RSC – Chem. Sci. latest articles
- Cation Gating-Breathing Synergetic Mechanism in K-MER Zeolite Enables Unprecedented Selective CO₂ Separation from Hydrocarbon Gas Streams October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03281D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Renhao Li, Chenxu Liu, Wenli Bao, Lin Li, Jingfeng Han, Xiaoxin Zou, Xiaowei Song, Donghai Mei, Zhiqiang LiangThe ubiquitous presence of CO2 impurity in industrial hydrocarbon streams underscores the critical need for developing […]Renhao Li
- Integrating a hydrogen-bonded complex as a secondary building unit to construct a multivariate framework for programmable drug delivery October 13, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC04021C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xujiao Ma, Zhong Zhang, Xianghui Ruan, Jiarui Cao, Ye Yuan, Yajie Yang, Nan Gao, Guangshan ZhuPorous organic frameworks (POFs) consisting of organic building blocks through covalent bonds are novel functional solids.To cite this […]Xujiao Ma
- The Optical Response of Aromatic Cyclocarbons October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05519A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simone Grillo, Olivia Pulci, Tommaso GiovanniniCyclo[n]carbons are a recently synthesized class of carbon allotropes that offer a unique platform to probe electron delocalization, quantum confinement, and strong correlation effects. Their peculiar electronic properties […]Simone Grillo
- Enhanced MOF performance in chromium (VI) removal from water using tailored MOF-polymer composites October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05812K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Timo Felder, Wei Shi, Daniel T Sun, Till Schertenleib, Emad Oveisi, Jordi Espín, Wendy Lee QueenFunctionalizing the internal and external surface of MOFs with polymers allows for tailor-made improvements in their performance for […]Timo Felder
- Room Temperature Dinitrogen Cleavage and Hydrogenation with Organometallic Complexes of Uranium October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07194A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Angus C Shephard, Lucie Pedussaut, Linda De Marchi, Luca Demonti, Thayalan Rajeshkumar, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Thomas Simler, Grégory NoctonThe conversion of dinitrogen into ammonia plays an important role in sustaining […]Angus C Shephard
- Brønsted acid-promoted ethylene dimerization to 1-butene over Ni-containing zeolite catalysts October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05078B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Landong Li, Yuchao Chai, Li Wang, Yuwen Ni, Jingyao Yang, Guangjun WuEthylene dimerization is a critical industrial process traditionally catalyzed by homogeneous systems employing cocatalysts or solvents. Although heterogeneous catalysts show potential to […]Landong Li
- Large-area thin-film synthesis of photoactive Cu3PS4 thiophosphate semiconductor with 0-14 pH stability range October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05882A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lena Angelika Mittmann, Javier Sanz Rodrigo, Eugène Bertin, Giulia Dalmonte, Jean Claude Grivel, Ivano E. Castelli, Andrea CrovettoThe vast and versatile group of phosphorus- and sulfur-based inorganic materials, phosphosulfides, has sparked growing interest […]Lena Angelika Mittmann
- Solvent-Induced Oriented FAPbI3 Single Crystals towards Highly Efficient Self-Powered X-ray Detectors October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04089B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fang Liu, Yu Zou, Pengxiang Wang, Hu Wang, Jiahao Guo, Yugang Liang, Haifei Wang, Wenji Zhan, Zhengzheng Dang, Jixin Wu, Yanming Wang, Bowei Li, Yanfeng Miao, Yuetian Chen, Yao Wang, Yixin ZhaoPerovskites are […]Fang Liu
- Trapping Carbon Suboxide with a Carbene and Isolation of the Carbene-stabilized Carbon Suboxide Dimer October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06444A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tanner George, Erin R. Johnson, Jason Douglas MasudaCarbon suboxide (C 3 O 2 ), the heavier cousin of carbon carbon monoxide, CO, and carbon dioxide, CO 2 , is an unstable gas at […]Tanner George
- Air-Water Interfacial Nitrogen Cycle Produces Irrigatable-Level Ammonium Nitrate October 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05754J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaowei Song, Basheer Chanbasha, Jinheng Xu, Richard N. ZareWe report a sustainable, air-based strategy for synthesizing ammonium nitrate (NH4NO3) by harnessing the redox-active properties of microscale air–water interfaces. The process proceeds through two […]Xiaowei Song
