RSC – Dalton Trans. latest articles- Copper(III) organometallic complexes of non (anti)aromatic and aromatic doubly N-confused porphyrinoids: syntheses and characterization January 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03265A, PaperHarapriya Rath, Anirban Panua, Gunasekaran Velmurugan, Peter CombaRetrosynthetically designed and synthesis of three unprecedented doubly N-confused porphyrinoids with tunable aromaticity are reported. Controlled modification of types of oxidants (chloranil vs. DDQ) has led to the isolation of...The content of this RSS Feed (c) The Royal Society of ChemistryHarapriya Rath
- Polydopamine-coated cerium oxide core-shell nanoparticles for efficient and non-damaging chemical-mechanical polishing January 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03546A, PaperXiaohai He, Bo Gao, Qingyuan Wu, Chengrui Xin, Junjie Xue, Fangwei Lu, Xin-Ping Qu, Simin Li, Fan Zhang, Hui ShenChemical mechanical polishing (CMP) represents one of the most important steps in the manufacturing of integrated circuits and high surface quality is always required for the CMP processes of shallow...The […]Xiaohai He
- An isolable boron-centered radical anion stabilized by a carbazole moiety January 27, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03314K, CommunicationNingning Yuan, Tingchun Zhu, Jianping Ma, Yunsheng Xue, Yirui LiuA carbazole-stabilized boron-centered monoradical has been isolated and characterized. Interestingly, the B–N bond was elongated and activated in 1˙−[Na(15-crown-5)2]+, which provides a new idea for the subsequent activation of the B–N bond.To cite this article before page numbers are assigned, […]Ningning Yuan
- Synthesis of Base-free Boriranes and their Conversion to Borirenes Using Strong Reductant January 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00069F, PaperSimon Dotzauer, Sourav Kar, Theresa Swoboda, Christoph Weidemann, Andreas Häfner, Rian David Dewhurst, Holger BraunschweigBoriranes, highly strained three-membered cyclic organoboron heterocycles, have emerged as potential synthons for the synthesis of many organoboron species. However, the synthesis of boriranes with tricoordinate, sp2-hybridised boron and tetracoordinate,...The content of this RSS Feed […]Simon Dotzauer
- Nickel(II) complexes with covalently attached quinols rely on ligand-derived redox couples to catalyze superoxide dismutation January 27, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03331K, PaperRobert Boothe, Julian Oppelt, Alicja Franke, Jamonica L. Moore, Andrea Squarcina, Achim Zahl, Laura Senft, Ina Kellner, Akudo L. Awalah, Alisabeth Bradford, Segun V. Obisesan, Dean D. Schwartz, Ivana Ivanović-Burmazović, Christian R. GoldsmithNi(II) complexes with quinol-containing ligands are efficient catalysts for the degradation of superoxide despite relying on redox […]Robert Boothe
- Metal-ligand and Hydrogen Bonding in the Active Site of Fe(III)-, Mn(III)- and Co(III)-myoglobins January 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03246B, PaperMarek Freindorf, Elfi KrakaWe investigated in this work the strength of metal–ligand bonding in complexes formed between Fe(III)- , Mn(III)- and Co(III)-myoglobin and methanol, water, nitrite, and azide, serving as neutral and ionic...The content of this RSS Feed (c) The Royal Society of ChemistryMarek Freindorf
