RSC – Dalton Trans. latest articles- Solvent-free mechanochemical access to phase-pure Cs–Co–Cl halometalates with tuneable electronic properties for energy applications June 26, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01355K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pablo Garrido, Darío Espinoza, Karem Gallardo, Rosa M. González-Gil, Rodrigo CastilloSolvent-free mechanochemistry enables the synthesis of CsCoCl3, Cs2CoCl4, and Cs3CoCl5 with tunable dimensionality and optoelectronic properties dictated by the Co2+ coordination environment.To cite this […]Pablo Garrido
- Metal–organic frameworks for methanol-to-olefins (MTO) products purification June 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01117E, FrontierBaobing Tang, Xueyue Yu, Yunling LiuEthylene and propylene are fundamental feedstocks in the chemical industry, and their production currently relies predominantly on petroleum cracking. In recent years, the maturation of methanol-to-olefins (MTO) technology has opened...The content of this RSS Feed (c) The Royal Society of ChemistryBaobing Tang
- Engineering an Amine-Functionalized Zn(II) Interpenetrated Metal-Organic Framework for Comprehensive Iodine Uptake Across Diverse Phases and Selective Azo Dye Adsorption June 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01228G, PaperShaikh Arfa Akmal, Mohd Khalid, M. Shahid, Musheer AhmadIn this study, a two-fold interpenetrated 3D Zn-based metal-organic framework, {[Zn2(btc)(Hata)(H2O)2]}n (AR-2), was successfully synthesized via a hydrothermal approach using 1,2,4,5-benzene tetracarboxylic acid and 3-amino-1,2,4-triazole as oxygen and nitrogen donor...The content of this RSS Feed (c) The Royal Society of ChemistryShaikh Arfa Akmal
- Acoustic shock wave driven dynamic recrystallization induced reversible rod-to-cube morphology transition in CdS: preserving structural integrity with optical modifications June 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00998G, PaperF. Irine Maria Bincy, Oviya Sekar, Kannappan Perumal, Ikhyun Kim, S. A. Martin Britto DhasAcoustic shock wave driven dynamic recrystallization induced reversible rod-to-cube morphology transition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]F. Irine Maria Bincy
- Pt-cathode hydrogen evolution enabled by low-potential [Co(en)3]-intercalated layered MnO2 anodes on bamboo and CNT composite films June 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01069A, PaperRyo Sasaki, Riku Okiguchi, Ayuri Senuma, Kazuaki TomonoLow-potential hydrogen evolution (+1.10 V vs. Ag/AgCl) is enabled by [Co(en)3]-intercalated layered MnO2 anodes grown on bamboo and CNT films, driving continuous H2 release at a Pt cathode.To cite this article before page numbers are assigned, use the DOI form of citation […]Ryo Sasaki
- Coordination Polymers with Iridium(III) Metalloligands: The Effect of Pore Size Upon Luminescent Cation Sensing June 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00813A, PaperZhejun Hong, Pattara Siripanich, Oliver Grant Stansfield, Christopher R. Hall, Timothy U Connell, Carol HuaThe chemical sensing of metal ions is important in environmental monitoring and biomedical diagnostics. Iridium(III) metalloligand-based coordination polymers (CPs) containing Cd(II): [Cd{(Ir(ppy)2(dcbpy)}2] (1), [Cd{(Ir(ppy)2(dcbpy)(H2O)2}2]∙8H2O (1-H2O), [Cd2{Ir(dfppy)2(dcbpy)}4]∙DMF (2) and [Cd{Ir(bt)2(dcbpy)}2]∙DMF (3)...The content of this RSS Feed […]Zhejun Hong
- Dynamically Tunable Strong Coupling via Insulator-Metal Phase Transition in VO2 Coupled to Mid-infrared SrTiO3 Phonons June 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01112D, PaperYuliang Zhi, Xin Cui, Qi Fang, Gaige ZhengDynamically tunable strong light-matter coupling in the mid-infrared (MIR) regime holds significant promise for next-generation photonic and thermal devices, especially in the long-wave infrared (LWIR) range of 19-23 $\mu m$, where...The content of this RSS Feed (c) The Royal Society of ChemistryYuliang Zhi
- Rational engineering of a tetrametal–organic framework for enhanced electrocatalytic oxygen evolution June 24, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00451A, PaperYanmei Xie, Fuhe Le, Xue Yang, Wanting Shu, Rui Sheng, Anjie Liu, Wei JiaTetrametallic NiFeCoV-MOF-74 demonstrates exceptional oxygen evolution reaction performance, attributed to the synergistic interplay of multiple metals and the in situ formation of highly active NiOOH and CoOOH catalytic sites.To cite this article before page numbers are […]Yanmei Xie
- Physicochemical Characterization of MMP-14 Active Site–Zn(II)–Peptide Inhibitor Ternary Complexes: A Strategy for Matrix Metalloproteinase Inhibition in Cancer Progression June 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01074H, PaperPaulina Potok, Martyna Zawada, Robert Wieczorek, Elżbieta Gumienna-Kontecka, Slawomir PotockiCancer metastasis remains the leading cause of cancer-related morbidity and mortality, highlighting the urgent need for novel therapeutic strategies. Matrix metalloproteinases (MMPs), i.a. the membrane-bound MMP-14, play pivotal roles in...The content of this RSS Feed (c) The Royal Society of […]Paulina Potok
- Effects of the anion exchange between I− and NCS− coordinated to Co2+-centered tetrahedra in the organic–inorganic hybrid halides June 24, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00924C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Takuya Ohmi, Ryuju Ito, Sergey A. Nikolaev, Kotaro Fujii, Iain W. H. Oswald, Koki Matsushima, Yuiga Nakamura, James R. Neilson, Masatomo Yashima, Masaki Azuma, Takafumi Yamamoto(CH3NH3)2Co(NCS)4 and (CH3NH3)3CoI4(NCS) with isolated Co2+-centered tetrahedra were successfully […]Takuya Ohmi
