RSC – Polym. Chem. latest articles- Prompt2Poly: Ask, Specify, Create – A Dialogue-Based Large Language Model for Targeted TSMPs Design Tháng 10 31, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00921A, PaperBorun Das, Andrew J Peters, Guoqiang Li, Xiali HeiDesigning polymers with targeted properties is a complex task that often relies on expert knowledge and multi-step computational workflows. Existing approaches typically require rigid input formats and post hoc property...The content of this RSS Feed (c) The Royal Society of ChemistryBorun Das
- Investigating Thermomechanical Behavior, Molecular and Dynamics of Rigid-Flexible Bio-based Copolyesters Tháng 10 29, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00870K, PaperLesly Dasilva Wandji Djouonkep, Yingzi Zuo, Zhengzai Cheng, Mario GauthierPetroleum-based plastics contribute significantly to global pollution due to their poor degradability, highlighting an urgent need for green alternatives that simultaneously offer thermomechanical performance comparable to commercially available plastics and...The content of this RSS Feed (c) The Royal Society of […]Lesly Dasilva Wandji Djouonkep
- Non-toxic Degradation of Anhydride-cured Epoxy Thermoset Using a Deep Eutectic Solvent Tháng 10 28, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00829H, PaperWendi Tian, Enjian He, Shuhan Zhang, Yixuan Wang, Zhijun Yang, Yan Ji, Guoli Wang, Qiulin Chen, Yen Wei, Huan LiangAnhydride-cured epoxy thermosets, unparalleled in electrical insulation, mechanical strength and chemical stability, serve as indispensable materials in electrical engineering. Efficient degradation of cured epoxy resins is a critical key to...The […]Wendi Tian
- Synthesis of molecularly tunable, dual-reactive poly(4-hydroxystyrene)-based photoresists via anionic polymerization, sequential deprotection, and reprotection reactions Tháng 10 27, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00941C, PaperDong-Jin Shin, Sang-Woog RyuThe quantitatively introduced acetoxy and acetal groups in the controlled polymers can be selectively removed under basic and acidic conditions, respectively, enabling the formation of photoresists with precisely controlled compositions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content […]Dong-Jin Shin
- Interpenetrating vitrimers based on dioxaborolane metathesis and imine-aldehyde exchange Tháng 10 27, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00851D, PaperLarissa Hammer, Renaud NicolaÿWe report a simple methodology to prepare interpenetrating vitrimers based on dioxaborolane metathesis and imine-aldehyde exchange. The interpenetrating vitrimers exhibit a combination of properties superior to those of the constituent vitrimers.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Larissa Hammer
- Thermally stable vanadium(V) complexes bearing bidentate phenoxy-phosphine ligands: synthesis, characterization, and catalytic properties for alkene polymerization Tháng 10 22, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00730E, PaperBiao Li, Yingli Ding, Huan Gao, Li Pan, Yuesheng LiVanadium catalysts with bidentate phenoxy-phosphine ligands exhibited high performance in olefin (co)polymerization. Subtle variations significantly modulated this performance, emphasizing the importance of precise ligand and comonomer selection.To cite this article before page numbers are assigned, use the DOI form of […]Biao Li
- Turning down the heat: catalyst-free, low-temperature chemical degradation of thermoplastic polyurethanes Tháng 10 21, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00881F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Adrià Roig, Hao Wang, Filip E. Du PrezThe straightforward incorporation of labile β-amino ester moieties into the main backbone of industrially relevant thermoplastic polyurethane allows for a catalyst-free synthesis and chemical degradation under mild […]Adrià Roig
- Emulsion polymerisation stabilised by block-random copolymers: ultra-small particles at low stabiliser levels Tháng 10 15, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00884K, CommunicationArthur Werner, Connor A. Sanders, Sandra E. Smeltzer, Michael F. CunninghamBlock-random copolymer stabilisers enable synthesis of ultra-small PMMA particles at low stabiliser levels. Latexes with particle diameters varying from 30–200 nm were prepared using as little as 0.01 wt% relative to monomer.To cite this article before page numbers are […]Arthur Werner
- Reversible addition–fragmentation chain transfer depolymerization of poly(methyl methacrylate) in toluene Tháng 10 13, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00576K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Don X. Bones, Adarsh Kumar, Emily Nelson, Bryanna Fofie, Erik P. Hoy, William M. GramlichTrithiocarbonates are more effective and have a different initiation mechanism than dithiobenzoates for the RAFT depolymerization of PMMA in toluene.To […]Don X. Bones
- Upcycling of polymer waste to closed-loop recyclable polymers Tháng 10 12, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00858A, PaperSourabh Singh, Ramkrishna SarkarThis study presents a novel approach aimed at developing the reclamation of waste plastics and the utilization of bio-based resources to develop sustainable and closed-loop recyclable polymers.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS […]Sourabh Singh