- Synthesis, structures, and magnetic properties of alkali metal manganese(III) fluorophosphates containing low-dimensional S = 2 spin structures January 27, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT02768J, PaperXiedong Cheng, Feifan Li, Qingqing Huang, Laura C. J. Pereira, Rui Cui, Yaping Li, Minfeng LüFluoride-rich hydrothermal synthesis enables access to five alkali metal manganese(III) fluorophosphates containing low-dimensional S = 2 spin structures, which include a uniform chain, a zigzag chain and a triangular network.To cite this article before […]Xiedong Cheng
- Tetra-Coordinated Organoboron Complexes with Triaminoguanidine-Salicylidene based Ligands: Aggregation Induced Enhanced Emission and Mechanoresponsive Features January 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03217A, PaperBalamurugan Tharmalingam, Rajendran Kishore Kumar, Ottoor Anitha, Werner Kaminsky, Jan Grzegorz Małecki, Murugesapandian BalasubramanianOrganoboron complexes have garnered significant attention due to their remarkable optical properties and diverse applications. However, synthesizing stable fused five-, six- and seven-membered organoboron complexes poses significant challenges. In this...The content of this RSS Feed (c) […]Balamurugan Tharmalingam
- Sn-modified Zr-UiO-66 metal-organic frameworks for dihydroxyacetone conversion into lactic acid January 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02975E, PaperKarina Kurmanbayeva, Semyon Nikulaichev, Viktoriia Torbina, Nikolai A. Sokovikov, Olga VodyankinaDihydroxyacetone is a valuable waste-valorization compound, which is a main intermediate in lactic acid production from different recyclable sources. In the present work, the Sn incorporation into the Zr-based metal-organic...The content of this RSS Feed (c) The Royal Society […]Karina Kurmanbayeva
- Cationic and Neutral Ruthenium(II) Complexes bearing Silyl-Phosphines; Synthesis, Structures, and Catalytic Studies in Selective Hydroboration of Carbonyl Compounds January 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03550J, PaperAmiya Kumar Sahoo, Rageshree Dash, Suraj Agarwala, Chandra Shekhar Purohit, Adinarayana DoddiReactivity of ortho-silylted phosphines featuring SiMe3, and SiR2H (R = Me, Ph) units has been studied towards ruthenium(II) metal precursors. The reactions of phosphino-trimethylsilane (1a) with [Ru(p-cymene)Cl2]2 in the presence...The content of this RSS Feed (c) The Royal […]Amiya Kumar Sahoo
- An anionic metal-organic framework and its r-graphene oxide composite for selective adsorption and separation of methyl blue from aqueous solution January 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03471F, PaperUddit Narayan Hazarika, Prithiviraj Khakhlary, Anisha Pegu, Shrutipriya Devi, Surajit Konwer, Moirangthem Kameshwor Singh, Simi Gogoi, Mintumoni PeguAA mono-metallic MOF (Mn-FM) and r-GO composite of the MOF (rGO@Mn-FM) were synthesized with simple and cost-effective method. The MOF contains Mn2+ metal centre with in situ generated ligand from...The content of […]Uddit Narayan Hazarika
- Ni-Pd bimetallic nanoparticles stabilized polymer membrane as an efficient dip-catalyst for oxidative coupling of aromatic amines to access symmetrical and unsymmetrical azo compounds January 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT01995D, PaperAnshuman ., Raj Laxmi, Padmini Gupta, Renu Mishra, Biplab Kumar Kuila, Neelam GuptaThe azo linkage is an important chemical motif with wide applications in the pharmaceutical, agrochemical, textile, paint, and food industries. The development of effective dip-catalysts that would convert aromatic amines...The content of this RSS Feed (c) The […]Anshuman .
