RSC – Chem. Sci. latest articles- Modulation of electronic structure of nickel selenide via iron doping for energy-saving hydrogen production coupled with sulfion upgrading May 28, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01884F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rui-Qing Li, Shuixiang Xie, Yuhuan Li, Xiaojun Wang, Shijie Liu, Jiahui Qian, Yuhan Zhang, Linling Jiang, Zhe Cao, Zhenhao Yan, Xiaoyu Wan, zhaohang Yang, Longhua Zou, Wei ZhangHybrid water electrolysis is a promising […]Rui-Qing Li
- Revealing Axial-Ligand-Induced Switching of Spin States for Controllable Single Electron Transfer-based Radical Initiation May 28, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02194D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.jingyi Qin, Yiyan Yin, Xiaowen Guan, Xiyang Ge, mengyu Cao, Jin Ouyang, Na NaRadicals are highly reactive for coupling reactions while the applications are normally limited by the uncontrollable initiation and chaotic conversions. […]jingyi Qin
- X-ray fluorescence microscopy and X-ray absorption spectroscopy reveal the stability of the plecstatin-1 scaffold in biological model systems: comparison of Ru, Os and Ir analogues May 28, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC02925B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.James H. Lovett, Barry P. Lai, Hugh O. Bloomfield, Ani T. Baker, Matthew P. Sullivan, Christian G. Hartinger, Hugh H. HarrisLigand exchange reactions often impact our understanding of metal-based cancer drug prototype actions. […]James H. Lovett
- Decarboxylative sulfation by persulfates May 28, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC03129J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhen Xia, Ting Deng, Chunlan Song, Jiakun LiDecarboxylative radical sulfation is achieved with persulfates functioning as both oxidants and sulfating agents to facilitate C–OSO3− bond formation. Synthesis of organosulfates from carboxylic-acid-based drugs may […]Zhen Xia
- Strong Acceptor Incorporated Phenothiazine-C60 Multi-Redox Push-Pull Conjugates: Demonstration of C60’s Superior Electron Acceptor Characteristics May 28, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02950C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Pankaj Gupta, Chamari V. Ileperuma, Rajneesh Misra, Francis D'SouzaAmong the several exceptional properties of fullerene, C60, its electron acceptor property is a highly studied topic. This work demonstrates the superior electron acceptor property […]Pankaj Gupta
- Guided Multi-objective Generative AI to Enhance Structure-based Drug Design May 28, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01778E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Amit Kadan, Kevin Ryczko, Erika Lloyd, Adrian E. Roitberg, Takeshi YamazakiGenerative AI has the potential to revolutionize drug discovery. Yet, despite recent advances in deep learning, existing models cannot generate molecules that satisfy […]Amit Kadan
- Response of reaction mechanisms to electric-field catalysis on carbon nanotubes in microfluidic reactors May 27, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC02934A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.M. Ángeles Gutiérrez López, Alenka Marsalek, Naomi Sakai, Stefan MatileScalable electric-field catalysis on carbon nanotubes in electromicrofluidic reactors is shown to accelerate and direct reactions toward intrinsically disfavored products.To cite this article before […]M. Ángeles Gutiérrez López
- A Design Strategy for Single-Molecule Magnet Materials with Fullerene Confinement-Induced Unpaired f-Electrons May 27, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01607J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao-Kun Zhao, Jing Zhao, Shiru-ru Wei, Yun-Ze Qiu, Yang He, Han-Shi Hu, Jun LiEndohedral metallofullerenes (EMFs) are promising platforms for single-molecule magnets (SMMs) due to their internal cavities, which enable effective coupling of […]Xiao-Kun Zhao
- NMRExtractor: leveraging large language models to construct an experimental NMR database from open-source scientific publications May 27, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08802F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qinggong Wang, Wei Zhang, Mingan Chen, Xutong Li, Zhaoping Xiong, Jiacheng Xiong, Zunyun Fu, Mingyue ZhengNMRExtractor is a large language model-powered pipeline that automatically extracts experimental NMR data from massive open-access publications, resulting […]Qinggong Wang
- Identifying the Superatomic AuCu56 Nanocluster through a Ligand-exchange Coupled Metal-exchange Induced Transformation May 27, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02515J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.SANIYA GRATIOUS, Bo Li, Dipanjana Mondal, Dayona Aleyamma Varghese, Alok Kumar, Jibin Thomas, De-En Jiang, Vinayak B. Kamble, Sukhendu MandalQuantum-sized metal nanoclusters can be viewed as superatoms that mimic the electron-shell closing behaviours […]SANIYA GRATIOUS
