RSC – Dalton Trans. latest articles- Fixing CO2 from the air to assemble Dy8 zero-field single-molecule magnet and Gd8 magnetocaloric molecular material March 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00214E, PaperCai-Ming Liu, Xiang HaoAssembling Ln(III) clusters by capturing and fixing CO2 from the air is a unique and eco-friendly approach to multinuclear single-molecule magnets and magnetocaloric molecular materialss. However, the conditions or factors...The content of this RSS Feed (c) The Royal Society of ChemistryCai-Ming Liu
- Correction: An N-heterocyclic carbene-based pincer system of palladium and its versatile reactivity under oxidizing conditions March 2, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT90035F, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Haobin Li, Bo Zhang, Rui Feng, Shuai GuoTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryHaobin Li
- Solution-processable Homoleptic Aluminum(III) Catecholaldimine Complex as an Active Material for RRAM Switching Device March 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02954F, PaperVivek Sharma, Anupam Chetia, Rishabh Raj Upadhyay, Purva Dua, Satyajit Sahu, Ramesh K. MetreIn this paper, we report the synthesis and structural characterization of a new mononuclear aluminum complex 1, containing redox-active hydrazine based catecholaldimine ligand (4,6-ditert-butyl-2,3-dihydroxybenzylidene)furan-2-carbohydrazide (LH 3 ). Complex 1 was...The content of this RSS Feed (c) […]Vivek Sharma
- Combining gold(I/III) complexes and ferrociphenol scaffold for the generation of bimetallic complexes with anticancer activity March 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00049E, PaperMagda Křelinová, Jérémy Forté, Tom Lacoma, Giulia Annesi , Alessandra Folda, Maria Pia Rigobello, Michèle Salmain, Petr Štěpnička, Jiří Schulz, Benoît BertrandA series of eleven heterobimetallic Au/Fe complexes featuring [Au(I)-thioglucose tetraacetate], [Au(I)-NHC], [(C^N)Au(III)Cl], [(C^N^C)Au(III)] or [(C^C)Au(III)Cl] fragments and (diphenylphosphino)ferrociphenol or (diphenylphosphino)ferrocene ligands have been synthesized. The compounds were fully […]Magda Křelinová
- Modulation of the electrocatalytic performance of rGO/CoCuFe[Ni(CN) 4 ] pillared with pyridine derivatives in Zinc-air batteries March 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02812D, PaperE. Arturo Quintanilla-Serrano, Prospero Acevedo-Peña, Edilso Reguera, Marlene M. GonzálezComposites consisting of cobalt, iron, and copper tetracyanonickelates, pillared with different organic ligands, were obtained via chemical precipitation and subsequently exfoliated in a rGO suspension. Exfoliation and the presence of...The content of this RSS Feed (c) The Royal Society of […]E. Arturo Quintanilla-Serrano
- Developing Ni3N/NiO Heterostructure Catalysts to Enhance Hydrogen Evolution Reaction in Alkaline Medium via a Surface-Dependent Mechanism February 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00031B, PaperFangfang Liu, Shan Ji, Yongwei Li, Zhihao Fang, Vladimir Linkov, Yucheng Dong, Hui WangIn the construction of sustainable energy systems, the development of efficient and stable electrocatalysts for the hydrogen evolution reaction (HER) is of crucial significance. This study adopts an in-situ oxidation-nitridation...The content of this RSS Feed (c) […]Fangfang Liu
- Pendant-cation assisted spontaneous axial halide substitution in group 7 M(L)(CO)3X complexes February 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02433A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wesley W. Kramer, Thomas R. Sheridan, Jorge Pérez-Vázquez, Christophe A. Boivin, Amanda M. Browne, Catherine G. Logan, Brian C. SandersThe presence of pendant cationic functional groups in group 7 fac-tricarbonyl complexes produces unusual axial-halide […]Wesley W. Kramer
- A di-nuclear μ-oxido rhenium(VI) complex: from deep purple to catalytic applications February 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00039H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tobias A. Doliner, Peter E. Hartmann, Gernot Oberwinkler, Ferdinand Belaj, Antoine Dupé, A. Daniel Boese, Jörg A. SchachnerFrom lab curiosity to a novel Re(VI) oxyanion reduction catalyst, we proudly present deep purple.To cite this […]Tobias A. Doliner
- Fraternal twins: B2O2- or B2N2-doped polycyclic π systems and their formation mechanism via regiodivergent Au-versus amine catalyzed cycloadditions February 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00412A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Simon M. Mittag, Jonas Klopf, Alexander Virovets, Eugenia V. Peresypkina, Hans-Wolfram Lerner, Holger Helten, Matthias WagnerBE-doped polycyclic aromatic hydrocarbons (PAHs; E = NR, O) often exhibit superior optoelectronic properties compared to their carbonaceous congeners. […]Simon M. Mittag
- Structural transformation and redox chemistry of Pd/CeO 2 during SO2 -induced sulfurization: An in situ XAFS study February 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00070C, PaperSaki Shigenobu, Takeharu Sugiyama, Hajime Hojo, Hisahiro EinagaIn situ X-ray absorption fine structure (XAFS) spectroscopy was employed to elucidate the structural evolution of Pd/CeO 2 catalysts during SO 2 -induced sulfurization. Linear combination fitting of Ce L...The content of this RSS Feed (c) The Royal Society of ChemistrySaki Shigenobu
