RSC – Chem. Sci. latest articles
- Functional metal–organic liquids Tháng Năm 7, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01793E, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nattapol Ma, Soracha Kosasang, Ellan K. Berdichevsky, Taichi Nishiguchi, Satoshi HorikeThis review explores principles governing melting behaviors in coordination polymers and metal–organic frameworks, overviews their practical applications, and discusses design strategies for achieving […]Nattapol Ma
- Confined dual Lewis acid centers for selective cascade C–C coupling and deoxygenation Tháng Năm 7, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D3SC06921D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Houqian Li, Jifeng Pang, Wenda Hu, Vannessa Caballero, Junming Sun, Mingwu Tan, Jian Zhi Hu, Yelin Ni, Yong WangDual Lewis acidic centers, CeOx and framework Sn, confined in Beta zeolite, catalyze the acetone […]Houqian Li
- High-order layered self-assembled multicavity metal-organic capsules and anti-cooperative host-multi-guest chemistry Tháng Năm 7, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01204F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kaixiu Li, Zhenguang Li, Jie Yuan, Mingzhao Chen, He Zhao, Zhiyuan Jiang, Jun Wang, Zhilong Jiang, Yiming Li, Yi-Tsu Chan, Pingshan Wang, Die LiuThe construction and application of metal-organic cages with accessible internal […]Kaixiu Li
- Diachronic evolvement from tetra-icosahedral to quasi-hexagonal close-packed bimetal clusters Tháng Năm 7, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC00942H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shisi Tang, Endong Wang, Yanzhen Wu, Tongxin Song, Meng Zhou, Xiao Cai, Yi Gao, Weiping Ding, Yan ZhuHere we report a diachronic evolvement from tetra-icosahedral Au30Ag12(CCR)24 to quasi-hcp (hexagonal close-packed) Au47Ag19(CCR)32 which might […]Shisi Tang
- Periodic table screening for enhanced positive contrast in MRI and in vivo uptake in glioblastoma Tháng Năm 7, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01069H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Aitor Herraiz, Maria del Puerto Morales, Lydia Martínez-Parra, Nuria Arias-Ramos, Pilar Lopez-Larrubia, Lucia Gutierrez, Jesús Mejías, Carlos Díaz-Ufano, Jesús Ruiz-Cabello, Fernando HerranzThe quest for nanomaterial-based imaging probes that can provide positive contrast in […]Aitor Herraiz
- Aromatization-driven deconstructive functionalization of spiro dihydroquinazolinones via dual photoredox/nickel catalysis Tháng Năm 7, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01111B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hongjie Miao, Jin-Hua Zhang, Wenke Li, Wenpeng Yang, Hong Xin, Pin Gao, Xin-Hua Duan, Li-Na GuoAromatization-driven deconstruction and functionalization of spiro dihydroquinazolinones via dual photoredox/nickel catalysis is developed. The aromatization effect was introduced […]Hongjie Miao
- Future Prospects of High-Entropy Alloys as Next-Generation Industrial Electrode Materials Tháng Năm 7, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D3SC06784J, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Saikat Bolar, Yoshikazu Ito, Takeshi FujitaThe rapid advancement of electrochemical processes in industrial applications has increased the demand for high-performance electrode materials. High-entropy alloys (HEAs), a class of multicomponent alloys with unique properties, […]Saikat Bolar
- Tuning white light emission using single-component tetrachroic Dy3+ metallacrowns: the role of chromophoric building blocks Tháng Năm 7, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC00389F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Elvin V. Salerno, Svetlana V. Eliseeva, Stéphane Petoud, Vincent L. PecoraroThe fine tuning of CIE coordinates was demonstrated in a series of molecular tetrachroic chromophores, Dy3+/Ga3+ metallacrowns, through modifications of the symmetry around […]Elvin V. Salerno
- nach0: multimodal natural and chemical languages foundation model Tháng Năm 7, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC00966E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Micha Livne, Zulfat Miftahutdinov, Elena Tutubalina, Maksim Kuznetsov, Daniil Polykovskiy, Annika Brundyn, Aastha Jhunjhunwala, Anthony Costa, Alex Aliper, Alán Aspuru-Guzik, Alex Zhavoronkovnach0 is a novel multi-domain and multi-task language model pre-trained on unlabeled […]Micha Livne
- Site-directed Conjugation of Single-Stranded DNA to Affinity Proteins: Quantifying the Importance of Conjugation Strategy Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01838A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andres Rocha Tapia, Fabrice Abgottspon, Johan Nilvebrant, Per- Åke Nygren, Sarah Duclos Ivetich, Andres Javier Bello Hernandez, Ioanna Thanasi, Peter Szijj, Ghali Sekkat, François M Cuenot, Vijay Chudasama, Nicola Aceto, Andrew deMello, Daniel […]Andres Rocha Tapia
