RSC – Dalton Trans. latest articles- Halogen Substitution of Aromatic Cations for Phase Transition Control and High-Efficiency Luminescence in 0D Manganese-Based Hybrid Perovskites Tháng 6 25, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01114D, PaperKaijian Yu, Qiong Ye, Yuechuan Wu, Yawen YangZero-dimensional (0D) organ-ic-inorganic hybrid manga-nese halides are emerging as attractive materials for optoe-lectronic applications, owing to their structural versatility, low toxicity, and excellent luminescence properties. Nevertheless, achieving simul-taneous control over...The content of this RSS Feed (c) The Royal Society of ChemistryKaijian Yu
- Zwitterionic-to-cationic ruthenium carbazole complexes: structure and selective hydroboration of quinolines and pyridines Tháng 6 25, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00915H, PaperGabriela Sanchez-Lecuona, Garrett M Wells, Matthew Robert Gyton, Julio Zamora-Moreno, Simon B Duckett, Charles E Webster, Virginia Montiel-PalmaWe report the synthesis of the Ru(II) zwitterionic complexes [MeRu(η⁶-carbazole-N-EMe2Cl)(PPh3)2] (E= Al, Ru-1; Ga, Ru-2) via a one-pot reaction of RuCl2(PPh3)3 with carbazole in the presence of excess group 13...The content of […]Gabriela Sanchez-Lecuona
- Novel Ruthenium(II) Complexes Bearing Polypyridyl and 1,2,4-Oxadiazole Ligands: From Synthesis to In Vitro and In Vivo Anticancer Evaluation Tháng 6 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00693K, PaperLaura Marretta, Daniel Valcanover, Maria Pia Buono, Christine Pirker, Sara Amata, Bernhard K Keppler, Antonio Palumbo Piccionello, Alessio Terenzi, Walter Berger, Giampaolo BaroneWe report on the synthesis and characterization of four novel Ru(II) polypyridyl complexes incorporating bipyridine or phenanthroline ancillary ligands. Substituted 1,2,4-oxadiazoles are introduced here for the first […]Laura Marretta
- Carbonyl insertion into metal-boron based clusters: Pathway to a rhodathiacarborane Tháng 6 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00931J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Susana Luaces, Jonathan Bould, Fernando J. Lahoz, Ramón MacíasThe reaction of the ten-vertex hydridorhodathiaborane [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] (1) with excess of carbon monoxide at room temperature yields a novel eleven-vertex rhodathiacarborane [1,1-(CO)(PPh3)-3-(OH)-closo-1,2,3-RhSCB8H8] (4). The formation of […]Susana Luaces
- Distorted Octahedral Supramolecular Cages Based on spirobiindane with Enhanced Emission Tháng 6 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01222A, PaperYijun Xiao, Zhantao Wang, Ning Wang, Fan Fu, Wanying Zhong, Zhengguang Li, Zhilong Jiang, Jun Wang, Pingshan Wang, Mingzhao ChenAlthough the structural framework for constructing regular polyhedral supramolecular cages from symmetric ligands is relatively well established, assembling distorted polyhedra using ligands of lower symmetry remains a considerable challenge. Herein,...The […]Yijun Xiao
- Low-Temperature Operating and Highly Moisture-Resistant Urchin-shaped CuO Microspheres Sensor for n-Pentanol Detection Tháng 6 24, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01166G, PaperNa Wang, Kai Lv, Mengxiang Shang, Pengzhi Xu, Hongyu Sun, Jianan Dai, Yang LuIn this work, urchin-shaped CuO hierarchical microspheres assembled from two-dimensional nanosheets were synthesized via a facile one-step hydrothermal route for n-pentanol detection. Structural characterizations confirm the pure phase and porous...The content of this RSS Feed (c) […]Na Wang
- [Rb4Cl][Cd11In9Se26]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics Tháng 6 24, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00409A, PaperPengzhi Xie, Qixian Ren, Junwei Feng, Hong Du, Shuyi MiBy tuning [Cd11In9Se26]3− polymerization via [Rb4Cl]3+, we synthesized SIC [Rb4Cl][Cd11In9Se26] with uniformly aligned T2 supertetrahedral.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of […]Pengzhi Xie
