RSC – Dalton Trans. latest articles- Reactive Main Group Metal Complexes of the Neutral NNNN Macrocycle, Me4TACD May 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03357D, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jun Okuda, Priyabrata Ghana, Louis J. MorrisCurrently, there is considerable interest in introducing molecularly defined main group metal compounds as precursors and model complexes of homogeneous catalysts for various bond cleavage and forming transformations. […]Jun Okuda
- High C-rate Li-NMC/Graphite Pouch Cell End-of-Life Prediction via Cycle-Dependent Variations and Machine Learning May 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00659G, PaperJung-goo Choi, Jethro Daniel Agbayani Pascasio, Jaeyoung LeeThe accurate prediction of end-of-life for lithium-ion batteries is crucial for enhancing safety, reliability, and cost-efficiency in electric vehicles and energy storage systems. This study investigates the degradation characteristics of...The content of this RSS Feed (c) The Royal Society of ChemistryJung-goo Choi
- Ferroelectricity and phase transition of halide solid-solution dabcoH(BrxI1−x) May 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00583C, PaperYuki Ohishi, Junya Fujiwara, Atsuko Masuya-Suzuki, Yoko Tatewaki, Sadafumi Nishihara, Shun Dekura, Tomoyuki Akutagawa, Ryo TsunashimaThe ferroelectricity and phase transition of the solid solution of relaxor ferroelectric dabcoHI and dabcoHBr were studied.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Yuki Ohishi
- Self-assembled multidyes-sensitized erbium single molecules for boosting energy transfer light-upconversion in solution. May 28, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00438A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Claude Piguet, Filipe Alves, Ines Taarit, Laure GuénéeEfficient near-infrared (NIR) to visible (VIS) light-upconversion should combine large absorption coefficients NIR with massive quantum yields UC so that the overall brightness BUC = NIRUC is […]Claude Piguet
- Multi -functional zinc cobaltite materials for perovskite solar cell and hydrogen evolution reaction applications May 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00765H, PaperK. P. Muthukumaran, V. Arjun, A. Nithya, Jingbo Zhang, S. KaruppuchamySpinel ZnCo2O4 nanoparticles for perovskite solar cell and HER applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryK. P. Muthukumaran
- Nickel complexes based on amidine for applications in gas-assisted methods and photocatalysis May 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00550G, PaperA. Butrymowicz-Kubiak, A. Topolski, T. M. Muzioł, I. B. SzymańskaWe report the conventional and mechanochemical ‘green’ synthesis of amidine-carboxylate and imidoylamidinate complexes, their characterization, and evaluation for potential use in gas-assisted methods: CVD, FEBID and FIBID.To cite this article before page numbers are assigned, use the DOI form of […]A. Butrymowicz-Kubiak
- Chemistry of Silylated Rare Earths and Heavier f-Elements: Ready to Enter the Next Stage May 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00956A, Frontier Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christoph MarschnerThe last few years have witnessed exciting development in the chemistry of silylated rare earths and heavier f-elements. First examples of silylated lanthanum (La) and praseodymium (Pr) complexes have been...The content of this […]Christoph Marschner
- Synthesis of bulky hydride ligands: m-terphenylborohydride complexes with trivalent uranium and neodymium May 27, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01076D, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Peter A. Zacher, Daniel K. Unruh, Scott R. DalyThe first coordination complexes containing a bulky m-terphenyltrihydroborate ligand are described with [M(H3BArtBu4)3L2] where M = U or Nd, ArtBu4 = 2,6-(3,5-tBu2C6H3)2C6H3, and L = tetrahydrofuran […]Peter A. Zacher
- ortho-Nb2O5 as a recyclable heterogeneous catalyst for the synthesis of 2-substituted benzimidazoles and quinazolinones in an aqueous medium via oxidative dehydrogenative coupling May 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00353A, PaperRajasekharan Jayakumari Deepak, Thiagu Pavin, Ramasamy KarvembuNiobium pentoxide with deformed orthorhombic phase (ortho-Nb2O5) is found to be an efficient heterogeneous catalyst for the synthesis of N-heterocyclic compounds such as 2-substituted benzimidazoles and quinazolinones from primary alcohols...The content of this RSS Feed (c) The Royal Society of ChemistryRajasekharan Jayakumari Deepak
- Synthesis and characterisation of uniform CoPt nanoparticles using red blood cell ghosts conjugated with peptides on their inner surface May 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00502G, CommunicationShota Matsumoto, Zhang Yiyang, Nobuto Yoshinari, Kazuma Yasuhara, Masaaki Ohba, Tomomi KoshiyamaHybrids of metal nanoparticles (NPs) and lipid vesicles are attractive materials in a wide variety of fields including catalysis, sensing, and biomedical applications. Lipid vesicles can entrap metal NPs on...The content of this RSS Feed (c) The Royal […]Shota Matsumoto
