RSC – Faraday Discuss. latest articles- Spectro-electrochemistry of guaiacol oxidation: tracking intermediates in a membrane-separated cell with in situ attenuated total reflectance-infrared spectroscopy Tháng 10 27, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00069F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sibylle M. K. Schwartmann, Mariangela Biggiero, Sander Deelen, Bettina Baumgartner, Bert M. WeckhuysenMembrane-separated ATR-IR spectro-electrochemistry enables real-time tracking of guaiacol oxidation intermediates, revealing pathways and suppressing side reactions.To cite this article before page numbers […]Sibylle M. K. Schwartmann
- Spiers Memorial Lecture: Compostable plastics: promise and pitfalls Tháng 10 27, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00111K, PaperEric D. Rachita, Jinsol Yook, Annabelle Watts, Christopher J. Ellison, Marc A. HillmyerIn this perspective, we make the case for wider use of compostable plastics in food packaging, review labeling, infrastructure, and regulatory hurdles facing their adoption, and discuss the future of compostable-polymer research and development.To cite this article […]Eric D. Rachita
- Mechanically alloyed NiCuMnWX (X = Co, Fe, or Mo) high-entropy alloy electrocatalysts for alkaline water splitting Tháng 10 5, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00094G, PaperHossein Mahdavi, Armin Asghari Alamdari, Jonathan Quinson, Uğur Ünal, Hadi JahangiriThis study investigates the electrocatalytic performance of high-entropy alloy powders prepared with equimolar ratios of Ni, Cu, Mn, and W, with additional elements (Co, Fe, or Mo) introduced to optimize their activity for the HER and OER.To cite this […]Hossein Mahdavi
- Spiers Memorial Lecture: Multicomponent and high-entropy materials: an overview Tháng 9 8, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00110B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Brian CantorThis paper attempts to summarise some of the fundamental discoveries we have made about the geography of multicomponent phase space and the wide range of complex new materials that we have found within […]Brian Cantor
- Optical responses from high-entropy alloys: experimental results and perspectives Tháng 8 31, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00086F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexandre Nominé, Alexander I. Solomonov, Juš Polanšek, Maxime Vergès, Yann Battie, Stéphanie Bruyère, Jaafar Ghanbaja, Jean-François Pierson, Janez Zavašnik, Michael Feuerbacher, Uroš Cvelbar, Thierry Belmonte, Valentin MilichkoFrom elemental optical constants, we estimate HEA absorption […]Alexandre Nominé
- Optimising descriptors to correlate stability of C- or N-doped high-entropy alloys: a combined DFT and machine-learning regression study Tháng 8 26, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00107B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chih-Heng Lee, Jyh-Wei Lee, Hsin-Yi Tiffany ChenIn this study, we employed DFT calculations combined with MC simulations and an MLIP to identify the optimal combination of descriptors in linear regression models to predict the […]Chih-Heng Lee
- Tailoring Pd content for optimal stability in FeCoNiCu multielement alloy electrocatalysts for oxygen evolution reaction Tháng 8 13, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00084J, PaperBing Zhu, Qiqi Huang, Okkyun Seo, Yee Yan Tay, Jiayi Tang, Huayu Gu, Tong Li, Dongshuang WuWe investigate the effect of palladium incorporation on the electrochemical performance and structural durability of FeCoNiCu MEA nanoparticles.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Bing Zhu
- Elucidating the reversible exsolution–dissolution behaviour of high-entropy oxides in crystalline and amorphous phases Tháng 8 13, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00081E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qingju Wang, Hailing Yu, Kevin Siniard, Zhenzhen Yang, Sheng DaiSelf-healing high-entropy oxides enable reversible metallic phase exsolution and dissolution under redox conditions.To cite this article before page numbers are assigned, use the DOI form […]Qingju Wang
- Hot-drawing ionic liquid-spun lignin–poly(vinyl alcohol) fibres increases strength and polymer alignment Tháng 8 11, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00099H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Enny Tran, Joanne Pui Fai Ng, Lucie Diéval, Stéphan Rouzière, Pascale Launois, Milo S. P. Shaffer, Agnieszka Brandt-TalbotIn this study, alignment was induced in high lignin content fibres wet-spun from a low-cost ionic liquid […]Enny Tran
- Harnessing data and control with AI/ML-driven polymerization and copolymerization Tháng 8 11, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00066A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rigoberto Advincula, Ilia Ivanov, Rama Vasudevan, Rajeev Kumar, Panagiotis Christakopoulos, Marileta Tsakanika, Jihua Chen, Jan Michael Carillo, Qinyu Zhu, Bobby SumpterUnderstanding hierarchical approaches in optimizing the polymerization and copolymerization process via AI/ML to target […]Rigoberto Advincula
