RSC – Dalton Trans. latest articles- Indications of Ferroelectric Behaviour Near Room Temperature in the Organic–Inorganic Hybrid Q₂CuBr₄ September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01668A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Agnieszka Cizman, Dorota A. Kowalska, Paweł Szarek, Wojciech Medycki, N. A. Wojcik, Marek A. Gusowski, Monika Trzebiatowska, Adam Bartosiewicz, Liudmyla Filevska, Piotr Staniorowski, Ewelina JachA quinuclidinium-based copper bromide molecular ferroelectric, exhibiting a spontaneous polarization […]Agnieszka Cizman
- Using a sequential synthesis approach to fabricate (Ni,Co)Se2 electrodes for high-performance supercapacitors September 29, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01607J, PaperYi Wang, Sicong Zhang, Qingfeng Zhan, Jingce Bi, Ningning Liu, Xia Zhang, Zhuopeng Wang, Yide Han(Ni,Co)Se2 electrode materials with a rose-petal-like morphology have been fabricated through a sequential synthesis method and exhibit excellent supercapacitor performance.To cite this article before page numbers are assigned, use the DOI form of citation […]Yi Wang
- Structurally Modified Dipyrazinylpyridine-Based Homoleptic Cu(II) Complexes: Comparative Cytotoxic Evaluation in Breast Cancer Cell Lines September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01877C, PaperIndrajit Roy, L. Karthikeyan, Sourav Deb, Sharan Shanmuga Vuppaladadium Rathnam, Jitender Jangra, Snehashish Patra, Anindya Roy, Somnath MajiThe DNA interaction ability of transition metal complexes is closely related to the ligand structure, which plays a crucial role in therapeutic applications. In this context, two mononuclear homoleptic Cu(II)...The content of […]Indrajit Roy
- ICG revisited: Excited-state dynamics as a function of dye concentration and solvent environment September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01894C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maria Lahm, Pascal Rauthe, Kai-Ching Fan, Claus Feldmann, Andreas Neil UnterreinerIndocyanine green (ICG) is a clinically approved tricarbocyanine dye widely used in medical imaging and photodynamic therapy. Its incorporation into inorganic hybrid nanoparticles (IOH-NPs) […]Maria Lahm
- Reactivity of molybdenum–nitride complex bearing NHC-based PCP-type pincer ligand toward unsaturated substrates September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02036K, PaperTomoyuki Miyazaki, Shun Suginome, Taiji Nakamura, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki NishibayashiReactivity of a molybdenum–nitride complex bearing an N-heterocyclic carbene (NHC)-based PCP-type pincer ligand (1), whose nitride ligand is derived from dinitrogen, toward various unsaturated substrates was systematically investigated. The reaction...The content of this RSS Feed (c) The Royal […]Tomoyuki Miyazaki
- Catalytic Degradation of N-Acyl Homoserine Lactone Using Copper Complex of TACN Derivative: Implications for Quorum Sensing Interference September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01612F, PaperDenisa Skurková, Hanna Zhukouskaya, Michaela Buziková, Andrii Mahun, Lívia Kanizsová, Miroslav Vetrik, Jan Kotek, Martin Hruby, Tomáš TobrmanMedical treatment of bacterial biofilms represents a significant challenge, not only in the case of implant-associated infections but also in chronic inflammation of soft tissues. Therefore, further research is crucial...The content of […]Denisa Skurková
- A Digermylene (LGeI -GeIL) on a N-Heterocyclic Carbene-Fluorenyl Hybrid Ligand (L) and its Oxidation by TEMPO and Ph2E2 (E = S, Se) September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02074C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sumana Mondal, Subham Sarkar, Chhotan Mandal, Dibyendu Mallick, Debabrata MukherjeeA hybrid N-heterocyclic carbene (NHC)-fluorenyl ligand (L) supported GeIICl complex ([LGeCl]; 1) is made from GeCl2(dioxane) and [LK]n. 1 is reduced by Jones’ MgI2 dimer […]Sumana Mondal
