RSC – Chem. Sci. latest articles- Tandem Rh(II)-catalyzed 1,3-acyloxy migration/intermolecular [2+2] cycloaddition of electronically deficient propargylic esters with alkenes and alkynes November 20, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06458E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zurong Xu, Dong Zhu, Rui Wu, Shifa ZhuTransition metal-catalyzed 1,3-acyloxy migration of propargylic esters represents one of the most straightforward routes to access allene intermediates, which could engage in various fascinating subsequent transformations. […]Zurong Xu
- Aluminium porphyrins catalyse the hydrogenation of CO2 withH2 November 20, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC03665D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nitin Kumar, Gabriela Gastelu, Martin Zabransky, Jaroslav Kukla, Jorge Gustavo Uranga, Martin HullaBoron-based frustrated Lewis pairs (FLPs) have become well-established catalysts for the hydrogenation of a wide range of functional groups. Conversely, aluminium-based […]Nitin Kumar
- Enantioselective Nickel-Catalyzed Electrochemical Reductive Conjugate Alkenylation of α,β-Unsaturated Ketones November 20, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06891B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Siriphong Somprasong, Syuzanna R. Harutyunyan, Bin WanCatalytic electrochemical asymmetric catalysis starting to emerg as a promising strategy for the synthesis of chiral compounds. Herein, we report an asymmetric electrochemical nickel-catalysed reductive conjugate addition […]Siriphong Somprasong
- Recent progress in small-molecule fluorescent probes for the detection of superoxide anion, nitric oxide, and peroxynitrite anion in biological systems November 20, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06722C, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yongqing Zhou, Xuan Kuang, Xiaofeng Yang, Juan Li, Xianzhe Wei, Won Jun Jang, Shan-Shan Zhang, Mei Yan, Juyoung YoonIn this review, we summarized the latest progress (2020–2023) in small-molecule fluorescent probes for monitoring […]Yongqing Zhou
- Effective Design Strategy for Thermally Activated Delayed Fluorescence Emitters with Aggregation-Induced emission to Enable Sky-blue OLEDs Achieving EQE Nearly 30% November 20, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06613H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hui Dai, Yaohui Liang, Xiang Long, Tianyi Tang, Haozhi Xie, Zhiwei Ma, Gaoyu Li, Zhiyong Yang, Juan Zhao, Zhenguo ChiPure organic thermally activated delayed fluorescence (TADF) materials hold great promise for efficient organic […]Hui Dai
- Molecular origins of exciton condensation in van der Waals heterostructure bilayers November 20, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04149F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lillian I. Payne Torres, Anna O. Schouten, David A. MazziottiA “critical seed” of exciton condensation is found in molecular-scale fragments of van der Waals heterostructure bilayers via the theoretical signature for exciton condensation, […]Lillian I. Payne Torres
- Structural Characterization of Surface Immobilized Platinum Hydrides by Sensitivity-Enhanced 195Pt Solid State NMR Spectroscopy and DFT Calculations November 20, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06450J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benjamin A. Atterberry, Erik Wimmer, Sina Klostermann, Wolfgang Frey, Johannes Kästner, Deven Estes, Aaron J RossiniSupported single-site platinum hydride compounds are promising heterogeneous catalysts for organic transformations. Few methods exist to describe the […]Benjamin A. Atterberry
- Strongly Photoluminescent and Radioluminescent Copper(I) Iodide Hybrid Materials Made of Coordinated Ionic Chains November 19, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06242F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jingwen Chen, Kang Zhou, Jingbai Li, Guozhong Xu, Xiuze Hei, Jing LiScintillation-based X-ray detection has been widely used in various fields from medical diagnostics to security. In this study, we report four new […]Jingwen Chen
- Main-chain stiff-stilbene photoswitches in solution, in bulk, and at surfaces November 19, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06470D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Naoki Kaneda, Keiichi Imato, Ayane Sasaki, Ryo Tanaka, Ichiro Imae, Toyoaki Hirata, Takuya Matsumoto, Yousuke OoyamaMolecular photoswitches have been incorporated into polymer backbones to control the macromolecular conformations by structural changes of the […]Naoki Kaneda
- Switchable Magnetic Resonance Imaging Nanoplatform for in Situ MicroRNA Imaging November 19, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04675G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yan Tan, Junren Wang, Qian Wan, Jinlong Yang, Jinkun Huang, Zijia Zhou, Haifeng Dong, Xueji ZhangAberrant microRNA (miRNA) expression is associated with various types of carcinogenesis, making miRNA a promising candidate for diagnostic […]Yan Tan
