RSC – Dalton Trans. latest articles- Advance and prospect of MIL-based drug delivery system in diagnosis and treatment of cervical cancer June 8, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00965D, PerspectiveYize Zhang, Yanna Ye, Qiyi Zhong, Zhiheng Yan, Ziyu Feng, Alireza Nezamzadeh-Ejhieh, Guanming Jiang, Ying Pan, Zhanping Gou, Jian-Qiang LiuCervical cancer, a common gynecological malignant tumor, poses a serious threat to women's health. Despite significant advances in cancer treatment, there is still a lack of effective early detection methods,...The […]Yize Zhang
- Pyrene-based Metal-Organic Frameworks (MOFs) and Hydrogen-Bonded Organic Frameworks (HOFs) for Photocatalytic Applications June 8, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00763E, PerspectiveMo Qijie, Jiewei LiuPyrene-based metal–organic frameworks (MOFs) and hydrogen-bonded organic frameworks (HOFs) have emerged as a distinctive class of photoactive crystalline materials for photocatalytic applications. The exceptional photophysical properties of pyrene, including strong...The content of this RSS Feed (c) The Royal Society of ChemistryMo Qijie
- Enhancing the potential of Cs 0.1 MA 0.9 PbI 3 perovskite layer through the suspension of pure and vanadium-doped metal sulphides for solar cells June 7, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01055E, PaperDhanasekaran Vikraman, Hailiang Liu, Sajjad Hussain, K. Karuppasamy, Jungwon Kang, Jongwan Jung, Akram Alfantazi, Hyun-Seok KimThough perovskites remain a vital component of the electronics industry and solar cell technology, the defects that occur in perovskite films due to uncontrollable crystallization and the fragility of ionic...The content of this RSS […]Dhanasekaran Vikraman
- Structural Insights into Chalcogen Polycations and Their Stabilization via (Hydrogen)polysulfates June 7, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01115B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jan Langwald, Sergi Burguera Piña, Antonio Frontera, Mathias Siegfried WicklederWe report the preparation and characterization of the cations [Se4]2+, [Te4]2+ and [Te6]4+, stabilized as polysulfates, namely [Se4][S2O7], [Se4][HS2O7]2, [Se4][HS3O10]2, [Te4][HS3O10]2, [Te6][HS3O10]4 and [Te6][S4O13]2. In […]Jan Langwald
- Ligand flexibility and counterion-driven diversity in morpholine-based Cd(II), Cu(II), Zn(II), and Ni(II) complexes: crystallographic, computational, and cytotoxicity insights June 7, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00736H, PaperMusa Ahmadi, Majid Rezaeivala, Elnaz Zeynaloo, Yu-Ping Yang, Robert William Gable, Navneet KhetrapalLigand flexibility and counterion effects govern structural diversity and functional behvior in a series of Cd(II), Cu(II), Zn(II), and Ni(II) coordination complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Musa Ahmadi
- Hydroxide Anion Attack Governs O-O Bond Formation in Water Oxidation Catalysed by a Mononuclear Manganese Complex June 7, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00843G, PaperQinyi Huo, Morteza Jamshidi, Zhuofei Liu, Matthew Longhurst, Rob Stranger, Alireza AriafardElectrocatalytic water oxidation by the mononuclear Mn(II) pyridinophane complex [{Py₂N(tBu)₂}Mn(H₂O)₂]²⁺ has been experimentally observed to occur under strongly basic conditions (pH = 12.2). In this work, the mechanism of this...The content of this RSS Feed (c) The Royal […]Qinyi Huo
- Rare-earth orthoferrites (RFeO3, R = La, Y) as next-generation electrode materials for high-performance supercapacitors June 7, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00836D, PaperArshad Iqbal, Abdul Hakeem Anwer, Abdelbaki Benamor, Mohd Arshad, Naseem Ahmad, Tahira Khatoon, Nafees AhmadThis study addresses the synthesis and electrochemical assessment of nanocrystalline orthoferrites (RFeO3, R = La and Y) synthesized via a sol–gel auto-combustion method.To cite this article before page numbers are assigned, use the DOI form […]Arshad Iqbal
- Alkali-Site Lithium Doping Enables a High-Performance Na3Fe2(PO4)(P2O7) Cathode for Sodium-Ion Batteries June 5, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT01061J, PaperZijun Sun, Wenzhu Cao, Xiyang Hu, Ze YangIron-based polyanionic Na3Fe2(PO4)(P2O7) (N3F2PP) has emerged as a compelling cathode candidate for sodium-ion batteries (SIBs) owing to its cost-effectiveness and structural stability. Nevertheless, its practical application is constrained by intrinsically...The content of this RSS Feed (c) The Royal Society of ChemistryZijun Sun
- .Reduction of nitric oxide to HNO by sodium dithionite: kinetics and mechanism June 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00559D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paola Vargas, Mateus F. Venâncio, Willian R. Rocha, Sebastian A. Suarez, Fabio DoctorovichSodium dithionite is a widely used reductant in biochemical and industrial applications, yet its intrinsic instability and complex redox chemistry continue to […]Paola Vargas
- Understanding the reactivity and activation barrier origins in the cycloaddition of triplet pnictinidenes with phenylacetylene June 4, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT01126H, PaperZheng-Feng Zhang, Ming-Der SuAs the atomic radius of the Group 15 center increases, the deformation energy of Ar′CCH becomes larger, resulting in higher activation barriers for the [1 + 2] cycloaddition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Zheng-Feng Zhang
- Ce(III) containing tricobalt-substituted silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)]13-: A versatile nano-cluster with a multitude of applications June 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00088F, PaperShivani ., Vivek Das, Ahsan ul Haq, Shivangi Prandiyal, Anwar Alam, Anne-lucie Teillout, Pedro de Oliveira, Arun Kant, Himani Chahar, Debabrata Mishra, Olivier Blacque, Firasat HussainIn this work, we report a structurally distinct cerium-containing tricobalt-substituted Keggin-type silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)] 13-. In addition to the Ce-based complex (2a), we have also […]Shivani .
