RSC – Dalton Trans. latest articles- Assessing structure and dynamics of iron complexes supported by tris(amidate)amine ligands June 18, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01284H, PaperLucy Huffman, Anjana Seshadri, Christopher D. Hastings, William W. Brennessel, Ignacio Franco, Brandon R. BarnettChelating ligand platforms derived from tris(2-aminoethyl)amine (TREN) can facilitate low coordination numbers and provide opportunities to tune the steric and electronic profile of the secondary coordination sphere. Herein, we examine...The content of this RSS Feed […]Lucy Huffman
- Carboranyl Diphosphenes: Synthesis, Structure and Reactivity June 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01239B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tek Long Chan, Jie Zhang, Zuowei XieCarboranyl-diphosphenes {1-P-2-[C(tBu)=N(Ar)]-1,2-C2B10H10}2 [Ar = Dmp (6) or Ph (7); Dmp = 2,6-Me2C6H3, Ph = C6H5] are prepared in good yields by the reduction of iminocarboranyldichlorophosphines 1-PCl2-2-[C(tBu)=N(Ar)]-1,2-C2B10H10 [where Ar […]Tek Long Chan
- Electrochemical synthesis of palladium N-heterocyclic carbene (NHC) complexes June 17, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00575B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Roman V. Larkovich, Francis Bru, Maxime R. Vitale, Laurence Grimaud, Catherine S. J. CazinPd–NHC complexes are shown to be accessible through a novel aerobic electrochemical synthetic strategy.To cite this article before page numbers are […]Roman V. Larkovich
- Visible-light-driven photocatalytic CO2 reduction using ruthenium complexes having a CNC-type pincer ligand: comparison of substituent effect on a CNC ligand June 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00900F, PaperYasuhiro Arikawa, Momo Morinaga, Miyu Kubota, Kenichiro Omoto, Eri Sakuda, Keisuke UmakoshiA series of ruthenium complexes bearing a CNC-type pincer ligand with different substituents (CF3, H, and OMe) were synthesized and characterized for visible-light-driven photocatalytic CO2 reduction. The photocatalytic reactions were...The content of this RSS Feed (c) The Royal […]Yasuhiro Arikawa
- Cumulative Enhancement Effect of Proton Conductivity in the Possible Hydrogen Fuel Cell Material Dysprosium Sulfate June 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01177A, PaperJinxiang Yang, Jiasheng Wang, Bo Li, Yuqing Yan, Zhiwu Qiao, Haibo Liu, Yicong ZhuIn this study, we successfully synthesized an anhydrous crystalline material based on the lanthanide metal dysprosium coordinated with the sulfate ligand. This material exhibits a unique cumulative enhancement effect: during...The content of this RSS Feed (c) […]Jinxiang Yang
- Oxidative addition of Si H bonds to metal-decorated Zintl clusters [Hyp3Ge9Ir(CO)PR3] (R = Ph, ptolyl, Me) June 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01147G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nicole Willeit, Tim Kratky, Viktor Hlukhyy, Sebastian Guenther, Thomas F FässlerCatalytic reactions with metalated Zintl cluster as catalysts are an increasing research field, whereby the concept of heterogeneous single site catalysis is transferred towards […]Nicole Willeit
- Bismuth dithiocarbamate complexes as anticancer agents and beyond: a comprehensive review June 17, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00656B, PerspectiveDeepika Verma, Kiran Gupta, Snober S. Mir, Om PrakashThis review highlights the synthesis, anticancer mechanisms, antimicrobial and antileishmanial activities, and diagnostic applications of bismuth dithiocarbamate complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal […]Deepika Verma
- Design of new thorium nuclear clock materials based on polyatomic ions June 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00736D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Harry William Toriel Morgan, Hoang Bao Tran Tan, Andrei Derevianko, Ricky Elwell, James Terhune, Eric R Hudson, Anastassia AlexandrovaCompounds of polyatomic anions are investigated theoretically as hosts for thorium in nuclear clock devices. The […]Harry William Toriel Morgan
- Copper(II) Complex with a Redox Noninnocent Schiff Base Bearing a Tetraphenyldisiloxane Unit: Synthesis, Structure and Catalytic Oxidation of Cyclohexane June 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01028D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vladimir Arion, Christopher Wittmann, Oleg Palamarciuc, Mihaela Dascalu, Maria Cazacu, Dmytro Nesterov, Armando J. L. Pombeiro, P. RaptaAn organic-inorganic diamine, 1,3-bis(aminopropyl)tetraphenyldisiloxane was prepared and introduced as a flexible spacer in the structure of a […]Vladimir Arion
- Rapid and sensitive determination of etomidate based on colorimetric assays with chromium(III) complex June 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00849B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leo K B Tam, Weijun Ma, Boyang Li, Waygen Thor, Ho-Fai Chau, Ka Leung WongVaping etomidate with E-cigarette is currently a red-hot social issue in Hong Kong and China, in which the drug abuse […]Leo K B Tam