- Fibrous Intrinsic Zeolitic Pickering Emulsifier October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04922A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shuangjia Wang, Xiaoliang Huang, Fei Ma, Wenjun Jiang, Zhifeng Zeng, Yang Zhang, Yuyan Yao, Jiuxing JiangThe intrinsic amphiphilicity that enables the grafting-free zeolite Pickering emulsification has been reported previously by us. However, only […]Shuangjia Wang
- Tailoring Polymer-Metal-Organic Frameworks (PolyMOFs) using Telechelic Poly(octenamer)s October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05704C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Prantik Mondal, Debobroto Sensharma, Seth M CohenPolymer-metal-organic frameworks (polyMOFs) represent an unusual class of polymer-MOF hybrids, but inadequate methods for designing and tailoring their underlying polymeric building blocks has been a limitation of […]Prantik Mondal
- Leveraging an intelligent slug flow platform for self-optimization of reaction systems with categorical variables October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04715C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Florian Wagner, Gernot Neun, Thomas Tampone, Zhen Lei, Frederic Buono, Christopher A. Hone, C. Oliver KappeIn this work we describe the development of a chemistry-based encoding approach utilizing nucleophilicity to perform Bayesian optimization […]Florian Wagner
- Near-Unity and Narrow Green Emission from a Manganese(II) Bromide for Efficient WLEDs and 3D X-ray Imaging October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04721H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mengzhu Wang, Xiaolong Li, Siwen Zou, Haixia Cui, Yongjing Deng, Jiangang Li, Yi Jiang, Longlu Wang, Shu-Juan Liu, Qiang Zhao, Yun MaDeveloping efficient, narrow-band, and environmentally friendly emitters is crucial for advanced optoelectronics. […]Mengzhu Wang
- Single atom-bridged Au nanozymes boost glucose oxidase-like activity in acidic media October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05430C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Luo, Feilong Tan, Zhenglong Mao, Yan Zhang, Yinjun Tang, Cang-Long Wang, Wenling Gu, Cao Li, Juewen Liu, Chengzhou ZhuAu nanozymes hold great promise as glucose oxidase (GOx) mimics; however, their catalytic activity […]Xin Luo
- Chromophore charge-state switching through copper-dependent homodimerisation of an engineered green fluorescent protein October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06589E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rochelle Ahmed, Danoo Vitsupakorn, Kieran D Hartwell, Karma Albalawi, Pierre Rizkallah, Peter Watson, D. Dafydd JonesHere, we have linked one of the most common protein-protein interaction events, homodimerisation, to an essential trace metal, […]Rochelle Ahmed
- Conjugated Microporous Polymer Electrodes for Supercapacitors: Recent Progress, Key Challenges, and Future Directions October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05384F, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mohammed G. Kotp, Mohamed Gamal Mohamed, Shiao-Wei KuoConjugated Microporous Polymers (CMPs) have shown great potential class of materials for supercapacitor electrodes, offering a distinctive blend of extensive surface area, tunable porosity, redox activity, […]Mohammed G. Kotp
- Design Principles of Spacer Cations for Suppressing Phase Segregation in 2D Halide Perovskites October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06511A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Junsang Cho, Seonhong Min, Manish Mukherjee, Gabor Gabor Szabo, Prashant V KamatSuppression of photoinduced halide segregation in mixed halide perovskites remains a significant challenge for their application as wide bandgap semiconductors in solar […]Junsang Cho
- Detection of single-cell enzyme activity by single-time-point stable isotope probing-mass spectrometry October 12, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC04171F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xianzhe Wu, Qingxi Ma, Haoran Chen, Chuhao Cheng, Jiapu Li, Feifei Xu, Yun ChenDevelopment of a single-time-point stable isotope probing-mass spectrometry (SIP-MS) assay for revealing enzyme activity heterogeneity in single cells.To cite this […]Xianzhe Wu
- Isolation of Ce(IV) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency October 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06415E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dominic Shiels, Michele Pittalis, Nadeeshan Gunarathna, Adriana C Berlfein, William W. Brennessel, Michael T Ruggiero, Ellen MatsonThe new CeIII centered sandwich-type complex (TBA)3[Ce{W4O13(OMe)4MoNO}2] is reported. The redox properties of this molecule, and its […]Dominic Shiels
- Cation Gating-Breathing Synergetic Mechanism in K-MER Zeolite Enables Unprecedented Selective CO₂ Separation from Hydrocarbon Gas Streams October 13, 2025