RSC – Dalton Trans. latest articles- Design and synthesis of pillared metal-organic frameworks featuring olefinic fragments October 4, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02397H, PaperRachel Leigh Mander, Ashley Schmidt, Michael Ruf, Maciej Damian KorzynskiWhile metal-organic frameworks (MOFs) are known primarily for their well-defined crystalline porous structures that make them desirable in myriads of applications, they also distinguish themselves with their chemical tunability. One...The content of this RSS Feed (c) The Royal Society of […]Rachel Leigh Mander
- Al(III) and Ga(III) triflate complexes as solvate ionic liquids: speciation and application as soluble and recyclable Lewis acidic catalysts October 3, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02314E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Justyna Więcławik, Alina Brzęczek-Szafran, Sebastian Jurczyk, Karolina Matuszek, Malgorzata Swadzba-Kwasny, Anna ChrobokThis work reports the on first solvate ionic liquids (SILs) based on aluminium(III) or gallium(III) triflate, M(OTf)3 and triglyme (G3). Liquid-phase speciation of […]Justyna Więcławik
- Uranium-bridged Dimeric Keggin-type Polyoxometalate and its Proton Conductive Properties October 3, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02077D, CommunicationYuting Wei, Weixin Du, Haiying Wang, Xiaoyue Wang, Keqin Shen, Minghui Xiong, Dongdi ZhangA novel dimeric structure based on the trilacunary Keggin-type [SbW9O33]9− was synthesized and comprehensively characterized. Different from the conventional dimeric structures, the compound (NH4)10[(SbW9O33)2(UO2)2(H2O)2(SbOH)2]·7H2O ({U2Sb4}) features two additional Sb3+ cations....The content of this RSS Feed (c) […]Yuting Wei
- A low iridium content greatly improves the peroxidase-like activity of noble metal nanozymes for sensitive colorimetric detection October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02065K, PaperKai Cai, Jian Hao, Rui Shang, Miaotian Shi, Jincheng Yuan, Yi Tan, Jiawei LiuThe enzyme-like activity of noble metal nanomaterials has been widely demonstrated. However, as an important noble metal, iridium (Ir) and its alloy nanomaterials have been less studied, especially regarding the...The content of this RSS Feed (c) […]Kai Cai
- BODIPY dyes for optical limiting applications on the nanosecond timescale October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02505A, FrontierJohn Mack, Gugu Kubheka, Aviwe May, Bokolombe Pitchou Ngoy, Tebello NyokongSince 2017, the Institute for Nanotechnology Innovation at Rhodes University has studied the optical limiting properties of boron dipyrromethene (BODIPY) dyes with respect to high-intensity nanosecond timescale laser pulses. Concerns...The content of this RSS Feed (c) The Royal Society […]John Mack
- Bipyridyldicarboxamides and f-metals: Electron effects influence the structure, stability, separation properties, and photophysics October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02489C, PaperNataliya E. Borisova, Anastasia V Kharcheva, Tsagana Sumyanova, Victoria E. Gontcharenko , Petr I. Matveev, Leonid Yurievich Starostin, Alexander Trigub, Alexey V. Ivanov, Svetlana PatsaevaThe three isomeric fluorinated bipyridyldicarboxamides were studied for impact of fluorine atom position on structure, stability, Am(III)/Ln(III) separation, and photophysical properties of their complexes. The […]Nataliya E. Borisova
- Binuclear Cyclometalated Ir(III) Complexes With Bis-Bidentate Butterfly Shaped Ligands: Synthesis, Characterizations, and Application to Efficient Yellow-Orange Light-Emitting Electrochemical Cells October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01958J, PaperMilad Mazaheri, Babak Nemati Bideh, Ahmad SousaraeiTwo yellow to orange-emitting binuclear iridium complexes of the form [Ir2(ppy)4(N^N)](ClO4)2 (namely IrL1 and IrL2) were designed and synthesized by phenylpyridine (ppy) as cyclometalating ligand (C^N) and phenanthroimidazole-based bridging compounds...The content of this RSS Feed (c) The Royal Society of ChemistryMilad Mazaheri
