RSC – Chem. Sci. latest articles
- In situ transmission electron microscopy characterization and manipulation of the morphology, composition and phase evolution of nanomaterials under microenvironment conditions May 6, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01214G, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Na Li, Tian Wang, Bo Wen, Zicheng Yin, Xinyang Li, Jie Feng, Shujiang Ding, Shengchun Yang, Guorui Yang, Yawei YangNanomaterials possess a broad range of applications in areas such as catalysis, energy, and […]Na Li
- Binding assays enable discovery of Tet(X) inhibitors that combat tetracycline destructase resistance May 6, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC00964B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew J. Beech, Edmond C. Toma, Helen G. Smith, Maria M. Trush, Jit H. J. Ang, Mei Y. Wong, Chung H. J. Wong, Hafiz S. Ali, Zakia Butt, Viha Goel, Fernanda Duarte, Alistair […]Matthew J. Beech
- Correction: A comprehensive approach for elucidating the interplay between 4fn+1 and 4fn5d1 configurations in Ln2+ complexes May 6, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC90097B, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maria J. Beltran-Leiva, William N. G. Moore, Tener F. Jenkins, William J. Evans, Thomas E. Albrecht, Cristian Celis-BarrosTo cite this article before page numbers are assigned, use the DOI form of citation above.The content […]Maria J. Beltran-Leiva
- Harnessing C–H acetoxylation: a gateway to oxygen-enriched organic frameworks May 6, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00449G, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jagrit Grover, Bishal Dutta, Devika Ghosh, Prakash Kumar Shee, Siddhartha Maiti, Daniel B. Werz, Debabrata MaitiTransition metal catalyzed C-H functionalization has emerged as a robust tool in organic synthesis, as it utilizes the […]Jagrit Grover
- Two-dimensional Infrared Spectroscopy as a Tool to Reveal the Vibrational and Molecular Structure of [FeFe] Hydrogenases May 6, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01811K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cornelius Constantin Maria Bernitzky, yvonne rippers, Denise Poire, Mathesh Vaithiyanathan, Solomon Lewis David Wrathall, Barbara Procacci, Igor V. Sazanovich, Gregory M Greetham, Patricia Rodriguez Macia, Neil Hunt, James A. Birrell, Marius Horch[FeFe] hydrogenases […]Cornelius Constantin Maria Bernitzky
- Light-induced twisting, untwisting, and retwisting of aromatic polyamides: an interplay between the induced chirality and the co-facial π-stacking interactions May 6, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08795J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Subhendu Samanta, Raj Kumar RoyThis functionalized aromatic polyamide dynamically switches between two ordered structures (helix and pleated sheet). A photoresponsive merocyanine acts as a conformational switch for its secondary structure.To cite this article […]Subhendu Samanta
- Unveiling the Covalency of Versatile Pu(III)–N bonds in a Unique Plutonium(III) Complex May 5, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01808K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhuanling Bai, Madeline C. Martelles, Joseph M. Sperling, Thomas E. AlbrechtA trivalent plutonium-pyrizinyl-tetrazolate complex Na2[Pu(Hdtp)(dtp)2(H2O)4]·9H2O (Pu_dtp, H2dtp = 2,3-di-1H-tetrazol-5-ylpyrazine) was synthesized through metathesis reaction of plutonium bromide and Na2(dtp)·2H2O in water. This structure […]Zhuanling Bai
- Endoplasmic reticulum-targeting activatable nanophotosensitizers for hypoxia relief and enhanced photodynamic therapy May 5, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00534E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shanchao Diao, Xiaowen He, Ying Wu, Likun Yin, Yuxin Huang, Wen Zhou, Chen Xie, Quli FanPhotodynamic therapy (PDT) is a promising cancer therapeutic modality. However, the specific targeting capability of conventional photosensitizers is […]Shanchao Diao
- Exciton and charge transfer processes within singlet fission micelles May 5, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01479D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Daniel Malinowski, Guiying He, Bernardo Salcido-Santacruz, Kanad Majumder, Junho Kwon, Matthew Y. Sfeir, Luis M. CamposMultiexciton (ME) mechanisms hold great promise for enhancing energy conversion efficiency in optoelectronic and photochemical systems.To cite this […]Daniel Malinowski
- Expanding the Toolbox for Supramolecular Chemistry: Probing Host-Guest Interactions and Binding with in situ FTIR Spectroscopy May 5, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01329A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael D Pluth, Darren Johnson, Shiva Moaven, Douglas A Vander GriendAssociation constant (Ka) measurements provide fundamental information on host-guest interactions in supramolecular chemistry and other areas of science. Here we report the use […]Michael D Pluth
