RSC – Dalton Trans. latest articles- Cleaving a C-F Bond of C6F6 at a Gallium(I) Centre Catalyzed by Nitrogen-Containing Lewis Bases and Its Kinetic Analysis September 8, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01990G, CommunicationTao Ding, Makoto YamashitaGallylenes, gallium(I) molecules in the oxidation state of one, supported by NacNac or Boxm ligand, underwent an efficient C–F bond cleavage of C6F6 upon addition of a stoichiometric/catalytic amount of...The content of this RSS Feed (c) The Royal Society of ChemistryTao Ding
- Dual excitation-wavelength-dependent luminescence and proton transfer in ESIPT-active zinc(II) complexes with 2-(1H-pyrazol-1-yl)-4-(2-hydroxyphenyl)pyrimidine September 8, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01688F, PaperNikita Shekhovtsov, Sofia Vorobyeva, Alexey A. Ryadun, Elena B Nikolaenkova, Alexey Y Tikhonov, Mark B BushuevDinuclear ESIPT-active complexes, [Zn 2 (HL) 2 X 4 ] (X = Cl, Br, I), were synthesized on the base of 2-(1H-pyrazol-1-yl)-4-(2-hydroxyphenyl)pyrimidine (HL). Along with an ESIPT site with a...The content of this RSS […]Nikita Shekhovtsov
- New Dithiooxamide Derivatives as Promising Precursors for ALD/MLD applications September 8, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01405K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Parmish Kaur, Mikko Nisula, Christophe Detavernier, Anjana DeviHybrid materials synthesized combining atomic layer deposition and molecular layer deposition (ALD/MLD) results in advantageous material properties owing to the functionalities contributed from the inorganic and organic […]Parmish Kaur
- Remarkable Coordination Variability of P,C,P-pincer ligand in Organotin(IV) Compounds - A Promising Message for Other p-Block Elements. September 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01873K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Richard Chlebík, Erik Kertész, Milan Erben, Aleš Růžička, Roman Jambor, Zoltán Benkő, Libor DostálThe coordination properties of the P,C,P-pincer ligand (Ar = 2,6-(tBu2PO)2C6H3) to organotin(IV) compounds were examined. For this purpose, a set of […]Richard Chlebík
- Ligand Driven Heterolytic O-O Bond Cleavage in a non-haem Phenolato-Fe(III)-OOH Complex to Yield a Formal Fe(V)=O intermediate September 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01477H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniël R. Duijnstee, Marika Di Berto Mancini, Cornelis Maurits de Roo, Duenpen Unjaroen, Moniek Tromp, Ronald Hage, Wesley R. Browne, Marcel SwartFe(V)=O species can be generated by the heterolytic cleavage of the O-O bond […]Daniël R. Duijnstee
- Double epitaxial growth of ultra-stable Ga2O3/CsPbBr3/CsGaSi2O6 heterostructure for multimodal applications September 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01686J, PaperGuofu Wei, Wei Wang, Jian Ma, Peng Liu, Ming-Dong Zhou, Yan XuConstructing multicomponent heterostructures of lead halide perovskite nanocrystals is crucial for achieving highly stable and enhanced photoluminescence, as well as expanding optoelectronic applications. Herein, a MCM-41 molecular sieves induced double...The content of this RSS Feed (c) The Royal […]Guofu Wei
- Simultaneous electrochemical sensing of Pb2+ and Hg2+ in aqueous media using 5-amino-1,3,4-thiadiazole-2-thiol functionalized mesoporous silica September 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01618E, PaperBipasha Saha, Manjula Pal, Hiroshi Uyama, Mahasweta NandiMetal ion pollution is a major environmental concern with toxic metals like lead (Pb) and mercury (Hg) contaminating water, soil and air which pose serious risks to human health and...The content of this RSS Feed (c) The Royal Society of ChemistryBipasha Saha
