RSC – Dalton Trans. latest articles- Synergistic WO₃-PBI Hybrid Electrochromic Materials with Enhanced Diffusion Coefficient and Cycling Reversibility Inspired by "Big Rocks" Theory August 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01423A, PaperChunxia Hua, Huanyu Tan, Shujin Ma, Jiaxue Hou, Ming Gong, Jia Chu, Xiaoqin Wang, Shanxin XiongThe key technology underlying intelligent energy conversion and display systems hinges on high-performance electrochromic materials. To derive their electrochemical redox reactions, facilitating ion/electron transport and intercalation/deintercalation via the rational design...The content of this RSS […]Chunxia Hua
- Magnetic order in the disordered NiCr(BO₃)O August 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01230A, PaperYulia Sergeevna Gokhfeld, Natalia Kazak, Anastasia Sergeevna Tarasova, Aleksandr Sukhikh, Dmitry Velikanov, E. V. Eremin, Oleg Kondratev, Anna O. Belyaeva, Sergey Yu. Gavrilkin, Alexander D. Vasil'ev, Sergei G OvchinnikovA novel oxyborate, NiCr(BO₃)O, has been synthesised using a flux. This material crystallises in an orthorhombic warwickite-like structure, space group Pbnm […]Yulia Sergeevna Gokhfeld
- Construction of 2,2':6',2''-Terpyridine Modified Porous Organic Polymers via Building Unit Engineering: Preferred and Universal Transition Metal Carrier and Catalytic Application August 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01504A, PaperZhengguang Li, Yaqin Li, Yongxin Liu, Kaixiu Li, Fan Fu, Mingliang Liu, Jie Yuan, Tao Zhang, Jun Wang, Yiming Li, Fenghua Shen, Hui Liu, Pingshan Wang, Die LiuPorous organic polymers (POPs) serve a key function as transition metal carriers and have drawn widespread attention in the catalysis field. However, […]Zhengguang Li
- Preparation of Selenium Doped CuCoO2 Nanosheets as an Efficient Electrocatalyst for the Oxygen Evolution Reaction August 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01517K, PaperQingyang Shen, Lihong Zhao, Jilin Bai, Chao Jiang, Yue Mi, Wei Liao, Dehua XiongHydrogen is a renewable clean energy source that is expected to replace traditional fossil fuels. The key technology for producing hydrogen from electrolyzing water depends on the efficiency and cost...The content of this RSS Feed (c) […]Qingyang Shen
- Structural, Spectroscopic, Theoretical, and Magnetic Investigations of a Novel Cubane-like Tetranuclear Copper(II)-Hydrazone Complex August 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01463H, PaperLucia Santa maria de la parra, Leonardo E. Riafrecha, Gustavo A. Echeverría, Luis Lezama, Oscar Enrique Piro, Diego M. Gil, Antonio Frontera, Ignacio LeonThis study details the synthesis of a novel ligand, (E)-5-chloro-N'-(2-hydroxy-3-methoxybenzylidene) thiophene-2-carbohydrazide ligand (for short, H2L), and its tetranuclear Cu(II) complex (Cu4L4), together with their X-ray crystal […]Lucia Santa maria de la parra
- Significant electrochemical performance improvement for anion MOF-based solid-state electrolyte across wide temperature range via ion exchange strategy August 3, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01485A, PaperChangqi Gu, Wenyu Ding, Sheng Jin, Xinyu Tang, Xin Zhang, Li Fan, Zhiliang Liu, Xiaomin KangAbstract: Low ionic conductivity (σ) and high activation energy (Ea) seriously hinder the development of solid-state electrolytes (SSEs). Herein, a series of post-modified Li⁺@Ni-MOF-X (X = 1, 2, 3) materials...The content of this RSS […]Changqi Gu
- Dynamic processes of the First NHC-Substituted Rhenium Heptahydrides [ReH7(NHC)2] August 3, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01655J, PaperPasquale Gabriele Grieco, Adriano Pierini, Marco PieriniIn this paper are presented possible geometries and fluxional mechanisms of three [ReH7(NHC)2] complexes (NHC= IMes (1) (1,3-bis(2,4,6-trimethyl phenyl) imidazol-2-ylidene), IMesCl2 (2) (4,5-dichloro-1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene), BIMes (3) (1,3-Bis(2,4,6-trimethylphenyl)-benzo imidazole ylidene). Using DFT...The content of this RSS Feed (c) The Royal Society of ChemistryPasquale Gabriele Grieco