- Macrocyclic Transition-Metal Parashift Complexes for MRI at Clinical and Pre-clinical Magnetic Fields June 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01149C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nicola J. Rogers, Ashok KUMAR Chowan, Daniel Bowdery, Carlson Alexander, Galina Ernestovna Pavlovskaya, Peter HarveyA series of macrocyclic transition-metal complexes, including Fe(II), Co(II), Ni(II), and Cu(II) complexes, have been evaluated for parashift MRI imaging […]Nicola J. Rogers
- Liquid metal/ionic liquid lubricants: rational design and tribological performance evaluation June 24, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01049G, PaperChuan Li, Wenyang Huang, Xu Tan, Wenqi Zhang, Enzhu Hu, Xingkai DingTo improve the performance of lubricants, a liquid metal/ionic liquid 1-hexyl-3-methylimidazole hexafluorophosphate (LM/IL) additive was prepared in this study using a simple ultrasonic dispersion method.To cite this article before page numbers are assigned, use the DOI form of […]Chuan Li
- Thermal activation of g-C3N4-tourmaline to drive the Fenton reaction in the dark: promoting carrier migration through a polarization electric field and a heterojunction structure June 24, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00949A, PaperXiao Zhou, Tao Yang, Yu Zhang, Lan Yang, Chunfang DuUnder the synergy of a polarization electric field and a heterojunction structure, the electrons were easily transferred from CN to tourmaline by elevating the temperature, promoting the Fenton reaction rate and the cycling process.To cite this article before page numbers […]Xiao Zhou
- 1-D polymeric and 2-D layered zinc monoalkyl phosphates bearing long alkyl chains: Synthesis, structural transformations and thermal behaviour June 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00783F, PaperHarsha Arya, Ramaswamy MurugavelReactivity of two different alkyl phosphate esters with zinc metal ion has been explored. The reaction of zinc nitrate with n-octyl phosphate leads to a mixture of [(nOctO)PO3Zn(DMF)]n (1) and...The content of this RSS Feed (c) The Royal Society of ChemistryHarsha Arya
- Solubilizing dimolybdenum paddlewheel complexes for energy storage applications June 24, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01246E, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simon G. Gersib, S. M. Supundrika Subasinghe, Neal P. MankadMo≣Mo paddlewheel complexes bearing solubilizing groups were synthesized for their tunable physical properties relevant to energy storage applications.To cite this article before page numbers are […]Simon G. Gersib
- A strongly hydrogen-bonded one-dimensional high-spin dinuclear Fe(II) complex June 24, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01007A, CommunicationHoa Phan, Kieu Thuy Thi Thai, Nobuto Funakoshi, Huyen Thu Thi Tran, Masahiro Yamashita, Michael ShatrukIn this study, we report the synthesis and detailed characterization of a novel chain compound, composed of hydrogen-bonded dinuclear complexes, in which two Fe(II) ions are bridged by a 2,2′-biimidazolate (bim2−) dianion.To cite this […]Hoa Phan
- Partial congener substitution induced wide band gap witnessed in diamond-like chalcogenide ZnHg2P2S8 and its second-order nonlinear optical properties June 23, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01124H, PaperChunlan Tang, Aoge Yao, Wenhao Xing, Jian Tang, Lei Kang, Wenlong Yin, Jieyun Wu, Bin KangPartial congener substitution widens the band gap while preserving a strong nonlinear optical response.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed […]Chunlan Tang
- Unquenched orbital angular momentum in quasi-linear two-coordinate transition metal complexes featuring sterically bulky carbazole ligands June 23, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00782H, CommunicationSadia Noor, Samantha Stegman, Jacob B. Palmer, Brian S. DolinarA new carbazole based bulky ligand has been employed to synthesize a series of quasi-linear two-coordinate complexes. The cobalt(II) complex with a non-Aufbau ground state exhibits slow magnetic relaxation.To cite this article before page numbers are assigned, use the DOI […]Sadia Noor
- Photoswitching chiroptical response in camphorate-based chiral metal-organic frameworks June 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00814J, PaperKatelyn Mary Clutterbuck, Hunter J. Windsor, Deanna Michelle D'Alessandro, Girish LakhwaniPhoto-switchable chiral materials are highly sought for various applications, including sensing, nonlinear optics, and liquid-crystalline devices. However, the origin and control of switching have not been well studied. Here, we...The content of this RSS Feed (c) The Royal Society […]Katelyn Mary Clutterbuck
- Osmium-terpyridine complexes linked with stilbene-coupled naphthalene, anthracene, and pyrene moieties act as multichannel sensors for F- and Hg2+ via non-classical interactions June 23, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01134E, PaperTanusree Ganguly, Tuhin Abedin, Sujoy BaitalikFluoride (F-) and mercuric (Hg2+) ion sensing behaviours of homoleptic Os(II)-terpyridine complexes coupled with stilbene-appended naphthalene, anthracene and pyrene motifs have been thoroughly investigated here through the intermediacy of multiple...The content of this RSS Feed (c) The Royal Society of ChemistryTanusree Ganguly
- Solvent-free mechanochemical access to phase-pure Cs–Co–Cl halometalates with tuneable electronic properties for energy applications June 26, 2025
