RSC – Polym. Chem. latest articles
- 3D-printed microfluidic dialysis apparatus for efficient polymer purification Tháng 8 20, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00608B, PaperTimo Koswig, Robert Geitner, Ilya Anufriev, Ivo Nischang, Stefan Zechel, Ulrich S. Schubert, Tanja JunkersThe study focuses on the optimization of a polymer purification system based on dialysis. The aim of the study is to optimize the purification efficiency by maintaining a homogenously mixed...The content of this RSS Feed […]Timo Koswig
- Incorporating Polar Oxazolidinones into Polycyclooctadiene via Frontal Ring-Opening Metathesis Polymerization Tháng 8 20, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00721F, PaperJazmin E. Aguilar-Romero, Elizabeth Rogan, Allison R. Wong, Brandon Hosford, Angela Mosconi, Jessica R LambFrontal ring-opening metathesis polymerization (FROMP) is a rapid, facile method that requires little energy input by utilizing the polymerization exotherm to self-propagate. Although FROMP is efficient, its scope has been...The content of this RSS Feed […]Jazmin E. Aguilar-Romero
- Iron-initiated radical polymerization of acrylate monomers Tháng 8 19, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00645G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Benedetta Palucci, Adriano Vignali, Fabio Bertini, Simona LosioIn this study, we present a novel Fe-H initiated radical polymerization method for various acrylate monomers, using commercially available iron(III) acetylacetonate as a catalyst and tetramethyldisiloxane (TMDSi) […]Benedetta Palucci
- Highly 1,4-Selective Copolymerization of Ethylene and 1,3-Butadiene using Phenoxy–Imine–Ligated Titanium Complexes: Synthesis of Metathesis-Degradable Copolymers Containing Internal Olefins in the Main Chain for Telechelic Polyethylene Tháng 8 19, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00482A, PaperTadashi Naito, Ryohei Ogawa, Yusuke MizobuchiA phenoxy-imine-ligated titanium (Ti) complex in combination with modified methylaluminoxane efficiently facilitated the selective 1,4-insertion of 1,3-butadiene (BD) during the copolymerization of ethylene and BD, achieving a selectivity of 85%....The content of this RSS Feed (c) The Royal Society of ChemistryTadashi Naito
- Long-Term Humid Adhesion of Sulfur Thermoplastics Polymers Enabled by Thioctic Acid-Initiated Polymerization Tháng 8 18, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00658A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tongye Zhang, Zhiyue Fang, Shifang Luan, Lei Wang, Hengchong ShiInverse vulcanization shows great feasibility for the utilization and conversion of sulfur by-product into high-performance sulfur-rich polymers. However, its practical application is hindered by poorly […]Tongye Zhang
- Poly(bridged bicycle)s synthesized via cyclopolymerization of cyclic diacrylates Tháng 8 18, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00631G, PaperYasuhiro Kohsaka, Taichi Yoshida, Natsumi NishiieCyclopolymerization of cyclic diacrylate monomers prepared via a reversible conjugate substitution reaction provided polymers with bridged bicyclic skeletons. The monomer derived from salicylic acid formed a stable conformation with two...The content of this RSS Feed (c) The Royal Society of ChemistryYasuhiro Kohsaka
- A thiol-functional amine synergist as a co-initiator for DLP 3D printing applications Tháng 8 18, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00603A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Magdalena Jankowska, Ozge Ozukanar, Emrah Çakmakçi, Joanna OrtylThis article describes a newly synthesized thiol-functional amine synergist and its application as a co-initiator in two-component initiating systems to initiate radical photopolymerization in 3D printing.To cite […]Magdalena Jankowska
- Preparation of bimodal polyethylene with different branching densities by co-anchoring strategy Tháng 8 15, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00110B, PaperChuncai Zhao, Shiwei Dai, Huiyu Yu, Wen-Min Pang, Fuzhou Wang, Daohong Liao, Wenbing Wang, Chen ZouAmong various polyolefin products, bimodal polyethylene is widely used as an important polyolefin, which is usually composed of high molecular weight polyethylene and low molecular weight polyethylene, however, having both...The content of this RSS […]Chuncai Zhao
- Polyimides via regioselective Friedel–Crafts hydroxyalkylation polycondensation with the reaction-enhanced reactivity of intermediate mechanism Tháng 8 14, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00683J, PaperXinqi Li, Lantian Dong, Yu Zhao, Xinxin Fu, Fengyu Wan, Lei Zou, Xiaohua Ma, Yongjun ZhangThis article presents a mild, efficient, feasible, and atomically economic Friedel-Crafts hydroxyalkylation polycondensation reaction for the synthesis of polyimide with novel triarylmethane backbone structure.To cite this article before page numbers are assigned, use the […]Xinqi Li
- Special interplay of hydrogen bonds and dynamic covalent bonds in sustainable polyurethane vitrimers with excellent recyclability and reprocessability Tháng 8 14, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00728C, PaperXiaoyu Du, Lang Shuai, Shiqiang Wang, Haitao Wu, Jianglong Li, Jianlong Wen, Maiyong Zhu, Jie Hu, Yijing NieSustainable polyurethane vitrimers with excellent mechanical properties, recyclability and reprocessability were prepared, and the interplay between the dynamic imine bond network and hydrogen bond network is revealed.To cite this article before page […]Xiaoyu Du