- Bi-doped CoTe Nanoparticles For Nonlinear and Optoelectronics Applications August 3, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01043H, PaperSwikruti Supriya, Gangamani Tudu, Prabhukrupa Chinmay Kumar, Monalisa Pradhan, Ramakanta NaikThe exceptional properties and broad applicability of CoTe nanoparticles make them highly relevant for various technological applications, particularly in optoelectronics. Introducing a metal dopant into a nanomaterial matrix has been...The content of this RSS Feed (c) The Royal Society […]Swikruti Supriya
- Silver Dithiocarbamates Derived from Amino Acid Esters August 3, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01476J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vreni Behling, Jakob Heinrich, Dolores Díaz, Elias Heiko Paul Brohmer, Julian Heinrich, Nils Schloerer, Stephan Kupfer, Nora Kulak, Phil KöhlerWe report herein a series of new silver compounds with dithiocarbamate ligands derived from amino […]Vreni Behling
- Synthesis and characterisation of MoIV-oxo dithiolenes: formate dehydrogenase active site mimetics August 3, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01233C, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Isaac J. Furney, Joseph A WrightThe active sites of metalloezymes continue to inspire synthetic chemists to create structural models of the intricate structures seen in biology. As well as the fundamental intellectual challenge, this […]Isaac J. Furney
- The miracle of self-assembly: a journey of the {Ln6F8} core in the world of lanthanides August 3, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01105A, PaperEvgeny D. Boltkov, Mikhail E. Buzoverov, Elmira Kh. Lermontova, Yury A. Belousov, Dmitry A. Steshenko, Victoria E. Gontcharenko, Tatyana Yu. GlazunovaIn this work, a wide range of compounds with the structural fragment {Ln6F8} has been obtained for the first time.To cite this article before page numbers are assigned, use […]Evgeny D. Boltkov
- Crystal Engineering of Dinitropyrazine-Based Sodium E-MOFs: Toward Thermally Robust and Low-Sensitivity Energetic Materials August 3, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01508A, PaperManojkumar Jujam, Abhishek Kumar Yadav, Srinivas DharavathThe strategic development of thermally stable and low-sensitive energetic materials is vital for next-generation defence and aerospace applications. Herein, we report the synthesis of novel three-dimensional energetic metal–organic frameworks (E-MOFs),...The content of this RSS Feed (c) The Royal Society of ChemistryManojkumar Jujam
- Varying Anion Coordination in New Families of Dinuclear NiIILnIII Complexes: Zero Field Slow Relaxation of Magnetization and Theoretical Validations August 1, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03529A, PaperBiswarup Dutta, Ibtesham Tarannum, Zvonko Jaglicic, Saurabh Kumar Singh, Debashis RayHerein we report the room-temperature synthesis, structural accounts, and magnetic performances of two new families of dinuclear NiII–LnIII complexes, [NiLn(HL)2(NO3)3]·nH2O·CH3CN (1a-1c) (n=1for Ln = Tb and n= 1.5 for Dy,...The content of this RSS Feed (c) The Royal Society […]Biswarup Dutta
- Supramolecular assemblies and nanoparticle integration studied through quantitative image analysis and 3D reconstruction July 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01505G, PaperDaeun Jeong, Hyoung Wook Kang, Seojeong Woo, Semi Kim, Soo Ryeon Yoon, Jaedeok Lee, Cheongwon Bae, Ho-Jun Cho, Mingyu Gu, Jong Hwa Jung, Ju Hyun Kim, Kwang Seob Jeong, Sung Ho Jung, Juyeong KimNanoparticle incorporation to supramolecular assemblies is essential for designing hybrid nanostructures with tailored optical and structural […]Daeun Jeong
