RSC – Dalton Trans. latest articles- Single-component white-light-emitting hybrid copper(I) halide constructed by supramolecular cation for WLED August 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01801C, PaperRong-Yan Zhang, Ting Zhu, Jin Zhang, Dong-Sheng Shao, Ying-Zhao Ma, Guo Peng, Xiaoming RenSingle-component white-light-emitters ensure color stability while reducing device complexity, which are ideal candidates for white light-emitting diodes (WLEDs). However, the realization of single-component white-light emission with high efficiency and stability...The content of this RSS Feed (c) […]Rong-Yan Zhang
- Constructing Ni(OH)2 nanosheets on nickel foam electrode for efficient electrocatalytic ethanol oxidation August 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01777G, PaperShasha Ma, Di Chen, Zhaobin Ye, Yuanlong Wang, Jie Xu, Jianyong ZhangThe main bottleneck faced by traditional hydrogen production technology through water electrolysis lies in the high energy consumption of anodic oxygen evolution reaction (OER). Combining thermodynamically favorable ethanol oxidation reaction...The content of this RSS Feed (c) The Royal […]Shasha Ma
- Interplay between the morphology, crystal facets and silver modifications of titanium dioxide nanomaterials in the context of photocatalysis August 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01597A, PaperNasir Shakeel, Ireneusz Piwoński, Aneta Kisielewska, Maciej Krzywiecki, Edyta Matyja, Magdalena Małecka, Tomasz Szmechtyk, Andrzej Kruk, Younas Sohail, Muhammad NaveedTitanium dioxide (TiO2) having the morphology of nanofibers (TNFs), nanorods (TNRs), and nanograss (TNGs) nanostructures was prepared.To cite this article before page numbers are assigned, use the DOI form of […]Nasir Shakeel
- 2D-Self-Assembly of Twisted Porphyrin Appended on Multiwalled Carbon Nanotubes for Oxygen Reduction Reaction August 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01591J, PaperVarusha Bhardwaj, Varsha Singh, Vellaichamy Ganesan, Muniappan SankarThe spontaneous formation of an ordered array of twisted cobalt(II) porphyrin yielding a 2D self-assembled structure is wrapped around multiwalled carbon nanotubes (MWCNT) and characterized by different techniques. The approach...The content of this RSS Feed (c) The Royal Society of ChemistryVarusha Bhardwaj
- Semiconductor-to-semimetal transition on Te doping in a new semiconducting material Ba2.75Pb1.1Sb4.1Se10 August 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01185J, Paper Swati, Subhendu Jana, Sayani Barman, Sweta Yadav, Jai PrakashNew quaternary Ba2.75Pb1.1Sb4.1Se10 and its Te-substituted derivatives have been synthesized. Te substitution has significantly improved the electrical conductivity of the parent Ba2.75Pb1.1Sb4.1Se10, which has ultralow thermal conductivity.To cite this article before page numbers are assigned, use the DOI form of […]Swati
- Nanoscale Ruthenium(III) Complexes with Bioactive Ligands: Structural, Colloidal, and Dual Antimicrobial–Cytotoxic Investigations August 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01857A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rudi van Eldik, Olga Impert, Anna Katafias, Maciej Witwicki, Anna Kozakiewicz, Pawel Pomastowski, Oleksandra Pryshchepa, Michalina Ehlert, Barbara Kubiak, Yogeswara Rao Pateda, Erik Rakovský, Natalia Balinska, Natalia CzernieckaThis study comprehensively analyses two new ruthenium(III) […]Rudi van Eldik
- Trifluoroborate-Appended Cyclen Complexes of Paramagnetic Transition Metals (Ni2+, Co2+) as Fast-Relaxing 19F MRI Probes August 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01834J, CommunicationCharline Sire, Francesca Garello, Noemie Lalaoui, Nathalie Saffon-Merceron, Nicolas Le Poul, Raphael Tripier, Lorenzo Tei, Thibault TroadecFor the first time, trifluoroborate groups (BF3s) have been investigated as sensitive probes for 19F Magnetic Resonance Imaging (MRI) in paramagnetic complexes. Using a macrocyclic BF3-appended cyclen ligand, complexes of...The content of this […]Charline Sire
