RSC – Dalton Trans. latest articles- The effect of substituents on the P-P and P=C bond properties in phosphanylphosphaalkenes April 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00692A, CommunicationAleksandra Ziolkowska, Wiktoria Błaszkiewicz, Tomasz KruczyńskiA new lithium salt of diphosphane, (iPr₂N)PhP-P(SiMe₃)Li (2), featuring two electronically differentiated substituents, is presented. Its reaction with benzophenone was then carried out, yielding a novel phosphanylphosphaalkene (3). The isolated...The content of this RSS Feed (c) The Royal Society of ChemistryAleksandra Ziolkowska
- Theoretical Study on the Modulation of Oxygen Electrocatalysis in Co-Based Single-Atom Catalysts by N and S Co-Coordination April 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00771B, PaperRui He, Xinyu Zhang, Linlin Zhang, Nan Chen, Zhen Gao, Yanning Wang, Kai XiongUnderstanding how local coordination environments influence oxygen electrocatalytic activity is essential for designing efficient non-precious metal catalysts. In this work, density functional theory (DFT) calculations were performed to systematically explore...The content of this RSS Feed (c) […]Rui He
- (C5N2H7)IO2F2 and (C3N6H8)(IO2F2)2 : Two new organic-inorganic hybrid fluoroiodate birefringent crystals April 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00524H, PaperSi Yuan, Chun-Li Hu, Jiang-Gao MaoBirefringent crystals are anisotropic material commonly used in modern optical devices to obtain polarized light. Traditional commercial birefringence crystals, such as, MgF2 and CaCO3, have the problems of small birefringence...The content of this RSS Feed (c) The Royal Society of ChemistrySi Yuan
- Nanosensors for hazardous pesticides and nanofertilizers for sustainable agricultural: Contribution of carbon quantum dots April 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00633C, PerspectiveTumpa Biswas, Jiko Raut, Diptiman De, Prithidipa SahooThe increasing global population threatens food security, necessitating sustainable agricultural practices. Intensive farming has led to the excessive use of pesticides and fertilizers, contaminating soil and water sources causing the...The content of this RSS Feed (c) The Royal Society of ChemistryTumpa Biswas
- Selective detection of SO2 in NU-1000 via organometallic nickel silylphosphine post-synthetic complex incorporation April 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D3DT03985D, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Juan L. Obeso, Luz Barrios-Vargas, Valeria López-Cervantes, Yoarhy Amador-Sánchez, Nancy Martín-Guaregua, Ricardo A. Peralta, Ramon Munoz, Ana Martínez, Carolina Leyva, Diego Solis-Ibarra, Elí Sánchez-González, Ilich A. Ibarra, Virginia Montiel-PalmaThe adsorption and detection of SO2 […]Juan L. Obeso
- Fe and Cu co-doping induces abundant oxygen vacancies in MnO2 for efficient ozone catalytic oxidation of toluene at room temperature April 23, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00289C, PaperXinuo Cai, Jiahong Liao, Yushui Jiang, Yani Zhang, Lixia Qiu, Lecheng Lei, Xingwang Zhang, Chunlin YuFe and Cu co-doping induces abundant oxygen vacancies in MnO2 for efficient ozone catalytic oxidation of toluene: firstly, ozone is activated to generate reactive oxygen species (ROS), and secondly, ROS attack toluene for degradation.To cite this […]Xinuo Cai
- The Role of Manganese Oxidation State in SF6 Degradation Performance of SiC-Supported Composites April 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00714C, PaperYaru Zhang, Xiang Meng, boxu Dong, Fengxiang Ma, Zhao Yue, Xinhua He, Shan Zhu, Jiantao ZaiSulfur hexafluoride (SF6) is a potent greenhouse gas with a significant impact on the environment and there is a need to develop effective degradation strategies. In this study, a series...The content of this RSS […]Yaru Zhang
- CsCl−Flux Synthesis of Titanium Oxynitride Ti2.85O4N for Photocatalysis April 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00406C, PaperXiaoxuan Xie, Zihan Wang, Yatong Wang, Wenqian ChenThe molten salt method is a key approach for preparing high−performance metal oxide photocatalysts, though its use in metal oxynitrides remains limited. In this work, we successfully synthesized titanium oxynitride...The content of this RSS Feed (c) The Royal Society of ChemistryXiaoxuan Xie
- Interplay of Cu···Cu distance and coordination geometry as a factor affecting the quantum efficiency in dimeric copper(I) halide complexes with the derivatives of 4-pyrazolylpyrimidine-2-thiol April 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00498E, PaperSofia Skvortsova, Fyodor Verkhov, Elena B Nikolaenkova, Marianna I Rakhmanova, T. E. Kokina, Taisiya Sergeevna Sukhikh, Nikita Shekhovtsov, Mark B BushuevBicyclic pyrazolylpyrimidine compounds, 2-benzylthio-4-(3,5-dimethyl-1H-pyrazol-1-yl)pyrimidine (LH) and 2-benzylthio-4-(3,5-dimethyl-1H-pyrazol-1-yl)-6-methylpyrimidine (LMe) were synthesized and studied as ligands for the preparation of copper(I) halido complexes. In the solid state, LH and LMe demonstrate […]Sofia Skvortsova
- Metal Complexes with a Twist: Modified Rhodamines as a Promising Theranostic Approach for Combating Cancer April 22, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03575E, Frontier Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Fábio Martins, Maria da Graça P. M. S. Neves, Ana M.G. SilvaRhodamines have been recognized for their exceptional optical properties, making them suitable for detection, imaging, and disease diagnosis. However, their use as photosensitizers […]Fábio Martins
