RSC – Dalton Trans. latest articles- Vanadyl complexes supported by O,O-and N,O-chelate ligation: Structures and polymerization catalysis Tháng 3 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00387G, PaperKaname Shibata, Kenji Michiue, Ignas Motuzis, Mark Robert James Elsegood, Carl RedshawReaction of dibromosalicylic aldehyde and 2,6-diisopropylaniline, followed by sodium borohydride, and 2-chloromethylpyridine hydrochloride/triethylamine, and then with [VO(OiPr)3] led to [VO(L)(LH)] (where L = 2,6-iPr2C6H3N=CH-2-(O)-C6H2Br2-3,5) (1) as the major product, together...The content of this RSS Feed (c) The Royal […]Kaname Shibata
- Catalytic Hydroboration of α,β-Unsaturated Ketones Using β-Diketiminate Magnesium Hydride and Mechanistic Insights Tháng 3 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00286B, PaperAnubhab Das, Sayantan Mukhopadhyay, Sagrika Rajput, Sharanappa NembennaWe report the selective hydroboration of ynones and enones catalyzed by DepNacnac stabilized magnesium hydride, Mg-1 [{LMgH}₂; L = DepNacnac = (DepNCMe)2CH; Dep = 2,6-Et2-C6H3] under mild conditions. A wide...The content of this RSS Feed (c) The Royal Society of ChemistryAnubhab Das
- SnCl2[SC(NH2)2]: Lone-Pair and Hydrogen-Bonding Triggered Chromophore Assembling for Dual Optical Optimization Tháng 3 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00144K, PaperXing-Yu Bi, Yuting Gao, Chenyuan Ma, Zhi Fang, Mei-Hong DuanDesigning birefringent crystals with wide band gap presents significant challenges, especially within chalcogenide systems. Herein, motivated by the high structural anisotropy of thiourea, along with the ultraviolet compatibility and birefringence...The content of this RSS Feed (c) The Royal Society of […]Xing-Yu Bi
- 4d Orbital Ruthenium Doping Enables High-Capacity and Stable α-MnO 2 Cathodes for Aqueous Zinc-Ion Batteries Tháng 3 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00187D, PaperXinyang Zhang, Guochao Zhao, Xueyan Yang, Dewei Wang, Yuhong Chen, Chunping HouThe electrochemical performance of α-MnO 2 cathodes in aqueous zinc-ion batteries is limited by their low electronic conductivity, structural instability due to Jahn-Teller distortion, and slow Zn²⁺ diffusion kinetics. Despite...The content of this RSS Feed (c) The Royal […]Xinyang Zhang
- How copper(II) and zinc(II) bind to Tau protein and how might this promote aggregation? Tháng 3 12, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03057A, PaperBettina Diána Balogh, Giuseppe Di Natale, Giuseppe Pappalardo, Katalin VárnagyNeurodegenerative taupathies are characterized by extracellular protein deposits of amyloid-β and intracellular aggregates of hyperphosphorylated tau in the brain. Great number of publications supports that essential metal ions (such as...The content of this RSS Feed (c) The Royal Society of […]Bettina Diána Balogh
- Deciphering the Mechanistic Insights and Reactivity Trend of High-Valent Mn/Fe/Co-oxo Species toward C-H Bond Activation and Oxygen Atom Transfer Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03104D, PaperMukhtar Ahmed, Manjeet Kumar, Mursaleem Ansari, Manoj K. Gupta, Azaj AnsariUnderstanding the structure and reaction pathways of high-valent metal-oxo species in C-H bond activation and oxygen atom transfer reactions is of great importance for improving their reactivity. Herein, we examine...The content of this RSS Feed (c) The Royal Society […]Mukhtar Ahmed
- Organoceria nanostructured hybrid materials: a novel approach for band gap modulation in ceria Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00140H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.María Puerto-Jiménez, Enqi Bu, Daniel Goma Jiménez, Almudena Aguinaco, Juan J Delgado, Jose Pintado, Ginesa Blanco, Adrián Bogeat-BarrosoThe development of efficient visible light photocatalysts based on ceria (CeO2) requires precise control over both morphology […]María Puerto-Jiménez
- Transition metal complexes with phosphine oxide appended aza-macrocycles – effects of ring size and denticity Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00255B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julie Herniman, George Keeling, Rhys P. King, Navya Kandathil-Sintho, Mark E. Light, Kate Snowsill, Gillian ReidTwo new phosphine oxide appended aza-macrocyclic ligands, L1 and L3, have been prepared in good yield from the reaction […]Julie Herniman
- Spin dynamics and long phase-memory times in structurally distinct non-oxido vanadium(IV) complexes with rigid ligand frameworks relevant to molecular qubits Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02909K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Oluseun Akintola, Sudhir Lima, Michael Seifert, Benjamin Kintzel, Helmar Görls, Rupam Dinda, Winfried PlassWe report two chemically very similar non-oxido V(IV) complexes that feature distorted octahedral and distorted trigonal prismatic coordination geometries, as elucidated […]Oluseun Akintola
- Synthesis of hybrid phosphinoferrocene ligands bearing amine pendants and catalytic evaluation of their gold(I) complexes Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00321D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.David Rezazgui, Ivana Císařová, Petr Štěpnička, Jiří SchulzA series of hybrid, ferrocene-based phosphines bearing additional amine substituents has been synthesized and evaluated in gold catalysis. The series includes 1,1′- and 1,2-disubstituted phosphinoferrocene donors with […]David Rezazgui
