RSC – Inorg. Chem. Front. latest articles- Phosphorus chirality assignment and solution dynamics of lanthanide(III) complexes of a monomethylphosphinate analogue of Htext-decoration:underline"4dota: A multinuclear NMR and DFT study. November 6, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01885D, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Adam Svítok, Carlos Platas-Iglesias, Jan Kotek, Petr HermannAnalogues of H4dota form kinetically inert and thermodynamically stable complexes with lathanide(III) ions and they are used in many applications in biology and medicine, mostly […]Adam Svítok
- The effect of the large cation matrix and delocalization of electronic density on the switchable behaviour of heterotrimetallic cyanido-bridged FexMn9−xW6 clusters November 5, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01515D, Research ArticleJedrzej Kobylarczyk, Marcin Kozieł, Katarzyna Dziedzic-Kocurek, Jan M. Michalik, Dawid Pinkowicz, Magdalena Fitta, Barbara Sieklucka, Robert PodgajnyA Mn(II)-cation-based large matrix stabilizes the HT phase and shapes the phase transitions and spin-state equilibria in a trimetallic {FeIIxMnII9−x[WV(CN)8]6(MeOH)24}·nMeOH cluster series.To cite this article before page numbers are assigned, use […]Jedrzej Kobylarczyk
- Reactive Flux Assisted Metal Oxide-Boron-Sulfur Routine for Syntheses of CsRESiS 4 (RE = Sm, Gd-Ho): Featuring Nonlinear Optical Activity and Wide Band Gaps † November 5, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01851J, Research ArticleZhen-Cheng Wu, Fang-Xu Tian, Rui Xiao, Mao-Yin Ran, Wen-Long Liu, Wentong Chen, Sheng-Ping GuoThe study of infrared nonlinear optical (NLO) materials with wide band gaps and high laser induced damage thresholds (LIDTs) is an urgent and challenging topic. Here, we reports the NLO...The content of this RSS […]Zhen-Cheng Wu
- Unveiling Anionic Migration Mechanisms Governed by Mixed-Anion Chemistry in Melilite Oxyfluorides November 5, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01806D, Research ArticleLijia Zhou, Li Yang, Aydar Rakhmatullin, Shipeng Geng, Xiaoyan Yang, Mathieu Allix, Jiazheng Hao, Lunhua He, Mingxue Tang, Zewei Quan, Xiaojun KuangMixed-anion compounds provide a chemically flexible platform for tuning the anion sublattice configurations and defect landscapes, making them promising platforms for the design of novel anionic […]Lijia Zhou
- Acid–base interactions in luminescent silver(I) and gold(I) complexes with phosphine–phosphinate/phosphinite ligands November 4, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01622C, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mariia Beliaeva, Andrey Belyaev, Henna Korhonen, Ondrej Mrózek, Janne Jänis, Andreas Steffen, Igor O. KoshevoyHybrid phosphines with anionic functions form luminescent complexes with d10 coinage metals and provide an adaptable ligand environment, […]Mariia Beliaeva
- Aqueous-Phase NADH Regeneration Using Rh(N-Heterocyclic Carbene) Catalysts with Enhanced Hydride Kinetics November 3, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01887K, Research ArticleVinothkumar Ganesan, Dharmalingam Sivanesan, Sungho YoonNicotinamide adenine dinucleotide (NADH) serves as a two-electron and one-proton donor in redox biocatalysis, yet its high cost and stoichiometric consumption limit large-scale application. A [Cp*Rh(N^C)Cl]+ complex featuring a mono(NHCpyridyl)...The content of this RSS Feed (c) The Royal Society of ChemistryVinothkumar Ganesan
- Assembly and solution phase properties of Ag+–mediated adenine-thymine DNA duplexes October 31, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01833A, Research ArticleEshana Bethur, Ziqian Zhao, Rweetuparna Guha, Hongbo Zeng, Stacy M. CoppSilver cations (Ag+) exhibit site-specific coordination with the natural nucleobases, which can be exploited within DNA nanostructures. Understanding the thermodynamics of formation and organization of DNA complexes formed by these...The content of this RSS Feed (c) The […]Eshana Bethur
- Dual Function of Additives in Controlling Al Siting and Nanocrystals Assembly of MEL Zeolite for Enhanced Methanol-to-Olefins Performance October 31, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01588J, Research ArticleJunwei Wu, Qiudi Yue, Diogenes Honorato-Piva, Chunzheng Wang, Svetlana MintovaThe catalytic performance of zeolites is governed by crystal morphology, acidity, and the spatial distribution of framework Al atoms. However, achieving precise control over these physicochemical properties during zeolite synthesis...The content of this RSS Feed (c) The Royal […]Junwei Wu
- Mesoporous Carbon-Encapsulated Co Single Atoms via NH4Cl-Templated ZnCo-ZIF Pyrolysis for Efficient Ammonium Perchlorate Catalysis October 31, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01431J, Research ArticleYuming Zhou, Peng Zhou, Xiaolin Tang, Bo Yuan, Jun Liao, Chongtao Ding, Junyu Li, Weihang Cheng, Xingang Wang, Chi HuangDue to limited accessibility of active sites and mass transfer efficiency, the application of single atom catalysts (SACs) in complex reactions faces challenges. Here, we report a hierarchical […]Yuming Zhou
- A Monolithic Chiral Perovskite Crystal Enables Self-Powered, Full-Stokes Detection of Ultra-Weak Light October 30, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01944C, Research ArticleQuanlin Chen, Yangbin Xu, Qingming Wu, Yanxing Feng, Zhiqiang Huang, Hai Jia, shaoming Ying, Xiao-Hui HuangAccurate and chip-integrated full-Stokes polarization detection is essential for advancing multifunctional optoelectronic systems. However, conventional approaches relying on optical filters often suffer from significant optical losses and poor sensitivity under...The content of […]Quanlin Chen
