RSC – Dalton Trans. latest articles- S 2B or not 2B? November 22, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02191J, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ian DanceIn recent years a large collection of experimental information has prompted proposals that an atom, S2B, part of the catalytic metal cluster FeMo-co of the enzyme nitrogenase, is displaced during...The content of this […]Ian Dance
- Mononuclear FeII and Heterobinuclear FeIINiII Thiolate Complexes Derived from a Compartmental Hexaazadithiophenolato Ligand: Synthesis, Structure and Properties November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02350E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vanessa Stephan, Christian Zocher, Martin Börner, Jennifer Klose, Daniel Fuhrmann, Berthold KerstingCompartmental macrocycles have proven to be very successful for the synthesis of heterobinuclear transition metal complexes. We obtained a mixed-ligand FeNi thiolate complex, […]Vanessa Stephan
- Canonical Zn-Zn pseudo-triple bond with double aromaticity in D5h-Zn2Na5- cluster November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01407G, PaperXinluo Wu, Xingman Liu, Lifang Yan, Yue Huang, Xiaomeng Wang, Zhong-Min SuIn transition metals, the formation of intermetallic multiple bonds typically depends on d-orbital coupling. However, zinc, with its fully occupied 3d electron shell, struggles to form multiple bonds via this...The content of this RSS Feed (c) The Royal […]Xinluo Wu
- Oxidation-induced irreversible phase transformation of ethyltriphenylphosphonium-based copper chloride single crystals for achieving second harmonic generation and magnetism November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02573G, CommunicationMengjie Sang, Yanqing Liu, Guokui Liu, Yangyang DangThe irreversible transformation of ETPCuCl2 into ETPCuCl3 achieves functional switching from second harmonic generation to magnetism through an oxidation-induced phase transformation strategy, which not only offers a new approach to...The content of this RSS Feed (c) The Royal Society of ChemistryMengjie Sang
- In situ construction of a Zn2SnO4/TiO2/Ti3C2Tx heterostructured composite allows for rapid sensing of n-hexanol under ultraviolet light illumination November 21, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01961C, PaperXueyan Zhong, Keyue Gong, Ying Liu, Caihong Yuan, Xintong Dong, Lianying Wang, Ying GuoA nano-heterostructured Zn2SnO4/TiO2/Ti3C2Tx composite was prepared with modulated oxygen vacancy concentration to improve its n-hexanol gas sensing performance under UV illumination.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Xueyan Zhong
- Novel Alpha Functionalized Nickel (II) Phthalocyanines: Photochemical, Antioxidant, Antibacterial, Cytotoxicity Studies and Theoretical Insights November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02426A, PaperMustafa Akın, Ozan Cobanoglu, Neslihan Saki, Bilge Karaca, Armağan Günsel, Burak Tuzun, Ahmet Turgut Bilgicli, Gülnur Arabacı, Meryem Nilüfer YaraşırIn this study, novel nickel (II) phthalocyanines (1a-4a) with functional groups containing different atoms such as fluorine, sulfur, and oxygen connected through oxygen bridges from their non-peripheral positions were synthesized...The […]Mustafa Akın
- Microwave-Assisted Synthesis of Fe-based Single-Atom Nanozyme: A Colorimetric Approach to Detect Cr(VI) November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02062J, PaperZixiang Liao, Yue Ren, Bingzheng Yuan, Libo Li, Tianyan YouChromium(VI) (Cr(VI)), a toxic metallic element, is commonly present in water sources and exhibits high toxicity. There is an urgent need to establish an efficient and selective Cr(VI) detection method....The content of this RSS Feed (c) The Royal Society of […]Zixiang Liao
- Nickel and Copper Complexes of a New Multidentate Ligand: Synthesis, Characterization and Magneto-structural investigations November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02226F, PaperWajid Ali, Muhammad Usman Anwar, Hamed Bakhshi, Abdul Jabbar, Jeremy Michael Rawson, Ahmed Al-Harrasi, Melanie PilkingtonThe ligand LH 8 Cl 2 (LH 6 •2HCl) [(3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene)pyridine-2,6-dicarbohydrazide dichloride] was prepared from the Schiff base condensation of pyridine-2,6-dicarbohydrazide with pyridoxal hydrochloride in methanol. Reaction of LH 6 •2HCl...The content of this RSS […]Wajid Ali
- Unraveling the role of Se defects on Fe3Se4 for electrocatalytic oxygen evolution reaction November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02582F, PaperWenjuan Chen, Jinting Wu, Yunfei Zhang, Wan Liu, Zhen-Feng Huang, Ji-Jun Zou, Yong-Chao Zhang, Xiao-Dong ZhuThe high cost of catalysts remains a major bottleneck for water electrolysis hydrogen production, making the development of cost-effective and efficient non-precious-metal catalysts an urgent priority. In this study, we...The content of this RSS […]Wenjuan Chen
- TODGA-inspired complexant for minor actinide extraction November 21, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02197A, CommunicationKrishna P. Gnyawali, Jesse D. CarrickAn N,N,N′,N′-tetraoctyldiglycolamide (TODGA)-inspired, amide-functionalized complexant for the selective partitioning of 241Am3+ from 154–152Eu3+ was designed, synthesized, and evaluated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryKrishna P. Gnyawali
