RSC – Dalton Trans. latest articles- Facile Time-Controlled Synthesis of Two-Dimensional Zr-Perylenediimide MOF Nanosheets for Ultrasensitive DNA Fluorescent Biosensing September 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01883H, CommunicationShiyang He, Yuhong Chen, Jiayi Wang, Xiaoyang Guo, Xiangrong Pan, Yumeng Su, Xiaoyan Lu, Zhan Zhou, Lufang MaThis study demonstrates a facile, surfactant-free strategy for synthesizing uniform two-dimensional (2D) rhombic Zr-PDI (perylenediimide) metal-organic framework (MOF) nanosheets (NSs) (~17 nm thick) by precisely controlling the solvothermal reaction time...The content of […]Shiyang He
- Multimodal Synergistic Thermometry: Designing Wide-Range Optical Thermometers via Eu 3+ /Er 3+ Co-Doped YVO4 September 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01830G, PaperZiyuan Li, Qiao Liang, Lu He, Xiaoli WuIn this paper, a five-mode synergistic thermometry system based on Eu3+/Er3+ co-doped YVO4 fluorescent material was developed. By utilizing the spectral properties of the phosphor, two luminescence intensity ratio (LIR)...The content of this RSS Feed (c) The Royal Society of ChemistryZiyuan Li
- Bulky Bis-Guanidine Ligand Based Neutral and Cationic Zinc Alkyl, Halide, and Hydride Complexes: Synthesis, Characterization, and Catalytic Application September 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02907K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rajata Kumar Sahoo, Sayantan Mukhopadhyay, Sagrika Rajput, Achintya Jana, Sharanappa NembennaThe tetra-aryl substituted bis-guanidine ligand L(3H) (L(3H) = {(ArHN)(ArNH)-C=N-C=(NAr)(NHAr)}; Ar=2,6-iPr2-C6H3), was used for the synthesis of mononuclear zinc(II) alkyls [L(2H)ZnR, R = Me (Zn-1), […]Rajata Kumar Sahoo
- Heteroleptic Tethered NHC Rare Earth Initiators for the Ring Opening Polymerisation of rac-Lactide September 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01352F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joseph W. Walker, Tajrian Chowdhury, Georgina Rosair, Joy Farnaby, Stephen M Mansell, Ruaraidh D McIntoshThe importance of catalyst design is shown by the contrasting reactivity of tethered NHC and Tp ligands with rare-earth metal […]Joseph W. Walker
- Phosphinoamine coinage metal complexes with a coumarin fluorophore: synthesis, characterization, and in vitro (photo)cytotoxicity September 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01532D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vanitha R. Naina, Shubham, Franziska Rönicke, Hans-Achim Wagenknecht, Peter W. RoeskyA coumarin-substituted phosphinoamine ligand was employed to synthesize Cu(I) and Au(II) complexes. The fluorophore in the ligand resulted in emissive complexes, which enabled cell […]Vanitha R. Naina
- Synthesis of Pd(II)–NHC complexes via C–H oxidative addition of triazolium salts to Pd(0) September 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01695A, CommunicationAnes Kovacevic, Sean Parkin, Jay H. BaltisbergerAir-stable Pd(II)–NHC complexes are synthesized via direct oxidative addition of 1,2,4-triazolium salts to Pd2(dba)3. Both cis and trans isomers are observed and structurally characterized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS […]Anes Kovacevic
- Triggering the intrinsic catalytic activity of electrodeposited CoNiFe LDH via Pt decoration for an efficient hydrogen evolution reaction September 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01617G, PaperS. Vijaya, L. John KennedySchematic representation of (a) the preparation of CNF and Pt@CNF, and (b) a symmetric electrolyser using two identical hybrid Pt@CNF electrodes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]S. Vijaya
- Upconversion luminescence and temperature sensing of Dy3+ and Yb3+ codoped Bi2WO6 powder in aqueous environments September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01331C, PaperJiachen Shi, Linxiang Wang, Mengliang Jiang, Xin Feng, Yan Zhangx%Dy3+, y%Yb3+: Bi2WO6 (x=0.5, 1, 3, 5; y=1, 6, 10, 15) upconversion luminescent powders were prepared using a high-temperature solid-phase method. X-ray diffraction experiments revealed that moderate amounts of Dy3+...The content of this RSS Feed (c) The Royal Society of […]Jiachen Shi
- Oxygen Vacancy-Rich Co-Doped V2O5 as a High-Performance Cathode for Aqueous Zinc-Ion Batteries September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01909E, PaperWei Cao, Chenhan Xiong, Yanqiu Yu, Xiang Ji, Hao Xu, Yingge Guo, Ziwei Chen, Jun ChenDeveloping high-performance cathode materials is crucial for advancing aqueous zinc-ion batteries (AZIBs). In this work, we report a Co-doped V2O5 (CoVO) material engineered with abundant oxygen vacancies (Od -CoVO) via...The content of this RSS […]Wei Cao
- Zeolite encapsulated Cu(II)-salen complexes for catalytic Rhodamine B degradation September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01828E, PaperShuyu Li, Tiankun Guo, Zecui Hui, Han Wang, Kaili MaWe successfully synthesized two copper complexes (CuL1 and CuL2) with N₄-tetradentate salen-ligands and encapsulated them within zeolite frameworks. Comprehensive characterization of both free and encapsulated complexes was performed using multiple...The content of this RSS Feed (c) The Royal Society of […]Shuyu Li