- Multimetallenes and their electrocatalytic applications October 29, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01584G, Review ArticleNaiwen Liu, Wenxia Xu, Jianping Lai, Lei WangThis review focuses on multimetallene electrocatalytic materials, summarizing synthesis strategies, multidimensional structural optimization, and applications in high-current-density oxygen reduction and overall water splitting.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]Naiwen Liu
- Localizing Tetrahedral Aluminum in Nitrate-Bearing Gibbsite to Constrain Defect-Impurity Coupling October 29, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01703C, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Trent R Graham, Micah P Prange, Xin Zhang, Jonathan David Bazak, Nancy Washton, Khashayar Ghandi, Gregory Schenter, Carolyn PearceThe enhanced radiolytic stability of gibbsite (α-Al(OH)3) containing trace nitrate (NO3-) is a critical […]Trent R Graham
- Different roles of similar aromatic rings in half-sandwich lanthanide single-ion magnets unravelled by ab initio electronic structure calculation October 28, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01822F, Research ArticleYan-Ling Hu, Xuan Wang, Hao Liu, Bing YinHerein, a systematic ab initio study was carried out in a group of half-sandwich lanthanide (Ln) single-ion magnets (SIM) composed of one LnIII ion, one aromatic ring and several non-aromatic...The content of this RSS Feed (c) The Royal Society of […]Yan-Ling Hu
- Transformation of Bimetal Carboxylate-MOF into Phosphonate-based MOF as Multifunctional Photocatalyst October 28, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01658D, Research ArticleAihui Cao, kang Li, Xiao Xu, Longtian Kang, Min ZhangOver the last ten years, there has been significant ongoing development of metalorganic framework (MOF) catalysts designed for artificial photosynthesis, converting solar energy into chemical fuels. In contrasted to the...The content of this RSS Feed (c) The Royal […]Aihui Cao
- Sustainable solar seawater splitting over a BaTaO2N photoanode enabled by chloride recirculation October 28, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01561H, Research ArticleJeongsuk Seo, Seongeon Mun, Van-Huy TrinhSustainable solar seawater splitting over a BaTaO2N photoanode via Cl− regeneration and closed-loop operation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryJeongsuk Seo
- Janus structure Ir–Ir3Ce@IrO2 nanocrystals as excellent bifunctionality catalysts for acidic overall water splitting October 28, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00479A, Research ArticleYue Feng, Ying Chang, Shaohong Guo, Yaqiong Su, Jingchun Jia, Meilin JiaWe synthesized the Ir–Ir3Ce Janus nanocrystalline nanoparticles loaded with defective carbon encapsulated by IrO2 were synthesized by a simple method, which exhibited excellent catalytic performance during the acidic overall water splitting.To cite this article before page […]Yue Feng
- A simple and practical wax-encapsulation method for air-sensitive XAS samples October 27, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01913C, Research ArticleOscar Oehlsen, Frank MacGregor, Matthew J. F. Jones, Alejandra Gómez-Torres, Liane M. Moreau, Joshua Wright, Lu Ma, Skye FortierA simple method is presented for encapsulating highly air-sensitive samples in paraffin wax, providing an airtight seal that preserves sample integrity during XAS analysis.To cite this article before page […]Oscar Oehlsen
- Counterions manage metal-to-metal electron transfer: the role of intermolecular interactions in MMET-active [Fe4Co4] cubes October 27, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01982F, Research ArticleRen-He Zhou, Hui-Ying Sun, Du-Yong Chen, Yu-Jing Gao, Cheng Yi, Meng-Jia Shang, Liang Zhao, Yin-Shan Meng, Tao LiuA counterion strategy was used to synthesize [Fe4Co4] cubes (1·BF4, 2·ClO4, 3·PF6, 4·AsF6, and 5·SbF6) with tunable intermolecular interactions. This tunes coordination geometry and the metal center electrostatics, modulating the […]Ren-He Zhou
- High-performance organic–inorganic hybrid manganese halide scintillator array for superior-resolution X-ray imaging October 27, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01886B, Research ArticleMengyue Wu, Jun'an Lai, Yongqiang Zhou, Faguang Kuang, Kang An, Sijun Cao, Yayun Pu, Heng Luo, Peng He, Baofei Sun, Xiaosheng TangPb-free organic–inorganic metal halides play an increasingly important role in X-ray scintillator imaging applications because of their high luminescent quantum yield, excellent stability, and environmentally friendly […]Mengyue Wu
- Ru species decoration on hierarchical Nb2O5-x triggers product selectivity inversion for CO2 photoreduction October 24, 2025Inorg. Chem. Front., 2026, Accepted ManuscriptDOI: 10.1039/D5QI01749A, Research ArticleYeqiang Zhai, Guimin Wang, Nan Wang, Yanqing Jiao, Dongxu Wang, Haijing Yan, Yuxian Jiang, Aiping Wu, Honggang FuPhotocatalytic CO2 reduction to CH4 is a promising route to convert greenhouse gases into value-added fuels and chemicals. Nevertheless, achieving high efficiency and product selectivity remains a formidable challenge due...The […]Yeqiang Zhai
- Phosphorus chirality assignment and solution dynamics of lanthanide(III) complexes of a monomethylphosphinate analogue of Htext-decoration:underline"4dota: A multinuclear NMR and DFT study. November 6, 2025
