RSC – Dalton Trans. latest articles- Manganese MOF-derived ruthenium-doped MnxOy catalyst for enhanced oxygen evolution reaction and energy-efficient lead recovery July 13, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01109D, PaperXiaoyue Wang, Rajapriya Andavar, Jiahong Xie, Wenli Liu, Yanzhi Sun, Yongmei Chen, Yang Tang, Pingyu Wan, Junqing PanMnxOy@RuO2 was served as the anodic catalyst for lead recovery from lead MSA electrolyte, reducing OER overpotential and suppressing PbO2 formation, thus lowering energy consumption.To cite this article before page numbers are […]Xiaoyue Wang
- Immobilization of Keggin-type polyoxometalates in cyclodextrin-based polymers for oxidation catalysis July 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01317H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sana Aniba, Nathalie Leclerc, Clément Falaise, Catherine Roch, Samah Toumi Akriche, Emmanuel Cadot, Mohamed HaouasImmobilization of polyoxometalates (POMs) in organic materials by electrostatic attraction has emerged as one of the most effective methods to […]Sana Aniba
- Bifunctional Sr(II)-Based Coordination Polymer for Sensing of Ba(II)/Nitro-aromatic Compounds and Supercapacitor Applications July 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00731C, PaperShama Firdaus, Waris ., Mohd Tameem, Arif Ali, Sumra Dilshad, Musheer Ahmad, Mohammad Zain Khan, Farman Ali, Aiman AhmadMain group element-based coordination polymers (CPs) are being widely studied for energy storage and sensing applications because of their structural versatility and electropositive properties. In this work, Sr(II)-CP namely, (SA2)...The content […]Shama Firdaus
- An Imidazolium Dication Affords a Stable UWY-like Zeolite and Enables a Subtle Structure Direction Towards EMM-17 July 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01413A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Huajian Yu, Peng Lu, Zihao Rei Gao, A. Blanco, Miguel A. CamblorZeolites with interconnected medium (10Ring) and large (12R) pores, such as the UWY framework type, hold significant potential for catalysis but may suffer […]Huajian Yu
- Fluorescent Chemosensing of Epinephrine by a Bis-Boronic Molecular Receptor in Aqueous Media. Crystal Structure, Spectroscopic Studies and Visual Detection July 13, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00784D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alejandro O. Viviano-Posadas, Josue Valdes-García, María Karina Salomón-Flores, Diego Martínez-Otero, Joanatan Bautista-Renedo, Nelly Gonzalez-Rivas, Hilda Sánchez-Vidal, Juan Manuel German-Acacio, Jesus Valdes-Martinez, Alejandro Dorazco-GonzálezSelective neurotransmitter recognition and sensing in aqueous media by artificial receptors is […]Alejandro O. Viviano-Posadas
- Crown-type tetranuclear Ag-POM exhibits excellent proton conductivity performance July 11, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01141H, PaperYahao Sun, Minzhen Cai, Pengtao Ma, Jingping Wang, Jingyang NiuA case of crown-type tetranuclear Ag-POM, Na24[Ag3.4Na0.6(As4W40O140)]‧82H2O (1), was synthesized based on the structural features of {As4W40} using simple materials through hydrothermal method. The polyanion of compound 1 consists of...The content of this RSS Feed (c) The Royal Society of […]Yahao Sun
- α-MoO3 Hybrid with Sulfuric Acid-Intercalated 4,4′-Bipyridine for Adsorptive Dye Removal July 11, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01311A, PaperAnkita Pardiwala, Ritambhara JangirHerein, a polyoxometalate hybrid material, [MoVI3O9(H2SO4)]ꞏ[(bpy)0.5] (1), has been specifically designed for efficient dye adsorption. The molecular structure of 1 was elucidated via single-crystal X-ray diffraction (SC-XRD), revealing a well-defined...The content of this RSS Feed (c) The Royal Society of ChemistryAnkita Pardiwala
