RSC – Dalton Trans. latest articles- Unveiling the Unique Site Preference of Ga in the Defect Wurtzite Type In2Se3-Ga2Se3 System: An Experimental and Computational Study April 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00231A, PaperSiddha Sankalpa Sethi, Achintya Lakshan, Ahin Roy, Siddhartha Das, Karabi Das, Partha Pratim JanaThe pseudo-binary phases in the In2Se3-Ga2Se3 system have drawn attention due to their interesting structural features and exciting non-linear optical (NLO) properties. Although the phases have been known since 1977,...The content of this RSS Feed (c) […]Siddha Sankalpa Sethi
- Polymerisation Isomerism of Tungsten(VI) Oxomethoxide: New Insights into Structure and Reactivity of Non-Cluster Metal Oxoalkoxide Aggregates April 17, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00348B, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gulaim A. Seisenbaeva, Lars kloo, Peter Agback, Vadim G KesslerPolymerization isomerism is potentially important for metal alkoxides as precursors of oxide materials. Here, we present this phenomenon for tungsten oxo-methoxide reporting the molecular and […]Gulaim A. Seisenbaeva
- Well-defined Pt(0) heterogeneous hydrosilylation catalysts supported by a surface bound phosphenium April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00680E, CommunicationDamien Culver, Marco Mais, Min-Chul Kang, Lin Zhou, Frédéric PerrasSingle atom, low valent transition metals are important for heterogeneous catalysis but are challenging to generate and stabilize in a well-defined manner. Herein, we explored the functionalization of silica with...The content of this RSS Feed (c) The Royal Society of […]Damien Culver
- Surface reinforcement of perovskite films with heteroatom-modulated carbon nanosheets for heat-resistant solar cells April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00652J, PaperLele Qiu, Wanyu Tian, Ming Xu, Jian Xiao, Jing Liang, Fang-Jing Liu, Yunpeng ZhaoThe stability issue induced by surface defects of perovskite films remains one of the key constraints in facilitating the commercial adoption of perovskite solar cells (PSCs). Developing reliable passivation strategies...The content of this RSS Feed (c) […]Lele Qiu
- Tailoring Zero-Point Energies in Nanocrystalline 3D Hofmann-Type Spin-Crossover Networks {Fe1−xMx(pz)[Pd(CN)4]}: Impact of Size, Composition, and Surrounding Matrices April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00565E, PaperPradip Chakraborty, Chinmoy Das, Ajana Dutta, Denisa Coltuneac, Laurentiu StoleriuWe report the variation in zero-point energies, ΔE0HL and their distribution, investigated through changes in thermal spin relaxation behavior and cooperativity, in the 3D Hofmann-type guest-free, different-sized nanocrystalline spin-crossover coordination...The content of this RSS Feed (c) The Royal Society of […]Pradip Chakraborty
- Single-component white-light-emitting materials based on lanthanide coordination assemblies April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00172B, PerspectiveM. L. P. Reddy, BEJOY MOHAN DAS K SWhite light-emitting materials (WLEMs) offer significant advantages over traditional incandescent light bulbs and compact fluorescent lamps due to their ability to provide pure white-light emission, low energy consumption, and suitability...The content of this RSS Feed (c) The Royal Society of ChemistryM. L. P. Reddy
- C=O and C=S bond activation by an annulated 1,4,2-diazaborole April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00642B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vignesh Pattathil, Conor PranckeviciusThe reaction of an ambiphilic 1,4,2-diazaborole with C=O and C=S bonds results in formal (3+2) cycloaddition and has allowed the synthesis of a family of 1,3,2-oxazaborole and 1,3,2-thiazaborole derivatives. Computational...The content […]Vignesh Pattathil
- Blue-Light Hydrogen Production via CdS/g-C₃N₄ Heterojunctions April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00187K, PaperKaren Valencia G., Agileo Hernández-Gordillo, Lorena Cerezo Duran, Sandra Elizabeth RodilThis study introduced advanced photocatalytic heterojunctions by integrating CdS nanofibers with defect-rich polymeric carbon nitride (g-C₃N₄-V₀). Two g-C₃N₄-V₀ variants (CN1 and CN2) with varying nitrogen vacancy concentrations were synthesized, enhancing...The content of this RSS Feed (c) The Royal Society […]Karen Valencia G.
