RSC – Dalton Trans. latest articles- Minimal liquid-assisted method for synthesis of ammonium, sodium, and potassium intercalated zirconium hydrogen phosphate: The effect of the cation used on the formation of an α- or γ-structure December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02548F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Klara Melanova, Ludvík Beneš, Rokas Lemežis, Vytautas Klimavičius, Jan SmolíkZirconium hydrogen phosphates intercalated with ammonium, sodium, and potassium cations were successfully synthesized via a minimal liquid-assisted approach, involving the grinding of a zirconium precursor […]Klara Melanova
- Coordination Interaction of Gd Metal-Organic Frameworks and Bismuth Halides for Efficient X-ray Shielding December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02611C, PaperNazmul Hossain, Shanmugam Mahalingam, Seok-Gyu Kang, Dae Seong Kwon, Hyeon Kwang Kim, Junghwan KimX-ray radiation is widely used in industry, medicine, and space engineering, but its potential hazards necessitate effective shielding materials to protect both humans and the environment. Although lead (Pb) has...The content of this RSS Feed (c) […]Nazmul Hossain
- Recent Advances in Non-Precious Metal Catalysts for Anion Exchange Membrane Water Electrolysis December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02543E, PerspectiveSuprobhat Singha Roy, Sreenivasan Nagappan, Prasita Mazumder, Fajar Dhanish C P , Vishesh Vishesh, Subrata KunduThe increasing global demand for green and sustainable energy has positioned hydrogen as a crucial energy carrier. Among various production methods, water electrolysis, particularly anion exchange membrane water electrolysis (AEMWE),...The content of this RSS […]Suprobhat Singha Roy
- From discrete to polymeric assemblies: exploring supramolecular structural diversity in transition metal phosphinates with N-donor ligands December 15, 2025Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT01622C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Archana Kumari Pattnaik, Gobinda Chandra BeheraMetal phosphinates evolve from discrete-to-polymeric forms via monodentate, chelating, and μ-bridging modes; N-donors tune metal geometry and packing, while H-bonds unify frameworks into diverse supramolecular architectures.To cite this article […]Archana Kumari Pattnaik
- Structural diversity in Zn(II)/Cu(II) complexes with salicylic/acetylsalicylic acids and bis(4-pyridylthio)methane: coordination polymers, one organic cocrystal, and one organic salt December 15, 2025Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02303C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Olaya Gómez-Paz, Rosa Carballo, Ana B. Lago, Ezequiel M. Vázquez-López, Berta CoveloSolid-state reactions of Zn(II) and Cu(II) with salicylic acid, acetylsalicylic acid, and bis(4-pyridylthio)methane(SCS) yielded 1D–3D coordination polymers, an organic salt, and an organic […]Olaya Gómez-Paz
- Self-Assembled Nanocomposite of HKUST-1 and Laponite: Towards Hydrogel with High Mechanical Strength for Selective Dye Adsorption and Column Chromatographic Separation December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02005K, Paperjyoti sharma, Chhaya Vashistha, Vinod Kumar, Anindita ChakrabortyHerein, we report the synthesis of a novel hydrogel nanocomposite, HKUST-1@LP, through the self-assembly of a prototype metal-organic framework (MOF), HKUST-1 and the nanoclay, laponite (LP). The nanocomposite was characterized...The content of this RSS Feed (c) The Royal Society of Chemistryjyoti sharma
- Emission and ESA/GSA thermographic properties of Pr-doped tungstate phosphors under Vacuum Ultraviolet and Visible Excitation December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT01985K, PaperRadoslaw Lisiecki, Nadiia Rebrova, Przemysław Jacek DereńThe impact of synchrotron radiation, temperature, and optically active ion concentration on the emission and thermographic properties of Pr-doped NaY 0.5 Gd 0.5 (WO 4 ) 2 , NaGd(WO 4...The content of this RSS Feed (c) The Royal Society of ChemistryRadoslaw Lisiecki
- Spectroscopic and DFT Study on the Complexation of Np(V) with Amidoxime-Derived Ligands in Aqueous Solutions: Speciation and Structural Optimization December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02697K, PaperYuxiao Guo, Zhijin Zhao, Huai Xin Hao, Yishi Yu, Hong Cao, Jing Chen, Zhipeng Wang, Chao XuThe pentavalent neptunyl ion (Np(V)) is the most stable form of neptunium in aqueous solutions. Studying its complexation is essential for developing ligands for Np separation and environmental management. This...The content of this […]Yuxiao Guo
- Dual-Functional Phosphomolybdic Acid-Polypyrrole-Ionic Liquid Nanocomposites for Energy Storage and Hydrogen Evolution: Experimental and Theoretical Studies December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02621K, PaperMuhammed Anees P. K., Iniyan Selvaraj, Chandrodai Singh, Murugavel Kathiresan, Sailaja Krishnamurty, Sib Sankar MalRecent advancements in pseudocapacitive materials for energy storage and catalytic activities highlight the benefits of incorporating nanostructured active materials. This study investigates the modification of polypyrrole (PPy) surfaces using polyoxometalates...The content of this RSS Feed […]Muhammed Anees P. K.