- Accelerated Crystallization of All-Silica TON-type Zeolite: Mechanistic Insights into Methanol as a Dual-Function Agent July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01133G, PaperYijia Shi, Shiqi Wen, Xiaotao Yu, Yuxuan Chen, Yinying Jin, Min Guo, Song Lu, Jiadi Ying, Tiancun Liu, QI Shen, Yeqing Wang, Zhixin YuRapid and straightforward synthesis of all-silica zeolites is essential for scaling up their industrial applications in adsorption and separation. However, the synthesis typically necessitates the use […]Yijia Shi
- Electronic structure analysis, a large Stokes shift of Bi3+ in BiSr3(YO)3(BO3)4 and color-tunable emissions by energy transfer to Eu3+ dopants July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01487E, PaperYan Gao, Guangxiang Lu, Rihong Cong, Tao YangA series of BiSr3(Y1-xEuxO)3(BO3)4 (0 ≤ x ≤ 0.4) phosphors with color-tunable emissions were synthesized, and their photoluminescence properties were systematically investigated. Powder X-ray diffraction confirmed the phase purity and...The content of this RSS Feed (c) The Royal Society of ChemistryYan Gao
- Spectroscopic, Structural and Photophysical Characterization of Chloro-Bridged Iridium(III) and Rhodium(III) Dinuclear Complexes with 1-Phenyl-1H-pyrazole and their analogues with 1-(2,4-difluorophenyl)-1H-pyrazole July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01156F, PaperPatryk Wójcik, Camille Latouche, Anna Kamecka, Kinga SuwinskaThe paper deals with the synthesis and spectroscopic characterization of four important precursors, dinuclear [(C^N)2Ir-μ-Cl]2 and [(C^N)2Rh-μ-Cl]2 complexes, containing deprotonated 1-phenyl-1H-pyrazole or 1-(2,4-difluorophenyl)-1H-pyrazole as cyclometallating (C^N) ligands. The molecular structures...The content of this RSS Feed (c) The Royal Society of ChemistryPatryk Wójcik
- Sterically hindered P,N-type amidophosphines {(o-PPh2)C6H4}C(O) NH(R)}: synthesis, transition metal chemistry, and catalytic activity in stereoselective Heck coupling of aryl chlorides July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01353D, PaperGazal Sabharwal, Khilesh Chandra Dwivedi, Maravanji Shivaramaiah BalakrishnaThis paper reports the synthesis, coordination chemistry, and catalytic applications of two amide-based monophosphine ligands, {(o-PPh2)C6H4}C(O)N(H)(C12H18)} (L1) and {(o-PPh2)C6H4}C(O)NH(C33H28)} (L2). Ligand L1, upon reaction with [Pd(COD)Cl2] and [Pd(OAc)2], yielded dimeric...The content of this RSS Feed (c) The Royal Society of ChemistryGazal Sabharwal
- Facile and Green synthesis of [Pd(NHC)(η3-R-allyl)Cl] complexes and their Anticancer Activity July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01326G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Steven P Nolan, Riku Saito, Pierre Arnaut, Benon Maliszewski, Laura Tripodi, Flavio Rizzolio, Thomas Scattolin, Isabella CaligiuriA facile and environmentally friendly method for synthesizing a range of palladium-N-heterocyclic carbene (NHC) complexes—[Pd(NHC)(η3-R-allyl)Cl]—is described. This improved […]Steven P Nolan
- Zinc(II), Copper(II) and Silver(I) Salicylate-Metronidazole Complexes as novel Antimicrobial Agents July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01086A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Laura Contini, Raymond J Turner, Fabrizia GrepioniCombining zinc(II), copper(II) and silver(I) salicylates with metronidazole through via mechanochemistry and slurry, leads to the formation of the new metal complexes [Zn(Sal)2(MET)2] Form I (1a), [Zn(Sal)2(MET)2] Form […]Laura Contini
