RSC – Dalton Trans. latest articles- Photoinduced NO production from mononuclear {MnNO}6 complex bearing a metal-diaryldisulphide ligation March 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00165J, PaperYu-An Cheng, Su-Ying Chien, Peter Ping-Yu Chen, I-Jui Hsu, Chien-Ming LeeA solution of six-coordinate [Mn(PS2)2] (1) is inert towards nitric oxide (NO) at room temperature. In the presence of a proton source such as p-toluenesulfonic acid or perchloric acid, however,...The content of this RSS Feed (c) The Royal Society […]Yu-An Cheng
- Exploring the effect of Ru(II) arene complexes on cytotoxicity upon co-ligand variation and loading on amine functionalized silica nanoparticles March 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03536D, PaperSrijita Pal, Pragti Porwal, Amardeep Kumar, Suman MukhopadhyayTo overcome the undesirable side effects and acquired resistance associated with platinum based chemotherapeutics, scientists are searching for alternative strategies involving novel metal-based compounds having improved pharmacological properties. Ruthenium complexes...The content of this RSS Feed (c) The Royal Society of ChemistrySrijita Pal
- Exploring pseudocapacitive performance in Cr2CTx/NiFe2O4 composites: experimental insights March 30, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00446B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Madhushree R, Kalathiparambil Rajendra Pai SunajadeviCr2CTx/NiFe2O4 heterostructures have been hydrothermally synthesized for high-performance energy storage appication. The asymmetric device achieves a specific capacitance of 486.66 F g−1 with high energy density and power density.To […]Madhushree R
- Development of six-membered saturated cyclic diaminocarbene in main-group chemistry March 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00648A, PerspectiveGargi Kundu, Sakya Singha SenIn recent years, there has been a remarkable surge in the utilization of saturated N-heterocyclic carbenes (NHCs) as ligands in main group chemistry. While the field has predominantly focused on...The content of this RSS Feed (c) The Royal Society of ChemistryGargi Kundu
- Revisiting the structure and properties of mid-valent monopentamethylcyclopentadienylchromium complexes March 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00620A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Adrián Calvo-Molina, Jesús Jover, Adrian Perez-Redondo, Carlos YelamosThe structure and properties of half-sandwich chromium complexes derived from the dinuclear chloride compound[{CrCp*(μ-Cl)}2] (1)(Cp* = η5-C5Me5)are revisited.Complex 1 does not react with H2 and N2 but […]Adrián Calvo-Molina
- Stereochemically (In)active lone pairs in Sb(III) complexes of a soft scorpionate ligand March 30, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00261C, PaperMads Sondrup Møller, Vickie McKee, Christine J. McKenzieBis-homoleptic antimony complexes of hydrotris(3-methyl-2-thiooxoimidazolyl) borate (TMe) crystallize as either a penta- or hexa-coordinated isomer of [Sb(TMe)2]+; [Sb(κ3-TMe)(κ2-TMe)]+ or [Sb(κ3-TMe)2]+, depending on the counter anion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Mads Sondrup Møller
- Bulkiness effect dependent photosalient behaviours of photoactive cadmium coordination polymers March 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00208G, CommunicationQing-Shu Dong, Ning Wang, David James Young, Fei-Long Hu, Yan MiThree benzoic acids with different bulkiness of side chain groups of –Cl, –NO2 or –CH (CH3)2 were employed to modulate the CP frameworks and further tune the [2 + 2] photocycloaddition reaction and the photosalient behaviors.To cite this article […]Qing-Shu Dong
- Enhancing the hydrogen evolution activity of diiron molecular electrocatalyst by modulating substituent effect of carbon nanotubes March 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00138B, PaperPei-Hua Zhao, Shao-Jie Wang, Fan-Zeng Wei, Xue Su, Hui GaoDesigning molecular catalysts to enhance hydrogen evolution activity presents both great significance and challenges. In hydrogenases, the redox group (i.e., [4Fe4S] subcluster) near catalytic active center (i.e., [2Fe2S] subcluster) plays...The content of this RSS Feed (c) The Royal Society of […]Pei-Hua Zhao
- Copper(II) complexes with (E)–4–(2–(pyridin–2–ylmethylene)hydrazinyl)quinazoline and non–steroidal anti–inflammatory drugs: Structure and biological evaluation March 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00435G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chrisoula Kakoulidou, Antonios Hatzidimitriou, George L PsomasFour novel Cu(II) mixed−ligands complexes containing the quinazoline (E)−4−(2−((pyridin−2−yl)methylene)hydrazinyl)quinazoline (HL) or its methoxylated derivative (HL1) and a non−steroidal anti−inflammatory drug (mefenamic acid, flufenamic acid, diflunisal or diclofenac) as […]Chrisoula Kakoulidou
- Synthesis of Pyridine-Functionalized Cyclic Aromatic Triamide and Formation of Copper Coordination Polymeric Complexes March 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00369E, CommunicationKoji Takagi, Taiga Shirai, Daiki Miyamoto, Takuya Nakashima, Tomoyuki Ikai, Yutaka Ie, Takanori FukushimaPyridine-functionalized cyclic aromatic triamide (C3A-1EPy) was synthesized by Stille cross-coupling reaction and the chiroptical properties of the separated enantiomers were investigated using CD and CPL spectra. Two copper coordination polymeric...The content of this RSS Feed (c) […]Koji Takagi