- Rhenium coordination-induced conformational modulation in nitrogen-doped nanographene May 5, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC02827B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Eldhose V. Varghese, Yi-Hung Liu, Hsing-Yin Chen, Chien-Hung Li, Chia-Hsiang ChenWe report the synthesis and characterization of nanographene–Re complexes and investigate Re(I)-induced structural and chiral transformations in nanographene.To cite this article before page […]Eldhose V. Varghese
- Multiple stimulus modulated organic crystal polymorphs with tunable luminescence behavior May 5, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01503K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qian Zhou, Mingxia Feng, Caihong Shi, Mengqiu Qian, Xiurong Ma, Runying He, Xian Meng, Yonggang Shi, Qiue Cao, Liyan ZhengThree crystal polymorphs of p-An-Br with green, yellow and red fluorescence are achieved through […]Qian Zhou
- Advances in sulfonyl exchange chemical biology: Expanding druggable target space May 5, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02647D, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lyn H JonesTargeted covalent inhibitors possess advantages over reversible binding drugs, that includes higher potency, enhanced selectivity and prolonged pharmacodynamic duration. The standard paradigm for covalent inhibitor discovery relies on the use...The content of […]Lyn H Jones
- A Platform for SpyCatcher Conjugation to Native Antibodies May 5, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02286J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Soňa Krajčovičová, Thomas Wharton, Claudia L. Driscoll, Thomas A King, Mark R. Howarth, David R SpringProtein-antibody conjugates represent major advancements in targeted therapeutics. However, platforms enabling ‘off-the shelf’ antibody conjugation are seldom reported. […]Soňa Krajčovičová
- Enhancing Photostability of Red Fluorescent Proteins through FRET with Si-Rhodamine for Dynamic Super-Resolution Fluorescence Imaging May 4, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02442K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xuelian Zhou, Lu Miao, Wei Zhou, Yonghui Chen, Yiyan Ruan, Xiang Wang, Guangying Wang, Pengjun Bao, Qinglong Qiao, Zhaochao XuRed fluorescent proteins (RFPs) are extensively utilized in biological imaging. However, their susceptibility to […]Xuelian Zhou
- Combined Effect of High Voltage and Large Li-ion Flux on Decomposition of Li6PS5Cl May 4, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02018B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Deye Sun, Wenru Li, Yantao Wang, Jiangwei Ju, Pengxian Han, Shanmu Dong, Jun Ma, Guanglei CuiHigh voltage has been considered the culprit causing electrolyte decomposition in all-solid-state lithium batteries. However, whether high voltage […]Deye Sun
- Unveiling the molecular basis of selective fluorination of SAM-dependent fluorinases May 4, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00081E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ravi Kumar Verma, Wan Lin Yeo, Elaine Tiong, Ee Lui Ang, Yee Hwee Lim, Fong Tian Wong, Hao FanS-Adenosylmethionine (SAM)-dependent fluorinases have emerged as environmentally friendly enzymatic alternatives for organofluorine chemical synthesis. However, […]Ravi Kumar Verma
- Stereoselective synthesis of heterocyclic tetraphenylethylene analogues with configuration-dependent solid-state luminescence May 4, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08333D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mathilde Seinfeld, Jean Rouillon, Raphael Rullan, ERWANN JEANNEAU, Stephan N. Steinmann, Chantal Andraud, Tangui Le Bahers, Cyrille MonnereauWhile ubiquitous in a variety of optoelectronic applications, fluorophores displaying aggregation induced emission (AIE) and in […]Mathilde Seinfeld
- L/Z-ligand type amphoterism of an acridinium unit May 4, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00965K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Elishua D. Litle, Shantabh Bedajna, François P. GabbaïAs part of our study of ambiphilic carbenium-based ligands, we now report on the coordination chemistry of the known acridinium phosphine ligand [(o-Ph2P(C6H4)Acr)]+ ([Lacr]+, Acr = […]Elishua D. Litle
- N-Heterocyclic carbene-catalyzed enantioselective (dynamic) kinetic resolution for the assembly of inherently chiral macrocycles May 4, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01773D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhipeng Li, Jingyang Zhang, Wanmeng Zhu, Tianyi Wang, Yefeng jian wang, Jian WangHeterocalixaromatics play a significant role in supramolecular chemistry and material sciences. However, the absence of robust enantioselective synthetic methods has constrained […]Zhipeng Li
- In situ transmission electron microscopy characterization and manipulation of the morphology, composition and phase evolution of nanomaterials under microenvironment conditions May 6, 2025