- Investigating the DNA binding properties of two new RuII(dppz) complexes incorporating the facially coordinated ligands tris(pyridin-2-yl)methylamine and di(pyridin-2-yl)methylamine September 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01159K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tom Andrews, Craig C. Robertson, Anthony J. H. M. Meijer, Jim A. ThomasBy employing the facially coordinated tris(pyridin-2-yl)methylamine ligand, a route to the synthesis of the complex ([Ru(tpyma)(dppz)(py)]2+ (dppz = dipyrido[3,2-a:2’,3’-c]phenazine) py = pyridine) […]Tom Andrews
- Effect of Rb+ co-doping on the optical properties in VIS and NIR emitting CsPbCl3:Yb3+ perovskite powder September 7, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01084E, PaperWeronika Jagiełowicz, Bartosz Bondzior, Kamila Rajfur, Maciej Ptak, Mariusz StefanskiAn increase in the concentration of Rb ions in powdered CsPbCl3:10%Yb3+ leads to the appearance of structural defects of a different type, allowing the intensity of the emission bands of both the matrix and the optically active dopant to be modified.To […]Weronika Jagiełowicz
- Pressure-induced tuning of the triangular-honeycomb structure of ferroelectric quantum spin liquid candidate, TbInO3 September 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01863C, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christopher J Ridley, Aly Abdeldaim, Craig L. Bull, Kate Tustain, Lucy ClarkThe pressure response of the triangular-honeycomb-structured quantum spin liquid candidate, TbInO3, has been determined via neutron powder diffraction up to 5.75(5) GPa. The […]Christopher J Ridley
- Controllable synthesis of ortho-hexagonal ZnAl-LDHs nanosheets for high-performance room-temperature ethanol gas sensing September 7, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01659B, PaperKun Li, Xia Zhao, Yalin Zhang, Zhen Sun, Wanru Xu, Lanxiang Yao, Xueli YangZnAl-LDHs with tailored Zn/Al ratios were synthesized to regulate oxygen vacancies and nanosheet structure, achieving high-performance ethanol sensing at room temperature.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Kun Li
- Controlled Synthesis and Multi-Effect Synergistic Lithium Storage of Micron-Sized Porous Hexagonal Prismatic Titanium-Based High-Entropy Oxide Anodes September 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01653C, PaperYuqing Cai, Ming-Zhang Huang, Shan He, Ziquan Li, Wen-Juan Xu, Zhen-Dong HuangMetal-organic frameworks (MOFs) have emerged as promising precursors or alternative anode materials for lithium-ion batteries (LIBs). In this work, a Ti-based MOF (Zn0.18Mg0.2Co0.31Ni0.37-Ti-EG (ethylene glycol)) was controllably synthesized through a...The content of this RSS Feed (c) The Royal […]Yuqing Cai
- A tetraphosphino-bis(s-triazine) from cyanuric chloride and Ph2PH: new unexpected tandem C–C/C–P coupling reaction September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01861G, PaperAlexander Artem'ev, Maria Davydova, Anton V. Kuzmin, Marianna I Rakhmanova, Irina Yu. BagryanskayaSerendipitous synthesis of 4,4',6,6'-tetrakis(diphenylphosphino)-2,2'-bi(s-triazine) (Tr2P4) – a novel promising polyphosphine ligand – from cyanuric chloride and diphenylphosphine is reported. This unusual reaction represents the first example of tandem C–C/C–P coupling...The content of this RSS Feed (c) The […]Alexander Artem'ev
- Pincer Chromium (II) Catalyzed Hydrogenation of CO2, and Bicarbonate to Formate September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00070J, PaperTushar Singh, Subrata ChakrabortyPresenting here is catalytic hydrogenation of carbon dioxide to formate using a Cr(II) pincer complex. The complex CrCl2(PNP) C-1 {PNP = N,N-bis(diphenylphosphinoethyl)amine} in combination with NaHBEt3 in the presence of...The content of this RSS Feed (c) The Royal Society of ChemistryTushar Singh
