RSC – Dalton Trans. latest articles- Single- and Tri-Doping Strategies with Mn2+, Sn2+, and Pb2+ in Cadmium-Based Metal Halides for Primary-Color and Tunable White-Light Emission June 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01111J, PaperMin Chen, Junhui Liu, Kaiwen Sun, Youcai Hu, Junjie Dong, Yue Jiang, Xintong Li, Juan Wang, Fengwan GuoAchieving tunable white-light emission from a single-component cadmium-based metal halide remains challenging. Starting from the three primary-color emissions, the synergistic contribution of red, green, and blue emissions enables the material...The content of […]Min Chen
- Engineering the rhenium metalation of phenanthroline imino complexes for variable structure activity relationships June 28, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00636A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Frederick J. F. Jacobs, Eleanor Fourie, Alice BrinkThe systematic development of mononuclear to symmetrical dinuclear and to asymmetrical di-rhenium complexes with modulated non-covalent interactions influencing biological activity.To cite this article before page numbers are […]Frederick J. F. Jacobs
- Pyridinium amidate (PYA) substituents impact ligand-centered hydride formation and (catalytic) hydride transfer reactivity June 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01322H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Laura Monte, Nicolas Lentz, Martin AlbrechtIridium complexes with pyridinium amidate (PYA) ligands reversibly bind hydrides on the PYA ligand rather than at the iridium center, thus enabling hydride storage and release akin to NAD+/NADH. […]Laura Monte
- Peptide-Coated Magnetic Cobalt Nanozymes with Enhanced Mucus Diffusion and Oxidative Catalysis June 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01241H, PaperJuan Du, Lina Wang, Weixiao Yan, Lingna Meng, Zhaozhu ZhengCystic fibrosis (CF) is a typical chronic respiratory disease in which the highly viscous mucosal barrier in the airways poses a major obstacle to efficient drug delivery. Existing pulmonary inhalation...The content of this RSS Feed (c) The Royal Society of […]Juan Du
- Crystal structures and luminescence properties of Ca3RE2Si4O8N4 (RE = Y, La, and Ce) activated by Ce3+ June 28, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01213B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Makoto Kobayashi, Takuya Yasunaga, Chikako Nagahama, Kotaro Fujii, Masatomo Yashima, Minoru Osada, Hideki Kato, Masato KakihanaNew oxynitrides, Ca3RE2Si4O8N4 (RE = Y, La, Ce), contain rare isolated 12-membered Si(O,N)4 ring units and four distinct cation sites. Ce3+-activated samples […]Makoto Kobayashi
- Outstanding Reviewers for Dalton Transactions in 2025 June 28, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT90092E, EditorialWe would like to take this opportunity to highlight the Outstanding Reviewers for Dalton Transactions in 2025, as selected by the editorial team for their significant contribution to the journal.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS […]
- CuI passivation layer for stabilizing BiI3-sensitized QDSSCs: long-term performance stability assessment June 28, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00958A, PaperShahroz Saleem, Tian-Yi Hu, Kezhen Hui, Ye Feng Wang, Jing Hui ZengPoor performance stability in quantum dot-sensitized solar cells (QDSSCs), mainly arising from electrolyte-induced degradation at the ETM/QD interface, has not been widely investigated.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Shahroz Saleem
- Electronic Effects of 4/-Aryl Substitution in Terpyridine Copper(II) Complexes: Structural Insights, DNA-Binding Affinity, and Cytotoxic Evaluation June 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00795C, PaperL. Karthikeyan, Shobhit Mathur, Nafeesa Shahnaz, Snehashish Patra, Anindya Roy, Somnath MajiEver since the early success of anticancer medications, DNA has been one of the major target molecules in chemotherapeutic drug development. Herein, three new mononuclear Cu(II) complexes [Cu(L1)(L/)](ClO4)2; 1, [Cu(L2)(L/)](ClO4)2;...The content of this RSS Feed (c) The Royal […]L. Karthikeyan
- Isolation of a Trigonal Bipyramidal Mn(II) Diradical Complex with an Intermediate Spin State (S = 3/2) June 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01052K, CommunicationSujit Das, Björn Schwarz, Kartik Chandra MondalIsolation of Mn(II) complexes featuring an intermediate spin state (SMn2+ = 3/2) is quite rare. Previous studies have only speculated on such it in systems such as paddlewheel-type tris(cyclopentadienyl)manganese(II) and...The content of this RSS Feed (c) The Royal Society of ChemistrySujit Das
- Zwitterionic-to-cationic ruthenium carbazole complexes: structure and selective hydroboration of quinolines and pyridines June 25, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00915H, PaperGabriela Sanchez-Lecuona, Garrett M. Wells, Matthew R. Gyton, Julio Zamora-Moreno, Simon B. Duckett, Charles Edwin Webster, Virginia Montiel-PalmaA cationic Ru–carbazole catalyst enables selective hydroboration of pyridines and quinolines under mild, additive-free conditions, affording regiodivergent access to 1,4-dihydropyridines and 1,2-dihydroquinolines.To cite this article before page numbers are assigned, use the […]Gabriela Sanchez-Lecuona
