RSC – Dalton Trans. latest articles- Effects of Intercalated Anions on the Interfacial Oxygen Evolution Activity and Selectivity of NiFe(OH)₂ Nanosheet Array Electrodes for Seawater Electrolysis March 31, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00456C, PaperFengyan Xiao, Fangfang Liu, Qin Xing, Runlai Jiang, Yangjing Liu, Jiaxing Ge, Haofeng Yan, Jianwei Ren, Hui WangNickel–iron layered double hydroxides (NiFe-LDHs) are widely recognized as highly effective components for oxygen evolution reaction (OER) catalysis. However, their interfacial OER activity and selectivity under seawater electrolysis conditions remain...The content of […]Fengyan Xiao
- Triplet State Stabilization and Synergistic Energy Transfer in BOPHY-Functionalized NU-1000 for Enhanced Photocatalytic Aerobic Oxidation March 31, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00478D, PaperYena Choe, Seung Jun Lee, Tra Phuong Trinh, Hyung Joo Lee, Hyun Seok Lee, In Guk Song, Hyejin Kang, Gajendra Gupta, Jun-Hyun Kim, Chul Hoon Kim, Chang Yeon LeeHerein, we report the post-synthetic incorporation of an iodinated boron-difluoroboron hydrazone photosensitizer (I-BOPHYPhCOOH) into the zirconium-based metal-organic framework (NU-1000) via solvent-assisted […]Yena Choe
- A novel green-emitting phosphor NaLa9Ge6O26:xTb3+ with anti-thermal quenching for WLEDs March 31, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00231E, PaperZhenwei Jia, Yijie Ren, Mengdi Yue, Jiaqi Wang, Jing Meng, Li Wu, Yongfa Kong, Jingjun XuDefect engineering enhances the thermal stability and performance of green-emitting phosphors for WLEDs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) […]Zhenwei Jia
- Impact of the three-fold channel substitution D131N on kinetics of translocation of Fe2+ across the protein coat is more severe for human cytosolic H-chain ferritin than for human mitochondrial ferritin. March 31, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02739J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zinnia Bugg, Charlie Lewis Phillips Hazlewood, Andrew Hemmings, Justin Michael Bradley, Nick Le BrunFerritins play a key role in iron management in organisms from all kingdoms of life. Excess iron is sequestered in mineral […]Zinnia Bugg
- Nitro-substituted ruthenium(II) polypyridyl complexes synergise with ATR inhibitors to enhance replication stress in cancer cells March 31, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00099A, PaperYian Chee Gan, Nur Aininie Yusoh, Suet Lin Chia, Xiaohe Tian, Martin R Gill, Haslina AhmadRuthenium(II) polypyridyl complexes (RPCs) are promising anticancer candidates owing to their ability to intercalate DNA and disrupt DNA replication. Here, we report a series of nitro-substituted ruthenium(II) complexes of the...The content of this RSS […]Yian Chee Gan
- Oxidative cyclometallation across metal-carbon bonds; exo-metallated metallacyclopentadiene synthesis March 31, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00300A, CommunicationHarrison J Barnett, Anthony HillThe carbido complex [Rh2(μ-C)Cl2(μ-dppm)2] reacts with triphenyl cyclopropenium hexafluorophosphate to afford the exo-metallated metallacyclopentadiene salt [Rh2(μ-C4Ph3)Cl2(μ-dppm)2]PF6. via formal insertion of a metal-carbon multiple bond into the cyclopropenium ring.The content of this RSS Feed (c) The Royal Society of ChemistryHarrison J Barnett
- Controlled Charge Transfer in Well-Structured Cs3Bi2Br9@TiO2 Heterojunctions for Enhanced Visible-Light Photocatalytic Degradation of Tetracycline Hydrochloride March 30, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00279J, PaperChunyu Zhao, Boyang Zhou, Hengjian Mou, Zhang Haonan, Chengyu Shi, Jinyang Luo, Ying Zhou, Jian Wang, Christophe Len, Tao Tian, Aizhao PanThe efficient removal of antibiotic residues has become a significant concern, yet it remains a considerable challenge. Constructing heterojunctions with enhanced interfacial charge transfer represents a promising approach […]Chunyu Zhao
