RSC – Dalton Trans. latest articles- Plasma-Enhanced Atomic Layer Deposition of AlPO4/AlPxOy: Comparing Dual Source and Supercycle Approaches for Composition Control October 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02282G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Florian Preischel, David Zanders, Jean-Pierre Glauber, Karl Rönnby, Detlef Rogalla, Thomas Gemming, Peter Dement, Michael Nolan, Anjana DeviIn pursuit of developing a plasma-enhanced atomic layer deposition (PEALD) process for AlPO4, we explored two different […]Florian Preischel
- Rh,Sb-codoped SrTiO3 cubic nanoparticles encapsulated by ZnIn2S4 nanosheets for efficient visible-light-driven hydrogen evolution October 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02148K, PaperJunzhe Jiang, Yiquan Zhan, Bingxue Li, Quan Li, Yongsheng Liu, Jin-Biao Liu, Liqing Li, Yoshihisa SakataStrontium titanate (SrTiO3) is a typical kind of titanate photocatalyst for solar-driven hydrogen production, but its sunlight absorption is confined to the ultraviolet region. Indium zinc sulfide (ZnIn2S4) materials can...The content of this RSS […]Junzhe Jiang
- BaAlPO4F2：Structure and Properties of the First Barium Fluoroaluminophosphate with Mixed Anion Group [Al2PO8F5] October 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02249E, PaperYanhui Zhang, Jiajia Li, Yaqing Ding, Kaitong Liu, Xiaofeng GuThe mixed-anionic compounds are attractive hunting grounds for probing optical crystals due to their interesting physiochemical properties. Herein, the first barium fluoroaluminophosphate, BaAlPO4F2, was synthesized by high temperature reactions in...The content of this RSS Feed (c) The Royal Society of […]Yanhui Zhang
- Structural Investigation of the Protonation States of Sulfamic Acid October 31, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02262B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Valentin Bockmair, Andreas Klöck, Lukas Stanzel, Sven Ringelband, Frank Tambornino, Andreas KornathHerein, we report on the O-monoprotonated and double O-hemiprotonated species of sulfamic acid in the binary superacidic systems HF/L (L = BF3, GeF4, […]Valentin Bockmair
- Dinitrogen-bridged diruthenium complexes bearing 2,6-pyridinedicarboxylate in the mixed-valence state October 31, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02337H, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kazunari Uehara, Nayoung Kim, Aya Benzaki, Midori Otsuka, Tomoyo Misawa-Suzuki, Hirotaka NagaoA dinitrogen-bridged ruthenium dinuclear complex in a mixed-valence state of Ru(II)–Ru(III), [{Ru(κ2-pydc)(NH3)3}(μ-N2){Ru(κ2-pydc)(NH3)2(OH)}], has been synthesized by a reaction using dinitrogen or hydrazine as […]Kazunari Uehara
- Pd-loaded Modulated MOF-808: A Bifunctional Solid-Acid Catalyst for One-Pot Oxidation-Acetalization October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01970B, PaperZipeng Li, Jiaxin Geng, Li Sun, Laishuo Li, Zhichao Sun, Yao Wang, Ying-Ya Liu, Chong Peng, Anjie Wang, Lixian SunThe growing demand for fine chemicals and environmental concerns have driven research interest in catalytic cascade processes that offer operational efficiency and high atomic economy, though designing high-performance multifunctional solid...The […]Zipeng Li
- Re(I)-quinolinate-pyridyl complexes with disubstituted benzimidazole pharmacophore as anticancer agents October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01577D, PaperShanmugam Ramasamy, Reema Laxmikant Borkar, Chandra Lekha Putta, P Merlin, Nitisha Beniwal, Bharati Banoth, Abhishesh Kumar Mehata, Aravind Kumar RenganFive neutral heteroleptic complexes fac-[Re(CO)3(QN)(L-X)] (Re-F, Re-Cl, Re-Br, Re-Me, and Re-Np) comprising of fac-[Re(CO)3]+ core, 8-quinolinate (QN), and 2-(4-pyridyl)-5,6-disubstituted benzimidazole derivative (L-X = 2-(4-pyridyl)-5,6-difluorobenzimidazole (L-F) or 2-(4-pyridyl)-5,6-dichlorobenzimidazole (L-Cl) or 2-(4-pyridyl)-5,6-dibromobenzimidazole...The […]Shanmugam Ramasamy
- CO-free selective hydrogenation of CO2 to value-added formate under low-temperature aqueous conditions using a heterogenized Ru-PNP catalyst October 30, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01972A, PaperHongjin Park, Minkyoung Go, Sungho YoonCO2/H2/KOH-mediated hydrogenation over Ru-MACHO-POMP affords CO-free potassium formate with high selectivity at 80 °C.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryHongjin Park
- Dynamic self-regulating interfaces enable crystallization control and lead sequestration in perovskite photovoltaics October 30, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01789K, PaperWenhui Meng, Haojie Sui, Zan Li, Xinjing Chen, Yongjia Li, Shufang Zhang, Hai Zhong, Qi Zhang, Changlin YaoWith the pioneering development of a nickel acetate-enabled dynamic interface, controlled Pb2+ release from in situ-formed NA suppresses nucleation while passivating defects, achieving 18.43%-efficient HTM-free C-PSCs with minimized Pb leakage.To cite this […]Wenhui Meng
- In situ polypyrrole coating on copper foam via femtosecond laser-irradiation for supercapacitor applications October 30, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02043C, PaperMuhammad Faheem Maqsood, Faisal Ghafoor, Syed Muhammad Zain Mehdi, Iqra RabaniThe growing need for fast, efficient, and durable energy storage, especially in electric vehicles and renewable energy systems, has made supercapacitors (SCs) increasingly important.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]Muhammad Faheem Maqsood