- Correction: Charge compensation endows K0.16Na0.05(NH4)0.71V4O10−x·0.63H2O cathode with tunable lattice strain for efficient Zn2+ storage December 15, 2025Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT90218E, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xueke Zhu, Dong Fang, Lang Zhang, Jianhong YiTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryXueke Zhu
- A novel neodymium-based porphyrin metal-organic frameworks for dual-mode detection of iron ions December 15, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02758F, PaperYan Wan, Congping Zhao, Yan Zhou, Lin Li, Xianfeng Wang, Tao Zhong, Yan Yang, Huan Li, Yi Yang, Jing LiuEffective identification of iron ions (Fe3+) in the environment and food supplements is essential but challenging. Though traditional single-mode fluorescent sensing methods are user-friendly and sensitive, their accuracy is prone...The […]Yan Wan
- Dodecanuclear MnII -GdIII metallomacrocycles: magnetic and refrigerant response December 12, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02886H, PaperErnesto Costa-Villén, Cristina Puigjaner, Júlia Mayans, Albert EscuerTwo dodecanuclear metallomacrocycles with a {MnII6GdIII6 } skeleton have been synthesized employing the Schiff base derived from the condensation of carbohydrazide and o-vanillin. The paramagnetic centers show a weak AF...The content of this RSS Feed (c) The Royal Society of ChemistryErnesto Costa-Villén
- Pressure-induced metallization and electronic transition in two-dimensional ferroelastic semiconductor of Nb2SiTe4 under different hydrostatic environments December 12, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02937F, PaperXinyu Zhang, Lidong Dai, Haiying Hu, Meiling Hong, Bing Lv, Xuefei Liu, Juxiang Shao, Ming Yang, Shiwei Xie, Hongchun Luo, Yu Gao, Tao Wang, Miao Ren, Haonan ChengNb2SiTe4, a representative two-dimensional (2D) ferroelastic semiconductor, becomes research focus due to its high carrier mobility, ambipolar carrier transport, exceptional ferroelasticity and […]Xinyu Zhang
- Crystallographic Evidence of a Trinuclear (salen)Manganese(IV/III/IV)-μ-Oxo Formed during Catalytic C(sp3)–H Oxidation Reactions December 11, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02844B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bhaswati Paul, Kusalvin Dabare, Joshua D Bocarsly, L. Reginald MillsThe formation of manganese-oxo catalysts involved in C(sp3)–H bond oxidation was explored in the targeted synthesis of (salen/salophen)manganese complexes that varied axial ligand identity and […]Bhaswati Paul
- Thermal Monomerization Unlocks 3/2↔5/2 Spin Crossover in a Kinetically Trapped High Spin Fe(III) Dimer December 11, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02175H, PaperBijoy Dey, Jan Titis, Sakshi Mehta, Abhishake Mondal, Vadapalli ChandrasekharWe report a novel iron(III) coordination system featuring a thermally controlled dimer-to-monomer transformation accompanied by a pronounced change in the spin state. At room temperature, the reaction of an insitu...The content of this RSS Feed (c) The Royal Society of […]Bijoy Dey
- HC 3 As, the simplest arsadiyne December 10, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02772A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arun-Libertsen Lawzer, Thomas Custer, Jean-Claude Guillemin, Robert Kolos1-Arsabutadiyne (2-propynylidynearsine, HC₃As), is efficiently produced by photolysis of propynylarsine isolated in solid argon. The observed infrared absorption spectra and predicted molecular parameters of HC₃As and HC₃P […]Arun-Libertsen Lawzer
- Selenium vacancy engineering in MoSe2 nanoflowers: Unlocking high-rate and durable potassium storage through plasma-mediated defect activation December 10, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02507A, PaperYi Feng, Zhi-Yuan Song, Yuanna Zhu, Caili Lv, Lin-Lin Fan, Yun-Dong Cao, Hong LiuRechargeable potassium-ion batteries (PIBs) have emerged as promising sustainable alternatives to lithium-ion systems. However, their practical application is limited by the scarcity of high-performance electrode materials that can effectively accommodate...The content of this RSS Feed (c) […]Yi Feng
- Nanosized Al-rich MFI zeolite synthesized by zeolite hydrothermal conversion in the presence of zeolite nanosheet seeds December 10, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02498F, PaperTareq W M Amen, Tsubasa Kitagawa, Nao TsunojiThe development of nanosized zeolites with enhanced catalytic performance presents a significant challenge due to the need for cost-effective and sustainable synthesis methods suitable for large-scale production and practical applications....The content of this RSS Feed (c) The Royal Society of ChemistryTareq W M Amen
- Isocyanide-functionalised phosphines: an uncharted field December 10, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02652K, Frontier Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Petr ŠtěpničkaWhile numerous functional phosphines have been reported, investigated, and applied to date, phosphines equipped with an additional isocyanide moiety have received only limited attention. This frontier article provides an overview...The content of this […]Petr Štěpnička
- Ligand-Mediated Modulation in Copper(II) Complexes for Four-Electron Oxygen Reduction in Neutral Medium December 10, 2025Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT01736J, PaperSavi Chaudhary, Ramaswamy MurugavelEfficient molecular catalysts for the oxygen reduction reaction (ORR) are essential for advancing sustainable energy technologies. Inspired by copper-based metalloenzymes, this study reports the synthesis and characterization of two copper(II)...The content of this RSS Feed (c) The Royal Society of ChemistrySavi Chaudhary
- Minimal liquid-assisted method for synthesis of ammonium, sodium, and potassium intercalated zirconium hydrogen phosphate: The effect of the cation used on the formation of an α- or γ-structure December 15, 2025