- Water-soluble silver nanoparticles stabilized by amino acid-derived N-heterocyclic carbenes: synthesis, properties and theoretical study of the nucleation process Tháng 3 11, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00206D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Carlos J. Carrasco, Regla Ayala, Sara Garrido, Francisco Montilla, Agustín GalindoNHC-stabilized Ag-NPs exhibit ligand-dependent stability, with the less steric demanding species displaying robustness, redispersibility and effective catalytic behavior. The stability trends, nucleation and NP […]Carlos J. Carrasco
- Spontaneous assemblies of gigantic poly-oxomolybdates; from structure and properties to synthetic methods Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03084F, Tutorial Review Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vishal Lakhanpal, Deliang Long, Lee CroninGigantic polyoxomolybdates, dominated by the Molybdenum Blue (MB) family, constitute a key subclass of polyoxometalates (POMs) and play a fundamental role in elucidating structural construction principles and showcasing […]Vishal Lakhanpal
- Structural Characterization, Proton Conductivity and Furfural Catalysis of Novel Polyfunctional Zirconium Phosphonates Tháng 3 11, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02947C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Montse Bazaga García, Rosario M. Pérez Colodrero, Álvaro Vílchez, Pascual Olivera Pastor, Juan Antonio Cecilia, Lukasz Kurowski, Jan Kazimierz Zaręba, Aurelio Cabeza DíazZirconium phosphonates combine the thermal robustness of Zr–O frameworks with the rich […]Montse Bazaga García
- NO photoswitches: a single photoinduced linkage isomer in diamagnetic {MNO}8 complexes Tháng 3 10, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00116E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Artem A. Mikhailov, Axel Gansmüller, Asma Hasil, Sébastien Pillet, Gennadiy Kostin, Guillaume Chastanet, Theo Woike, Dominik SchanielIn electron rich {MNO}8 complexes, a single photoinduced linkage isomer corresponding to an isonitrosyl configuration can be generated.To […]Artem A. Mikhailov
- Influence of anionic substitutions on the nonlinear-optical and luminescent properties of Ca 9.75 Eu 0.5 (VO 4 ) 7 Tháng 3 10, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02750K, PaperVladimir V. Titkov, Egor Latipov, Oksana V. Baryshnikova, Fedor D. Fedyunin, Dina V. Deyneko, Bogdan LazoryakNew anion-substituted vanadates Ca 9.75±δ Eu 0.5 (XO 4 ) 0.1 (VO 4 ) 6.9 (X = As 5+ , S 6+ , Sb 5+ , Ta 5+ , Mo...The content of this RSS Feed […]Vladimir V. Titkov
- Combined Computational and Experimental Study on Nitrilimines Generated from 2,5-Substituted Tetrazoles Tháng 3 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00045B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael Thomas Thoenen, Aleska Milosavljevic, Davin Piercey, Paul Wenthold Nitrilimines are a useful chemical intermediate for the synthesis of a variety of nitrogen heterocycles for use in pharmaceuticals, energetics, and other energy storage applications. […]Michael Thomas Thoenen
- Position-Oriented N-Methylation Engineering: Multidimensional Regulation of Energy-Safety Balance in Energetic Copper Complexes Tháng 3 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00365F, PaperChao Zhang, Tingwei Wang, Shaoqun Li, Zu-Jia Lu, Cong Li, Meiqi Xu, Binshan Zhao, Qiyao Yu, Jianguo ZhangThe development of green and insensitive primary explosives to replace toxic heavy-metal-based energetic materials (e.g., lead azide) remains a central challenge in the field of modern energetic materials. This work...The content of […]Chao Zhang
- Synthesis, Structural Characterization and Rigidity Dependent Dual Luminescence Behavior of High-Energy Phosphorescent Zinc(II) Cyclic (Alkyl)(Amino)carbene Complexes Tháng 3 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00177G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mousree Mitra, Ondřej Mrózek, Andrey Belyaev, Lars Janiak, Christel Maria Marian, Andreas SteffenThe study explores the synthesis, structural characterization, and photophysical properties of cyclic (alkyl)(amino)carbene (cAAC) zinc(II) complexes, focusing on their unique rigidity-dependent dual […]Mousree Mitra
- Uncovering Lithium Iron Metaphosphate as a Cathode Material Through Organophosphate Assisted One-Pot Synthesis Tháng 3 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00283H, PaperYongda Guo, Jingbo Huang, Junzheng Wei, Yating Hu, Shaoming Huang, Ximeng LiuMetaphosphate–based polyanionic compounds represent an underexplored class of cathode materials for lithium–ion batteries, despite their rigid framework chemistry and intrinsic safety advantages. Herein, we report the first systematic investigation of...The content of this RSS Feed (c) The Royal […]Yongda Guo
- Synthesis of Mn-bearing Layered Perovskite-type Niobate and Its Delaminated Nanosheet Tháng 3 9, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00131A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yasuo Ebina, Yuichi Michiue, Nobuyuki Sakai, Takayoshi SasakiLayered perovskite-type compounds with the general formula MCa2MnNb3TiO13 (M = K, Rb), in which Mn2+ is incorporated into the A-site of the perovskite layers, were synthesized via […]Yasuo Ebina
- Vanadyl complexes supported by O,O-and N,O-chelate ligation: Structures and polymerization catalysis Tháng 3 12, 2026
