RSC – Dalton Trans. latest articles- Alkali-Site Lithium Doping Enables a High-Performance Na3Fe2(PO4)(P2O7) Cathode for Sodium-Ion Batteries Tháng 6 5, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01061J, PaperZijun Sun, Wenzhu Cao, Xiyang Hu, Ze YangIron-based polyanionic Na3Fe2(PO4)(P2O7) (N3F2PP) has emerged as a compelling cathode candidate for sodium-ion batteries (SIBs) owing to its cost-effectiveness and structural stability. Nevertheless, its practical application is constrained by intrinsically...The content of this RSS Feed (c) The Royal Society of ChemistryZijun Sun
- Transition Metal-type Reactivity at Trivalent P-Centers: How Structural Distortions Promote Bond Breaking and Forming via Two-Electron Redox Reactions and/or Phosphorus-Ligand Cooperativity Tháng 6 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00735J, FrontierMatthew F CainAn ongoing goal to use Main Group Elements like phosphorus to promote Transition Metal-type reactivity has received significant attention across the chemistry community. Transition metal (TM) complexes are unique because...The content of this RSS Feed (c) The Royal Society of ChemistryMatthew F Cain
- Regulation of Bis(triarylamine) Conformation by Auxiliary Ligands in Coordination Polymers for Modulation of Redox-Activity Tháng 6 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00981F, CommunicationSheng-Yu Jin, Ya-Ru Meng, Fan Ji, Zhong-Yuan Cai, Yuan Liang, Gen Zhang, Jian SuBy introducing auxiliary ligands of different lengths, four bis(triarylamine)-based coordination polymers were constructed, and their crystal structures and redox activities were studied. Structural analysis revealed that a higher degree of...The content of this RSS Feed (c) […]Sheng-Yu Jin
- Unraveling the structural features of Dion--Jacobson--type layered perovskite-related material HCa2Nb3O10·1.5H2O Tháng 6 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03086B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zihao Zhang, Jun Kano, Shu MORITA, Hiromu Shimokawa, Minoru OsadaHydrated layered oxides are widely encountered, yet the presence of disordered interlayer water often complicates crystal structure determination from laboratory X-ray diffraction. Here, we report […]Zihao Zhang
- A Ligand in the Metal Salt Sea: Extreme Metal-to-Ligand Ratios and the Thermodynamic Driving Force of the Halogen Bond Tháng 6 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00722H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alper YardanThis study presents the rational design, synthesis, and comprehensive structural elucidation of a novel series of halogenated coordination complexes featuring Cu(II), Co(II), Cd(II), and Mn(II) centers. By deliberately employing an...The content of this […]Alper Yardan
- .Reduction of nitric oxide to HNO by sodium dithionite: kinetics and mechanism Tháng 6 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00559D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paola Vargas, Mateus F. Venâncio, Willian R. Rocha, Sebastian A. Suarez, Fabio DoctorovichSodium dithionite is a widely used reductant in biochemical and industrial applications, yet its intrinsic instability and complex redox chemistry continue to […]Paola Vargas
- Understanding the reactivity and activation barrier origins in the cycloaddition of triplet pnictinidenes with phenylacetylene Tháng 6 4, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01126H, PaperZheng-Feng Zhang, Ming-Der SuAs the atomic radius of the Group 15 center increases, the deformation energy of Ar′CCH becomes larger, resulting in higher activation barriers for the [1 + 2] cycloaddition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Zheng-Feng Zhang
- Ce(III) containing tricobalt-substituted silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)]13-: A versatile nano-cluster with a multitude of applications Tháng 6 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00088F, PaperShivani ., Vivek Das, Ahsan ul Haq, Shivangi Prandiyal, Anwar Alam, Anne-lucie Teillout, Pedro de Oliveira, Arun Kant, Himani Chahar, Debabrata Mishra, Olivier Blacque, Firasat HussainIn this work, we report a structurally distinct cerium-containing tricobalt-substituted Keggin-type silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)] 13-. In addition to the Ce-based complex (2a), we have also […]Shivani .
