RSC – Dalton Trans. latest articles- Dual Tuning of Nodes and Functional Guests of Polyoxometalate@Metal-Organic Frameworks for Enhanced Photocatalytic Oxidative Coupling May 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00655D, PaperZhiqiang Jiang, Qi Xin Zhao, Yang Zeng, Tengfei Gong, Zhenxuan Huang, Zeyu Chen, Jiefeng Shen, Weimin XuanMetal-organic frameworks are versatile platforms for photocatalysis owing to their facile capacity to incorporate active sites within organic linkers, nodes and open channels. However, the dual tuning of both nodes...The content of this […]Zhiqiang Jiang
- A water-soluble heterometallic iron(IV)–ruthenium(IV) μ-nitrido porphyrin complex: synthesis, structure and catalytic activity† May 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00712G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rain Ng, Wai-Man Cheung, Cheuk-Pui Leung, Chun Kit Au, Yat-Ming So, Herman H-Y. Sung, Wan Chan, Ian Duncan Williams, Wa-Hung LeungA heterometallic Fe(IV)–Ru(IV) nitrido complex bearing a water-soluble porphyrin ligand has been synthesized, and […]Rain Ng
- Precisely tailoring Lewis pairs in polyoxotitanium clusters for efficient photocatalytic production of hydrogen peroxide May 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00085H, PaperMengke Gao, Shiming Zhang, Yayu Yan, Zehao Qian, Liyang Qin, Xiaoyu Liu, Qing-Rong Ding, Qiao-Hong Li, Xin Wu, Jian ZhangHydrogen peroxide (H₂O₂) is a vital chemical with promising potential as an energy carrier. Photocatalytic H₂O₂ production has emerged as a sustainable and environmentally friendly approach. However, current photocatalysts often...The […]Mengke Gao
- A Chloride-doped Cu18 Nanocluster: Synthesis, Bonding and Nonlinear Optical Property May 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00851D, PaperXuekun Gong, Chan Zheng, Dongjie Zuo, Simin Li, Wei-Hui Fang, Hui ShenAtomically precise copper nanoclusters have emerged as an essential class of materials that have found applications in a wide range of fields. However, the design and development of copper cluster...The content of this RSS Feed (c) The Royal […]Xuekun Gong
- Alkylzinc-Mediated Transmetallation of a Calcium Hydride May 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00958H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kyle G. Pearce, Mary F Mahon, Michael HillThe dimeric β-diketiminato calcium hydride, [(BDI)CaH]2 (BDI = HC{(Me)CNDipp}2; Dipp = 2,6-i-Pr2C6H3), reacts with dialkylzinc reagents in a 1:2 ratio through sequential dialkyl(hydrido)zincate formation, calcium alkyl extrusion followed […]Kyle G. Pearce
- Recent developments in atomically precise metal nanocluster-based photocatalysts for hydrogen production May 6, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00283D, PerspectiveRugma T. P., Michael N. Pillay, C. W. LiuThis review covers atomically precise metal nanocluster-based photocatalysts for hydrogen production, focusing on their unique structures, strong light harvesting abilities, and charge-transfer mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Rugma T. P.
- Water Soluble Palladium Complexes Bearing NNN-Pincer Ligands: Synthesis, DFT Modeling, cT-DNA Interactions and In Vitro Cytotoxicity Studies Against Breast Cancer Cell Lines May 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00224A, PaperHafiz Muhammad Rizwan Sarwar, Muhammad Jamshaid, Sara Masood, Gul-e-Saba Chaudhry, Sameen Fatima, Itrat Zahra, Arusa Akhtar, Muhammad Tahir, Ehsan Ullah Mughal, M. Naveed ZafarIn the pursuit of designing new anticancer pharmaceuticals and enhancing the therapeutic effectiveness of metal-containing compounds, two new Pd(II) pincer complexes, [Pd(o-LMe)Cl](OTf) (5) and [Pd(o-L′Me)Cl](OTf) (6), […]Hafiz Muhammad Rizwan Sarwar
- Reactivity of a dithorium oxo complex from adventitious water May 6, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00855G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Pritam Mahawar, Steven P. Kelley, Justin R. WalenskyTreatment of [(C5Me5)2ThCl2] with degassed H2O forms a bridging oxo complex, [{(C5Me5)2ThCl}2(μ-O)], which is derivatized to its methyl analogue using MeMgCl. When treated with Me3SiCl and AlCl3, the title compound […]Pritam Mahawar
- Cadmium sulfide quantum dots functionalized with serine, proline, and aspartic acid homologs to study the influence of ligand size on the induced circular dichroism. May 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00778J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Milan Balaz, Yoonbin A. Joh, Krisztina VargaChirality, a fundamental property of molecules and materials, underlies numerous critical chemical, biochemical, and optical phenomena. Chiral organic molecules, termed capping ligands, have been shown to induce chirality […]Milan Balaz
- Catalytic Regioselective 3,4-Difunctionalization of 3-Iodo-o-Carborane via Pd Migration May 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00981B, CommunicationXianren Jiang, Chang-Hua Ding, Zaozao Qiu, Zuowei XieA Pd-catalyzed one-pot regioselective difunctionalization of 3-iodo-o-carborane has been achieved for the synthesis of a wide variety of 3-alkyl-4-Nu-o-carboranes (Nu = aryl, alkyl, amino, or thio groups) in moderate to...The content of this RSS Feed (c) The Royal Society of ChemistryXianren Jiang