- High-throughput synthesis of multi-element alloy nanoparticles using solvothermal continuous-flow reactor Tháng 8 4, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00103J, PaperMegumi Mukoyoshi, Kohei Kusada, Xin Zhou, Takaaki Toriyama, Tomokazu Yamamoto, Yasukazu Murakami, Hiroshi KitagawaWe developed an automated continuous-flow reactor system capable of synthesising a wide variety of multi-element alloy nanoparticles (MEA NPs) under controlled solvothermal conditions (up to 400 °C and 35 MPa).To cite this article before page numbers […]Megumi Mukoyoshi
- Stabilisation of FeCoNiCuPt high-entropy alloy nanoparticles by surface capping Tháng 7 31, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00088B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anurag Sharma, Andrew L. HectorFeCoNiCuPt HEA nanoparticles prepared by NaCl-assisted solid-state reaction. Hydrophobic and hydrophilic capping agents are used to control particle size growth, provide stability, and prevent agglomeration.To cite this article before page […]Anurag Sharma
- Morphological, structural and compositional evolution of PtPdFeCoNi high-entropy alloy nanoparticles towards bifunctional oxygen electrocatalysis Tháng 7 29, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00092K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Priya Jain, Pouya Hosseini, Aleksander Kostka, Eko Budiyanto, Patrick Diehl, Martin Muhler, Harun Tüysüz, Dongshuang Wu, Tong LiThe PtPdFeCoNi HEA nanoparticles show high ORR stability with minimal surface changes, while OER triggers formation of […]Priya Jain
- Computational insights into the corrosion behavior of NbTaMoW and NbTaMoWV high-entropy alloys in molten fluoride salts Tháng 7 28, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00102A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Agnes Britte Katai, Arjun Varma Ramasimha Varma, Conrard Giresse Tetsassi FeugmoThis study explores the corrosion properties of NbTaMoW and NbTaMoWV in FLiBe molten salt via density functional theory and ab initio molecular dynamics simulations.To […]Agnes Britte Katai
- Processing-driven chemical ordering and its effect on magnetic properties in a high entropy alloy Tháng 7 23, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00105F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.V. Chaudhary, S. Dasari, A. Sharma, R. V. Ramanujan, R. BanerjeeProcessing-driven chemical ordering in a high entropy alloy governs nanoscale phase evolution and magnetic behavior, enabling tunable coercivity and dual magnetic transitions for cryogenic […]V. Chaudhary
- X-ray and neutron diffraction patterns of the AlCrTiV high-entropy alloy and quaternary Heusler structures Tháng 7 20, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00079C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nedjma Kalliney, Michael WidomNeutron diffraction reveals chemical ordering more clearly than X-ray diffraction for compounds such as the high-entropy alloy AlCrTiV that potentially exhibit Heusler order.To cite this article before page numbers are assigned, […]Nedjma Kalliney
- Molecular weight dependent water uptake and dynamics in lignin-based epoxy anticorrosive coatings Tháng 7 17, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00065C, PaperAzade Kafashan, Timon Binger, Markus Schackmann, Kim Dam-Johansen, Narayanan RajagopalanThe effect of lignin molecular weight on water transport in epoxy coatings is studied in comparison to iron oxide as a reference pigment.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Azade Kafashan
- Evaluation of microstructure and phase formation in nanocrystalline FeCoCuNbMo high-entropy alloy synthesised by mechanical alloying Tháng 7 14, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00085H, PaperJ. Sharath Kumar, K. Nanda Kishore, Rakesh Kumar, Rajeev VermaNanocrystalline FeCoCuNbMo HEA was synthesised via high-energy mechanical alloying using a SPEX mill. XRD confirmed stable dual-phase solid solutions (Mo-based BCC and Cu-based FCC). Milling refined crystallite size, increased lattice strain, and produced porous equiaxed particles.To cite this article before […]J. Sharath Kumar
- Thermal stability of CoNiPtCuAu nanoalloys: from segregation to melting properties Tháng 7 10, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00096C, PaperAnissa Acheche, Jaysen Nelayah, Riccardo Gatti, Damien Alloyeau, Christian Ricolleau, Hakim AmaraSegregation and melting properties of CoNiPt nanoparticles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryAnissa Acheche
- Modelling adsorbate coverage on complex alloy surfaces Tháng 7 9, 2025Faraday Discuss., 2025, Advance ArticleDOI: 10.1039/D5FD00089K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Martin L. S. Nielsen, Jack K. Pedersen, Marcus F. Nygaard, Mads K. Plenge, Henrik H. Kristoffersen, Jan RossmeislAdsorbate interactions facilitate the adsorption onto otherwise inaccessible sites as showcased here for the fully covered Pd(111) […]Martin L. S. Nielsen
- Spectro-electrochemistry of guaiacol oxidation: tracking intermediates in a membrane-separated cell with in situ attenuated total reflectance-infrared spectroscopy Tháng 10 27, 2025
