RSC – Green Chem. latest articles
- Alternative materials for interfacial polymerization: recent approaches for greener membranes April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00466C, Critical ReviewAdi Ben-Zvi, Usman Taqui, Guy Ramon, Suzana P. NunesThin-film selective layers fabricated via interfacial polymerization (IP) form the core of membrane-based water purification and desalination, as well as other molecular separations. The monomers and organic solvents used in...The content of this RSS Feed (c) The Royal Society of […]Adi Ben-Zvi
- A heuristic process prediction model for screening the optimal green entrainer with TAC and LCA impacts based on PSE concepts April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00129J, PaperQinggang Xu, Yangyang Wang, Kexin Yin, Hongwei Xu, Peizhe Cui, Jianguang Qi, Yinglong Wang, Zhaoyou Zhu, Limei Zhong, Yixin MaThe key to extractive distillation separation lies in screening a suitable entrainer. Based on the chemical process system engineering (PSE) concepts, the novel heuristic process prediction model proposed with minimized...The […]Qinggang Xu
- From Quarry to Carbon Sink: Process-based LCA Modelling of Lime-based Construction Materials for Net-Zero and Carbon-Negative Transformation April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D3GC04599D, PaperAgustin Laveglia, Neven Ukrainczyk, Nele De Belie, Eddie A KoendersA comprehensive decarbonization approach is reported, involving Direct Separation Reactors (DSR) and eco-efficient energy sources in the production of hydrated lime. Environmental and economic impacts are calculated through an in-depth...The content of this RSS Feed (c) The Royal Society of […]Agustin Laveglia
- Ethanol-assisted mechanochemical asymmetric cross-dehydrogenative coupling reaction with recoverable chiral amine/NaCl for accessing chiral α-alkyl α-glycine derivatives April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00947A, PaperJingbo Yu, Hong Chen, Ziwen Zhang, Yuxin Fang, Tao Ying, Weike SuChiral α-alkyl α-glycine acids are a prevalent structural motif found in pharmaceuticals and natural products, making them a significant dimension for exploration in modern pharmaceutical and medicinal chemistry. However, the...The content of this RSS Feed (c) The Royal […]Jingbo Yu
- Fuel from Waste: Electrosynthesizing Ammonia Directly from Agricultural Digestate through Ligand Isomerization April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00740A, PaperRahul Mahadeo Mendhe, Ritwik Mondal, Alagar Raja, Akshay Haridas, Harish M. N. K., Vinod Prabhakaran, Ravikumar Thimmappa, Musthafa Ottakam ThotiylWe demonstrate that the catalytic metal centre for ammonia production can be selectively activated with only a slight alteration in ligand isomerization (α and β isomers), making it practical and...The […]Rahul Mahadeo Mendhe
- Biodegradable, Crosslinked Silicone-Gelatin Hydrogels April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00402G, PaperAna Pricu, Michael A. Brook, Kaitlyn E. C. Silverthorne, Erin Donahue-Boyle, Angela Yayun LiElastomers, including thermoset silicone rubbers, are known for exceptional stability, which compromises their circularity; these materials are not expected to undergo facile degradation in the environment. Crosslinkers based on the...The content of this RSS Feed (c) […]Ana Pricu
- Green and sustainable in situ water treatment: a review of noble-free catalysts for electrochemical oxygen reduction to hydrogen peroxide April 22, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00387J, Critical ReviewJiahao Liu, Cheng Li, Zhaorui Zhang, Jiacheng Wang, Minghui YangWater treatment is an essential process for ensuring access to clean and safe drinking water. Activation of hydrogen peroxide (H2O2) to ·OH is considered to be one of the most...The content of this RSS Feed (c) The Royal Society […]Jiahao Liu
- Long-lived triplet state carbon nitride (urea-CNx) catalyzed metal-free photo-ATRP with oxygen acceleration April 21, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC01025F, PaperChen Wang, Bo Hu, Xiaoyu Guo, Lin LeiIn this study, a long-lived triplet state urea-functionalized carbon nitride (urea-CNx) was successfully synthesized. It possesses a significant specific surface area, an extended excited state lifetime, and a wide band...The content of this RSS Feed (c) The Royal Society of ChemistryChen Wang
- Efficient Electrochemical CO2 Reduction in Acidic Electrolyte Using Armor-Like Iron Nanoparticles/Porous Nitrogen-Doped Carbon April 21, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00060A, CommunicationWenli Hao, Li Peng, Rongxing Qiu, Tianwei Xue, Ruiqing Li, Qing-Na Zheng, Jia Yu, Tongxin Qiao, Linxiao Cui, Yuzhong Su, Yanzhen Hong, Hongtao Wang, Shuliang Yang, Jun LiElectrochemical reduction of CO2 presents a persistent challenge in achieving high selectivity and stability, particularly in acidic electrolytes. Here, we successfully engineer […]Wenli Hao
- Chemoenzymatic synthesis of amino-esters as precursors of ammonium salt-based surfactants from 5-hydroxymethylfurfural (HMF) April 21, 2024Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC00425F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Carlos Moriana Herraiz, Karen S. Arias, Maria J. Climent, Sara Iborra, Avelino CormaPrecursors of ammonium salt biosurfactants have been obtained from HMF by coupling cobalt-catalyzed reductive amination with selective bio-esterification using an immobilized lipase […]Carlos Moriana Herraiz
