RSC – Dalton Trans. latest articles- Organometallic Nickel NCN Pincer Complex Promotes L-Lactate Racemization in Water October 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01550B, PaperThomas D. Dow, Derek R Kuno-Williams, Toby John Woods, Yu ZhangThe air-stable and water-soluble salt [(NCNMe+)Ni(NCCH3)](OTf)2 (NCNMe+= 3,5-bis(4,4-dimethyl-4,5-dihydrooxazol-2-yl)-1,2,6-trimethylpyridin-1-ium) was synthesized and characterized. As a partial structural mimic, [(NCNMe+)Ni(NCCH3)]2+ retains the unusual 4-pyridylidene-based pincer framework present in the nickel pincer nucleotide...The content of this RSS Feed (c) The Royal Society […]Thomas D. Dow
- Electronic Effects in Early Transition Metal Catalyzed Olefin Polymerization: Challenges in Featurization and Descriptor Strengths and Weaknesses October 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02170G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christian Ehm, Gianluigi Galasso, Antonio Vittoria, Pietro Oriente, Luigi Maiale, Peter H.M. Budzelaar, Roberta Cipullo, Vincenzo BusicoIn olefin polymerization, even seemingly simple concepts like the influence of electronic effects have sometimes eluded qualitative understanding […]Christian Ehm
- From 1D to 3D: dimensional control of low-coordinate lanthanide coordination polymers with SMM feature and white-light emission October 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02266E, PaperXiang Tao Dong, Ting Zhu, Rong-Yan Zhang, Guo Peng, Lijun Fu, Xiaoming RenThe self-assembly of 1,1',1''-((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(pyridin-4(1H)-one) (TTP) ligand with Dy(III) ions afforded three lanthanide coordination polymers: [Dy(TTP)₂(H₂O)]Cl₃·C₃H₆O·7H₂O (1), [Dy(TTP)₂](CF₃SO₃)₃·2H₂O (2), and [Dy(TTP)₂(H₂O)](CF₃SO₃)₃·2H₂O (3). The structural dimensionality of complexes 1-3 varies from one-dimensional...The content of this RSS Feed (c) The […]Xiang Tao Dong
- One-pot straightforward access to a cyclometalated acetate platinum(II) complex exhibiting mechanochromic luminescence October 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01895A, CommunicationEgor Sosunov, Sergei V. Tatarin, Ivan V. Skabitsky, Alexandra Grigorievna Son, Ilya Yakushev, Maria PaninaA mononuclear cyclometalated acetate platinum complex (ppy)Pt(Py)(OAc) (1) was prepared by a convenient synthetic approach. The target compound was isolated in three different polymorphic modifications, with variation of number of...The content of this RSS Feed […]Egor Sosunov
- Imidazo[1,5]carbachlorin as a hybrid ligand October 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03034F, PaperKinga Szydełko, Sebastian Koniarz, Michał J Bialek, Piotr Jan ChmielewskiA family of novel complexes of imidazo[1,5]carbachlorin has been synthesized and characterized by spectroscopic, X-ray diffraction, and electrochemical methods. In most of these compounds, both macrocyclic crevice and the fused...The content of this RSS Feed (c) The Royal Society of […]Kinga Szydełko
- Exploring early transition metal coordination: a synthetic and computational study of tripodal ligand complexes October 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01888A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jewelianna M. Moore, Brennan M. Vaught, Tabitha J. Miller, George Nunn, Lindsey S. Elford, Kelly L. Gullett, Paul H. Walton, Alison R. FoutThe synthesis of early transition metal complexes with a tripodal ligand reveals […]Jewelianna M. Moore
- Study on voltage-selective urea oxidation over NiTi@Ni(OH)2 October 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02151K, PaperTaozhu Li, Yu LiangNiTi alloys for urea electrooxidation: Ni(OH)2 formation, potential-tunable selectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryTaozhu Li
- Enhancing hybrid supercapacitor performance using porous bimetallic nickel cobalt telluride hexagonal nanoplates October 14, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01242B, PaperAkbar Mohammadi Zardkhoshoui, Hadi Arabdashti, Saied Saeed Hosseiny DavaraniPorous NiCoTe hexagonal nanoplates are fabricated for supercapacitors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryAkbar Mohammadi Zardkhoshoui
- Effect of the Counter Anion to Slow Magnetic Relaxation of Hexacoordinate Co(II) Complexes. October 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01360G, PaperMagdalena Malik, Alina Bieńko, Roman Boca, Jan Titis, Cyril Rajnák, Anna Świtlicka, Dariusz Bieńko, Mykhaylo Ozerov, Andrew OzarowskiThree mononuclear Co(II) complexes have been synthesized and structurally fully characterized by X-ray crystallography and physicochemical methods. They contain trans-{CoIIN2O4} for 1 and 2, but cis-{CoIIN2O4} for 3. Ab initio...The content of […]Magdalena Malik
- Understanding the effect of hydrogen bonding on the structural transition and emission properties in zero-dimensional hybrid metal halides: (3,5-DMP)3BiX6 (X = Cl, Br, I) October 14, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01876E, PaperSubhasish Sahoo, Rajanikanta Rana, Chakali Srinivas, Parameswar Krishnan Iyer, Laxmipriya Dash, Himansu S. Biswal, Saroj L. SamalSignificant H-bonding-induced (BiCl6)3− polyhedral distortion favours localized self-trapped excitons, leading to superior photoluminescent properties in (3,5-DMP)3BiCl6 over Br and I-analogues.To cite this article before page numbers are assigned, use the DOI form of […]Subhasish Sahoo