- Direct characterisation of mJ = ± 15/2 ground state in octahedral Dy(III) single-molecule magnets April 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00862J, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vijay Parmar, Gemma Kate Gransbury, Sophie C. Corner, Wei-Hao Chou, Stephen Hill, Richard E. P. Winpenny, Nicholas F Chilton, David P MillsTwo heteroleptic octahedral Dy(III) cis-aryloxidecomplexes, [Dy(OPh*)2(THF)3X] {HOPh* = 2,6-bis(diphenyl-methyl)-4-tert-butylphenol; X = Cl (1), […]Vijay Parmar
- Electronic Structure of Molybdenum Chalcogenide Clusters as Supports for Low-Valent Actinides April 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02911A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Pere Miro, S. Genevieve DugganThe metallation, bonding, and electronic structure of redox active incomplete-cubane M3(μ3-Q)(μ2-Q)3 chalcogenide clusters with early actinides were studied using density functional theory and multireference methodologies. We confirmed that the incorporation...The […]Pere Miro
- Lone pair electron-induced attrition of lanthanide ions from a sillenite-structured bismuth gallate host April 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03483J, PaperNistha Singh, Sandeep Nigam, Chiranjib Majumder, Nidhi Gupta, Vasanthakumaran SudarsanThe correlation between local structure & stereochemical activity of Bi3+ ions lone pairs has been observed. This correlation governs attrition of lanthanide ions from penta-coordinated Bi sites in bismuth gallate during conversion from nano to bulk.To cite this article before […]Nistha Singh
- Nonconductive ferrofluids from permanently magnetic nanoplatelets hybridized with polar phosphonic ligands April 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00281H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ali Tufani, Nina Popov, Janez Kovac, Stanislav Čampelj, Andraž Mavrič , Tomas Landovsky, Martin Cigl, Petra Vaňkátová, Martin Loula, Vladimira Novotna, Matic Poberžnik, Gabriela Herrero-Saboy, Layla Martin-Samos, Alenka Mertelj, Darja LisjakFerrofluids composed of permanently […]Ali Tufani
- Six-Coordinate Lanthanide Complexes Based on Bidentate Phosphine Oxide Ligands: Synthesis, Structure and Magnetic Properties April 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00422E, PaperXiao-Jun Wu, Hong-Yao Guo, Wei-Quan Lin, Yan Meng, Ji-Dong LengThree six-coordinate mononuclear lanthanide complexes of the formula [Ln{(O=PPh2)2CH2}2Cl2]Cl·THF based on the Kramers ions Dy3+ (1), Er3+ (2) and Yb3+ (3) have been synthesized and structurally characterized. Single-crystal X-ray diffraction...The content of this RSS Feed (c) The Royal Society of […]Xiao-Jun Wu
- Metal Ion Independent Conductance Through Bis-chelated Metal Complex Molecular Wires based on a Bis(diphenylphosphino)aniline Derivative April 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00292C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marco Filippo Gatto, Sara Sangtarash, David Jago, R. Tom Abram, Eleanor Barrett, Amit Sil, George Koutsantonis, Simon Higgins, Craig Robertson, Richard J. Nichols, Hatef Sadeghi, Andrea VezzoliIt is becoming increasingly evident that transition metal […]Marco Filippo Gatto
- Ultrathin, 2D PdAg alloy mesoporous nanosheets enriched with nanogaps promote electrocatalytic CO2 reduction to formate April 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00436E, PaperShangqing Sun, Miaomiao Liu, Yalan Mao, Fang Liu, Xinyuan Xu, Yuan Li, Ximei Lv, Shulin Zhao, Xiaojing Liu, Yuping Wu, Yuhui ChenPd-based catalysts have emerged as one unique class of the promising catalysts capable of selectively producing formate near the equilibrium potential during CO2 electroreduction, but still suffering from […]Shangqing Sun
- Spin reorientation and magnetic frustration in Fe32+δGe35−xSix with a kagome lattice broken by crystallographic intergrowth April 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00654F, PaperRoman A Khalaniya, Valeriy Verchenko, Andrey V. Mironov, Alexander N. Samarin, Alexey Bogach, Aleksandr Kulchu, Alexey O. Polevik, Wei Zheng, Evgeny V. Dikarev, Raivo Stern, Andrei V ShevelkovFe32+δGe35−xSix was synthesized using solid-state and chemical vapor transport reactions both in powder and single crystalline forms. Single crystal and high-resolution powder […]Roman A Khalaniya
- Novel specific binding of copper ions to naturally modified base pairs involving 5-fluorouracil in duplex DNA April 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00619H, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hidetaka Torigoe, Kei Hirabayashi, Saki Adachi, Jiro KondoOnly merury(II) and silver(I) ions specifically bind to natural and naturally modified base pairs in duplex DNA to form metal-mediated base pairs. We found novel specific binding […]Hidetaka Torigoe
- Synthesis of Highly DispersibleTiO2 Nanoparticles and Their Application in Quantum Dot Light Emitting Diodes April 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00410A, PaperBotao Hu, Mengxin Liu, Xinan Shi, Daocheng PanMetal oxide nanoparticles are commonly used as electron transport layers (ETLs) in quantum dot light emitting diodes (QLEDs) because of their wide band gap, high electron mobility, and appropriate conduction...The content of this RSS Feed (c) The Royal Society of ChemistryBotao Hu
- Achieving balanced UV SHG response, optical band gap and birefringence in rare earth compounds Ln(IO3)(SO4)·3H2O (Ln = Y, Gd, Er, Ho, Dy, Eu) April 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00613A, PaperShihua Ma, Lei Geng, Baozhu Zhu, Chang Yu MengA series of rare earth iodate sulfate UV compounds, Ln(IO3)(SO4)·3H2O (Ln = Y, Gd, Er, Ho, Dy, Eu), have been successfully synthesized by hydrothermal method at 200 °C. These isostructural...The content of this RSS Feed (c) The Royal Society of ChemistryShihua Ma
- Ruthenium(II) and copper(II) polyamine complexes as promising antitumor agents: synthesis, characterization, and biological evaluation April 14, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D4DT03377A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yoel Garrosa-Miró, Laura Muñoz-Moreno, Gerardino D'Errico, Matilde Tancredi, M. Jose Carmena, M. Francesca Ottaviani, Paula Ortega, Javier de la MataNew Ru(II) and Cu(II) complexes with polyamine ligands show high cytotoxicity against prostate cancer cells, […]Yoel Garrosa-Miró
- Unveiling the Unique Site Preference of Ga in the Defect Wurtzite Type In2Se3-Ga2Se3 System: An Experimental and Computational Study April 17, 2025