- Solvent-free copper-catalyzed trisilylation of alkynes: a practical and atom-economical approach for accessing 1,1,1-trisilylalkanes April 18, 2024Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC00220B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jia Li, Shaozhong GeCopper-catalyzed 1,1,1-trisilylation of alkynes was developed with Cu(OAc)2 and PnBu3. Mechanistic studies reveal that this reaction occurs through sequential dehydrogenative silylation of alkynes and dihydrosilylation of alkynylsilane intermediates.To cite this article […]Jia Li
- Electric Field-Inducing Phosphorization to CoP@Biochar Composites for Efficient Bifunctional Oxygen Electrocatalysis† April 18, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00551A, PaperXianli Wu, Ting Zhou, Teng Teng, Shuling Liu, Bangan Lu, Mehdi Sehrish, Yanyan Liu, Jianchun Jiang, Yongfeng Wang, Baojun LiThe large-scale use of Zinc-air batteries (ZABs) have been limited by the sluggish OER and ORR kinetics. The current synthesis of catalysts of the air electrodes requires harsh conditions. The...The […]Xianli Wu
- Facile Preparation of Lignocellulosic Xerogel by Alkali Freezing and Ambient Drying April 18, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00825A, PaperQiaoling Huang, Zerong Li, Jialong Hu, Wei Wang, Wei LiRecently, ambient drying method for the preparation of xerogel has attracted great attention due to its low cost and high drying efficiency. However, strong capillary force existing during ambient drying...The content of this RSS Feed (c) The Royal Society of […]Qiaoling Huang
- Light-promoted photocatalyst-free and redox-neutral hydrosulfonylation of unactivated alkenes using sulfinic acid April 18, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00440J, PaperYibo Song, Cheng Li, Xueyuan Hu, Hongdie Zhang, Yujian Mao, Xiachang Wang, Chen Wang, Lihong Hu, Jianming YanA hydrosulfonylation reaction of unactivated alkenes with sulfinic acids was realized under light irradiation. The reaction features photocatalyst- and additive-free conditions. A diverse set of unactivated alkenes can be transformed...The content of […]Yibo Song
- The selective oxidation of thioanisole to sulfoxide using a highly efficient electroenzymatic cascade system April 18, 2024Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC00674G, PaperXuefang Zhu, Xiyue Liu, Yu Ding, Shuni Li, Yucheng Jiang, Yu ChenConstruction of an electroenzymatic cascade catalytic system based on a CPO-ILEMB@NMCNs-PEI biohybrid for selective oxidation of thioanisole to methyl phenyl sulfoxide with high catalytic activity.To cite this article before page numbers are assigned, use the DOI form of […]Xuefang Zhu
- Electrochemically Driven Green Synthesis to Unlock Sustainable Routes to β-Keto Spirolactones April 17, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC01127A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ian MacLean, Montaña J García, Silvia Cabrera, Leyre Marzo, Jose AlemanIn this work we present a sustainable and environmentally bening electrochemical method for the synthesis of β-keto spirolactones. The reaction is carried out using […]Ian MacLean
- Ketoreductase-catalyzed dynamic reductive kinetic resolution of sterically hindered 2-aryl-1,5-benzothiazepin-3,4(2H,5H)-diones: asymmetric synthesis of a key diltiazem precursor and its analogues April 17, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC01478B, PaperZijun Guo, Zexin Wu, Xiaofan Wu, Li Zhang, Zedu Huang, Fener ChenOwing to its associated advantages such as generation of two stereocenters in 100% maximum theoretical yield, mild reaction conditions and environmentally friendliness, ketoreductase (KRED)-catalyzed dynamic reductive kinetic resolution (DYRKR) is...The content of this RSS Feed (c) The Royal […]Zijun Guo
- Green, efficient and controllable synthesis of high-quality MOF-74 with high gravity technology April 17, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC01350F, PaperXin-Ran Shi, Meng Qiao, Yan Wei, Ling-Xia Yun, Jie Xin Wang, Jian-Feng ChenMOF-74 or M2(dhtp) (M = metal ions, dhtp = 2,5-dihydroxyterephthalic acid) as a typical metal-organic framework (MOF), has garnered considerable interest due to their abundant unsaturated metal sites. However, environmental...The content of this RSS Feed (c) The […]Xin-Ran Shi
- Integrating climate policies in the sustainability analysis of green chemicals April 17, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4GC00392F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Abhinandan Nabera, Antonio Jose Martin, Robert Istrate, Javier Pérez-Ramírez, Gonzalo Guillén-GosálbezNew and enhanced processes will not be the only drivers toward a sustainable chemical industry. Implementing climate policies will impact all components of the […]Abhinandan Nabera
- Prospective Hazard and Toxicity Screening of Sodium-ion Battery Cathode Materials April 17, 2024Green Chem., 2024, Accepted ManuscriptDOI: 10.1039/D3GC05098J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Manuel J. Baumann, Jens Peters, Marcel Häringer, Marius Schmidt, Luca Schneider, Werner Bauer, Joachim R Binder, Marcel WeilSodium-ion batteries (SiB) are considered as a serious alternative to current Lithium-ion batteries (LiBs). However, SiB are […]Manuel J. Baumann
- Alternative materials for interfacial polymerization: recent approaches for greener membranes April 22, 2024