RSC – Dalton Trans. latest articles- Theoretical study of ether group substitution effects on electrochemical properties of Ti-modified vanadium-oxide clusters February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02395E, PaperKexin Wang, Shuang Wu, Sihan Wei, Li-Kai YanIn this study, the effects of ether group substitution on the electrochemical properties of [Ti2V4O5(OCH3)14] (Ti2V4) and [Ti3V3O4(OCH3)15]+ (Ti3V3+) were investigated by combining density functional theory (DFT) calculations and molecular...The content of this RSS Feed (c) The Royal Society of ChemistryKexin Wang
- Cyclam-based Cu(II) and Fe(III) complexes for antifouling coatings development February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT01700A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Inês Nunes, Bruno J. C. Vieira, João C. Bentes Waerenborgh, Maria João Romeu, Rita Teixeira-Santos, Ana Carapeto, Noelia Losada-Garcia, Filipe Mergulhão, Elisabete Ribeiro Silva, Luis AlvesBiofouling, the accumulation of microorganisms and macroorganisms on submerged […]Inês Nunes
- Magneto-structural and theoretical insights into Ni2Dy2 butterfly single-molecule magnets with diverse anionic co-ligands February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02843D, PaperAnangamohan Panja, Zvonko Jaglicic, Daniel Aravena, Narayan Ch. Jana, Paula BrandãoFive defective dicubane Ni2Dy2 complexes with the general formula [Ni2Dy2(L)4X2(solvent)n], where X = NO3– (1), acetylacetonate (2), NCS– (3), OAc– (4), and pivalate (5)), were synthesized and structurally characterized to...The content of this RSS Feed (c) The Royal Society […]Anangamohan Panja
- Promoting nickel oxidation state transformation in NiFe hydroxide nanosheets for efficient oxygen evolution reaction February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03117F, PaperWenwen Peng, Xueqiu Qin, Xiaocan Mo, Jinrui Zhao, Shuhan Li, Guanfang Liang, Tong Chen, Jiaao Wei, Shuifeng Zhang, Xiaokun Li, Youlin Zhang, Wei ChenPromoting the formation of high oxidation state transition metal species in hydroxide catalysts can enhance their catalytic activity for the oxygen evolution reaction (OER). In this […]Wenwen Peng
- The roles of Asn7 and Trp67 in tuning the ferryl haem form of Staphylococcus aureus IsdG February 12, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02793D, PaperA. Grover, A. Nabi, M. A. Conger, M. D. LiptakThe ferryl haem form of W67F IsdG contains an organic radical. This variant yields a biliverdin product, distinct from the staphylobilin product of wild-type enzyme.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]A. Grover
- The single-crystal to single-crystal transformation in pentagonal bipyramidal Fe(II) complex with N 3 S 2 chelating ligand: switching on single-ion magnet properties via axial ligand substitution † February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03074A, PaperLeokadiya Zorina, Sergey Vladimirovich Simonov, Valentina D Sasnovskaya, Maxim Andreevich Blagov, Denis V. Korchagin, Michael V. Zhidkov, Alexey I. Dmitriev, Evgeny Khramov, Eduard Borisovich YagubskiiA new pentagonal bipyramidal Fe(II) complex [Fe II (H2L)(MeOH)2]Cl2•MeOH (1) with a pentadentate N3S2 chelating ligand 2,6-diacetylpyridine bis(4-N-(4-ethylphenyl)thiosemicarbazone) (H2L) was synthesized. It was found that […]Leokadiya Zorina
- Locking the Spin States of Anionic Fe(L)text-decoration:underline"2 Units in Coordination Polymers through Alkali Metal Ions Incorporation February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00162A, PaperJing-Yao Zhou, Hong-dong Zhang, Fan Yin, Zheng-Zhong Zhu, Lipeng Zhou, Chong-Bin Tian, Qing-Fu SunDiscrete FeII spin crossover (SCO) compounds have garnered significant interest over the past decades. However, assembling these units into coordination polymers via the incorporation of a second metal ion and...The content of this RSS Feed (c) […]Jing-Yao Zhou