- High-performance anthrone-based low-migration photoinitiators for low-power photopolymerization Tháng 10 12, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00786K, PaperXinquan Wang, Zecong Ye, Hui Liang, Shaomin Ji, Yanping Huo, Yingxiao MuAnthrone-based donor-acceptor-donor photoinitiators were synthesized for efficient radical photopolymerization with an iodonium co-initiator.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of […]Xinquan Wang
- Enhanced suppression of chain transfer in ethylene (co)polymerization via synergistic axial substituent effects in pyridine-imine Ni(II) and Pd(II) catalysts Tháng 10 12, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00857C, PaperHuijun Fan, Mengya Ma, Shengyu DaiThis work demonstrates that judicious ligand design—balancing steric protection and flexibility—can simultaneously optimize molecular weight, branching control, and MA incorporation in late-transition-metal-catalyzed olefin polymerization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed […]Huijun Fan
- Rapid and living polymerization of renewable methylene butyrolactones via borane/phosphine Lewis pairs Tháng 10 8, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00789E, PaperYun Bai, Lieqiang Liao, Shuang Liu, Yibao Li, Jianghua He, Yuetao ZhangThis study presents a highly effective organic Lewis pair system, combining tris(pentafluorophenyl)borane (B(C6F5)3) with the strong organophosphorus superbase P(NIiPr)Ph2, enabling rapid and living polymerization of renewable methylene butyrolactones.To cite this article before page numbers are assigned, use the […]Yun Bai
- Photocontrolled cationic polymerization of fluorinated vinyl ethers Tháng 10 8, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00648A, PaperJianxu Chen, Xun Zhang, Zan Yang, Yu Jiang, Saihu LiaoVisible light-regulated photocontrolled cationic RAFT polymerization has been successfully developed for the synthesis of fluorinated polymers.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]Jianxu Chen
- Tetraphenylethylene-appended poly(ethylene-alt-maleic anhydride) derivatives: functional group-dependent stimuli-responsive fluorescence Tháng 10 8, 2025Polym. Chem., 2025, 16,4686-4695DOI: 10.1039/D5PY00657K, PaperRanran Gao, Qu Wang, Qian Li, Chenchi Hua, Xiaoning Guo, Li Wang, Wantai YangAn effective post-polymerization modification strategy has been developed to endow commercial maleic anhydride copolymer with highly differentiated and functional group-dependent stimuli-responsive aggregation-induced emission activity.The content of this RSS Feed (c) The Royal Society of ChemistryRanran Gao
- Self-stabilized precipitation polymerization of Fischer–Tropsch mixed olefins with maleic anhydride and vinyl acetate Tháng 10 8, 2025Polym. Chem., 2025, 16,4676-4685DOI: 10.1039/D5PY00612K, PaperYiran Li, Debang Qi, Xuanhao Zhang, Mingsen Chen, Yanbin Huang, Wantai YangNano-to-micron particles from FT mixed olefins were prepared through a self-stabilized precipitation polymerization method.The content of this RSS Feed (c) The Royal Society of ChemistryYiran Li
- Reactive Oxygen Species Sensitive Thioether-Bearing Poly(2-oxazoline)s: Direct and Controlled Polymerization using Initiator Salt. Tháng 10 8, 2025Polym. Chem., 2025, Accepted ManuscriptDOI: 10.1039/D5PY00659G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Saba Nemati Mahand, Anna-Lena Ziegler, Parsa Amin, Florian T. Kaps, Robert LuxenhoferReactive oxygen species (ROS)-responsive polymers have attracted significant attention for their potential in biomedical applications, particularly in drug delivery and tissue engineering. This […]Saba Nemati Mahand
- Bimetallic aluminum complexes bearing β-pyridyl-enamino ligands: synthesis, characterization and their applications in the ring-opening polymerization of ε-caprolactone Tháng 10 8, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00481K, PaperPeng Wang, Ziyao Su, Zeqian Yang, Jianhua Cheng, Hengquan Yang, Israel M. Kibeye, Xia ChenBimetallic aluminum complexes bearing β-pyridyl-enamino ligands were designed and synthesized. Efficient ring-opening polymerization of ε-CL was achieved by regulating the Al–Al distance and alkyl groups.To cite this article before page numbers are assigned, use the […]Peng Wang
- The effect of 1,2-dipiperidinoethane derivatives on the composition and hydride sequence distribution in the LAP of styrene and isoprene Tháng 10 8, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00352K, PaperYang Yang, Qiqi Dai, Yao Long, Yujie Wang, Zhifang Chen, Yi Yang, Le Zhou, Yi Xiao, Xinyu Han, Jiexun Zhang, Shihan Ding, Kun Liu, Lijun LiThe proposed mechanism of LAP of ST and IP under the effect of NN-i polar additives.To cite this article before page numbers are assigned, […]Yang Yang
- Synthesis of tetramethylguanidine-based photobase generators: light-guided dynamics in thioester networks Tháng 10 7, 2025Polym. Chem., 2025, Advance ArticleDOI: 10.1039/D5PY00779H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pia-Maria Egger, Hannah Sivetz, Simon Renner, Roman Korotkov, Christoph Schmidleitner, Marco Sigl, Inge Mühlbacher, Gregor Trimmel, Sandra Schlögl, Elisabeth RosseggerPhotolatent guanidine bases enable spatial and temporal control of thiol–thioester exchange in covalent adaptable networks, […]Pia-Maria Egger
- Prompt2Poly: Ask, Specify, Create – A Dialogue-Based Large Language Model for Targeted TSMPs Design Tháng 10 31, 2025