- Enhanced Methods for the Undecachlorination of [HCB11H11]- and Syntheses of [XCB11¬Cl11]- from [HCB11¬Cl11]- (X = Cl, Br, I, NH2) March 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03033H, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jack P. Raker, Jovanny J. Contreras, S. Olivia Gunther, Oleg V. OzerovUtilizing SbCl3/SbCl5 mixtures at reflux, or of TCCA in a solid-solid reaction at 200 °C (with properly described precautions) are described as reliable […]Jack P. Raker
- Stepwise transformation of a redox-active tetradentate ONNO ligand in the coordination sphere of tin(IV) March 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00430F, PaperIrina N Meshcheryakova, Anton Cherkasov, Maxim V. Arsenyev, Rinat R. Aysin, Alexey A Belikov, Artem Bogomyakov, Natalia A. Protasenko, Tatiana Kocherova, Svetlana V. Baryshnikova, Alexandr Vladimirovich PiskunovNew diorganotin(IV) complexes based on a redox-active tetradentate ONNO ligand, namely N,N'-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine (LH4) were synthesized. A methodology for the stepwise oxidation of tin(IV)-ONNO […]Irina N Meshcheryakova
- An iron and lanthanide heterobimetallic coordination polymer derived electrocatalyst showing Enhanced activity and stability for oxygen reduction reaction March 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00376H, PaperXin Liu, Pengpeng Guo, Kun-Zu Yang, Yong-Zhi Su, Chao Xu, Jin-Gang LiuIt is desirable to develop noble-metal-free electrocatalysts with both excellent activity and stability for the oxygen reduction reaction (ORR) in clean energy conversion devices. Herein, we report an Fe, La...The content of this RSS Feed (c) The Royal […]Xin Liu
- Stabilization of lead-free bulk CsSnI3 perovskite thermoelectrics via incorporating of TiS3 nanoribbon clusters March 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00326A, PaperAlexandra Ivanova, Lev Luchnikov, Dmitry S. Muratov, Margarita Golikova, Danila Saranin, Aleksandra Khanina, Pavel Gostishchev, Vladimir V KhovayloThe intense research for efficient low-temperature thermoelectric materials motivates the exploration of innovative compounds and composite systems. This study examines the effects of integrating low-dimensional titanium trisulfide (TiS3) into bulk...The content of […]Alexandra Ivanova
- Combination of 5-Amino-4-nitro-1,2-dihydro-3H-pyrazol-3-one and Azine Frameworks for Insensitive Heat-resistant Energetic Materials March 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00488H, PaperXiue Jiang, Ruihui Wang, Mingren Fan, Siwei Song, Yi Wang, Qinghua ZhangThe 5-nitro-1,2,4-triazol-3-one (NTO) is an important insensitive and high energy aromatic ketone compound in energetic materials. But its relatively low thermostability (Td: 236.0 °C) limits the application in heat-resistant energetic...The content of this RSS Feed (c) The Royal […]Xiue Jiang
- Investigating the Stable Structures of Yttrium Oxide Clusters: Yn Clusters as Promising Candidates for O₂ Dissociation March 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00357A, PaperVarun Vinayak Deshpande, Debashis Bandyopadhyay, Vaibhav Chauhan, Gayatri Kumari, Soumen BhattacharyyaThe study presents threshold photoionization (PI) spectra for a series of yttrium oxide clusters (YnOm, m = 2–8, n = 2–4) in the photon energy range of 192 to 300...The content of this RSS Feed (c) The Royal Society […]Varun Vinayak Deshpande
- Selective synthesis of a heterotetranuclear complex from a macrocyclic ligand with multiple identical chelating units March 27, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00623F, CommunicationKota Seki, Takashi NakamuraStepwise complexation via site-selective coordination has enabled the synthesis of a heteronuclear complex from a macrocyclic homooligomer.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryKota Seki
- Electrochemical sensing properties of cobalt-based coordination polymers for trace L-tryptophan in milk March 26, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00116A, PaperYichen Liu, Zhongqin Zhao, Rui Xin, Duqingcuo Li, Xiuyan Dong, Aparna Kushwaha, Mohammad Khalid Parvez, Mohammed S. Al-Dosari, Abhinav Kumar, Yong HuangTwo complexes 1 and 2 were synthesized via a hydrothermal method and their electrochemical sensing behavior for L-tryptophan (L-Try) was investigated. In addition, the sensor successfully detected L-Try […]Yichen Liu
- Solvent-directed assembly in MOFs with linear trinuclear cobalt(II) nodes: formation of inverted Figaro chains March 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00149H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Oluseun Akintola, Helmar Görls, Winfried PlassFour new cobalt(II) coordination networks based on the nitrilotribenzoic acid ligand (H3ntb) with the formula {[Co3(ntb)2(solv)2]}n (where solv = dmf, def, dma, and EtOH), denoted as JUMP-4(solv), are reported. […]Oluseun Akintola
- Charge optimization induces reconstruction via compounding Ni(OH)2 and CoP: a novel route to construct electrocatalysts for overall water-splitting March 26, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00056D, PaperHao Yin, Bingxian Wu, Xueyang Leng, Hong Gao, Jing YaoCompounding Ni(OH)2 and CoP to adjust the charge distribution can lead to the facilitation of surface reconstruction, thereby improving electrocatalytic activity. The resulting Ni(OH)2/CoP electrocatalyst exhibited excellent catalytic performance.To cite this article before page numbers are assigned, use the DOI […]Hao Yin
- Photoinduced NO production from mononuclear {MnNO}6 complex bearing a metal-diaryldisulphide ligation March 30, 2025