- Exploring the effect of copper on the bioactivity of 8-quinolines: an in vitro and in vivo study August 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01396H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alessia Sambugaro, Riccardo Po, Martina Lorenzetto, Rebecca Ceolin, Giuditta Palmerston, Erik Murador, Laura Cifalinò, Giulia Annesi , VALERIA SCALCON, Chiara Nardon, Valentina OliveriCurrent anticancer therapy is challenged by the adaptability and resistance of tumor […]Alessia Sambugaro
- A Tight Binding Pocket in Photoluminescent N^C^N Cyclometalated Pt(II), Pd(II), and Ni(II) Complexes August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01385B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maryam Niazi, Ivan Maisuls, Cristian A. Strassert, Pablo González-Herrero, Axel KleinIIn the frame of our research aiming to develop efficient triplet-emitting materials, we are exploring the role of the second coordination sphere in enhancing […]Maryam Niazi
- Dalton Transactions Spotlight Collection on Mixed-Anion Compounds : Structural and magnetic properties of the Mixed-metal (Bi2O2)(Fe1 xMxF4) Aurivillius oxyfluorides August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01303H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jonas Wolber, Victor Duffort, Claire Minaud, Marielle Huve, Mathieu DUTTINE, Angel M. Arevalo-Lopez, Oscar Fabelo, Clemens Ritter, Olivier MentréA series of mixed-metal Aurivillius oxyfluorides of ideal formula [Bi2O2][Fe1 xMxF4] is synthesized by hydrothermal synthesis […]Jonas Wolber
- Oxygen-Tolerant Hydrogen Evolution in Water Using Schiff Base Copper Complexes with Tuneable Secondary Coordination Environments August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01278C, PaperSantanu Ghorai, Gul Afshan, Abhishek Saini, Sukanta Saha, Chandan Das, Yashwant Pratap Kharwar, ARITRO SINHA ROY, Arnab DuttaGreen hydrogen is increasingly acknowledged as a pivotal facilitator for the transition to a sustainable and renewable energy paradigm, presenting a clean alternative to conventional fossil fuels. Fundamental to this...The content of […]Santanu Ghorai
- Structure-Directing Synthesis of Two Germanate Cages featuring Odd-Member Ring Windows August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01561H, PaperHao Li, Yanan Xu, shiyue Zhang, Pengliang Gu, Qing Hu, Yu Zhang, wenkai Wang, Zhan Shi, Fu Xin Yi, Hongbin DuZeolites and zeolite-like materials with unique pore structures have emerged as key functional materials in diverse fields such as the chemical industry, environmental protection, and energy, owing to their […]Hao Li
- Comparative Analysis of Metal-Binding Properties of C-Terminal FeoB Peptide Models from Selected Gram-Negative Bacteria August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01388G, PaperBartosz Orzel, Malgorzata Ostrowska, Slawomir Potocki, Henryk Kozlowski, Massimiliano Francesco Peana, Elzbieta Gumienna-KonteckaIn our previous work, we have analyzed the coordination chemistry of the peptidic model of the C-terminal part of E. coli FeoB protein, regarded as the most important Fe(II) bacterial...The content of this RSS Feed (c) The […]Bartosz Orzel
- Circularly Polarized Luminescent Low Molecular Weight Lanthanide Gels: Tunable Emission Including White Light August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01650A, CommunicationThoithoi Singh Loitongbam, Banshi Devi Ningombam, Darshana Deb, Saikat Ghosh , Raju LaishramCircularly Polarized Luminescent (CPL) lanthanide gels are seldom reported, despite their vast potential for various applications. Here we report CPL active lanthanide gel with a high dissymmetry factor (glum) and...The content of this RSS Feed (c) The […]Thoithoi Singh Loitongbam