- Ligand-driven redox transformations and catalytic activity of mononuclear copper complexes: structural and spectroscopic insights July 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01511A, PaperSoumen Rakshit, Jyotirmoy Mitra, Rajat Saha, Ram Chandra MajiEight mononuclear complexes have been synthesized, namely: [(L1)CuI]ClO4 (1), [(L2)CuI]ClO4·CH3CN (2·CH3CN), [(L2)CuII(DMF)](ClO4)2·2DMF·H2O (3·2DMF·H2O), [(L1)CuII(MeCN)](ClO4)2 (4), [(L1)CuII(Cl)]PF6 (5), [(tren)CuII(MeCN)](ClO4)2 (6), [(tren)CuII(Cl)]PF6 (7) and [(L2ˊ)CuII(DMF)](ClO4)2·DMF·H2O (8·DMF·H2O). In these complexes, copper atoms are...The content of this RSS Feed (c) The Royal Society of ChemistrySoumen Rakshit
- Coordination Clusters with [Ni4O4] Core as Catalysts for α‑Alkylation of Ketones with Benzyl Alcohols July 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00811E, PaperHari Pada Nayek, Kajal Kajal, Manish KumarThree tetranuclear Ni(II) compounds having molecular formula [Ni4L2(RCOO)2(MeOH)2]∙XH2O (1: R = Me and X = 7; 2: R = Ph and X = 6 and 3: R = 4-NO2-Ph and...The content of this RSS Feed (c) The Royal Society of ChemistryHari Pada Nayek
- Strategic Fluorine Atom Positioning in Carbazolyl Oxadiazole Derivatives: Constructing Asymmetric Ir(III) Complexes for Enhanced Electroluminescent Performance July 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01237F, PaperJia-Wei Liu, Xuecheng Wang, Li-Jing Wen, Hao-yu Chen, Jin-Xia Ren, Jie Li, Chang Liu, Yong-Hua Li, Bo Chen, Shi Wang, Kenneth Yin ZhangThe asymmetric coordination Ir(III) complexes hold promise as luminescent materials for organic light-emitting diodes (OLEDs). This study provides an efficient synthetic strategy for the construction of asymmetric […]Jia-Wei Liu
- N2O2S-Donor Redox-Active Ligand Coordinated Dinuclear Manganese(II) and Cobalt(II) Complexes: Crystal Structures, Magnetic Properties and Electrochemical Hydrogen Evolution† July 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00744E, CommunicationAsik Ikbal, Gouri Sankar Das, Sakshi Mehta, Suraj Agarwala, Chandra Shekhar Purohit, Nilankar Diyali, Abhishake Mondal, Bhaskar Biswas, Hari Sankar DasIn this study, we found the significant catalytic activity of two dinuclear complexes of manganese(II) and cobalt(II), supported by a biologically relevant pentacoordinated N2O2S-donor Schiff base ligand towards electrochemical […]Asik Ikbal
- Thio-iso-phthalamide Pincer Ligands Driven Oxidative Addition of a C-Br Bond to Gold(I): Synthesis and Studies of SCS-Gold(III) Pincer Complexes July 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00916B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Saravanan Raju, Sanhati Sharangi, Harkesh B Singh, Prabhuraj R S, Rohit Srivastava, R. J. Butcher, Sangit KumarThe chelating effect of thio-iso-phthalamide was utilized to facilitate the oxidative addition of the aryl Csp²-Br bond into […]Saravanan Raju
- A novel sensor behaviour of SDAB/MWCNTs to detect Cd(II) by electrochemical technique using oryza sativa L, egg yolk and camellia sinensis July 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01305D, PaperGayathri Jayagopi, Kumar Sangeetha Selvan, Sivakumar SivalingamThe present research endeavors to create a mercury-free electrode employing MWCNTs (nanotubes)/ SDAB ligand for measurement of Cd (II) via stripping voltammetry. In SEM with EDX, the modified electrode SDAB/MWCNTs/PGE...The content of this RSS Feed (c) The Royal Society of ChemistryGayathri Jayagopi
- Synergistic WO₃-PBI Hybrid Electrochromic Materials with Enhanced Diffusion Coefficient and Cycling Reversibility Inspired by "Big Rocks" Theory August 4, 2025