- Electrical conductivity of low-doped ceria-based ceramics May 27, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03165B, CommunicationIgor Zagaynov, Sergey V. Fedorov, Olga AntonovaCeria-based ceramic materials (M0.01Ce0.99O2) were successfully synthesized by the co-precipitation method and sintered at 1000 °C for 4 h in air. The electrical conductivity of these systems was measured by...The content of this RSS Feed (c) The Royal Society of ChemistryIgor Zagaynov
- Crown-ether coordination compounds of zirconium, hafnium and scandium using metal nanoparticles May 26, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00968E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lara-Pauline Faden, Lkhamsuren Bayarjargal, Victor Milman, Björn Winkler, Claus FeldmannZr(0)/Hf(0)/Sc(0) nanoparticles (2–8 nm) as starting materials lead to coordination complexes [AlCl2(12c4)][NaAl2Cl8], [ZrCl2(15c5)][Na2Al4Cl16], [HfCl2(15c5)][Na2Al4Cl16], [ScCl2(18c6)][AlCl4] with interesting structural and optical properties.To cite this article before […]Lara-Pauline Faden
- Synthesis and Characterization of Al and Si substituted Polyoxometalates May 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00894H, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jan-Christian Raabe, Saurabh Chitnis, Maximilian J. PollerPolyoxometalates with different transition-metals substituting the main framework element have recently been applied as promising catalysts. In comparison, polyoxometalates, featuring main-group elements in their framework are extremely rare. […]Jan-Christian Raabe
- Antimony vs bismuth: structural differences in Cat{[MCl5](I2)} halogen bond-linked supramolecular complexes May 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00697J, PaperNikita A. Korobeynikov, Andrey N. Usoltsev, Maksim Nailyevich Sokolov, Alexander S. Novikov, Sergey A AdoninFour new hybrid chloroantimonates(III) and chrorobismuthates(III) with halogen bond-linked I2, (H2bpe){[MCl5](I2)} (M = Sb(III) (1); M = Bi(III) (2); bpe – 1,2-bis(4-pyridil)ethane) and (H2bpp){[MCl5](I2)} – (M = Sb(III) (3); M...The content of this RSS Feed […]Nikita A. Korobeynikov
- Ionic transport and luminescence properties in sodium- and fluorine-co-doped rare-earth molybdates NaLn4Mo3O15F (Ln = Sm–Tb) May 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00809C, PaperEkaterina Orlova, Yelizaveta A. Morkhova, Timofei A. Sorokin, Elena Yu Zakharova, Elena Kharitonova, Nikolay Viktorovich Lyskov, Roman Shendrik, Artem A Kabanov, V. O. Yapaskurt, Olga AlekseevaHalogenated rare-earth molybdates of the NaLn4Mo3O15F (Ln = Sm–Tb) nominal composition were synthesized via a solid-state route and investigated for their structural, thermal, IR […]Ekaterina Orlova
- The impact of second coordination sphere functional group extension on product selectivity for manganese bipyridyl CO2 reduction electrocatalysts May 26, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00157A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lisa Suntrup, Vanna Blasczak, Roonak Saeedi, Mehmed Z. Ertem, Jonathan RochfordFour new Mn polypyridyl complexes are studied to probe the influence of distal, outer coordination sphere, H-bonding and steric effects on CO vs. HCO2− […]Lisa Suntrup
- Dicationic ionic liquids with difluorophosphate anions May 26, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00930H, PaperKentaro Kamada, Kohei Nishimoto, Toshiki Nokami, Hideto Nakajima, Jinkwang Hwang, Kazuhiko MatsumotoA new series of dicationic ionic liquids based on difluorophosphate anions have been synthesized and their physical and electrochemical properties were investigated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content […]Kentaro Kamada
- Ag(I) induced H-type and Pd(II) induced J-type phthalocyanines to enhance PDT applications: synthesis, optical behaviors, photochemical/photophysical properties, and DFT studies. May 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00590F, PaperElif Polat, Ahmet Turgut Bilgicli, Tenzile Alagöz, Hayriye Genç Bilgiçli, Hasan Pişkin, Burak Tuzun, Armağan Günsel, Ali Erdogmus, Meryem Nilüfer YaraşırThe literature shows that thiol compounds are important in various diseases, such as oxidative stress, enzymatic reactions, the respiratory system, metabolic disorders, and cancer. Thus, it is important to […]Elif Polat
- Operando Raman and ex situ characterization of an iron-based conductive MOF as a negative electrode in Li-ion batteries May 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00893J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Isabel Ciria-Ramos, Alex R. Neale, Laurence Hardwick, Emilio J. Juarez-Perez, Ignacio Gascón, Marta HaroAn iron-based electrically conductive Metal-Organic Framework (MOF), Fe-HHTP, formed by the coordination of Fe cations and the organic ligand HHTP (2,3,6,7,10,11-hexahydroxytriphenylene), […]Isabel Ciria-Ramos
- Photocatalyst based on transition metal-Schiff base ligand and V-doped Kegging-type polyoxometalate for efficient and stable CO2 reduction May 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01081K, PaperXiaoyu Bai, Yu Lv, Pinfang Yan, Jiulin Zhou, Jilei Wang, Hua Mei, Yan XuIn order to simultaneously control the greenhouse effect and solve the problem of energy depletion, the strategy of converting CO2 into other energy can be used. In this work, two...The content of this RSS Feed (c) […]Xiaoyu Bai
- Reactive Main Group Metal Complexes of the Neutral NNNN Macrocycle, Me4TACD May 28, 2025