- A dual-mode MOF sensor for Al 3+ detection based on red-shift ratiometric fluorescence and portable hydrogel-smartphone analysis March 30, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00554C, PaperYun Cao, Mengting Zhao, Yuxuan Zhang, Chunyin Ye, Junuo Zhang, Yan WangA three-dimensional MOF, {[Cd(bpdc)(L1)]·5H2O}n (1) (H2bpdc = biphenyl-4,4’-dicarboxylic acid; L1 = 1,1’-((2,4,6−trimethyl-1,3-phenylene)bis(methylene))bis(2-methyl-1H-imidazole)), was synthesized under hydrothermal conditions and comprehensively characterized. Luminescence studies reveal that complex 1 exhibits a distinct fluorescence...The content of this RSS Feed (c) The Royal […]Yun Cao
- Li3GaTe4O11: Small Ion-Driven Orientation of TeOn Units in Tunnel-Structured Tellurite March 30, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00583G, PaperJingfang Zhou, Pifu Gong, Chang Gao, Mingjun Xia, Jing Yu, Hongxia Zhang, Qian WuIn Li3GaTe4O11, asymmetric TeOn (n = 3, 4) polyhedra and GaO6 octahedra construct a three-dimensional (3D) tunnel framework, with Li+ cations occupying the sixteen-membered channels. High framework density (12.1) and...The content of this RSS Feed (c) […]Jingfang Zhou
- Reduced Graphene Oxide/NiCoP Electrocatalysts via a Facile Synthetic Strategy for Efficient Hydrogen Evolution in Alkaline Media March 30, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00533K, PaperHui Ni, Zhen Ma, Jianyi Qin, Xin Zhang, Jing Zhang, Bin ZhaoThe development of highly efficient and cost-effective non-precious metal electrocatalysts for the hydrogen evolution reaction (HER) in alkaline solutions remains a significant challenge in green hydrogen production through water electrolysis....The content of this RSS Feed (c) The Royal […]Hui Ni
- Host–guest adsorption energetics in functionalized UiO-66 nanocrystals for selective VOC sensing March 30, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00102E, PaperYueqin Zhang, Li Zhou, Yuexin Du, Jiaqiang Xu, Junchen Chen, Lien-Yang ChouFunctional-group engineering in UiO-66 enables predictable VOC selectivity: UiO-66-NH2 preferentially detects HCHO, while UiO-66-OH selectively responds to C3H6O, establishing a direct structure–response relationship for MOF-based sensing.To cite this article before page numbers are assigned, use the DOI form […]Yueqin Zhang
- In or out? Adaptive metal binding by a diphosphine-based Zr metal-organic cage March 30, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00536E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiehye Shin, Casey R. WadeA lantern-type Zr metal-organic cage (MOC), Zr-P2N2, has been synthesized using ditopic carboxylate linkers based on the 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligand platform. Single-crystal X-ray diffraction shows that the diphosphine groups of...The […]Jiehye Shin
- Phosphorescence properties of boron β-diketiminate complexes modulated by spiro structures March 30, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00417B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Keisuke Suwa, Shunichiro Ito, Kazuo TanakaBoron-based donor–spiro–acceptor systems were constructed using β-diketiminate units as acceptors. Room-temperature phosphorescence was achieved because of accelerated ISC through intra- and inter-ligand charge-transfer states.To cite this article before page […]Keisuke Suwa
- A Zn(II)-Based Metal–Organic Framework Constructed from Cyclotriphosphazene Hexacarboxylate and π-Conjugated Bisterpyridine Ligands for Dual Applications in Dye Photodegradation and VOC Sensing March 29, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00537C, PaperElif ÖzcanThe increasing demand for sustainable materials capable of addressing both water and air pollution has stimulated the search for multifunctional MOFs with integrated properties. Herein, we report the solvothermal synthesis...The content of this RSS Feed (c) The Royal Society of ChemistryElif Özcan
