RSC – Dalton Trans. latest articles- Solvents and their hydrogen bonding properties as general considerations in carbon dioxide reduction by molecular catalysts December 20, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT02682A, PaperXiaohan Li, Jeffrey J. WarrenSolvent hydrogen bonding properties exert a strong influence on electrocatalytic carbon dioxide reduction by molecular electrocatalysts.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryXiaohan Li
- Investigating the differences of active oxygen species and carbonate species on the surface of Ce0.95M (M = Mn and Zr)0.05O2−δ catalysts prepared by the aerosol method during CO oxidation using operando TPR-DRIFTS-MS December 20, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT02920H, PaperJiacheng Xu, Yan Sun, Shuiliang YaoMO plays a key role on the catalyst surface and can react with CO at low temperatures. Importantly, the high content of MO is conducive to the formation of monodentate carbonate (M–O–CO2).To cite this article before page numbers are assigned, use the DOI form […]Jiacheng Xu
- Study of multimodal light emissions from Pr3+/Yb3+ doped NaLa(MoO4)2 phosphors for optoelectronic devices and plant-growth applications December 19, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT02532F, PaperSonali Tomar, Neeraj Kumar Mishra, Vaibhav Chauhan, Kaushal Kumar, C. ShivakumaraRecent advancements in materials design have driven the scientific community to explore phosphor materials for multifunctional applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The […]Sonali Tomar
- Shape-responsive host-guest chemistry: metal-free tetra cationic porphyrin nonplanarity promoted by clay mineral interactions assessed by theoretical simulations December 18, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03437F, PaperEduardo Diaz Suarez, Filipe Camargo Dalmatti Alves Lima, Arles Victor Gil Rebaza, Vera R. Leopoldo Constantino, Helena Maria PetrilliDistortions in the porphyrin core from planarity can trigger a unique structure-property relationship, imparting its basicity, chemical stability, redox potential, and excited-state energetics, among other properties. The colour change promoted...The content […]Eduardo Diaz Suarez
- Two-fold proton coupled electron transfer of a Ta(V) aniline complex mediated by a redox active NNN pincer ligand December 18, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03281K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sotirios Pavlidis, Jasmin Alasadi, Amanda Opis Basilio, Josh AbbensethWe report the proton-coupled electron transfer (PCET) reactivity of an octahedral Ta(V) aniline complex supported by an acridane-derived redox-active NNN pincer ligand. The reversible binding of […]Sotirios Pavlidis
- Necrosis Inducing Tetranuclear Ru(II) - Re(I) Metal Complex for Anticancer Therapy December 18, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02992E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julia Schleisiek, Eleni Michaltsis, Stephan Mayer, Nicolas Montesdeoca, Johannes KargesChemotherapy is one of the most widely used anticancer treatments worldwide. However, despite its clinical effectiveness, most chemotherapeutic agents are associated with severe side effects. […]Julia Schleisiek
- Construction of ternary heterojunction photocatalyst Cu2Cl(OH)3/In/In2O3 for boosted photocatalytic CO2 reduction performance December 18, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03090G, PaperJiayang Huang, Yao Su, Zhangjie Qian, Miaoer Wu, Yunchang Xie, Chao ZengThe photocatalytic conversion of CO2 and H2O into useful chemicals or fuels over semiconductor photocatalysts is regarded as a promise technology to settle the problems of global warming and energy...The content of this RSS Feed (c) The Royal […]Jiayang Huang
- Rational side-by-side self-assembly of gold nanorods with short and medium aspect ratios via self-evaporation method to boost their potential as surface-enhanced Raman scattering (SERS) substrate December 18, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03259D, PaperKhương Quoc Võ, Thanh-Tuyen Thi Huynh, Anh Thu Nguyen, Trung Truong TanSurface-enhanced Raman scattering (SERS) represents a compelling detection methodology centered on the electromagnetic fields, commonly termed "hot spots", generated around noble nanoparticles. Nonetheless, the efficacy of electromagnetic field (EMF) amplification...The content of this RSS Feed (c) The Royal […]Khương Quoc Võ
- Extended chains in vanadium O-centered complex [V4OSe8I5]∞: synthesis and structure December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT02758B, PaperR. R. Galiev, V. Y. Komarov, M. R. Ryzhikov, S. G. Kozlova, V. A. Kuznetsov, E. D. Grayfer, S. B. Artemkina, V. E. FedorovO-centered tetranuclear vanadium selenoiodide [V4OSe8I5]∞ (1) was synthesized from the elements with the addition of a drop of water. It can also be assembled from the […]R. R. Galiev
- Rationally designed Cu(II) Schiff base metal complex anchored on NiFe2O4@chitosan: an efficient heterogeneous and magnetically retrievable hybrid nanocatalyst for the one-pot multi-component synthesis of bioactive 1-amidoalkyl-2-naphthols December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03009E, PaperSneha Paul, Pranjit BarmanWe reported, herein, the fabrication of a Cu(II) Schiff base metal complex, immobilized on chitosan surface coated on NiFe2O4 MNPs, intended as a novel heterogeneous and magnetically recyclable nanocatalyst, NiFe2O4@CS@CuSB.To cite this article before page numbers are assigned, use the DOI form of citation above.The content […]Sneha Paul