- Developing Two High-Nuclearity Ag Nanoclusters with Temperature-Sensitive Fluorescence Properties February 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02009C, PaperXiao-Lin Ye, Sobhan Rezayati, Fahime Bigdeli, Le Yang, Kuan-Guan Liu, Jianyu Wei, Ali MorsaliTwo new high-nuclearity silver nanopolyclusters, templated with chromate and molybdate, were synthesized through a simple synthesis process. The structure of the nanoclusters, with the formulas (CrO4)@Ag19(C≡CPh)7(Ph2PO2)8(H2O)‧(BF4)2‧CH3OH (YL-1) and (MoO4)@Ag19(C≡CPh)9(Ph2PO2)7‧(OTf)‧CH3OH (YL-5),...The content of this RSS Feed (c) […]Xiao-Lin Ye
- Sulfur Insertion into Group 12 Metal Dithiolate Complexes: Metal-Dependent Equilibria February 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00074F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Muhammad Sohail, Carsten Heinsen, Allen Grayson Oliver, Emily Y TsuiDianionic bis(carboxamide)pyridine-supported metal(II) dithiolate complexes of Cd2+ and Hg2+ showed isostructural [N3S2] coordination to a previously reported zinc variant, but changes in ionic radius resulted […]Muhammad Sohail
- Synthetic Method Analysis of Ir0.85Bi0.15 Solid-Solution Nanoparticles with Excellent Hydrazine-Decomposition Activity February 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00112B, CommunicationXinling Xiong, Zhenduo Liu, Bo HuangAtomic-level homogeneously mixed and well-dispersed Ir0.85Bi0.15 solid-solution nanoparticles (NPs) were synthesized successfully for the first time despite large differences of crystal structures, redox potentials and atomic radii between Ir and...The content of this RSS Feed (c) The Royal Society of ChemistryXinling Xiong
- Polysubstituted guanidine-based receptors for the selective extraction of pertechnetate anion from high-level waste February 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00057F, PaperUliana Leksina, Vladimir A Abramov, Petr I. Matveev, Pavel S. Lemport, Alexander Gopin, Egor D Glushkov, Konstantin Lyssenko, Alexander Trigub, Vladimir G. Petrov, Yuri Ustynyuk, Valentine NenajdenkoIn this work, we report the design and synthesis of a novel series of guanidine-based extractants tailored for the selective and efficient extraction […]Uliana Leksina
- Unveiling the role of structural water and achieving enhanced zn-ion storage via thermal dehydration of a Ni-containing heteropolyoxovanadate cathode February 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03044G, PaperNaibin Kuai, Aiping Yao, Shuangxue Wu, Li Liu, Xinlong Wang, Chao Qin, Zhong-Min SuThe widespread application of aqueous zinc-ion batteries (AZIBs) is hindered by the limited capacity and structural instability of cathode materials. In this work, a heteropolyoxovanadate, Na7[NiV14O40]·18H2O (Ni–NVOH), is synthesized and...The content of this RSS Feed (c) […]Naibin Kuai
- Uranium Tetrafluoride via Direct Conversion of Uranium Dioxide Using Silver Bifluoride in an Ionic Liquid Medium February 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02703A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Parveen Kumar Verma, Jason Victor, Frederic Poineau, Ken R. CzerwinskiConventional methods to prepare UF4 involve the fluorination of UO2 with corrosive chemicals (i.e., HF(g)) at elevated temperatures. Here, a novel method for producing UF4 […]Parveen Kumar Verma
- Field-induced slow magnetic relaxation, molecular docking and antibacterial studies of quasi-isotropic copper (II) (S = ½) systems stabilised by tetradentate (ONNO) and tridentate (NNO)-donor ligands February 10, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00119J, PaperAmit Saha Roy, Sourav Ghosh, Indranil Nath, Sergio Caballero, Albert Escuer, Julia Mayans, Shasank Sekhar SwainA series of penta-coordinate Cu(II) complexes were synthesised and structurally characterised to explore the relationship between coordinating environment, molecular magnetism, and antibacterial activities. A dinuclear complex, [Cu₂(L₁)₂] (1), derived from...The content of this RSS […]Amit Saha Roy