- Radical Switching Am/Eu Selectivity in Sterically Restricted Diglycolamides Tháng 6 23, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01117A, PaperMikhail A Kalinin, Mariia V. Evsiunina, Paulina Kalle, Petr I Matveev, Nataliya E BorisovaEight new bisoxolactams were prepared from 5-valerolactone and the corresponding amines. A protocol was developed for producing symmetrical and asymmetrical extractants for the separation of Am(III) and Eu(III). It was...The content of this RSS Feed (c) […]Mikhail A Kalinin
- UiO-66-Derived Carbon-Confined PtZn Alloy Catalysts: Synergistic Electronic Structure Regulation and Enhanced Hydrogen Evolution Performance Tháng 6 23, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00941G, PaperYibo Chen, Delai Wang, Xiruo Wang, Xiang Chen, Hai-Qun Xu, Shilong XuReducing Pt usage while maintaining high activity and durability remains a central challenge for acidic hydrogen evolution reaction (HER) electrocatalysts. Here, we report a confinement-alloying strategy that integrates PtM-u (M...The content of this RSS Feed (c) The Royal […]Yibo Chen
- Experimental and computational investigation of the intrinsic reactions of [UIIIF2]+: formation of [UIIIF(O2CR)]+ & [UIII(O2CR)2]+ by reactions with carboxylic acids Tháng 6 23, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01072E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samuel J. Lenze, Madeline R. Handel, Jacob A. Hartman, Allison P. Zeiss, Amina Ihabi, Theodore A. Corcovilos, Michael J. van StipdonkPreparative tandem mass spectrometry is used to generate gas-phase UIII carboxylate ions from a […]Samuel J. Lenze
- Homoleptic Nickel(II) and Cobalt(II) Complexes of N,N′-Dialkyl-β-dialdiminato Ligands Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01165A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Claire E Schmit, Gregory S GirolamiA series of volatile cobalt(II) and nickel(II) N,N′-dialkyl-bis(β-dialdiminato) complexes of stoichiometry M[RN(CH)3NR]2 (where R = methyl, ethyl, iso-propyl, or tert-butyl) have been prepared and characterized. NMR, IR, and UV-vis […]Claire E Schmit
- GdOCl-Modified Polymeric Carbon Nitride Heterojunction for One-Photon Excitation Efficiently Driven Photocatalytic Hydrogen Production Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00875E, PaperSadia Habib, Jing-Han Li, Aisha Habib, Shuai Chen, Hao-Yang Ding, Ru-Xin Tian, An-Wu XuVisible light driven photocatalytic hydrogen evolution using sacrificial agents is a promising route for solar to chemical energy conversion. However, achieving efficient charge separation and migration in heterogeneous semiconductor photocatalysts...The content of this RSS Feed (c) […]Sadia Habib
- Stepwise C−H bond activations and assembly of binuclear Ln3+ species coordinated by hexaanionic anti-η5:η5-dibenzopentalene-bridged bis(carbazolyl) framework Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01110A, PaperAlexander A. Trifonov, Gautier Félix, Dmitry Lyubov, Max Kallio, Veacheslav Vieru, Hamza Zakaria, Anna V Vologzhanina, Rinat R. Aysin, Joulia Larionova, Yannick GuariNew binuclear rare-earth complexes [(μ 2 -η 5 :η 5 ;κ 2 :κ 2 -N,C-L)Ln2(THF)4] (Ln = Y 3+ (1Y), Tb 3+ (1Tb), Dy 3+ (1Dy), Er […]Alexander A. Trifonov
- Long-Persistent Luminescent Zinc Coordination Polymer with Multi-Stimulus Responsiveness: Construction, Triple-mode Emission, and Applications in Information Encryption and Dynamic Anti-Counterfeiting Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00879H, PaperRui Wang, Su-Jia Liu, Yong-Sheng Shi, Dong-Dong Yang, Xiangjun ZhengPolymer-based long afterglow materials have garnered extensive research attention in information encryption and dynamic anti-counterfeiting, yet developing multi-stimulus-responsive and time-resolved long afterglow materials remains challenging. Herein, a novel zinc(II) coordination...The content of this RSS Feed (c) The Royal Society of […]Rui Wang