- “One-stop” polymer circularly polarized luminescence platform: easy construction of full-color circularly polarized luminescent materials Tháng 8 14, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00514K, PaperTing-Ting Xu, Shi-Yi Li, Ting-Ting Li, Yang Zong, Zheng Chen, Na Liu, Zong-Quan WuFluorescent groups with hydroxyl groups can be introduced into polyisocyanide copolymers by simple transesterification to prepare multicoloured CPL materials.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Ting-Ting Xu
- Zwitterionic polymerization of glycolide catalyzed by pyridine Tháng 8 13, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00762C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hans R. Kricheldorf, Steffen. M. WeidnerPyridine is shown to be an effective catalyst for the snthesis of low molar mass cyclic polyglcolides via zwittzerionic polymerization. The cyclic polyglycolides form extended-ring crystals in the mass […]Hans R. Kricheldorf
- Rapid and versatile polymer–polymer coupling via iodide–thiol substitution click chemistry Tháng 8 12, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00731C, PaperJirui Zhang, Atsushi GotoA rapid and efficient coupling of iodide-terminated poly(butyl acrylate) (PBA-I) chains using a dithiol linker (HS-R-SH) to generate a coupling product (polymer-R-polymer) was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The […]Jirui Zhang
- Homo(co)polymerization of bio-derived long alkyl chain methacrylate and methyl methacrylate using a readily accessible aminophosphine-based Lewis pair Tháng 8 12, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00224A, PaperBingqi Wang, Zhen Wu, Yin Cai, Fang Ge, Xiaowu WangThe homo- and copolymers of bio-derived lauryl methacrylate (LMA), which has the long alkyl side chain, were synthesized via Lewis pair polymerization with the modified new aminophosphine LB and characterized in detail.To cite this article before page numbers are assigned, use the […]Bingqi Wang
- Molecular weight regulates reversible adhesion of azopolymers with photoswitchable glass transition temperatures Tháng 8 12, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00606F, PaperZhe Wang, Wen-Cong Xu, Dachuan Zhang, Man Gao, Tao Chen, Youyi Sun, Shuofeng Liang, Si WuMolecular weight regulates reversible adhesion in azopolymers: low-molecular-weight azopolymers function as UV-weakened adhesives, while high-molecular-weight azopolymers display UV-enhanced adhesion.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Zhe Wang
- Synthesis of semi-rigid-biobased polyesters from renewable furanic cyclobutane diacid Tháng 8 11, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00485C, PaperLuan Moreira Grilo, Sara Faoro, Beatriz Agostinho, Andreia F. Sousa, Nathanael Guigo, Katja Loos, Dina Maniar, Talita Martins LacerdaA small library of polyesters was synthesized via melt polycondensation of various aliphatic diols and a furfural-derived cyclobutane diacid. The resulting polymers exhibited good thermal stability and char-forming properties, along with […]Luan Moreira Grilo
- Rigidity-tuned fluoroaromatic imine vitrimers yield ultra-high-strength, self-healing, and recyclable shape memory polybutadiene rubbers Tháng 8 7, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00590F, PaperYi Wu, Yingjia Yu, Guanliang He, Yuze Shi, Xuqing LiuImine crosslinked polybutadiene (PBD) with record-high strength was constructed via the reaction of amino modified PBD with a fluoroaromatic trialdehyde cross-linker, showing excellent reprocessability, shape memory and self-healing ability.To cite this article before page numbers are assigned, use the DOI […]Yi Wu
- Soft block sulfonated styrene–butadiene–styrene (SBS) triblock copolymer proton exchange membranes Tháng 8 3, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00569H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael K. Pagels, Ding Tian, Stefan Turan, Chulsung BaeA new synthetic method that generates a middle block sulfonated SEBS proton exchange membrane through partial hydrogenation of polystyrene-b-polybutadiene-b-polystyrene and a subsequent thiol–ene click reaction and […]Michael K. Pagels
- Block copolymers from coordinative chain transfer (co)polymerization (CCT(co)P) of olefins and 1,3-dienes and mechanical properties of the resulting thermoplastic elastomers Tháng 8 1, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00623F, Review ArticleSamy Alioui, Damien Montarnal, Franck D'Agosto, Christophe BoissonControlled coordination polymerization of olefins and 1,3-dienes enables macromolecular engineering and, in particular, the design of new thermoplastic elastomers with high mechanical properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Samy Alioui
- The side-arm-effect controlled stereodivergent polymerization of 1-butene Tháng 7 31, 2025Polym. Chem., 2025, 16,3675-3682DOI: 10.1039/D5PY00583C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Guangyu Zhu, Liang Wang, Wenjie Tao, Hongbin Hou, Guangqiang Xu, Bo Wang, Qinggang WangTridentate titanium complexes with different side-arm donors were employed for the efficient (activity of up to 3.41 × 106 g mol−1 h−1) […]Guangyu Zhu
- 3D-printed microfluidic dialysis apparatus for efficient polymer purification Tháng 8 20, 2025