- Photoabsorption of 1-2 nm Molecular Ce-oxo Nanoclusters Versus Ceria: Intervalence Charge Transfer but No Size Effects. May 27, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00905G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sebastian D Pike, Stephen E BrownThe absorption spectra of a series of Ce-oxo clusters (molecular nanoparticles) with sizes ranging from 3 to 100 Ce atoms per cluster are reported. The O 2p to […]Sebastian D Pike
- Site-selective ligand defects open up a Zr-oxo cluster electron transfer pathway for CO2 photoreduction May 27, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01194A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuhang Qi, Yiqiang He, Yuxin Liu, Zhe Zhang, Chunguang Li, Fanchao Meng, Shiyu Wang, Xiaobo Chen, Zhan Shi, Shouhua FengWhilst defect engineering is a sound approach to enhance CO2 photoreduction based on metal […]Yuhang Qi
- Correction: Exciton and charge transfer processes within singlet fission micelles May 27, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC90113H, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel Malinowski, Guiying He, Bernardo Salcido-Santacruz, Kanad Majumder, Junho Kwon, Matthew Y. Sfeir, Luis M. CamposTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Daniel Malinowski
- The contribution of cyclic imide stereoisomers on cereblon-dependent activity May 27, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01371B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuka Amako, Saki Ichikawa, Hannah C. Lloyd, N. Connor Payne, Zhi Lin, Andrew S. Boghossian, Matthew G. Rees, Melissa M. Ronan, Jennifer A. Roth, Qian Zhu, Bogdan Budnik, Ralph Mazitschek, Christina M. WooA […]Yuka Amako
- Mining Peptides for Mining Solutions: Evaluation of Calcium-Binding Peptides for Rare Earth Element Separations May 27, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02315G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Farid Farid Khoury, Bradley S. Heater, Daniel R. Marzolf, Sameera S. Abeyrathna, Jonathan W. Picking, Piyush Kumar, Steven A. Higgins, Randy Jones, Alan T. Lewis, Katarzyna H. Kucharzyk, Scott BantaRare earth elements (REEs), […]Farid Farid Khoury
- Steric Hindrance Modulated Efficient Thermally Activated Delayed Fluorescence with Non-linear Optical, Ferroelectric and Piezoelectric Properties May 26, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02107C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Madhusudan Dutta, Abhijit Chatterjee, Nilotpal Deka, Riteeka Tanwar, Vishnu Mishra, Arindam Saha, Pankaj Mandal, Ramamoorthy Boomishankar, Partha HazraMulti-carbazole-based benzonitrile systems are efficient thermally activated delayed fluorescence (TADF) materials for organic light-emitting diodes (OLEDs). […]Madhusudan Dutta
- High entropy hydroxide with hollow nanocage structure promotes efficient and stable water/seawater electro-oxidation May 26, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01961C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rui Chang, Yu Pang, Qin Yang, Ruotong Liu, Yang Yu, Yunmei Du, Kang Liu, Zexing Wu, Jianping Lai, Hongdong Li, Lei WangHigh-entropy hydroxides (HEHs) exhibit excellent performance in electrocatalytic reactions, but controlling the […]Rui Chang
- Interstitial Nitrogen Modified Rh Nanocrystal for Efficient and CO-Resistant Alkaline Hydrogen Oxidation Electrocatalysis May 26, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02884A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jianchao Yue, Chaoyi Yang, Yu Zhang, Qianqian Xiong, Wei LuoThe preparation of active and CO-tolerant platinum-free electrocatalysts toward hydrogen oxidation reaction (HOR) under alkaline condition is significant for the practical development of anion […]Jianchao Yue
- Privileged Metal Cluster Complexes May 26, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02924D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shiquan Lin, Dan Li, Dandan Zhang, Lijun Geng, Yuhan Jia, Weizhe Wang, Longjiu Cheng, Shiv N Khanna, Zhixun LuoClusters are a prominent subject of interest in modern chemistry research, bridging atoms and materials […]Shiquan Lin
- Precise Construction of Pd Superstructures with Superlattices for Solar-Driven Organic Transformation May 26, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01599E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Henglei Jia, Jingzhao Li, Fu-Kuo Chiang, Hao Wang, Fan Li, Zhongqing Lin, Qifeng Ruan, Chun-Yang ZhangPrecisely controlling the spatial arrangement of nanostructures offers unique opportunities for tuning physical and chemical properties, however, it […]Henglei Jia
- Modulation of electronic structure of nickel selenide via iron doping for energy-saving hydrogen production coupled with sulfion upgrading May 28, 2025