- [Cu(NHC)(OR)] (R = C(CF3)3) complexes for N-H and S-H bond activation and as pre-catalysts in the Chan-Evans-Lam reaction December 17, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03322A, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Steven P Nolan, Tommaso Ruggiero, Kristof Van Hecke, Catherine CazinThe synthesis, isolation, and full characterization of a series of NHC-copper perfluoro-alkoxide complexes are reported. Their exceptional stability resides with the steric hindrance of the […]Steven P Nolan
- Fabrication of 2D/2D Bi2MoO6/Sx@g-C3N(4-y) type-II heterojunction photocatalyst for enhanced visible-light-mediated degradation of tetracycline in wastewater December 17, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02334J, PaperSoorya K K, Adarsh Singh, Suneel K Srivastava, Animesh Bhattacharya, Amit Bhatnagar, Ashok Kumar GuptaAquatic biota and human health are seriously threatened by the dramatic rise in antibiotics in environmental matrices. In this regard, the present study aims to improve knowledge of the combined...The content of this RSS Feed […]Soorya K K
- Sr3Zr2Cu4Q9 (Q = S and Se): two novel layered quaternary mixed transition metal chalcogenides December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT02928C, PaperSayani Barman, Sweta Yadav, Akshay K. Ray, Swati, M. Deepa, Manish K. Niranjan, Jai PrakashTwo new isoelectronic compounds, Sr3Zr2Cu4S9 and Sr3Zr2Cu4Se9 have been synthesized. Photovoltaic and transport properties of these phases have been studied in detail.To cite this article before page numbers are assigned, use the DOI form of […]Sayani Barman
- Cu(II)-Mediated Tautomerization for the Pyrazole-Nitrile Coupling Reaction December 17, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02904F, CommunicationChang-Chih Hsieh, Chia-Wei Chen, Ming-Hsi Chiang, Yih-Chern HorngThis study investigates the mechanism of prototropic tautomerization in metal-bound asymmetric pyrazole (R-PzH) ligands during Cu(II)-mediated PzH-MeCN coupling reactions. Intrinsic prototropic tautomerization of metal-bound ligands has not been previously documented....The content of this RSS Feed (c) The Royal Society of ChemistryChang-Chih Hsieh
- A sulfur-templated Ni–Ni′ coordination polymer that relies on a polarizable nickel nitrosyl hub December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03174A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Manish Jana, Michael B. Hall, Marcetta Y. DarensbourgThe templating properties of a diazanickel-cis-dithiolate towards triphenylphosphinegold (d10-Au+) inspired the synthesis of {Ni-(NO)}10 as a redox-active and structurally mobile S-based adduct which was then condensed with […]Manish Jana
- Eu2Pt3Pb5 and SrPt2Pb4 — lead-based intermetallics with Y2Rh3Sn5 / NdRh2Sn4-type polyanionic platinum-lead 3D frameworks December 17, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03293D, PaperAnastasiya Yu Makhaneva, Elena Yu Zakharova, Sergey N Nesterenko, Sergey M. Kazakov, Konstantin Lyssenko, Alexey Bogach, Andrey Azarevich, Alexey N. KuznetsovTwo platinide plumbides, Eu2Pt3Pb5 and SrPt2Pb4, were discovered using high-temperature exploratory synthesis and flux-assisted crystal growth. Their crystal structures were determined from single-crystal X-ray diffraction. Both compounds crystallize in […]Anastasiya Yu Makhaneva
- Bisquinoline-based fluorescent cadmium sensors December 17, 2024Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02788D, FrontierYuji MikataRational molecular design afforded fluorescent Cd2+ sensors based on bisquinoline derivatives. Introduction of three methoxy groups at the 5,6,7-position of quinoline rings of BQDMEN (N,N’-bis(2-quinolylmethyl)-N,N’-dimethylethylenediamine) resulted in the reversal of...The content of this RSS Feed (c) The Royal Society of ChemistryYuji Mikata
- Thermoelectric and electrical properties of triple-conducting multicomponent oxides based on substituted barium cerate-zirconate December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT01992J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.M. M. Czudec, D. Jaworski, J. Budnik, A. Mielewczyk-Gryń, T. Subramani, M. Gazda, A. Navrotsky, T. MiruszewskiThe study explores multicomponent oxides based on substituted barium cerate-zirconate perovskites synthesized by a solid-state reaction. The structure, […]M. M. Czudec
- Emission enhancement in a luminescent polychlorinated diphenylpyridylmethyl radical through coordination to silver(I) December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03129F, PaperTakuto Mibu, Ryota Matsuoka, Masanari Nagasaka, Tetsuro KusamotoCoordination of a luminescent radical to AgI enhanced and red-shifted the radical-centered emission. This study demonstrates similar effects in the luminescence of the radical by complexation with group 11 d10-metal ions.To cite this article before page numbers are assigned, use the DOI […]Takuto Mibu
- Ring-opening polymerization of ε-caprolactone with a macrocyclic tetracarbene indium complex December 17, 2024Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03198A, CommunicationHenry R. Brothers, Raju Chambenahalli, Gary S. Nichol, Jennifer A. Garden, David M. JenkinsThe first chiral tetracarbene indium(III) complexes have been synthesized by employing a rigid dianionic macrocyclic tetra-NHC ligand.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS […]Henry R. Brothers
- Solvents and their hydrogen bonding properties as general considerations in carbon dioxide reduction by molecular catalysts December 20, 2024