- Phospha-Peterson reactions with esters and thioesters: Isolation of phosphaalkenes bearing C-heteroatom substituents † September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01781E, PaperAaron A. Mitchell, Paul Heine, Joseph Chang, Adam De Paolis, Brian O. Patrick, Derek P. GatesSeveral phospha-Peterson routes to phosphaalkenes from silylphosphines and various ester or thioester reagents are investigated. Treatment of MesP(SiMe 3 ) 2 with PhCO(OPh) in the presence of KOH (10 mol%)...The content of this RSS […]Aaron A. Mitchell
- Electrocatalytic urea synthesis from NO and CO2 on In1Pd single atom alloys September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02018B, PaperTingting Wu, Zihan Tian, Ziyang Zhang, Ye Tian, Ke ChuElectrocatalytic urea synthesis from CO2/NO co-electrolysis (EUCN) has emerged as a promising strategy for sustainable urea production, while simultaneously mitigating greenhouse gas emissions and NO pollutants. Herein, we develop single-atom...The content of this RSS Feed (c) The Royal Society of […]Tingting Wu
- Tripodal bisphenolate–bisphosphine ligands with hybrid hard/soft donors: titanium complexes and dinitrogen activation September 4, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01492A, PaperChunyan Xiong, Jinwei Zhang, Jingyi An, Zhiqiang Yuan, Zhaoxin Li, Yanhong Liu, Shaowei HuHybrid P2O2 ligands combine hard/soft donors stabilize Ti(IV/III). Reduction yields N2-bridged dimers, protonated to NH3 – demonstrating mild N2 activation and functionalization.To cite this article before page numbers are assigned, use the DOI form of citation […]Chunyan Xiong
- Modulating axial anisotropy in tetrahedral Co(II) phosphonate single-ion magnets through N-donor ligand September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01461A, PaperAnanta Patwal, Rajanikanta Rana, Gopalan Rajaraman, Ramaswamy MurugavelMononuclear cobalt(II) phosphonate complexes [Co(HL)2(dmpz)2] (1), [Co(HL)2(imz)2] (2) and [Co(HL)2(bimz)2] (3) (where dmpz = 3,5-dimethylpyrazole; imz = imidazole and bimz = benzimidazole) have been synthesized by reacting cobalt acetate tetrahydrate...The content of this RSS Feed (c) The Royal Society of ChemistryAnanta Patwal
- C2-Symmetric Ru(II) Bimetallic Complexes Catalysed Selective Degradation and Value Addition of Azo Dyes September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01813G, PaperGopal Diliprao Deshmukh, Thakur Rochak Kumar Rana, Neha Yadav, Gopalan Rajaraman, Ramaswamy MurugavelThe textile industry pollutes water with persistent azo dyes, yet their complete hydrogenation remains underexplored. Herein, we report first-time bimetallic Ru(II) complexes for catalytic azo bond activation, achieving complete degradation...The content of this RSS Feed (c) The […]Gopal Diliprao Deshmukh
- Unraveling the electronic mechanisms of transition metal and fluorine co-doping for enhanced electrochemical performance in sodium lithium manganese oxide cathodes September 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00638D, PaperNhan Duong Trong, Nguyen Vo Anh Duy, Nguyen Chi Ben, Duy Khanh Nguyen, Yohandys A. Zulueta, Nguyen To Van, Thi Viet Bac Phung, Nghia Nguyen Van, Minh T. Nguyen, Minh Triet DangEnhancing the structural stability and electronic and electrochemical properties of sodium-ion cathode materials is essential for developing the […]Nhan Duong Trong
- Cleaving a C-F Bond of C6F6 at a Gallium(I) Centre Catalyzed by Nitrogen-Containing Lewis Bases and Its Kinetic Analysis September 8, 2025