- Antiproliferative activity of a series of copper(II) complexes derived from a furan-containing N-acylhydrazone: monomers, dimers, charge status, and cell mechanistic studies on triple negative breast cancer cells January 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03445G, PaperOlivia Espíndola-Moreno, Fagner da Silva Moura, Lucía Santa María de la Parra, Carolina Stellet, Jilder D.P. Serna, Renata Diniz, Nicolás A. Rey, Ignacio LeonIn this work, we evaluated the anticancer activity of compounds 1 (mononuclear) and 2 (dinuclear) copper(II) coordination compounds derived from the ligand 5-methylsalicylaldehyde 2-furoyl hydrazone (H2L) […]Olivia Espíndola-Moreno
- The Structure-Property Relationship of Metallocene-based Ethylene Oligomerization Catalysts Using DFT and Graph Neural Networks January 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03065F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhudan Chen, hao Li, Xiaowei Xu, zhuozheng Wang, Yan Jiang, Yi Luo, Libo Wang, Weisheng YangEthylene oligomerization catalysts have been extensively studied in both experimental and simulation contexts, yet a molecular-level understanding of structure-property […]Zhudan Chen
- Reactions of chalcogens and borane with phosphazane macrocycles assembled from diethanolamine and P2N2 building blocks January 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03229B, PaperManu Goyal, Chandrakala Negi, Nitish Kumar Garg, Shalender Jain, Sanjay SinghPhosphazanes of the type [ClP(µ-NR)]2 are excellent building blocks for the formation of a range of macrocycles. The condensation reaction of the bifunctional linker, N-substituted diethanolamine with cyclodiphosphazane, [ClP(µ-NtBu)]2 leads...The content of this RSS Feed (c) The Royal Society […]Manu Goyal
- Synthetic Structure Effect of CuO/NaZSM-5 on Catalytic Oxidation of Chlorinated Aromatic Hydrocarbon January 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03299C, PaperMan Xie, Jiasheng Wang, Hangyu Zhou, Hao Zhang, Pengfei Sun, Xiaoping DongThe industries of petrochemicals, tobacco, and pharmaceutical processing extensively use chlorinated volatile organic compounds (CVOCs) as solvents and lubricants, which cause significant environmental hazards. Zeolite is a highly efficient catalytic...The content of this RSS Feed (c) The Royal […]Man Xie
- Theoretical Prediction of Metallomimetic Stable Cyclic Group 13 Carbenoids January 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03342F, CommunicationAshwini Kumar Phukan, Barsha Rani Bora, Barsha ChakrabortyDensity Functional Theory calculations were performed to design a new class of strongly nucleophilic cyclic intramolecular base stabilized group 13 carbenoids. The carbenoids were found to exhibit metallomimetic behaviour owing...The content of this RSS Feed (c) The Royal Society of ChemistryAshwini Kumar Phukan
- Transforming Delayed Fluorescence to Blue-shifted Phosphorescence in Aminoboranes via Oxygen-to-Sulfur Substitution on the Donor Amine January 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03200D, PaperAkkarakkaran Thayyil Muhammed Munthasir, Satyam Jena, P ThilagarThermally activated delayed fluorescence (TADF) and room-temperature phosphorescence (RTP) materials have found diverse applications, from optoelectronic devices to time-gated bioimaging. Recently, aminoboranes with donor-acceptor structures have been identified as promising...The content of this RSS Feed (c) The Royal Society of ChemistryAkkarakkaran Thayyil Muhammed Munthasir
- Cadmium-rich intermetallic phases ARh2Cd20 – Structure, magnetic behavior, 151Eu Mössbauer and 113Cd solid-state NMR spectroscopy January 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03523B, PaperLars Schumacher, Florian Schreiner, Aylin Koldemir , Rainer Pöttgen, Oliver Janka, Michael Ryan HansenThe cadmium-rich intermetallic compounds ARh2Cd20 (A = Ca, Sr, Y, La-Nd, Sm-Lu) were synthesized from the elements in sealed tantalum tubes. The elements were reacted in an induction furnace and...The content of this RSS Feed (c) […]Lars Schumacher
- Multicolor emission from 0D-doped hybrid halide (C8H14N2)2CdBr6 single crystal January 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03247K, PaperYuchen Xu, Wenxiao Dong, Shaoli Song, Huichao He, Hanmei Jiang, Bi Jia, Xiaoyan Liu, Jianbei Qiu, Tao HanTo achieve multicolor emission is a fascinating goal that remains challenging for zero-dimension (0D) hybrid halide. We successfully obtained a three-millimeter-scale 0D (MXDA)2CdBr6 (MXDA=C8H14N22+) single crystal (SC) by solvent-thermal method....The content of […]Yuchen Xu
- Copper(III) organometallic complexes of non (anti)aromatic and aromatic doubly N-confused porphyrinoids: syntheses and characterization January 27, 2025