- Hydrogen Adsorption and Dissociation on Transition Metal Anchored B12N12 Nanocages: Insights from Density Functional Theory October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01548K, PaperZainab Fareed, Tayyaba Tariq, Shaaban M. Shaaban, Muhammad Yar, Muhammad Ali Khan, Ajaz Hussain, Khurshid Ayub, Sehrish Sarfaraz, Yasser RiyadThe growing worldwide transition to carbon-neutral energy systems requires the development of novel, efficient, and sustainable catalysts for key reactions, including hydrogen dissociation. As hydrogen is increasingly recognised as a...The […]Zainab Fareed
- Exploring the Impact of Magnetic Field and Nanoparticle Size on the Magnetic Properties of Fe(II)-triazole Spin-Crossover Nanoparticles October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01886B, PaperAleksandra Pacanowska, Alejandro Regueiro, Paweł Czaja, Aleksandra Deptuch, Magdalena Fitta, Piotr KoniecznyThree types of iron(II)-triazole spin-crossover nanoparticles were synthesized using a micellar exchange approach, each coated with a thin silica shell. Two were obtained under optimized conditions, yielding rod-shaped nanoparticles (1np,...The content of this RSS Feed (c) The Royal […]Aleksandra Pacanowska
- Single-Crystal to Single-Crystal Synthesis of a Gold(I)-Ammonia Complex and H/D Exchange In Crystallo with D2O. October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02464A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chloe L. Johnson, Kris Mark Altus, Miquel Navarro, Jesús Campos, Simon B Duckett, Andrew S WellerSingle-crystal to single-crystal solid/gas reactivity of [LAu(C2H4/CO)][BArF4] [L = tris-2-(4,4’-di-tert-butylbiphenyl)phosphine] with NH3 or 15NH3 gives the ammonia complexes [LAu(NH3/15NH3)][BArF4]. […]Chloe L. Johnson
- Magnesium Catalyzed Hydroamination of Carbodiimide and Hydroboration of Cyanamides † October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02335A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sharanappa Nembenna, Anubhab Das, Sayantan Mukhopadhyay, Sagrika RajputA β-diketiminate magnesium hydride complex, Mg-1 [{LMgH}2; L = Dep Nacnac = (DepNCMe)2CH; Dep = 2,6-Et2C6H3], catalyzes the hydroamination of carbodiimide with primary aryl amines and the […]Sharanappa Nembenna
- Binder-free metal-organic framework-based core-shell arrays for supercapacitors October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01533B, FrontierLiuliu Zhang, Fujuan Luo, Cui Yang, Hongbo Yu, Kai TaoSupercapacitors (SCs) are regarded as a promising electrochemical energy storage devices, where the electrodes are vital in determining the performance of devices. Metal-organic framework (MOF) has recently emerged as a...The content of this RSS Feed (c) The Royal Society of […]Liuliu Zhang
- A Tetradentate Benzannulated P^N^N^P Ligand and Its Fe(II) Complex: Synthesis, Characterization, and Electrocatalytic Hydrogen Evolution October 30, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02202A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Baldeep K Sidhu, Amelia Kacperkiewicz , Jason D Braun, David E HerbertIron complexes supported by phosphine and pyridine-based ligands are widely seen as efficient molecular catalysts for catalytic transformations, but examples of these complexes […]Baldeep K Sidhu
- Lysosome-targeted Ru(II)-cyclopentadienyl organometallic anticancer complexes October 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01975C, PaperRicardo G Teixeira, Lívia Stenico, Xavier Fontrodona, Isabel Romero, Radosław Starosta, Maria João Moreno, Ana Isabel Tomaz, Ligia C. Gomes-da-Silva, Andreia ValenteCancer continues to pose a significant global health burden, prompting ongoing exploration of innovative therapeutic strategies. Ruthenium-based complexes have emerged as promising alternatives to platinum drugs due to […]Ricardo G Teixeira
- Interplay of Dual-Site Metal Disorder on the Thermodynamic Stability and Electronic Structures of Cu(I)-Containing Molybdovanadate and Tungstovanadate Compounds October 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02255J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Machima Mongkhonratanachai, Subhendu Jana, Paul MaggardCompounds combining Cu(I) and early transition-metal cations have attracted much attention as small-bandgap semiconductors. However, synthetic progress and new discoveries in these systems have been inhibited by their limited […]Machima Mongkhonratanachai
- Chiral Cu2-xS quantum dots and their near-infrared photothermal conversion properties October 29, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02539G, PaperGuangmin Li, xinyu Jin, Jiayun Zheng, Shuang Li, Hongfei Liu, anning guo, Zhibo Chen, Xiongzhe Fan, Hongbin Zhao, Jiajia Kang, Guozhi Jia, Jiafeng Li, Gaoling YangThe photothermal of semiconductor materials has been widely studied in recent years, while the chiral-related photothermal properties for semiconductor quantum dots is still unclear. […]Guangmin Li
- Structural modifications of M5O4I11 (M = Nb, Ta) cluster networks from heterogeneous solid-state reactions October 28, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02097B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Fabian Grahlow, Jan Beitlberger, Mario Martin, Eric Juriatti, Heiko Peisert, Marcus Scheele, Markus Ströbele, Carl P. Romao, Hans-Jürgen MeyerA series of cluster compounds sharing a [M5O4] cluster core (M = Nb, Ta) is obtained […]Fabian Grahlow
- Plasma-Enhanced Atomic Layer Deposition of AlPO4/AlPxOy: Comparing Dual Source and Supercycle Approaches for Composition Control October 31, 2025