- Crystal to non-crystal transformation in a Sn-based MOF anode with long cycle life for lithium storage June 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01226K, CommunicationJianbo Xiong, Ruoyu Wang, Jianhua Ding, Zaozao Wu, Qing Li, Hao Wang, Dongming Li, Zhipeng Yu, Yao Chen, Xiao-Lan TongA tin-based MOF (Sn(HHTP)) was synthesized for lithium storage via incorporating tin (Sn) nodes with lithium-active ligand (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene), which undergoes a transformation from crystalline to amorphous state during...The […]Jianbo Xiong
- Aromatic dicarboxylates induced structural diversity of CdII metal-organic frameworks from 2D layer to 3D pillar-layer network for fluorescence sensing cations, anions and L-serine June 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00305A, PaperHong-Li Yang, Rui-Jie Zhang, Teng-Fei Zheng, Chen Cao, Yan Peng, Jing-Lin Chen, He-Rui Wen, Sui-Jun LiuTwo distinct CdⅡ metal-organic frameworks (MOFs) with the formula {[Cd(BBZB)(oba)]n•H2O}n (JXUST-45) and {[Cd(BBZB)(bpdc)]•2H2O}n (JXUST-46) featuring 2D layer and 3D pillar-layer structures, respectively, have been prepared, which were regulated by aromatic...The content of this RSS […]Hong-Li Yang
- Bifunctional MOFs possessing both proton conductivity and fluorescence detection capabilities June 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00896D, PerspectiveYining Zhang, Xuebin Shang, Zhiyang Qi, Penglin Zhang, Chenxi Zhang, Qinglun WangThis review described recent advances in bifunctional metal–organic frameworks (MOFs) with both proton conduction and fluorescence sensing capabilities, providing valuable insights into the multifunctional synergistic mechanisms of MOFs.To cite this article before page numbers are assigned, use the […]Yining Zhang
- Structural Characterization of a Dicoordinated Bis(ferrocenyl)aluminum Cation June 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00966A, PaperTogo Anzai, Koh Sugamata, Shogo Morisako, Takahiro SasamoriThis study reports on the synthesis and structural characterization of a stable dicoordinated organoaluminum cation. The bis(ferrocenyl)aluminum cation, featuring sterically encumbered ferrocenyl substituents, was isolated and its solid-state structure analyzed...The content of this RSS Feed (c) The Royal Society of ChemistryTogo Anzai
- Magnetic Fe3O4@AuPd/PDA Nanospheres Exhibit Enhanced Catalytic Effects and Photothermal-magnetic Coupling Antibacterial Properties. June 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00865D, PaperJie Jin, Haoran Li, Yunqi Xu, Qunling Fang, Xia Chen, Weili Kong, Shouhu XuanPathogenic microorganisms and recalcitrant pollutants in water present a persistent and severe threat to human health. Consequently, there is an urgent need to develop an integrated solution that not only...The content of this RSS Feed (c) […]Jie Jin
- Structural stability and polymorphic transitions in LnSI (Ln = lanthanides) June 12, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00753D, PaperShohei Kawanishi, Suguru Yoshida, Hiroki Ubukata, Congling Yin, Yang Yang, Ryusei Morimoto, Simon J. Clarke, Hiroshi KageyamaChemical substitution and physical pressure drive Martensitic-like polymorphic transitions among FeOCl-, SmSI-, and SrI2-type structures in LnSI mixed-anion compounds, governed by the cation-to-anion radius ratio as a unifying geometric factor.To cite this article […]Shohei Kawanishi
- Heterobimetallic unsaturated silicon clusters (siliconoids) with transition metal-expanded scaffolds June 12, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01135C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Luisa Giarrana, Nadine E. Poitiers, Alida Stürmer, Michael Zimmer, Volker Huch, Bernd Morgenstern, David ScheschkewitzWe report the cluster expansion to an anionic iridasiliconoid with rare Ir–Li interaction revealing structural resemblance to the homonuclear Si7-species.To […]Luisa Giarrana
- Trinuclear rare earth pyridyl-β-diketonate complexes: developing new methods towards finding lost toroidal spin states June 12, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01067E, PaperPatrick Mangundu, Kate E. Tanner, Andrew Bloomfield, Peter J. Barnard, Keith F. White, Curtis C. Ho, Nageshwar R. Yepuri, Richard A. Mole, Rebecca O. FullerA series of rare earth (RE) ‘triangles’ have been synthesised to investigate the low energy excitations of toroic molecules using inelastic neutron scattering (INS) experiments.To […]Patrick Mangundu
- Relating structure, composition, and spin crossover properties in Hofmann complexes June 12, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01192B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hanna Boström, Matthew G. RobbSpin crossover (SCO) is attractive for applications within e.g. sensing or solid-state cooling,but controlling the properties is extremely challenging. Hofmann complexes, with formulaFeLx M(CN)4 ·G (L = organic ligand, G...The […]Hanna Boström
- Morphology-Controllable Cu2SnS3 Quantum Dots Sensitized Solar PEC Cells For Efficient Hydrogen Production June 12, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00955C, PaperAo Chen, Chuang Chen, Shuai Shao, Yang Lian, Yunlong Du, Yunna Gao, Jinwen Yi, Wei ZhengThe shape and size regularity of quantum dots (QDs) significantly influence the photoelectrical properties in solar photoelectrochemical (PEC) cells. Two types of green Cu2SnS3 (CTS) QDs, sphere-like and bullet-like, were...The content of this RSS […]Ao Chen
- Assessing structure and dynamics of iron complexes supported by tris(amidate)amine ligands June 18, 2025