- Rapid Flow-Based Synthesis of Post-Translationally Modified Peptides and Proteins: A Case Study on MYC’s Transactivation Domain Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00481G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Elyse T. Williams, Kevin Schiefelbein, Matthias Schuster, Ikhlas M. M. Ahmed, Marije De Vries, Rebecca Beveridge, Oliver Zerbe, Nina HartrampfProtein-protein interactions of c-Myc (MYC) are often regulated by post-translational modifications (PTMs), such as […]Elyse T. Williams
- Synergistic Interface and Structural Engineering for High Initial Coulombic Efficiency and Stable Sodium Storage in Metal Sulfides Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC02587C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chunrong Ma, Zhengguang Fu, Yanchen Fan, Hui Li, Zi-Feng Ma, Wei Jiang, Guangshuai Han, Haoxi Ben, Hui Claire XiongTransition metal sulfides (TMS) have gained significant attention as potential anode materials for sodium ion […]Chunrong Ma
- Mechanistic investigations of the Fe(II) mediated synthesis of squaraines Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01286K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yu Liu, Nathan Thomas Coles, Nathalia Cajiao, Laurence John Taylor, Edward Stephen Davies, Alistair Barbour, Patrick Morgan, Kevin Butler, Ben Pointer-Gleadhill, Stephen Argent, Jonathan McMaster, Michael L. Neidig, David Robinson, Deborah Lorraine KaysThe […]Yu Liu
- Insulated π-Conjugated 2,2’-Bipyridine Transition-Metal Complexes: Enhanced Photoproperties in Luminescence and Catalysis Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01046A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tomohiro Iwai, Shinsuke Abe, Shin-ya Takizawa, Hiroshi Masai, Jun Terao2,2'-Bipyridine has been identified as a privileged ligand scaffold for photofunctional transition metal complexes. We herein report on the synthesis and photoproperties of an […]Tomohiro Iwai
- Copper-Catalyzed Asymmetric Allylic Substitution of Racemic/meso Substrates Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC02135E, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jun Li, Junrong Huang, Yan Wang, Yuexin Liu, yuxiang zhu, Hengzhi You, Fener ChenThe synthesis of enantiomerically pure compounds is a pivotal subject in the field of chemistry. Enantioselective catalysis currently stands as […]Jun Li
- Quinoxaline-based Y-type acceptors for organic solar cells Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01481B, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Meiling Xie, Zhixiang Wei, Kun LuMinimizing energy loss plays a critical role in the quest for high-performance organic solar cells (OSCs). However, the origin of large energy loss in OCSs is complicated, involving the […]Meiling Xie
- CoH-Catalyzed Asymmetric Remote Hydroalkylation of Heterocyclic Alkenes: A Rapid Approach to Chiral Five-Membered S- and O-Heterocycles Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01149J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lingzi Zhao, Feipeng Liu, Yan Zhuang, Mengyang Shen, Jing Xue, Xuchao Wang, Yuting Zhang, Zi-Qiang RongSaturated heterocycles, which incorporate S and O heteroatoms, serve as fundamental frameworks in a diverse array of natural […]Lingzi Zhao
- Charge-Regulated Fluorescent Anchors Enable High-Fidelity Tracking of Plasma Membrane Dynamics During Biological Events Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01423E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiaqi Zuo, Aohui Peng, Penglei Wu, Junyi Chen, Chuangye Yao, Junjun Pan, Engao Zhu, Yingye Weng, Kewei Zhang, Hui Feng, Zhi-Gang Jin, Zhaosheng QianMany biological processes generally require long-term visualization tools for time-scale […]Jiaqi Zuo
- Photophysics of Fluorescent Nanoparticles Based on Organic Dyes – Challenges and Design Principles Tháng Năm 6, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01352B, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Stine Grønfeldt Stenspil, Bo W. LaursenFluorescent nanoparticles has become attractive for bioanalysis and imaging, due to their high brightness and photostability. Many different optical materials have been applied in fluorescent nanoparticles with a broad […]Stine Grønfeldt Stenspil
- Discovery of a lagriamide polyketide by integrated genome mining, isotopic labeling, and untargeted metabolomics Tháng Năm 6, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC00825A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Claire H. Fergusson, Julia Saulog, Bruno S. Paulo, Darryl M. Wilson, Dennis Y. Liu, Nicholas J. Morehouse, Samantha Waterworth, John Barkei, Christopher A. Gray, Jason C. Kwan, Alessandra S. Eustaquio, Roger G. LiningtonWhole […]Claire H. Fergusson
- Functional metal–organic liquids Tháng Năm 7, 2024