- Coordinatively unsaturated mononuclear europium (III) complex: a luminescent sensor for adenosine monophosphate in aqueous media September 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01849H, PaperTithi Maity, Raju Biswas, Manik Das, Toushique Ahmed, Soumik Laha, Rosa Maria Gomila, Antonio Frontera, Bidhan Chandra Samanta, Goutam PramanikLuminescent probes for sensing adenosine monophosphate (AMP), particularly in the presence of ADP and ATP, are rare. Herein, we report a novel Eu(III) complex, [(H2O)(L)2Eu(SO3CF3)2](SO3CF3) (EuC), for this purpose, which...The […]Tithi Maity
- Ligand-Protected Silver-Sulfur and Cadmium-Sulfur Clusters: Structures and Transformations September 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02085A, FrontierXinyu Tong, Yi-Jing Zeng, Yan-Xiang Ling, Ju-Suo Zhong, Zhan-Guo Jiang, Cai-Hong ZhanSilver-sulfur (Ag-S) and cadmium-sulfur (Cd-S) clusters, serving as critical bridges linking simple chalcogenides to semiconductor nanoparticles, have emerged as research hotspots in nanomaterials due to their unique optoelectronic properties, atomically...The content of this RSS Feed (c) The Royal […]Xinyu Tong
- Mixed ligand Cu(II) complexes as new precursors for the synthesis of CuO nanomaterials: development of homogeneous and heterogeneous catalysts for styrene epoxidation and phenol hydroxylation under mild conditions September 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01420D, PaperMitu Sharma, Mukesh Sharma, Sazida Yasmin Sultana, Mallayan Palaniandavar, Nashreen S. IslamA new synthetic strategy for obtaining CuO nanocatalysts has been devised using a pair of newly synthesized mixed ligand Cu(II) complexes as the precursors.To cite this article before page numbers are assigned, use the DOI form of citation […]Mitu Sharma
- Lanthanide complexes bearing a bioinspired CuII binding site with picomolar affinity: synthesis, structural, relaxometric and luminescence studies September 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01735A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Katharina Zimmeter, Bertrand Vileno, Agnès Pallier, Carlos Platas-Iglesias, Peter Faller, Célia S. Bonnet, Angélique SourTwo LnIII-DO3A-C3AmpicGH complexes (LnIII = GdIII, EuIII) exhibit high affinity for CuII and high selectivity over ZnII. The EuIII complex […]Katharina Zimmeter
- High-Sensitivity Optical Thermometry with Cr³⁺-Doped Hybrid Formate Perovskites: Comparative Analysis of Ratiometric and Lifetime-Based Approaches September 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01748C, PaperAdam Kabański, Kacper Caputa, Dagmara StefanskaOptical thermometry, due to its properties such as rapid response, usability, high sensitivity, and remote measurements—is gaining increasing interest among researchers. Particularly promising materials for low-temperature thermometry applications are metal-organic...The content of this RSS Feed (c) The Royal Society of ChemistryAdam Kabański
- NiFeCe nanosheet arrays by N and P doping as efficient electrocatalysts for oxygen evolution reaction September 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01787D, PaperChao Xu, Dan Wu, Qiangqiang Wang, Xuan Kuang, Xu Sun, Xiang Ren, Qin WeiThe oxygen evolution reaction (OER) is commonly considered to be the major bottleneck in electrochemical water splitting, characterized by high overpotential requirement, so the fabrication of low cost and high-performing...The content of this RSS Feed (c) […]Chao Xu
- Design of titanium-oxide cluster-based metal-covalent organic frameworks for efficient photocatalytic CO2 reduction September 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01871D, PaperTeng Liu, Yao-Mei Fu, Xing Meng, Li Xue, Hai-Ning Wang, Zhong-Min SuTi6-based MCOF-TDT was synthesized via a Schiff-base reaction and combined with PVDF to form flexible membranes with excellent CO2 to CO photoreduction and mechanical stability.To cite this article before page numbers are assigned, use the DOI form of […]Teng Liu
