RSC – Dalton Trans. latest articles
- Designing One-compartment H2O2 Fuel Cell Using Electroactive Phenalenyl-based [Fe2(hnmh-PLY)3] Complex as the Cathode Material March 26, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00134F, PaperNisha Kamboj, Ayan Dey, Sunita Birara, Moumita Majumder, Srijan Sengupta, Ramesh K. MetreThe sustainable chemical energy of H2O2 as a fuel and an oxidant in an advantageous single-compartment fuel cell design can be converted into electric energy, which requires molecular engineering to...The content of this RSS Feed (c) The […]Nisha Kamboj
- Inorganic−organic-hybrid Cu−dipyridyl semiconducting polymers based on redox-active cluster [SFe3(CO)9]2−: filling the gap in iron carbonyl chalcogenide polymers March 26, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00254G, PaperMing-Chi Hsu, Ru Yan Lin, Tzu-Yen Sun, Yu-Xin Huang, Min-Sian Li, Yu-Huei Li, Hui-Lung Chen, Minghuey ShiehThe construction of sulfur-incorporated cluster-based coordination polymers was limited and underexplored due to the lack of efficient synthetic routes. Herein, we reported the facile mechanochemical ways toward a new series...The content of this […]Ming-Chi Hsu
- Polyoxometalate-Based Reticular Materials for Proton Conduction: From Rigid Frameworks to Flexible Networks March 26, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00229F, FrontierXiang Li, Shengchao Chai, Haolong LiProton conductors play a crucial role in energy and electronic technologies, thus attracting extensive research interest. Recently, reticular chemistry has propelled the development of reticular materials with framework or network...The content of this RSS Feed (c) The Royal Society of ChemistryXiang Li
- A3Ti5NbO14 (A = H, Li and K) family: Ionic exchange, physical and electrochemical properties March 25, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00208C, PaperAudric Neveu, Justine Jean, Philippe Boullay, Vadim M. Kovrugin, Armance Sagot, Hari Raj, Valerie PralongA new layered titanoniobate, Li3Ti5NbO14, a member of the AxM2nO4n+2 family, has been synthesized using a molten salt reaction between H3Ti5NbO14 and an eutectic mixture of LiOH and LiNO3. This...The content of this RSS Feed […]Audric Neveu
- Reversible structural change of [Co2Fe2] complexes between diamagnetic hydrogen-bonded 1D chains and paramagnetic complexes within a layered structure of amphiphilic anions March 25, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00482E, PaperNozomi Mihara, Soyoka Iitsuka, Takuya Shiga, Masayuki NiheiCombination of amphiphilic ions and metal complexes may enable the construction of assemblies in which the assembly structure and electronic state of the metal complexes change concertedly. In this work,...The content of this RSS Feed (c) The Royal Society of ChemistryNozomi Mihara
- p-n heterogeneous Sb2S3/SnO2 quantum dots anchored reduced graphene oxide nanosheets for high-performance lithium-ion batteries March 25, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00153B, PaperHaiyan Yin, Guanghao Zhan, Ruibo Yan, Xiaohui Wu, Qianqian Hu, Xiao-Ying HuangAntimony sulfide (Sb2S3) has a high theoretical specific capacity due to its two reaction mechanisms of conversion and alloying during the Li+-(de)intercalation process, thus becoming a promising lithium-ion battery (LIB)...The content of this RSS Feed (c) The Royal […]Haiyan Yin
- Carbon quantum dots-decorated g-C3N4 composite as a sulfur hosting material for lithium-sulfur batteries March 25, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00511B, PaperYang Liu, Dandan Cai, Feng Zheng, Ziwei Qin, Ying Li, Wenxian Li, Aijun Li, Yufeng Zhao, Jiujun ZhangAlthough lithium-sulfur (Li-S) batteries have attracted strong consideration on their fundamental mechanism and energy applications, the inferior cycling performance and low reaction rate caused by the “shuttle effect” and the...The content of […]Yang Liu
- 1,1'-bis-(diphenylphosphino)ferrocene appended d8- and d10-configuration based thiosquarates: The molecular and electronic configurational insights into their sensitization and co-sensitization properties for dye sensitized solar cells March 25, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00151F, PaperAparna Kushwaha, Devyani Srivastava, Om Prakash, Gabriele Kociok-Köhn, Suresh Gosavi, Ratna Chauhan, Mohd. Muddassir, Abhinav KumarThree new d8- and d10-configuration based 1,1'-bis(diphenylphosphino)ferrocene (dppf) appended thiosquarates complexes with general composition [M(mtsq)2dppf] (M = Ni2+ (NiL2); Zn2+ (ZnL2) and Cd2+ (CdL2)) (mtsq = 3-ethoxycyclobutenedione-4-thiolate) have been synthesized...The content of this RSS […]Aparna Kushwaha
- Room temperature spin crossover properties in a series of mixed-anion Fe(NH2trz)3(BF4)2-x(SiF6)x/2 complexes March 25, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00267A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinyu Yang, Alejandro Enriquez-Cabrera, Kane Jacob, Yannick Coppel, Lionel Salmon, Azzedine BousseksouA series of mixed-anion Fe(NH2trz)3(BF4)2-x(SiF6)x/2 spin crossover complexes is obtained modifying the reaction time but also using an increase amount of tetraethyl orthosilicate […]Xinyu Yang
- Beyond copper: examining the significance of His-mutations in mycobacterial GroEL1 HRCT for Ni(II) complex stability and formation March 25, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00011K, PaperAnna Rola, Arian Kola, Daniela Valensin, Oscar Palacios, Merce Capdevila, Elżbieta Gumienna-Kontecka, Sławomir PotockiThe histidine-rich C-terminal domain of GroEL1 (M. tuberculosis) and its mutants were studied as ligands for Ni(II). The Ni(II)-binding motif for the domain was established as EXHX3HX3H. The relevance of Lys5 for the complex stability was […]Anna Rola