- Synthesis, Crystal Chemistry, and Semiconducting Properties of A3B14Se24 (A = Sn/Pb; B = In/Sb/Bi) with Step-Layered NaCl(111)-Type Slabs Interleaved by NaCl(100)-Type Ribbons March 29, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02970H, PaperGuan-Ruei Chen, Wan-Zhen Xiaoa, Yen-Han Huang, Chia-Wei Yang, Chi-Shen LeeNew multinary selenides A3B14Se24 (A = Sn/Pb; B = In/Sb/Bi) were discovered by exploratory synthesis in the (Sn/Pb)–In–(Sb/Bi)–Se systems. Single-crystal X-ray diffraction established this structure type for Pb3In5Sb9Se24, Pb3In6Sb8Se24, Sn3In5Sb9Se24,...The content of this RSS Feed (c) The Royal Society of […]Guan-Ruei Chen
- Comparative Biological Activity of Manganese(II) and Zinc(II) Hydrazone Complexes March 29, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00532B, PaperMilica Savić , Andrej Pevec, Irena Novaković, Ivana Matic, Tatjana Stanojkovic, Matija Zlatar, Maja Gruden, Božidar ČobeljićThis work comparatively investigates structurally related Mn(II) and Zn(II) hydrazone complexes within a unified structural, computational, and biological framework. Three Mn(II) complexes, whose crystal structures have been previously reported, are...The content of this […]Milica Savić
- Polyoxometalate-Embedded Cu-Triazole Cycle: Catalytic Oxidation of Alcohols March 29, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00581K, Paperwang quanzhong, Yahong Chen, Fengshou Tian, ruixia DouIn the present study, a novel three-dimensional (3D) porous framework, [Cu3ICu4IICl(TRZ)7][GeW12O40]·7H2O, designated as Cu-W-TRZ, was synthesized through a hydrothermal approach by integrating the {GeW12} cluster into a Cu(I/II)-TRZ framework. This...The content of this RSS Feed (c) The Royal Society of Chemistrywang quanzhong
- Single-Crystalline Ordered Mesoporous Indium Tin Oxides with Controlled Sn/In Ratio via Vapor-Phase Oxidation of Metal Chlorides within Silica Colloidal Crystals March 29, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03043A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tomohiro Okita, Ryoma Uchida, Atsushi Shimojima, Takamichi MatsunoThe properties of nanoporous metal oxides depend on their pore structure and the internal structure of the pore walls, and precise control of such factors is crucial. […]Tomohiro Okita
- An Ultra-Broadband and Multi-Frequency Switchable Terahertz Absorber Based on Patterned VO2 Multilayer Stacked Architecture March 29, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00317F, PaperShaokun Hu, Junliang Yao, Zhen CuiThis study designed a multilayer stacked ultra-broadband and multifrequency switchable terahertz absorber employing vanadium dioxide (VO2), polydimethylsiloxane (PDMS) and embedded Aurum (Au). This absorber achieves reversible phase transitions in VO2...The content of this RSS Feed (c) The Royal Society of ChemistryShaokun Hu
- La–[18/19F]fluoride complexes: a novel addition to the radiofluorination family March 29, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02645H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Martin Behe, Stefan Gruber, Cen Li, Georg Schreckenbach, Linjing Mu, Margret Schottelius, Radmila FaizovaNovel La–[18/19F]fluoride complexes lay a foundation towards 18F/225Ac/La theranostics. Systematic evaluation of La–F coordination chemistry reveals a fundamental trade-off: ligand electronics […]Martin Behe
- Effects of Intercalated Anions on the Interfacial Oxygen Evolution Activity and Selectivity of NiFe(OH)₂ Nanosheet Array Electrodes for Seawater Electrolysis March 31, 2026