- Atomically Dispersed Co-Cu Dual Active Sites in Carbon Networks as Efficient Oxygen Electrocatalyst September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01807B, PaperNibedita Sinha, Chandni Das, Santanu Pal, Rajashri Urkude, Tanbir Ahmed, Biplab Ghosh, Poulomi RoySingle-atom metal-based electrocatalysts offer extended advantages by maximizing the utilization of active sites but often suffers from complex synthesis processes and low-density metal loading. The present work showcases a strategic...The content of this RSS Feed (c) […]Nibedita Sinha
- Trinuclear Copper(I) Furanyl ortho-Diphosphine Halide Clusters: Structure, Photophysical and Photocatalytic Hydrogen Production Properties September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01864A, PaperXiang Chen, Li Liu, Xinxin Zhong, Hengjiang Cong, Fa-Bao Li, Fengyan Li, Yi ZhaoIn recent years, mono-and di-nuclear copper(I) ortho-diphosphine halide complexes have attracted much attention due to their excellent emissive properties. However, trinuclear copper(I) ortho-diphosphine halide clusters have not been reported so...The content of this RSS Feed (c) […]Xiang Chen
- A click grafted cobalt complex on chloromethyl polystyrene for the catalytic cycloaddition reaction of CO2 with epoxides September 14, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01670C, PaperZahra Khazaei, Maryam MohammadikishThe increasing amount of CO2 in the atmosphere has a great impact on all living systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryZahra Khazaei
- Inkless Rewritable Paper Enabled by a Scalable Photochromic Membrane September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01957E, PaperJunchao Liu, Chenfang Zhang, Tianyu Huang, Xusheng Guo, Zhenxin Kuang, Rong-Wei Kou, Yu Zhong, Pan Jia, Jingxia WangRewritable paper has attracted wide research attention in the field of environment-friendly information transmission owing to its potential possibility to promote a sustainable society development. Traditional organic dye-based rewritable paper...The content of […]Junchao Liu
- In Situ Confinement of CsPbBr 3 Quantum Dots within COF for Enhanced Photocatalytic CO2 Reduction September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01826A, PaperWenjian Lv, Jiacheng Wu, Ren Ma, Zhengqiang Xia, Sanping Chen, Gang XieConfining quantum dots (QDs) within covalent organic frameworks (COFs) has emerged as a promising strategy to address their inherent limitations, particularly the aggregation and environmental instability of perovskite QDs, as...The content of this RSS Feed (c) The Royal […]Wenjian Lv
- Nanoporous CoSe2 Polyhedron Imbedded Graphene as a Highperformance Sodium-ion Battery Anode Material September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01923K, PaperShujie Liu, Haiguang Guo, Bohao Wang, Liang Qiao, Xiaoying Hu, Junzhi LiSodium-ion batteries (SIBs) emerge as a promising candidate with the virtue of abundant sodium resources and low costs of sodium salts. CoSe2 as the anode material has attracted much attention...The content of this RSS Feed (c) The Royal […]Shujie Liu
- N-Heterocyclic Silylene Complexes of Nickel(0) September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01887K, PaperEduard Glok, Luis Werner, Udo RadiusReactivity studies on the nickel complex [Ni(Mes2NHSi)2(COD)] (1), ligated with the N-heterocyclic silylene 1,3-bis(2,6-dimesityl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene (= Mes2NHSi; COD = cyclooctadiene) are presented. Treatment of 1 with two equivalents of the phosphines...The content of this RSS Feed (c) The Royal Society of ChemistryEduard Glok
- Redox Transition and Property Modulation in Vanadium Oxide Nanourchins: From V2O5 to long hydrocarbon alkylammonium V7O162-. September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01489A, PaperTamara Bruna, Andres Ibañez, Daniel NavasUrchin-like vanadium oxide nanostructures (VOₓ–NUs) were synthesized using V⁵⁺ alkoxide precursors [VO(OCH(CH₃)₂)₃] and long-chain primary alkylamines (1 hexadecylamine and 1 octadecylamine) as structure-directing agents. The process involves intercalation-driven sol–gel assembly...The content of this RSS Feed (c) The Royal Society of ChemistryTamara Bruna
- Synthesis of Europium based Fluorescent Films for High Sensitivity Detection of Iron Ions via Layered Precursor Anion Exchange September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01750E, PaperLu He, Sen Qin, Haoxuan Zeng, Ziyuan Li, Qiao Liang, Xin Hu, Xiaoli WuIn this study, based on the anion exchange strategy, layered europium hydroxide (LEuH) film was used as a precursor to prepare luminescence films of sodium europium tungstate (NaEu(WO4)2) and sodium...The content of this RSS Feed (c) […]Lu He
- NCPA Templated Red Emitting Gold Nanoclusters: Turn-Off-On Fluorescent Probe for Rapid and Selective Detection of Cu2+Ions in Live Cells and Anticancer Activity September 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01825K, PaperElumalai Manikandan, Gopinath Nagaraj, Sankar Ganesh Ramaraj, Elangovan Vellaichamy, Hitoshi Tabata, Rajendiran NagappanRed-emitting gold nanoclusters (AuNCs) have gained significant attention as promising fluorescent probes for chemical and biomedical applications due to their excellent optical properties and inherent biocompatibility. In this study, a...The content of this RSS Feed (c) The […]Elumalai Manikandan
- Facile Time-Controlled Synthesis of Two-Dimensional Zr-Perylenediimide MOF Nanosheets for Ultrasensitive DNA Fluorescent Biosensing September 16, 2025