- Physicochemical properties and biological activity of heteroleptic cyclometalated Rh(III) complexes. A comparative analysis with Ir(III) analogues based on 3,5-dimethyl-1-phenyl-1H-pyrazole and auxiliary ligands Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00998K, PaperKarol Okła, Natalia Maciejewska, JERZY SITKOWSKI, Anna Kamecka, Katarzyna Kazimierczuk, Małgorzata Zienkiewicz-Machnik, Barbara Barszcz, Joanna MasternakTo directly probe the role of the metal centre in cyclometalated anticancer agents, we developed a new series of heteroleptic Rh(III) complexes as rhodium congeners of our previously reported Ir(III)...The content of this RSS […]Karol Okła
- Solvent-Directed Assembly of Ln and Ln-Co Complexes Based on a Pyridyl-Triazolyl Functionalized Nitronyl Nitroxide Radical: In Situ Reduction from NIT to IM and Magnetic Properties Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01257D, PaperCheng-Cai Xia, Li Fang, Mengli Wang, Xin Yan, Wen-Zheng WangA pyridine-triazole functionalized nitronyl nitroxide radical ligand NIT-4trz-3Py (NIT-4trz-3Py = 3-(4-(1-triazole)-3-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was designed to construct a series of lanthanide and Ln-Co magnetic complexes through solvent-regulated assembly. In total, seven complexes...The content of this RSS Feed (c) The Royal Society of […]Cheng-Cai Xia
- Ruthenium nitrosyl complexes with bidentate heterocycles: synthesis and the transformations in the solutions Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00903D, PaperAnastasiya O Brovko, Ivan A Yakovlev, Natalia Kuratieva, Dmitriy G. Sheven, Gennadiy KostinA series of novel complexes with the general formula [RuNO(NH₃)₂(L)(NO₃)] 2+ , where L is a bidentate ligand (bpym, bpy, or phen), was synthesized and characterized. Trans-(NO, NO₃) and cis-(NO,...The content of this RSS Feed (c) The […]Anastasiya O Brovko
- Exploration of Role of Carboxylate-Bridges on the Magnetisation Dynamics of {LnIII2} (Ln = Tb, Dy, Ho, and Er) Paddle-Wheel Single-Molecule Magnets: Structure-Property Correlations Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01456A, PaperVipanchi Vipanchi, Bapan Jana, Ganeshmoorthi Balan, Angshuman Roy Choudhury, Maheswaran Shanmugam, Kuduva R. VigneshLanthanide-based complexes are excellent candidates for observing single-molecule magnet (SMM) behaviour since the Ln(III) ions possess a strong magnetic anisotropy, which arises mainly from spin-orbit coupling of each single-ion magnetic...The content of this RSS Feed (c) […]Vipanchi Vipanchi
- Synthesis of Filled β-Mn-Type Ternary Tellurides Using a Boron-Tellurium Reaction Mixture Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00913A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chirantha Edirisinghe, Subhendu Jana, Eric Gabilondo, P. Shiv Halasyamani, Paul MaggardThe synthetic discovery of new metal-telluride phases remains challenging due to the limitations of stabilizing increasingly complex compositions using conventional solid-state reactions. Described herein, […]Chirantha Edirisinghe
- Ligand-Field Modulation, Jahn-Teller Distortion and Redox Behavior in Cu(II) Schiff Base Complexes Tháng 6 22, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00665E, PerspectiveShubham Vatagude, Masaki Horitani, Prabhuodeyara M. GurubasavarajCu(II) Schiff base complexes constitute a structurally versatile class of coordination compounds in which ligand architecture exerts decisive control over geometry, ligand-field stabilization and redox accessibility. This Feature Article organizes...The content of this RSS Feed (c) The Royal Society of ChemistryShubham Vatagude
- Halogen Substitution of Aromatic Cations for Phase Transition Control and High-Efficiency Luminescence in 0D Manganese-Based Hybrid Perovskites Tháng 6 25, 2026