- Tailoring porphyrinic MOF-545 performances for CO2 photocatalytic reduction through linker chlorination February 10, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02590G, PaperAmanda Lyn Robinson, Sadiya Sadiya, Sandeep Kumar, Francesc Penas-Hidalgo, Khadija Talbi, Zakaria Halime, Mathieu Frégnaux, Damien Aureau, Maria Gomez-Mingot, Pierre Mialane, Albert Solé-Daura, Caroline Mellot-Draznieks, Anne DolbecqChlorinating porphyrin linkers in MOF-545 boosts photocatalytic CO2-to-formate conversion under visible light by tuning the electronic structure and the band gap.To cite this […]Amanda Lyn Robinson
- Frontiers in Gas Sensing with Semiconducting Metal Oxide Array Electronic Noses February 10, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02516H, FrontierYuchen Xia, Heng Zhang, Xuerong Shi, Shusheng XuThe growing demand for rapid and selective detection of hazardous gases drives the development of electronic nose (E-nose) systems. By combining partially selective sensor arrays with pattern recognition algorithms, E-noses...The content of this RSS Feed (c) The Royal Society of ChemistryYuchen Xia
- A rational development of a drug delivery device based on MOF UiO-66 for calcium channel blockers drugs February 10, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02037A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Javier Salazar, Yoan Hidalgo-Rosa, Pia C. Burboa, Cesar Pazo-Carballo, Yazmín Arellano, Camila Le-Roy, Jaime Llanos, Yi-nan Wu, Nestor Escalona, Ximena Zárate, Eduardo SchottThe administration of drugs with low solubility or absorption, such as calcium […]Javier Salazar
- Stability vs. Activity in Electrocatalytic Hydrogen Production and Magnetic Studies of Mononuclear Labile Cu(II) and Ni(II) Complexes February 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00175K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maria Aziz Bhatti, Luca Carrella, Carsten Streb, Eva Rentschler, Sriram SundaresanIn this study, two new mononuclear Schiff base salen-derived complexes, [CuII(H2LMe)]·1.5 H2O (C1) and [NiII(H2LMe)]·3 H2O (C2), were prepared from 2,6-bis(hydroxymethyl)-4-methylphenol H4L and characterised […]Maria Aziz Bhatti
- Mechanistic insight into cooperative catalysis with pentanuclear nickel clusters: catalytic alkene dimerization and silyl-silylene and silylyne clusters February 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02642C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Samuel A. Johnson, Junyang Liu, Kethya SumThis work gives structural insights into potential intermediates relevant to the mechanism of stereoselective catalysis by pentanuclear Ni complexes, such as the previously reported stereoselective dimerization of norbornene […]Samuel A. Johnson
- Fabrication of Hollow-shape CuO Nanoparticle Assembly with Sacrificial W18O49 Template for C2+-Product-Selective Electrochemical CO2 Reduction February 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03033A, PaperShan Wang, Chen Yang, Feng Chen, Lin-Jun Zhu, Wen-Wen Wang, Qi Hong, Teng ZhangTungsten suboxide (W18O49) was used as a sacrificial template to prepare hollow-shape assembly of CuO nanoparticles as an active and stable catalyst for electrochemical CO2 reduction. Catalyst precursor materials Cu-W18O49-x’s...The content of this RSS Feed (c) […]Shan Wang
- Theoretical study of ether group substitution effects on electrochemical properties of Ti-modified vanadium-oxide clusters February 12, 2026