- Unraveling the structural features of Dion--Jacobson--type layered perovskite-related material HCa2Nb3O10·1.5H2O June 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03086B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zihao Zhang, Jun Kano, Shu MORITA, Hiromu Shimokawa, Minoru OsadaHydrated layered oxides are widely encountered, yet the presence of disordered interlayer water often complicates crystal structure determination from laboratory X-ray diffraction. Here, we report […]Zihao Zhang
- Regulation of Bis(triarylamine) Conformation by Auxiliary Ligands in Coordination Polymers for Modulation of Redox-Activity June 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00981F, CommunicationSheng-Yu Jin, Ya-Ru Meng, Fan Ji, Zhong-Yuan Cai, Yuan Liang, Gen Zhang, Jian SuBy introducing auxiliary ligands of different lengths, four bis(triarylamine)-based coordination polymers were constructed, and their crystal structures and redox activities were studied. Structural analysis revealed that a higher degree of...The content of this RSS Feed (c) […]Sheng-Yu Jin
- Transition Metal-type Reactivity at Trivalent P-Centers: How Structural Distortions Promote Bond Breaking and Forming via Two-Electron Redox Reactions and/or Phosphorus-Ligand Cooperativity June 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00735J, FrontierMatthew F CainAn ongoing goal to use Main Group Elements like phosphorus to promote Transition Metal-type reactivity has received significant attention across the chemistry community. Transition metal (TM) complexes are unique because...The content of this RSS Feed (c) The Royal Society of ChemistryMatthew F Cain
- A Ligand in the Metal Salt Sea: Extreme Metal-to-Ligand Ratios and the Thermodynamic Driving Force of the Halogen Bond June 4, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00722H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alper YardanThis study presents the rational design, synthesis, and comprehensive structural elucidation of a novel series of halogenated coordination complexes featuring Cu(II), Co(II), Cd(II), and Mn(II) centers. By deliberately employing an...The content of this […]Alper Yardan
- Amino-functionalized SiC electrodes for highly sensitive simultaneous detection of Pb2+, Cd2+, Cu2+, Hg2+ June 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00487C, PaperXin Wang, Linlin Zhou, Xin-Mei HouAnthropogenic and industrial activities release toxic and non-biodegradable heavy metal ions (HMIs) into the environment, posing severe ecological risks even at trace concentrations and necessitating their critical detection. Voltammetry has...The content of this RSS Feed (c) The Royal Society of ChemistryXin Wang
- Optical and dielectric properties of Sillén Bi2Y1-xMxO4Cl (M = Cu, Cd) June 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00244G, PaperMeena Sheokand, Shivangi Rao, Neetu Yadav, Rajamani NagarajanMixed-anion solids with reduced dimensionality and layered (2D) structures exhibit a range of advantages arising from their tunable bonding environments and structural flexibility. Studies involving cationic substitution in the Sillen...The content of this RSS Feed (c) The Royal Society of ChemistryMeena Sheokand
- Molecular Engineering of an 2,5-dithiophen-2-yl-pyrrole Bridged Terpyridine-Fe (II) Coordination Polymer toward Multi-State Electrochromic Energy Storage June 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00867D, PaperYuting Song, Hui Qiao, Lin Cheng, Zibo Wei, Beili Lu, Biao Huang, Jiayu TaoElectrochromic energy-storage materials are of great interest due to their ability to simultaneously achieve reversible color modulation and charge storage, where molecular engineering plays a key role in performance optimization....The content of this RSS Feed (c) […]Yuting Song
- Weakly Coordinating Borophosphates – Ca0.5M(H2O)2[B(PO4)2]•H2O (M = Mg, Mn, Co, Zn, Cd) June 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00484A, PaperVivien Wessels, Martina Mikuta, Henning A. HöppeUp to now, a considerable number of borophosphates have been reported, despite the young history of this material class.However, detailed Tanabe-Sugano analyses to investigate the coordination strength of the host...The content of this RSS Feed (c) The Royal Society of ChemistryVivien Wessels
- Gradually changing the fraction of clusters and nanoparticles in Au13/WO3-derived photocatalysts for H2O2 synthesis June 3, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00776G, PaperRohul H. Adnan, D. J. Osborn, Shaojing Yan, Yukatsu Shichibu, Hideki Nakajima, Katsuaki Konishi, Gregory F. Metha, Gunther G. AnderssonEvolution of the Au13 cluster size and the increase in the fraction of nanoparticles enhance the H2O2 yield and production rate due to the formation of a metal–support interaction and […]Rohul H. Adnan
- Advance and prospect of MIL-based drug delivery system in diagnosis and treatment of cervical cancer June 8, 2026