- Unlocking Regioselectivity: Steric Effects and Conformational Constraints of Lewis Bases in Alkyllithium-Initiated Butadiene Polymerization November 19, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05144K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Tang, Yuan Fu, Jing Hua, Jiahao Zhang, Shuoli Peng, Zhibo LiIn nonpolar solvents, alkyllithium-initiated 1,3-butadiene polymerization exhibits high 1,4-selectivity, which shifts towards 1,2-selectivity upon the addition of Lewis bases. For the past […]Jian Tang
- Dithienoarsinines: Stable and Planer π-Extended Arsabenzenes November 19, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06590E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Akifumi Sumida, Akinori Saeki, Kyohei Matsuo, Kensuke Naka, Hiroaki ImotoStable planar dithienoarsinines were synthesized and structurally characterized. These compounds exhibit monomeric structures in the solution and solid states, avoiding dimerization, even in the […]Akifumi Sumida
- Ru(II)-catalyzed regioselective oxidative Heck reaction with internal olefins that tolerated strongly coordinating heterocycles November 19, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC07036D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ci Chen, Qiaoya Zhang, Zhiwei Huang, Wensen Ouyang, Yang Gao, Jiye Luo, Yuan Liu, Yanping Huo, Qian Chen, Xianwei LiBy using imidate esters, oxidative Heck reaction of strongly coordinating heterocycles with internal olefins […]Ci Chen
- Enhanced Electrocatalytic Nitrate-to-Ammonia Performance from Mott-Schottky Design to Induce Electron Redistribution November 18, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06818A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ruikai Qi, Qiuling Jiang, Li Deng, Xianqiang Yu, Bingyan Shi, Mengxiao Zhong, Ying Wang, Xiaofeng LuConstructing highly efficient electrocatalysts via interface manipulation and structural design to facilitate rapid electron transfer in electrocatalytic nitrate-to-ammonia […]Ruikai Qi
- Donor-free 9,10-dihydro-9,10-dialuminaanthracenes November 18, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06940D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paula L. Lückert, Jannik Gilmer, Alexander Virovets, Hans-Wolfram Lerner, Matthias WagnerDespite their promising potential, e.g., as ditopic, cooperatively binding Lewis acids, 9,10-dihydro-9,10-dialuminaanthracenes (DAA-R2; R: terminal Al-bonded substituent) have remained unexplored for long due […]Paula L. Lückert
- Effects of benzoheterocyclic annelation on the s-indacene core: a computational analysis November 18, 2024Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06812B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gabrielle I. Warren, Katarzyna Młodzikowska-Pieńko, Said Jalife, Isabella S. Demachkie, Judy I. Wu, Michael M. Haley, Renana Gershoni-PoranneAromaticity and antiaromaticity are pivotal concepts in chemistry, with significant implications for molecular properties and reactivity.To […]Gabrielle I. Warren
- Reactivity of Metal Hydrides with CO2: Going Beyond Formate with a High-Valent Cationic Pentahydride Mo(VI) Complex November 18, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04345F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nicolas Queyriaux, Jorge Juan Cabrera-Trujillo, Nina Durvin, Laure Vendier, Karinne Miqueu, Antoine SimonneauThe cationic molybdenum pentahydride complex [MoH5(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) is shown to undergo two consecutive reactions with carbon dioxide. In the […]Nicolas Queyriaux
- SynAsk: Unleashing the Power of Large Language Models in Organic Synthesis November 18, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04757E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chonghuan Zhang, Qianghua Lin, Biwei Zhu, Haopeng Yang, Xiao Lian, Hao Deng, Jiajun Zheng, Kuangbiao LiaoThe field of natural language processing (NLP) has witnessed a transformative shift with the emergence of large language […]Chonghuan Zhang
- Tunable Synthesis of Heteroleptic Zirconium-Based Porous Coordination Cages November 18, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06023G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Merissa N. Morey, Christine M. Montone, Michael Dworzak, Glenn P A Yap, Eric D BlochZirconium-based porous coordination cages have been widely studied and have shown to be potentially useful for many applications as […]Merissa N. Morey
- Copper depletion-induced tumor cuproptosis November 18, 2024Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04712E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Min Zhou, Faheem Muhammad, Jingyuan Zhao, Yihong Zhang, Tong Li, Jiayuan Feng, Hui WeiCopper homeostasis is crucial for cells, especially for rapidly proliferating cancerous cells. Copper imbalance-induced cell death (i.e., cuproptosis) has emerged […]Min Zhou
- Tandem Rh(II)-catalyzed 1,3-acyloxy migration/intermolecular [2+2] cycloaddition of electronically deficient propargylic esters with alkenes and alkynes November 20, 2024