- Coke-Induced Deactivation in Zeolite Catalysts: Mechanisms, Anti-Coking Modifications, and Regeneration Approaches October 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01936B, PerspectiveMengdi Zhang, Jing Huang, Fanshuo Meng, Chundong Zhang, Zunmin ZhangZeolite catalysts, widely employed in petrochemical and refining processes, inevitably undergo gradual deactivation under industrial conditions. Among the various deactiva-tion pathways, coke-induced deactivation is the most critical, arising from the...The content of this RSS Feed (c) The Royal Society of […]Mengdi Zhang
- Recent advances and application of triazol-5-ylidene (MIC) adducts of the type MIC•E (E = BR3, CS2, CO2, CSN) and related mesoionic MIC=X (X = CR2, NR) species October 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01889G, FrontierMaria Guadalupe Torres-Salazar, Emmanuel Campos-Dominguez, Alejandro Alvarez-Hernandez, Daniel Mendoza-EspinosaN-heterocyclic carbenes (NHCs) are distinguished as exceptional nucleophiles capable of forming stable adducts when treated with a variety of electrophiles. Indeed, it has been reported that the nucleophilic attack of...The content of this RSS Feed (c) The Royal Society of ChemistryMaria Guadalupe Torres-Salazar
- In situ synthesis of NiMn-LDH-decorated CuCo2O4 core–shell nanoflowers on copper foam for high-performance supercapacitor October 13, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02073E, PaperShukai Zhang, Shiping Luo, Aijuan XieThe development of supercapacitors with high energy density and excellent multiplicity faces a key technological hurdle: optimizing energy storage and charge transfer efficiency in electrode materials.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Shukai Zhang
- Integration of noble metals with metal–organic frameworks for enhanced photocatalytic CO2 reduction October 13, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01635E, FrontierXiang-Yu Lu, Pei-Pei Cui, Wei-Yin SunThis frontier paper summarizes strategies for combining noble metals with MOFs to promote CO2 photoreduction from three key perspectives, offering insights for development of next-generation high-performance photocatalysts.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Xiang-Yu Lu
- Simulant chemistry for uranium and plutonium molten fuel salts: crystallographic investigation and thermodynamic modelling assessment of the NaCl-RECl-3 and NaCl-MgCl2-RECl3 (RE = Ce, Nd) systems October 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01486G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dennis Charley Alders, Ana Sacristán, Mädchen Wolff, Elisa Capelli, Christoph Hennig, Eleanor L Bright, Rudy Johannes Maria Konings, Anna Louise Louise SmithIn this study, new insights into the solid state chemistry of the systems […]Dennis Charley Alders
- Synthesis and cytotoxic activity of morpholino-s-triazine derivatives of POCOP-Ni(II) pincers October 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01322D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juan Sebastián Serrano-García, Andrés Amaya-Flórez, Antonino Arenaza-Corona, María Teresa Obdulia Ramírez-Apan, Adrian L. Orjuela, Jorge Alí-Torres, Marcos Flores-Alamo, Simon Hernandez Ortega, Patricia Cano-Sánchez, David Morales-MoralesSix POCOP-Ni(II) complexes (2, 3a, 3b, 4, 5, 6) bearing […]Juan Sebastián Serrano-García
- CNT serial copper-phenylacetylide to construct high-speed charge transfer/separation channels for effective photocatalytic degradation of PAHs October 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01783A, PaperHui-Ying Sun, Yueying Xu, Bailing Liu, Huaqiao TanThe teratogenicity, carcinogenicity and mutagenicity of polycyclic aromatic hydrocarbons (PAHs) pose a serious threat to human health. Due to their high bond energy aromatic ring structure and strong hydrophobicity, the...The content of this RSS Feed (c) The Royal Society of ChemistryHui-Ying Sun
- RCuMg2 compounds (R = Dy–Tm, Lu): crystal structure, chemical bonding and magnetic properties October 12, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01632K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.P. Solokha, D. Skachko, R. Freccero, J. Kortus, R. Gumeniuk, S. De NegriA combined study on the five {Dy, Ho, Er, Tm, Lu}CuMg2 new compounds was conducted following three main lines: crystal structure, chemical bonding […]P. Solokha
- Construction of high-performance single-molecule magnets with a high-axiality coordination environment surrounding a lanthanide spin center based on macrocyclic ligands October 12, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01658D, PerspectiveHan Yan, Wen-Bin SunThis review provides important guidance for designing high-performance SMMs from the perspective of coordination chemical synthesis involving macrocyclic compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryHan Yan
- Unveiling the interplay: comparing solvent extraction, structure, and stability constants in a phenanthroline diamide system with trivalent lanthanides October 12, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01636C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Emma M. Archer, Correy R. Vigil, Shane S. Galley, Jessica A. Jackson, Jenifer C. ShaferPhenanthroline diamide ligands have shown promise as extractants for the selective separation of the An(III) from the Ln(III) in used […]Emma M. Archer
- Organometallic Nickel NCN Pincer Complex Promotes L-Lactate Racemization in Water October 17, 2025