- Thermoreversible Hydrogel Containing Photoactivatable Tricarbonyl Mn(I) Terpyridine complexes for Therapeutic Carbon monoxide (CO) Release August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01527H, PaperAakshika Sree M, Amilan Jose DevadossCarbon monoxide (CO) is a well-established gasotransmitter known for its diverse physiological benefits. However, achieving controlled and targeted CO delivery remains challenging. To address this, light-activated carbon monoxide-releasing molecules (photoCORMs)...The content of this RSS Feed (c) The Royal Society of ChemistryAakshika Sree M
- Mixed-anion chalcogenide-halide semiconductors A2BaTaS4Cl (A = K, Rb, Cs) and K2BaNbS4Cl August 21, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01676B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Thomas S. Ie, Siddhartha S. Nathan, James M. Rondinelli, Mercouri G. KanatzidisThe synthesis and structural evolution of four novel mixed-anion compounds: K2BaTaS4Cl, Rb2BaTaS4Cl, Cs2BaTaS4Cl and K2BaNbS4Cl.To cite this article before page numbers are assigned, […]Thomas S. Ie
- Electrochemical water oxidation using single-site Cu(II) molecular complexes: A mechanism elucidated by computational studies August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01397F, PaperDev Raj, Koushik Makhal, Manaswini Raj, Aman Mishra, Rohan Mahapatra, Tanya Pattnaik, Bhabani S. Mallik, Sumanta Kumar PadhiIn this work, the penta-coordinated mononuclear Cu(II) complexes [Cu(QCl-Tpy)Cl2], [Cu1] (where QCl-Tpy = 3-([2,2':6',2''-terpyridin]-4'-yl)-2-chloroquinoline) and [Cu(8HQ-Tpy)Cl2], [Cu2] (where 8HQ-Tpy = 2-([2,2':6',2''-terpyridin]-4'-yl)quinolin-8-ol) had been utilized as an electrocatalyst for water oxidation...The content of […]Dev Raj
- Cd5Te4O12X2 (X = Cl, Br, I): A New Oxyhalide Family with [CdO4X] Mixed Anionic Units and Adjustable Optical Properties August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01473E, PaperMaqsood Iqbal, Jiazheng Zhou, Hongshan Wang, Juanjuan Lu, Shilie Pan, Junjie LiThree novel tellurate halides Cd5Te4O12X2 (X = Cl, Br, I) were rationally designed by introducing planar [TeO3] into the binary anionic compounds, and synthesized by the flux method in sealed...The content of this RSS Feed (c) The Royal […]Maqsood Iqbal
- Hidden Spin State Accessed by Light Irradiation in Iron(III) High-Spin Complex August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01604E, CommunicationHikaru Zenno, Rui Hieda, Ryosuke Nakao, Yoshihiro Sekine, Shinya HayamiHigh-spin (HS) iron(III) complex, [Fe(qsal)2]Cl·MeOH·H2O, was synthesised, and its crystal structures and photo-induced magnetic properties were characterised. Upon photo-excitation, the HS state is converted into a low-spin (LS) state, revealing...The content of this RSS Feed (c) The Royal Society of […]Hikaru Zenno
- Synthesis and Characteriza-tion of π Cyclo-pentadienyl Complexes of Manganese and Iron with One to Five Fluorosilyl Substituents. Crystal and Mo-lecular Struc-tures of [Mn(C5Br{SiMe2F}4)(CO)3] and [Mn(C5{SiMe2F}5)(CO)3] August 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01746G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Karlheinz Sünkel, Stephanie Bernhartzeder, Susanna SchubertThe reaction of AgSbF6 with the cymantrenyl hy-drosilanes [Mn{C5Br5-n(SiMe2H)n}(CO)3] (n= 1-5) gives the corresponding fluorosilanes. With the ferrocenylhydrosilanes [Fe{C5Br5-n(SiMe2H)n}(C5H5)] fluorination and oxidation to give the ferricenium salts [Fe{C5Br5-n(SiMe2F)n}(C5H5)]+SbF6- (n= […]Karlheinz Sünkel
- Single-component white-light-emitting hybrid copper(I) halide constructed by supramolecular cation for WLED August 25, 2025