- Triclinic La7Zn2P11 with P3–, P24–, and P35– units: A combined study by 31P solid-state NMR spectroscopy and single crystal X-ray diffraction March 23, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00529E, PaperJutta Kösters, Christopher Benndorf, Tobias Uesbeck, Thomas Wiegand, Hellmut Eckert, Hannes Lincke, Rainer PöttgenThe ternary polyphosphide La7Zn2P11 was synthesized from the elements by using a salt flux or via a ceramic method in sealed quartz ampoules. The obtained samples were investigated by X-ray...The content of this RSS Feed (c) […]Jutta Kösters
- Photocatalytic conversion of CO2 to CO by Ru(II) and Os(II) octahedral complexes: A DFT/TDDFT study. March 22, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00125G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Athanasios Tsipis, Antonia SarantouThe reaction mechanisms of the photocatalytic reduction of CO2 to CO catalyzed by [(en)M(CO)3Cl] complexes (M = Ru, Os, en = ethylenediamine) in the presence of triethanolamine (TEOA), R3N (R...The content […]Athanasios Tsipis
- Comprehensive study of the synthetic tychite, Na6Mg2(CO3)4SO4: synthesis, structure and conductive properties March 22, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00396A, PaperAlexander A. Shindrov, Yelizaveta A. MorkhovaThe successful synthesis conditions of Na6Mg2(CO3)4SO4 powder were selected. The structural features and conductive properties of the sample were studied comprehensively, including high-throughput calculations and advanced experimental techniques.To cite this article before page numbers are assigned, use the DOI form of citation above.The content […]Alexander A. Shindrov
- Cu(dppf) complexes can be synthesized from Cu-exchanged solids and enable a quantification of the Cu-accessibility by 31P MAS NMR spectroscopy March 22, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00147H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Elif Kaya, Daniel Dittmann, Maximilian Schmidt, Michael DyballaHerein, we apply three different copper-exchanged materials (Na-[Al]SBA-15, silica, Na-MCM-22) as hosts for a direct synthesis of CuI(1,1' bis(diphenylphosphino)ferrocene = dppf) complexes in cationic ion exchange position. […]Elif Kaya
- Correction: (TeCl)4(TiCl4) with isolated Te4Cl16 and TiCl4 molecules and second-harmonic-generation March 22, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT90051K, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maxime A. Bonnin, Klaus Beier, Lkhamsuren Bayarjargal, Björn Winkler, Claus FeldmannTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal […]Maxime A. Bonnin
- Chromium Iodate: Structure and Origin of Optical Second Harmonic Generation March 22, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00470A, PaperYang Chi, Mei-Ling XinIodate crystal materials are one of the important candidates for mid-infrared nonlinear optical (NLO) crystals. Almost all the structures and NLO properties of monometallic iodates have been studied, except for...The content of this RSS Feed (c) The Royal Society of ChemistryYang Chi
- Expanding dimensionality of bis(tetrazolyl)alkane-based Fe(II) coordination polymers by an application of dinitrile coligands March 21, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00462K, PaperAleksandra Tołoczko, Marcin Kaźmierczak, Maria Książek, Marek Damian Weselski, Joachim Kusz, Robert BroniszReactions between 1,2-di(tetrazol-2-yl)ethane (ebtz), 1,6-di(tetrazol-2-yl)hexane (hbtz) or 1,1’-di(tetrazol-1-yl)methane (1ditz) and Fe(BF4)2 in presence of adiponitrile (AND), glutaronitrile (GLN) or suberonitrile (SUN) resulted in formation of coordination polymers [Fe(μ-ebtz)2(μ-ADN)](BF4)2 (1), [Fe(μ-hbtz)2(μ-ADN)](BF4)2...The content of this RSS Feed (c) The […]Aleksandra Tołoczko
- Efficient electrochemical reduction of CO2 to CO in flow cell device by a pristine Cu5tz6-cluster-based metal-organic framework March 21, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00189C, PaperZijing Li, Yingtong Lv, Haoliang Huang, Zi-Jian Li, Tao Li, Linjuan Zhang, Jian-Qiang WangThe electrochemical reduction of CO2 to CO is a powerful approach to achieve carbon neutrality. Herein, we report a five-nuclear copper cluster-based metal–azolate framework CuTz-1 as an electrocatalyst for the...The content of this RSS Feed (c) […]Zijing Li
- Selective fluoride sensing by a novel series of lanthanide-based one-dimensional coordination polymers through intramolecular proton transfer March 21, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00598H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arun Kumar Bar, Vaibhav Singh, Lakshmi Thachanadan Suresh, Jean-Pascal SutterA novel series of one-dimensional coordination polymers (CPs) is achieved via a facile one-pot synthetic strategy employing the nitrate salts of trivalent lanthanides, a pentadentate […]Arun Kumar Bar
- Structural insight and in silico prediction of the pharmacokinetic parameters and toxicity of alkaline earth metal compounds strontium and barium with the non-steroidal anti-inflammatory drug nimesulide March 21, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00446A, CommunicationMałgorzata Rybczyńska, Artur SikorskiIn the crystals of alkaline earth metal compounds strontium and barium with the non-steroidal anti-inflammatory drug nimesulide, the metal ions have different coordination spheres, TCTPR-9 and TCTPR-10, respectively.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Małgorzata Rybczyńska
- Designing One-compartment H2O2 Fuel Cell Using Electroactive Phenalenyl-based [Fe2(hnmh-PLY)3] Complex as the Cathode Material March 26, 2024