanostructures with nanosized MoO2-Ni nanoparticles (NPs) and mesoporous SiO2(mSiO2) shells...The content of this RSS Feed (c) The Royal Society […]Yiran Sun
- Intermolecular non-covalent interactions in the organic perrhenates crystal structures: from theory to practice November 13, 2024CrystEngComm, 2024, Advance ArticleDOI: 10.1039/D4CE00951G, PaperAnton P. Novikov, Anastasiia V. Sitanskaia, Mikhail A. Volkov, Iurii M. Nevolin, Mikhail S. GrigorievThis manuscript reports the X-ray, MALDI and TG characterization of perrhenates. A dependence of the presence of Re–O⋯Re interactions and phase transitions in the crystal is assumed.To cite this article before page numbers are assigned, use […]Anton P. Novikov
- Intrinsically chiral paddlewheel diruthenium complexes November 13, 2024CrystEngComm, 2024, Advance ArticleDOI: 10.1039/D4CE01040J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Isabel Coloma, Santiago Herrero, Miguel CortijoThis work presents an axially chiral platform based on ruthenium units, evaluates the crystal structures, configurational stability and electronic structure tunability, and proposes a general nomenclature system for binuclear paddlewheel […]Isabel Coloma
- Bio-templated synthesis of hierarchical polypyrrole-coated VS4 for supercapacitors November 12, 2024CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE01010H, PaperYao Ding, Zhong Yi Shi, Kailin Li, Jinsong Rao, Xiaobin Gong, Shupei Liu, Bo Yang, Yuxin ZhangVanadium tetrasulfide (VS4) is increasingly acknowledged as a potential electrode material for supercapacitors, attributed to its unique one-dimensional structural characteristics and elevated sulfur content. However, its intrinsic low conductivity and...The content of this RSS […]Yao Ding
- Chiral-Driven Formation of Hybrid Cyanurates with Large Birefringence November 20, 2024