- Rational Design and Synthesis of a Novel Ternary Metal–Organic Framework with (3,5)-Connected Topology for Iodine Capture September 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01722J, PaperJingjing Yuan, Honghui Lei, Fahui Song, Binbin TuThe discovery of metal–organic frameworks (MOFs) with novel structures opens significant opportunities to improve their performance in gas storage, separation, and catalysis. Rational design of building blocks plays a pivotal...The content of this RSS Feed (c) The Royal Society of ChemistryJingjing Yuan
- Constructing MOF-on-MOF heterojunction on hematite photoanode for efficient photogenerated carrier transport September 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01814E, PaperYuhan Bai, Xiu-Shuang Xing, Mengshuo Yin, Wenting Zhang, Shaomei Wang, You-Juan Zhang, Zhongyuan Zhou, Jimin DuThe effective construction of surface catalyst and heterojunction can accelerate photogenerated carrier separation and transfer to further improve photoelectrochemical water splitting (PEC-WS) performance. Integration of two or more metal-organic frameworks...The content of this RSS […]Yuhan Bai
- Electrocatalytic water oxidation by an unsymmetrical dicopper complex with bridging imidazole-aldoxime ligands in neutral phosphate buffer September 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00962F, PaperSwati Basak, Pranjal Das, Hemrupa Kuilya, Kripangkar Choudhury, Pradyumna Mazumdar, Diganta Choudhury, Apurba KalitaElectrocatalytic water oxidation activity of an unsymmetrical dicopper complex, 1, [Cu2(L1H)(L1)2(OH2)](ClO4)2, with a redox active imidazole-aldoxime ligand, L1H, [L1H = N-hydroxo(4-methyl-imidazol-5-yl)methanimine], has been investigated. Complex 1 exhibit turnover frequency of...The content of this RSS Feed (c) […]Swati Basak
- Sodium phosphaethynolate as P-source for the synthesis of molecular rhodium phosphides: an exploratory study September 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02274F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jaap E Borger, Fabian Müller, Peter Coburger, Hansjörg Grützmacher, Zhongshu Li, Thomas L. Gianetti, Bruno PribanicMolecular transition metal phosphides (TMPs) containing a Rh2P2 and unprecedented Rh4P4 core could be generated from Na[OCP] and rhodium(I) […]Jaap E Borger
- Trinuclear gold chains and octanuclear copper gyrobifastigia stabilized using a fluorinated pyridyl ligand September 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02150B, PaperVo Quang Huy Phan, Mukundam Vanga, Benjamin T. Diroll, Alvaro Muñoz-Castro, H. V. Rasika DiasFluorinated pyridyl ligand allows the isolation of brightly photoluminescent, trinuclear gold(I) helices with aurophilic interactions and discrete, octanuclear copper(I) clusters with cuprophilic bonds.To cite this article before page numbers are assigned, use the DOI form […]Vo Quang Huy Phan
- High photoluminescence quantum yield modulation of zerodimensional organic-inorganic Mn(II) metal halides by substituent modification September 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01992C, PaperQing-Ling Cao, Wen-He Zhong, Jie-Yu Zhu, Cai-Hong Shi, Jia-Jia Zhao, Lizhuang ChenOrganic-inorganic hybrid metal halides have emerged as promising luminescent materials owing to their structural tunability and exceptional photoluminescence modulation capabilities, showing great potential in optoelectronic applications. Herein, we report the...The content of this RSS Feed (c) The Royal […]Qing-Ling Cao
- Indications of Ferroelectric Behaviour Near Room Temperature in the Organic–Inorganic Hybrid Q₂CuBr₄ September 29, 2025