- Rationally Tailored Passivator with Multisite Surface-anchors for Suppressing Ion Migration toward Air-Stable Perovskite Solar Cells April 22, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00352K, PaperYiqing Chen, Dandan Luo, Dingyu Xia, Fei Wang, Chong Jia, Qiang Zhao, Xinhua LiTrap states in perovskite films fabricated from solution-method can capture photo-generated carriers, expedite ion migration, and contribute to decomposition of perovskite layer, thereby emerging as a major threat to the...The content of this RSS Feed (c) […]Yiqing Chen
- Non-piezoelctric SiO2 amorphous nanomaterials for highly tribocatalytic water purification April 22, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00732A, PaperYan Zhang, Junling Che, Yuhang Gao, Cuijin Pei, Yanmin JiaBeing widely available in the rock layers of the earth, SiO2 is among the earth's most thoroughly distributed natural mineral resources. Here, the non-piezoelectric amorphous SiO2 mineral nanoparticles have been...The content of this RSS Feed (c) The Royal Society of […]Yan Zhang
- The connection between Hydride Affinity and Local Electrophilicity: A key factor in designing frustrated Lewis pairs for reversible H2 activation April 22, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03455D, PaperCésar Barrales-Martínez, Rocío Durán, Julio Caballero, Pablo JaqueWe present a clear relationship between hydride affinity and the condensed-to-boron electrophilicity index for 27 intramolecular aminoborane frustrated Lewis pairs (FLPs), employing Density Functional Theory calculations. First, the Gibbs free...The content of this RSS Feed (c) The Royal Society of ChemistryCésar Barrales-Martínez
- Ionic porous organic polymer as a bifunctional platform for CO2 photoreduction and proton conduction April 21, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03493G, CommunicationJun-Rui Liu, Yao-Mei Fu, Wen-Tao Ju, Meng Lian, Teng Liu, Xing Meng, Hai-Ning Wang, Zhong-Min SuAn ionic porous organic polymer served as a bifunctional platform and performed well in both CO2 photoreduction and proton conduction.To cite this article before page numbers are assigned, use the DOI form of citation […]Jun-Rui Liu
- Structural diversity of photoluminescent lanthanide(III) coordination compounds with an isothiazole derivative April 21, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00127G, PaperE. A. Sanzhenakova, K. S. Smirnova, I. P. Pozdnyakov, A. S. Berezin, V. I. Potkin, E. V. LiderTwo different series of europium(III), terbium(III) and gadolinium(III) complexes with 4,5-dichloroisothiazole-3-carboxylic acid (HL) were obtained.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]E. A. Sanzhenakova
- MgO nanoparticles decorated in-situ nitrogen doping porous carbon hybrid materials as advanced sulfur host in Li-S batteries April 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00475F, PaperLinyue Qu, Dongyuan Lei, Yang Bai, Ming Wu Xiang, Wei Bai, Jun-Ming Guo, Xinzhou Yang, Zixian YangPorous carbon combined with metal oxides modification shows great potential applications in lithium sulfur batteries due to these merits including high encapsulation capacity for active sulfur, short transport path for...The content of this […]Linyue Qu
- A Bioinspired Model for Copper Monooxygenase: A Direct Aromatic Hydroxylation Using O2 April 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02079K, PaperRamamoorthy Ramasubramanian, Karunanithi Anandababu, Mukesh Kumar, Ramasamy MayilmuruganA novel copper(I) complex, [CuI(L)(CH3CN)]CF3SO3 (1) (L = 1,1,2-tri(pyridin-2-yl)propan-1-ol), has been synthesized, characterized, and investigated as a bioinspired model for copper monooxygenases. Under aerobic conditions in CH3CN, complex 1 undergoes...The content of this RSS Feed (c) The Royal Society of ChemistryRamamoorthy Ramasubramanian
- Application of W1.33CTz MXene obtained by hydrothermal etching as an additive to enhance the electrochemical energy storage properties of binder-free Ti3C2Tx MXene films April 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00413F, PaperAlexey Tsyganov, Maria Vikulova, Ilya Zotov, Evgenii V. Korotaev, Ilya Plugin, Victor Sysoev, Demid Kirilenko, Maxim Konstantinovich Rabchinskii, Artur Asoyan, Alexander V. Gorokhovsky, Nikolay GorshkovIn this study, the electrochemical energy storage properties of Ti3C2Tx MXene films have been improved by the addition of W1.33CTz MXenes with ordered vacancies in […]Alexey Tsyganov
- Highly Tenebrescent Hackmanites from Natural Nepheline April 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00389J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cecilia Agamah, Sami Vuori, Ermei Mäkilä, Anssi Peuronen, Mika LastusaariPhotochromic hackmanites (Na,K)8Al6Si6O24(Cl,S)2, were synthesized with a solid state reaction route using natural nepheline, (Na,K)AlSiO4, as a starting material together with NaCl, KCl and Na2SO4. […]Cecilia Agamah
- Tunable Broadband Visible Emission Achieved by Phase Transformation-Driven Self-Reduction of Eu3+ to Eu2+ in Calcium Phosphate Matrix April 20, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00681C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sapargali Pazylbek, Jonas Stadulis, Guna Doke, Andris Antuzevics, Vladimir Pankratov, Greta Merkininkaite, Arturas Katelnikovas, Aleksej ZarkovIn this work, we report the synthesis of Eu2+-doped alpha-tricalcium phosphate (α-TCP, α-Ca3(PO4)2) via a phase transformation of Eu3+-doped […]Sapargali Pazylbek
- The effect of substituents on the P-P and P=C bond properties in phosphanylphosphaalkenes April 24, 2025