- Water Stable Colloidal PVP coated Spin Crossover Nanoparticles October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02670E, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Christina D Polyzou, Eleni Zygouri, Nikolia Lalioti, Ondrej Malina, Michaela Polaskova, Jiri Bednar, Vassilis TangoulisStable aqueous dispersions of spin-crossover (SCO) doped [FeII(Htrz)2(trz)](BF4) nanoparticles (NPs) were prepared by using water-soluble polyvinylpyrrolidone (PVP) as protecting polymer. […]Christina D Polyzou
- UV-Vis method for investigation of gallium(III) complexation kinetics with NOTA and TRAP chelators: advantages, limitations and comparison with radiolabelling October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02383H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Viktor Lebruška, Tereza Dobrovolná, Tereza Gemperle, Vojtech Kubicek, Susanne Kossatz, Petr HermannAn easy and cheap method for measurement of GaIII complexation kinetics was developed. The method is based on UV-Vis quantification of the non-complexed […]Viktor Lebruška
- A synergetic effect of light and anion: Near-infrared colorimetric monitoring of nitric oxide (NO) release from fluoride/cyanide anions and water responsive ruthenium nitrosyl complex October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02576H, PaperNancy Sharma, Nitin ., Srushti Gadiyaram, Amrita Ghosh, Amilan Jose DevadossNear-infrared (NIR) spectral responsive multitasking chemical systems is always advantageous in biological and environmental systems. Although Ruthenium complexes are highly attractive compounds for many applications; studies on NIR optical responsive...The content of this RSS Feed (c) The Royal Society […]Nancy Sharma
- Thermally stable Cr3+-activated silicate phosphors for plant-growth LEDs and three-mode optical thermometry October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02294G, PaperRongbo Ma, Tingting Zhang, Bin Cao, Xinyong Gong, Chaoyong Deng, Weichao HuangThe structural, optical and temperature-dependent luminescence properties of Y2Mg2Al2Si2O12:Cr3+ phosphors are investigated for their multifunctional applications. The as-prepared phosphors exhibited an intense far-red emission band around 600-850 nm with a...The content of this RSS Feed (c) The Royal […]Rongbo Ma
- Facile one-step synthesis of a WO3/ZnWO4 heterojunction modified using ZnFe LDH enhances the PEC water splitting efficiency October 2, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT01883D, PaperZiYang Liu, Shiyu Jia, Yiwen Hu, Yanling Fang, Yongjun Feng, Dianqing Li, Shouli Bai, Ruixian Luo, Aifan ChenA novel and efficient WO3/ZnWO4/ZnFe LDH photoanode has been successfully prepared by a one-step drop casting and electrodeposition method.To cite this article before page numbers are assigned, use the DOI form of […]ZiYang Liu
- Synthesis and Reactivity of a Heteroleptic Magnesium Hydride on a Dearomatized Picolyl-Based NNN-Chelator. October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02757D, PaperChhotan Mandal, Subham Sarkar, Sourav Panda, Dibyendu Mallick, Debabrata MukherjeeHeteroleptic magnesium hydrides are important for their stoichiometric and catalytic reduction chemistry. Their primary nucleophilic site is typically the hydride, while the ancillary ligands commonly used are mostly spectators. Chemically...The content of this RSS Feed (c) The Royal Society of […]Chhotan Mandal