- Synthesis, structure, magnetic and transport properties of CeFeSb3 July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01387A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Manuel Schulze, Bastian Rubrecht, Felix Seewald, Kati Finzel, B. Büchner, A. Wolter, Hans-Henning Klauss, Thomas Doert, Michael RuckCrystals of CeFeSb3 were synthesised using a Bi-flux. The compound crystallises in the CePdSb3 structure type and […]Manuel Schulze
- Reconfiguration of a mixed-valence copper complex during CO2 electroreduction promotes CO2-to-C2H4 conversion July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01169H, PaperXinkai Wang, Yang Yang, Xian-Ming ZhangDuring the electrochemical CO2 reduction reaction (ECO2RR), understanding the structural changes of high-performance ECO2RR-to-C2H4 catalysts and determining the mode of C-C coupling at active sites are crucial. Molecular catalysts with...The content of this RSS Feed (c) The Royal Society of ChemistryXinkai Wang
- Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene July 10, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01345C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander Evans, Thomas A. Q. Arnold, Paul Ransom, Samantha C. Binding, William K. Myers, Agamemnon E. Crumpton, Zoë R. Turner, Jean-Charles Buffet, Dermot O'HareThe heptamethylindenyl ligand (C9Me7; Ind*) has been used to synthesise manganese […]Alexander Evans
- Constructing crystalline NiCo2O4/amorphous MoNiCo-LDH through high valence Mo doping for high-performance hybrid supercapacitors July 10, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01251A, PaperJuan Lei, Yan Zhang, Yujing Wang, Xiaoli Ren, Lijun Cheng, Qinqin He, Shuang WangIn this work, high valence Mo was introduced to prepare amorphous MNC-LDH (MoNiCo-LDH) for constructing crystalline NCO/amorphous MNC-LDH (crystalline NiCo2O4/amorphous MoNiCo-LDH) composite. The prepared sample exhibited a three-dimensional pompom-like structure...The content of this RSS Feed (c) […]Juan Lei
- Mn(III) Porphyrins as Photosensitizers: Structural, Photophysical and Anticancer Studies July 9, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT03432E, PaperBidisha Bora, Namisha Das, Jakia Parbin Sultana, Md Kausar Raza, Tridib K. GoswamiHerein, we synthesized, characterized and explored the photo-triggered anticancer activity of five Mn(III) porphyrins Mn1-Mn5 viz. (diaqua)meso-(tetraphenylporphyrinato)manganese(III) propionate, [Mn(III)TPP(H2O)2]+(C3H5O2-) or Mn1; (diaqua)meso-tetrakis(4-methylphenylporphyrinato)manganese(III) propionate, [Mn(III)TMeP(H2O)2]+(C3H5O2-) or Mn2; (diaqua)meso-tetrakis(4-methoxyphenylporphyrinato)manganese(III) propionate, [Mn(III)TMP(H2O)2]+(C3H5O2-) or...The content of this RSS Feed (c) The […]Bidisha Bora
- Synthesis and Studies of meso-3-Pyrrolyl BODIPYnyl Porphyrins July 9, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00853K, PaperAbani Sarkar, Debendra Tewary, Ankit Kumar, Mangalampalli RavikanthNew meso-substituted porphyrins containing one to four 3-pyrrolyl BODIPY units at the meso-positions named as meso-3-pyrrolyl BODIPYnyl porphyrins were synthesized in 15-20% yields by condensing meso-4-formyl phenyl-3-pyrrolyl BODIPY, benzaldehyde, and...The content of this RSS Feed (c) The Royal Society of ChemistryAbani Sarkar
- Stabilization of the garnet lattice by silicon incorporation in polycrystalline Katoite July 9, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01202C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Artem Shevchenko, Keshia Morell, Sebastian Bette, Igor Moudrakovski, Bettina V. Lotsch, Robert E. DinnebierPolycrystalline single-phase bulk Hydrogrossulars (Ca3Al2(SiO4)3-x(OH)4x (0 ≤ x ≤ 3)) of various compositions were synthesized for the first time utilizing hydrothermal […]Artem Shevchenko
- Manganese MOF-derived ruthenium-doped MnxOy catalyst for enhanced oxygen evolution reaction and energy-efficient lead recovery July 13, 2025