- Retraction, republication and removal of expression of concern for ‘Synthesis and characterization of a novel copper carboxylate complex and a copper complex-coated polyether sulfone membrane for efficient degradation of methylene blue dye under UV irradiation: the single crystal X-ray structure of the copper carboxylate complex’ May 6, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT90068A, Retraction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rupy Dhir, Bulle Shah, Narinder SinghTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryRupy Dhir
- Structural Insights and In Vitro and In Vivo Anticancer Evaluation of Dithiocarbamate-Based Metal Complexes against Murine Lymphoma May 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00666J, PaperAnupam Singh, Riya Patel, Samrat Daripa, Manoj Kumar Bharty, R. J. Butcher, Sumit Kumar Hira, Lal Bahadur PrasadMetal-based chemotherapeutics have gained attention due to their ability to interfere with cellular functions. Dithiocarbamate ligands, known for their strong metal-binding properties, have been explored for their potential in anticancer...The content of […]Anupam Singh
- FLP-CO2 adducts: Convenient sources of frustrated Lewis pairs for stoichiometric and catalytic chemistry May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00942A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jordan Thomson, Marc-Andre Courtemanche, Rebecca Claire Neu, Douglas W. StephanThe compounds [tBu3PCO2B(C6F5)3] 1 and [TMPH][C5H6Me4NCO2B(C6F5)3] 7 are easily handled synthons releasing CO2 on warming generating the corresponding FLPs which can activate H2, disulfides, alkynes, […]Jordan Thomson
- Tungsten oxide as a universal source for the synthesis of complexes with different nuclearities in WO3/chalcogen/NaCN systems May 5, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00361J, PaperSpartak S. Yarovoy, Irina V. Mirzaeva, Taisiya S. Sukhikh, Yuri V. Mironov, Vadim Yanshole, Konstantin A. BrylevTungsten trioxide can be used as a readily available source in the one-step preparation of a variety of cyanide and chalcocyanide mononuclear and cluster complexes of tungsten.To cite this article before page numbers […]Spartak S. Yarovoy
- Efficient synergistic photocatalysis of supported Ir/Pd dual metal catalysts based on flexible polymeric brushes May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00593K, CommunicationWenyan Tian, Yongyue Luo, Siwen Zhu, Yang Zhou, Chuangchuang He, Xuebing MaDual metal complexes, Pd(PPh3)4 and Ir(ppy)2(dtbbpy)PF6, are simultaneously anchored onto SiO2-grafted poly(4-vinyl benzyl chloride) (PVBC) brushes via Friedel-Crafts alkylation in one-pot, affording supported dual Pd/Ir complexes with good yields in...The content of this RSS Feed (c) The Royal […]Wenyan Tian
- Toward Enhancing the Electromagnetic Wave Absorption Performance of CeFe-PBA Derived Composites: Morphology Controlling May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00780A, PaperXuan Zhang, Xueling Wang, Hongbo Tai, Zhiliang LiuThe preparation of high-efficiency electromagnetic wave (EMW) absorption materials usually requires matching dielectric and magnetic components. However, simultaneously tuning the dielectric and magnetic properties of materials still faces a significant...The content of this RSS Feed (c) The Royal Society of ChemistryXuan Zhang
- (C7H3NO4)2Sb2F2.2H2O: a pyridine-based compound shows large optical anisotropy May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00698H, CommunicationYaoguo Shen, Jiajia Xiong, Yiman Yang, Zhifeng TangA new organic-inorganic hybrid compound (C7H3NO4)2Sb2F2·2H2O was synthesized. It has two-dimensional [C14H10F2N2O10Sb2]∞ parallel layers structure, which are further optimally aligned by π-π conjugation mode. Remarkably, this compound exhibits a large...The content of this RSS Feed (c) The Royal Society of ChemistryYaoguo Shen
- Photo-release of acetonitrile in Ruthenium (II) complexes with various substituted terpyridine ligands May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00734H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Isabelle Malfant, Vladyslav Mudrak, Pascal G. Lacroix, Pablo Labra-Vázquez, Marine Tassé, Sonia Mallet-LadeiraThe photo-release of acetonitrile is investigated in a series of ruthenium (II) complexes of general formula [Ru(R-phtpy)(acac)(MeCN)](PF6) (phtpy stands for 4’phenyl-2,2′:6′,2″-terpyridine, and […]Isabelle Malfant
- Phosphine-induced conversion from Au36 to Au32 for constructing high-performance CO2RR catalyst May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00604J, PaperJiansheng Ye, Yali Dai, Wenjun Liu, Jingrou Xu, Jialing Li, Meng Chen, Sha Yang, Qinzhen Li, Yuanxin Du, Jinsong Chai, Manzhou ZhuTaking the Au36(CHT)24 (Au36 for short) as a precursor, a Au32(CHT)20(TFP) (Au32 for short) nanocluster is obtained with the aid of a phosphine-mediated approach. Structural analysis shows that […]Jiansheng Ye
- Pnictogen-Functionalised Isocyanide Ligands May 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00992H, PaperAnthony Hill, Ryan M. KirkThe reactions of a range of cyanometallate salts with ClAtBu2Bu2 (A = P, As, Sb, A ≠ Bi) afford the new phosphino, arsino and stibino-isonitrile complexes [M(CNAtBu2)(CO)5] (M = W,...The content of this RSS Feed (c) The Royal Society of ChemistryAnthony Hill
- Dual Tuning of Nodes and Functional Guests of Polyoxometalate@Metal-Organic Frameworks for Enhanced Photocatalytic Oxidative Coupling May 7, 2025