- Green synthesis of biomass-derived graphene for supercapacitor application February 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02322J, PaperAminata Fall, Martinson Addo Nartey, Daniel Nframah Ampong, Kwadwo Mensah-Darkwa, Ram K. GuptaGreen synthesis of biomass precursor into GO and rGO was achieved using hydrothermal carbonization. The synthesized material exhibited an enhanced specific capacitance of 552.48 F g−1 at 1 A g−1 with high redox activity.To cite this article […]Aminata Fall
- Single-Site Hydrogen-Bond Modulation Enhances Catalytic Ester Hydrolysis in a Zn(II)–TPA Scaffold February 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03058G, PaperHan Sol Kim, Soo Suk LeeZinc(II)-dependent metalloenzymes rely heavily on secondary-sphere interactions to modulate reactivity, inspiring the design of biomimetic Zn(II) catalysts that incorporate analogous features. Here, we introduce a hydroxymethyl-functionalized TPA ligand in which...The content of this RSS Feed (c) The Royal Society of ChemistryHan Sol Kim
- Rigidified cyclic diglycolamides: coordination and extraction of trivalent f-elements February 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00275G, PaperMariia V. Evsiunina, Mikhail A. Kalinin, Paulina Kalle, Danila A. Iakovlev, Stepan N. Kalmykov, Petr I. Matveev, Nataliya E. BorisovaConformationally rigid cyclic diglycolamides were synthesized for the first time. La(III) coordination revealed 1 : 1 and 2 : 1 ligand-to-metal complexes.To cite this article before page numbers are assigned, use the DOI form […]Mariia V. Evsiunina
- Zero valent iron and nickel coordination chemistry: metal atoms as direct approach to bis(benzene)chromium bridged N-heterocyclic silylene complexes February 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02957K, PaperJohannes M. Emmert, Jörg Rust, Christian W. Lehmann, Jörg J. SchneiderA bis(benzene) chromium bridged bidentate organometallic silylene pincer ligand is introduced for zerovalent iron and nickel. The pincer ligand and its Fe complex are accessible by a direct metal-atom route under extremely mild chimie douce conditions.To cite this article […]Johannes M. Emmert
- Homoleptic Complexes of Vanadium and N-Heterocycles Made via Oxidation of Vanadium Nanoparticles February 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00230G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Claus Feldmann, Lena BaumgärtnerThe four homoleptic coordination compounds [NaV(cbz)4] (1), [V(bipy)3] (2), [V(phen)3] (3), and [V(Hai)3(ai)2]·0.5 tol (4) are prepared by reaction of vanadium metal (V(0)) nanoparticles (mean size: 1.6±0.3 nm) with the...The content […]Claus Feldmann
- Tailoring In-Gap States for Optimizing the Band Gap in Mixed-Valent Bromometallates, Towards Lead-Free Photovoltaics February 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02874D, PaperTatiana Alekseevna Shestimerova, Angelina P Klykova, Alexey Medved'ko, Victor N Khrustalev, Michael A. Bykov, Denis A. Pankratov, Igor A Presniakov, Alexey N. Kuznetsov, Sergey Z. Vatsadze, Andrei V ShevelkovMotivated by the task to replace toxic lead halide perovskites with lead-free environmentally benign light-harvesting materials for photovoltaics, we have synthesized […]Tatiana Alekseevna Shestimerova
- Deciphering Cation-Driven Structure-Property Correlations in 0D Hybrid Ruthenium Halide Perovskites February 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02797G, PaperHimangshu Pratim Saikia, Ankita Likson, Khyati Anand, Bidyut Das, Abinash Tiwari, Sandeep Kumar Dey, Beatriz Gil-Hernández, Prashurya Pritam MudoiHybrid organic-inorganic halides have emerged as a structurally tunable class of materials that allows simultaneous modulation of optical properties and magnetic interactions. By varying the A-site cation with organic amines...The content […]Himangshu Pratim Saikia
- Dihalogen-substituted [MnIII(3,5-diHal-sal2323)]BPh4 salts: so similar but so different February 26, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03065J, PaperDenis V. Korchagin, Gennady V. Shilov, Michael V. Zhidkov, Alexey I. Dmitriev, Andrei Palii, Eduard Borisovich Yagubskii, Sergey M. AldoshinThree novel tetraphenylborate salts of Mn(III) complexes with the Schiff base ligands 3,5-diHal-sal2323 are synthesized and structurally and magnetically characterized: [Mn(3,5-Br,F-sal2323)]BPh4 (1), [Mn(3,5-diI-sal2323)]BPh4 (2) and [Mn(3,5-Cl,Br-sal2323)]BPh4 (3). Complex 1 exhibits...The […]Denis V. Korchagin
- Zn 2+ /Mo 6+ Modulated Phase Structure and Morphology of FeCoNi High-Entropy Hydroxide for Boosted Supercapacitor Electrode Performance February 26, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02988K, PaperBing Wu, Yunchan Zhou, Zhongning Shi, Hongbin Sun, Junli XuFeCoNi-based hydroxides are considered as great potential supercapacitor electrode materials, but their practical application is hindered by unsatisfactory specific capacitance and lifespan. In this study, FeCoNiMoZn high entropy hydroxide was...The content of this RSS Feed (c) The Royal Society of […]Bing Wu
- Accessing Osmium(VI) Nitrido Complexes with N-Heterocyclic Carbene Ligands February 26, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00234J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joshua Parche, Robin Sievers, Tim-Niclas Streit, Moritz MalischewskiThe synthesis of the first osmium(VI) nitrido complexes bearing NHC ligands is described. Hereby, [NBu4][OsNCl4] is reacted with two equivalents of the Cl-IMes NHC to afford the […]Joshua Parche
- Fixing CO2 from the air to assemble Dy8 zero-field single-molecule magnet and Gd8 magnetocaloric molecular material March 2, 2026