- Mixed-Ligand based water-stable Mn(II)-MOF for quick, sensitive, and reusable IFE-PET-RET facilitated detection of Formaldehyde and Cr(VI)-Oxoanions in Food and Industrial Water like real-field samples: Experimental and Theoretical insights October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02707H, PaperUdayan Mondal, Somrita Nag, Rajeshwari Pal, Priyabrata BanerjeeWe report the luminescence-based detection of Group-1 carcinogen formaldehyde (FA) and Cr(VI)-oxoanions by a mesoporous Mn(II)-MOF (1), featuring a uninodal 4-c net topology and linear 1D square channels forming a...The content of this RSS Feed (c) The Royal Society of ChemistryUdayan Mondal
- Unveiling the Impact of Enhanced Hydrophobicity of ZIF-71 on Butanol Purification: Insights from Experimental and Molecular Simulations October 2, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02485K, PaperNorma Tiempos-Flores, Oscar I. Arillo-Flores, Eugenio Hernández-Fernández, Victor M. Ovando-Medina, Marco A. Garza Navarro, Sandra Pioquinto-Garcia, Nancy Elizabeth Dávila GuzmánBiofuels offer significant potential for reducing carbon emissions and enhancing energy sustainability, but their efficient purification remains a significant challenge. In this study, the performance of a hydrophobic zeolitic imidazolate...The […]Norma Tiempos-Flores
- Spin Crossover FeIII Complexes with a Substituted Hqnal Ligand: Effects of Anions and Solvents October 1, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01954G, PaperFengli Chen, Xin-li Liu, Yue Zhao, Gang Li, Bohong Gao, Xin-Yi WangA new substituted Hqnal ligand, Hqnal-5-Brq, and four resulting FeIII complexes [Fe(qnal-5-Brq)2]A·sol (A = NO3−, sol = CH3OH 1; A = ClO4−, sol = CH3OH 2; A = OTf−, sol...The content of this RSS Feed (c) The Royal […]Fengli Chen
- A 2-fold interpenetrating 3D pillar-layered MOF for gas separation and detection of metal ions September 30, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02024C, CommunicationGuoqiang Peng, Zhibo Su, Falu Hu, Zhen-Yu Ji, Zhengyi Di, Guihua Li, Tingting Gao, Wei Guo, Mingyan WuA 2-fold interpenetrating 3D pillar-layered MOF, which is assembled from mixed-linker and paddle-wheel cluster, has been successfully synthesized. It possesses good thermal and water stability as well as highly selective...The content of […]Guoqiang Peng
- Recent advances of polyoxometalate-based catalysts for light-driven hydrogen evolution September 30, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02357A, FrontierMengyun Zhao, Qingqing Liu, Yeqin Feng, Hongjin LvPhotocatalytic hydrogen evolution reaction has been considered as an efficient route to address the energy and environmental issues. As an interesting type of multi-electron-transfer catalysts, polyoxometalates (POMs) have been widely...The content of this RSS Feed (c) The Royal Society of ChemistryMengyun Zhao
- Effect of the Co-doping on the electrochromic performance of hexagonal phase WO3 nanorods September 30, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02319F, PaperZhaozhu Qu, Ankang Li, Ming Gao, Xiaohui Sun, Xuyang Zhang, Guohua Wu, Xiangwei WangIn this study, cobalt-doped hexagonal phase WO3 nanorods were prepared by a template-free hydrothermal method The effects of varying the cobalt doping concentration on the microscopic morphology and electrochromic properties...The content of this RSS Feed (c) […]Zhaozhu Qu
- Ugi's amine based coordination polymers as a synergistic catalysts for electrocatalytic reduction of carbon dioxide September 30, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01181C, PaperMikhail Khrizanforov, Farida F. Nailieva, Kamil Ivshin, Almaz Zagidullin, Anastasiia P. Samorodnova, Ruslan Petrovich Shekurov, Polina Milyukova, Artem Laskin, Alexander S. Novikov, Miluykov VasiliThe escalating concentration of carbon dioxide in the atmosphere is a pressing environmental concern, necessitating the development of efficient technologies for CO2 reduction and utilization. In […]Mikhail Khrizanforov
- Design and synthesis of pillared metal-organic frameworks featuring olefinic fragments October 4, 2024