- Halogen Substitution of Aromatic Cations for Phase Transition Control and High-Efficiency Luminescence in 0D Manganese-Based Hybrid Perovskites June 25, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01114D, PaperKaijian Yu, Qiong Ye, Yuechuan Wu, Yawen YangZero-dimensional (0D) organ-ic-inorganic hybrid manga-nese halides are emerging as attractive materials for optoe-lectronic applications, owing to their structural versatility, low toxicity, and excellent luminescence properties. Nevertheless, achieving simul-taneous control over...The content of this RSS Feed (c) The Royal Society of ChemistryKaijian Yu
- Carbonyl insertion into metal-boron based clusters: Pathway to a rhodathiacarborane June 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00931J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Susana Luaces, Jonathan Bould, Fernando J. Lahoz, Ramón MacíasThe reaction of the ten-vertex hydridorhodathiaborane [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] (1) with excess of carbon monoxide at room temperature yields a novel eleven-vertex rhodathiacarborane [1,1-(CO)(PPh3)-3-(OH)-closo-1,2,3-RhSCB8H8] (4). The formation of […]Susana Luaces
- Novel Ruthenium(II) Complexes Bearing Polypyridyl and 1,2,4-Oxadiazole Ligands: From Synthesis to In Vitro and In Vivo Anticancer Evaluation June 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00693K, PaperLaura Marretta, Daniel Valcanover, Maria Pia Buono, Christine Pirker, Sara Amata, Bernhard K Keppler, Antonio Palumbo Piccionello, Alessio Terenzi, Walter Berger, Giampaolo BaroneWe report on the synthesis and characterization of four novel Ru(II) polypyridyl complexes incorporating bipyridine or phenanthroline ancillary ligands. Substituted 1,2,4-oxadiazoles are introduced here for the first […]Laura Marretta
- [Rb4Cl][Cd11In9Se26]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics June 24, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00409A, PaperPengzhi Xie, Qixian Ren, Junwei Feng, Hong Du, Shuyi MiBy tuning [Cd11In9Se26]3− polymerization via [Rb4Cl]3+, we synthesized SIC [Rb4Cl][Cd11In9Se26] with uniformly aligned T2 supertetrahedral.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of […]Pengzhi Xie
- Low-Temperature Operating and Highly Moisture-Resistant Urchin-shaped CuO Microspheres Sensor for n-Pentanol Detection June 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01166G, PaperNa Wang, Kai Lv, Mengxiang Shang, Pengzhi Xu, Hongyu Sun, Jianan Dai, Yang LuIn this work, urchin-shaped CuO hierarchical microspheres assembled from two-dimensional nanosheets were synthesized via a facile one-step hydrothermal route for n-pentanol detection. Structural characterizations confirm the pure phase and porous...The content of this RSS Feed (c) […]Na Wang
- Distorted octahedral supramolecular cages based on spirobiindane with enhanced emission June 24, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01222A, PaperYijun Xiao, Zhantao Wang, Ning Wang, Fan Fu, Wanying Zhong, Zhengguang Li, Zhilong Jiang, Jun Wang, Pingshan Wang, Mingzhao ChenBy employing a C2-symmetric spirobiindane core, two distorted octahedral cages (S1 and S2) were successfully synthesized. Among them, S1 exhibited a high fluorescence quantum yield (ΦF) of up to 96.24% […]Yijun Xiao
- UiO-66-Derived Carbon-Confined PtZn Alloy Catalysts: Synergistic Electronic Structure Regulation and Enhanced Hydrogen Evolution Performance June 23, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00941G, PaperYibo Chen, Delai Wang, Xiruo Wang, Xiang Chen, Hai-Qun Xu, Shilong XuReducing Pt usage while maintaining high activity and durability remains a central challenge for acidic hydrogen evolution reaction (HER) electrocatalysts. Here, we report a confinement-alloying strategy that integrates PtM-u (M...The content of this RSS Feed (c) The Royal […]Yibo Chen
- Radical Switching Am/Eu Selectivity in Sterically Restricted Diglycolamides June 23, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01117A, PaperMikhail A Kalinin, Mariia V. Evsiunina, Paulina Kalle, Petr I Matveev, Nataliya E BorisovaEight new bisoxolactams were prepared from 5-valerolactone and the corresponding amines. A protocol was developed for producing symmetrical and asymmetrical extractants for the separation of Am(III) and Eu(III). It was...The content of this RSS Feed (c) […]Mikhail A Kalinin
- Experimental and computational investigation of the intrinsic reactions of [UIIIF2]+: formation of [UIIIF(O2CR)]+ & [UIII(O2CR)2]+ by reactions with carboxylic acids June 23, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01072E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samuel J. Lenze, Madeline R. Handel, Jacob A. Hartman, Allison P. Zeiss, Amina Ihabi, Theodore A. Corcovilos, Michael J. van StipdonkPreparative tandem mass spectrometry is used to generate gas-phase UIII carboxylate ions from a […]Samuel J. Lenze
- Solvent-directed assembly of Ln and Ln–Co complexes based on a pyridyl-triazolyl functionalized nitronyl nitroxide radical: in situ reduction from NIT to IM and magnetic properties June 22, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01257D, PaperCheng-Cai Xia, Fang Li, Meng-Li Wang, Xin Yan, Wen-Zheng WangSolvent-regulated self-assembly yields cyclic cluster and 1D chain structures with slow magnetic relaxation and rare-earth fluorescence.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]Cheng-Cai Xia
- Single- and Tri-Doping Strategies with Mn2+, Sn2+, and Pb2+ in Cadmium-Based Metal Halides for Primary-Color and Tunable White-Light Emission June 28, 2026