- Mixed-ligand ZIF-doped perovskite films toward damp-heat stable solar cells November 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02603B, PaperShuaikang Chang, Zuoming Jin, Yu Wang, Siyuan Lin, Xueqian Han, Liqiang Zhang, Yuanqiang Wang, Jia Liang, Yichuan RuiPerovskite solar cells (PSCs) are susceptible to environmental factors such as humidity and heat. Here, the mixed-ligand zeolitic imidazolate framework (ML-ZIF) synthesized by partially replacing 2-methylimidazole (2-MIM) ligand in ZIF-8...The content of […]Shuaikang Chang
- High-nuclearity Cu hydride nanoclusters of Cu22H19 and Cu20H13 consolidated by an N-containing triphosphine ligand: synthesis, characterization and catalysis November 20, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02358K, PaperMeng-Xia Ma, Yi-Wu Zhou, Zi-Jian Gui, Ting-Hong Huang, Qing-Ling Ni, Shi-Ming Li, Liu-Cheng Gui, Xiu-Jian WangTwo Cu hydride nanoclusters, [Cu22H19] and [Cu20H13], are synthesized and their compositions and structures are determined by 1H NMR, high-resolution ESI-MS and single-crystal X-ray diffraction analysis.To cite this article before page numbers are assigned, […]Meng-Xia Ma
- Cationic beryllium-group 13 heterobimetallic dimetallocenes with donor-acceptor bond November 20, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02345A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fathima Thanha Thazhe Namboorikandy, Pattiyil ParameswaranA comprehensive geometrical and bonding analysis of heterobimetallic dimetallocenes of the form [Cp–Be–M–Cp]+, where M represents group 13 elements (B, Al, Ga, In, Tl) is presented. The equilibrium geometry […]Fathima Thanha Thazhe Namboorikandy
- Blue to ultraviolet upconversion properties of Pr3+ doped Sr2MgSi2O7 phosphor November 20, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT02454D, PaperNadiia Rebrova, Andris Antuzevics, Alexander Grippa, Guna Doke, Pavels Rodionovs, Przemysław J. DereńThis paper reports on Sr2MgSi2O7:Pr3+ phosphors that simultaneously exhibit upconversion emission in the ultraviolet range (235–300 nm) and photoluminescence in the visible and near-infrared regions under excitation at 444 nm.To cite this article before page numbers are […]Nadiia Rebrova
- Unusual Products Arising from the Tandem Dehydrogenation of Mg(BH 4 ) 2 and Pyrrolidine November 19, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02376A, PaperMckinley A Prager, Craig M. JensenThe dehydrogeation of Mg(BH 4 ) 2 in the presence of O-Lewis base donors has been widely explored but there have been few very few studies of dehydrogenation of the...The content of this RSS Feed (c) The Royal Society of ChemistryMckinley A Prager
- LiBa3Al2B3O11: a deep-ultraviolet transparent optical borate featuring a 2D [Al2B3O11]∞ layered structure November 19, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02373D, PaperShuangyue Shang, Fan Liu, Lei Kang, Tong Wu, Tianhong Huang, Lijuan Liu, Xiaoyang WangBorates have garnered significant attention due to their rich structural diversity and versatile applications, particularly in the ultraviolet (UV) and deep-ultraviolet (DUV) transparent optical regions. In this study, a new...The content of this RSS Feed (c) […]Shuangyue Shang
- Adsorption properties of alpha-type layered and pillared zirconium phosphite phosphonates with high specific surface area and porosities November 18, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02320C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Monica Pica, Elena De Paolis, Emmanuele Cillo, Giorgio Gatti, Geo Paul, Elisa Calà, Fabrizio Olivito, Anna Santaniello, Giovanni GolemmeSingle phase mixed zirconium phosphite phosphonates with layered and pillared structures were prepared by direct reaction […]Monica Pica
- Experimental and Computational Investigation of the Intrinsic Reactions of [U IV F 2 (C≡CH)] + : Formation of [U IV F 2 (O 2 CR)] + , [U IV F(O 2 CR) 2 ] + and [U IV (O 2 CR) 3 ] + by Reactions with Carboxylic Acids November 18, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02372F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samuel J. Lenze, Justin Terhorst, Madeline R. Handel, Jacob A. Hartman, Allison P. Zeiss, Amina Ihabi, Theodore A. Corcovilos, Michael J. van StipdonkWhile there is extensive literature on the intrinsic reactions of gas-phase ions […]Samuel J. Lenze
- Strategies for improving oxygen evolution performance of MOFs nanoarrays November 18, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02272J, FrontierShuang-Yan Lin, Zhikun XuThe design of efficient electrocatalysts for the oxygen evolution reaction (OER) is crucial for addressing global energy challenges, yet remains a significant scientific hurdle. Metal-organic frameworks (MOFs) have emerged as...The content of this RSS Feed (c) The Royal Society of ChemistryShuang-Yan Lin
- Fluorescent Coordination-Polymer Single Crystals with Tunable Elastic-Plastic Transformations November 18, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT02338F, PaperJia-Hui Zhang, Yu-Xia Li, Kaige Gao, Xin-Li Shi, Jie-Sheng Hu, Hui Ai, Zi-Shuo Yao, Jun TaoAchieving and controlling mechanical responses in single crystals with complex coordination architectures remains challenging. Here, we report the design and synthesis of a homologous series of one-dimensional cadmium(II) coordination polymers...The content of this RSS […]Jia-Hui Zhang
- S 2B or not 2B? November 22, 2025