- Competitive Coordination of Uranium(VI) and Thorium(IV) by Tetradentate Phenanthroline Ligands: Structural and Spectroscopic Investigation of U(VI)-Th(IV) Mixed Ion Pair Formation Tháng 6 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00392C, PaperSvetlana Gutorova, Petr I. Matveev, Mariia V. Evsiunina, Qiushi Wang, Pavel S. Lemport, Paulina Kalle, Daniil S Koshelev, Valentina V. Utochnikova, Alexey A. Averin, Tatiana R. Poliakova, Mikhail A. Gerasimov, Vladimir G. Petrov, Yuri Ustynyuk, Stepan Kalmykov, Valentine NenajdenkoTetradentate phenanthroline-based ligands have demonstrated ability to efficiently extract uranium(VI) from […]Svetlana Gutorova
- A Dye-loaded Fe4L4 Cage for Efficient Photocatalytic C(sp3)-H Activation Tháng 6 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00729E, PaperJunhao Zhang, Youpeng Shi, Yuchen Wu, Fengyu Yang, Xu Jing, Chunying DuanWe report the rational construction of a novel cationic metal-organic cage C1 featuring a well-defined Fe₄L₄ tetrahedral structure. C1 possesses a large inner cavity and robust openings, which enable it...The content of this RSS Feed (c) The Royal […]Junhao Zhang
- Amino-functionalized SiC electrodes for highly sensitive simultaneous detection of Pb2+, Cd2+, Cu2+, Hg2+ Tháng 6 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00487C, PaperXin Wang, Linlin Zhou, Xin-Mei HouAnthropogenic and industrial activities release toxic and non-biodegradable heavy metal ions (HMIs) into the environment, posing severe ecological risks even at trace concentrations and necessitating their critical detection. Voltammetry has...The content of this RSS Feed (c) The Royal Society of ChemistryXin Wang
- Molecular Engineering of an 2,5-dithiophen-2-yl-pyrrole Bridged Terpyridine-Fe (II) Coordination Polymer toward Multi-State Electrochromic Energy Storage Tháng 6 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00867D, PaperYuting Song, Hui Qiao, Lin Cheng, Zibo Wei, Beili Lu, Biao Huang, Jiayu TaoElectrochromic energy-storage materials are of great interest due to their ability to simultaneously achieve reversible color modulation and charge storage, where molecular engineering plays a key role in performance optimization....The content of this RSS Feed (c) […]Yuting Song
- Optical and dielectric properties of Sillén Bi2Y1-xMxO4Cl (M = Cu, Cd) Tháng 6 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00244G, PaperMeena Sheokand, Shivangi Rao, Neetu Yadav, Rajamani NagarajanMixed-anion solids with reduced dimensionality and layered (2D) structures exhibit a range of advantages arising from their tunable bonding environments and structural flexibility. Studies involving cationic substitution in the Sillen...The content of this RSS Feed (c) The Royal Society of ChemistryMeena Sheokand
- Gradually changing the fraction of clusters and nanoparticles in Au13/WO3-derived photocatalysts for H2O2 synthesis Tháng 6 3, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00776G, PaperRohul H. Adnan, D. J. Osborn, Shaojing Yan, Yukatsu Shichibu, Hideki Nakajima, Katsuaki Konishi, Gregory F. Metha, Gunther G. AnderssonEvolution of the Au13 cluster size and the increase in the fraction of nanoparticles enhance the H2O2 yield and production rate due to the formation of a metal–support interaction and […]Rohul H. Adnan
- Weakly Coordinating Borophosphates – Ca0.5M(H2O)2[B(PO4)2]•H2O (M = Mg, Mn, Co, Zn, Cd) Tháng 6 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00484A, PaperVivien Wessels, Martina Mikuta, Henning A. HöppeUp to now, a considerable number of borophosphates have been reported, despite the young history of this material class.However, detailed Tanabe-Sugano analyses to investigate the coordination strength of the host...The content of this RSS Feed (c) The Royal Society of ChemistryVivien Wessels
- Spin-lattice relaxation of copper and vanadyl porphyrins in extended molecular framework materials Tháng 6 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00996D, CommunicationYukina Suzuki, Kazunobu Sato, Masanori Wakizaka, Ryota Sakamoto, Masahiro YamashitaSpin-lattice relaxation times (T₁) of Cu(II) and VO(IV) porphyrins in extended framework materials (covalent, hydrogen-bonded, and metal–organic frameworks) are investigated as prototypical molecular spin qubits. All framework materials studied here...The content of this RSS Feed (c) The Royal Society of […]Yukina Suzuki
- The design of earth abundant metal catalysts for nitrous oxide-based oxidations: Part I. N2O coordination and oxygen-transfer to metal Tháng 6 2, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01002D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kenneth M. NicholasNitrous oxide, thermodynamically unstable but kinetically unreactive, presents a challenge for catalysis. The viability of transition metal-catalyzed hydrocarbon oxidation by N2O is evaluated computationally based on the scheme above.To cite this article […]Kenneth M. Nicholas
- Accessing chiral NHC-boranes by abstraction of C6F5 from the B(C6F5)4− weakly coordinating anion Tháng 6 2, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02919H, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nicolas Niessen, Abel Idrice Adjieufack, Nikolay Tumanov, Johan Wouters, Benoît Champagne, Guillaume Berionni, Kajetan BijouardThe prolonged heating of an N-heterocyclic carbene-stabilised borenium cation resulted in the abstraction of a –C6F5 group from its B(C6F5)4− […]Nicolas Niessen
- Energetic Mn(II)/Ni(II) Coordination Compounds in Catalyzing RDX and HMX Decomposition and Enhancing Combustion Tháng 6 1, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00937A, PaperMingcheng Ge, Xuankun Liu, Jianguo Yang, Jinfeng Yan, Jianguo Zhang, Zhimin LiTo develop energetic combustion catalysts for solid propellants, two novel energetic metal coordination compounds, Mn(AIM)6(BF4)2 (Mn-ABF) and Ni(AIM)6(BF4)2 (Ni-ABF), were successfully synthesized in this study. These compounds were prepared by...The content of this RSS Feed (c) The Royal […]Mingcheng Ge
- Mechanochemical synthesis, solvent-controlled coordination, and catalytic oxidation activity of furoic acid-based Mo(VI) complexes Tháng 6 1, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00558F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Josipa Sarjanović, Béla Fiser, Jana PiskThis study shows that ligand design and coordinating solvents govern the structure, stability, and reactivity of Mo(VI) Schiff-base complexes. The resulting catalysts enable efficient and selective benzyl alcohol oxidation […]Josipa Sarjanović
- Alkali-Site Lithium Doping Enables a High-Performance Na3Fe2(PO4)(P2O7) Cathode for Sodium-Ion Batteries Tháng 6 5, 2026
