RSC – Inorg. Chem. Front. latest articles- Dual-State heptanuclear metal cluster-based MOF materials: Open Metal Sites Enhanced Acetylene/Ethylene Separation and Coordinated Water-Driven Propylene /Propane Kinetics May 6, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00788G, Research ArticleRizhao Zhang, Yaqing Fan, Yuqiao Chai , Xue Jinpeng, Bao Li, Jia LiIn cluster-based MOF materials, although clusters with open metal sites (OMSs) play a critical role in separation processes，excessively strong OMSs can lead to a large amount of co-adsorption with the...The content of this RSS Feed […]Rizhao Zhang
- Dual Atomic Defect Modulation in Three-Dimensional Mesoporous Graphene for High-Performance Potassium Ion Hybrid Capacitors May 6, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00267B, Research ArticleYize Wang, Wenda Qiu, Peijun Deng, Jing Fu, Guoxian Li, Chunjin Li, Mingzu Zhang, Pingji Yu, Huajie Feng, Xihong LuBy combining the high energy density of potassium ion batteries (PIBs) with the fast power delivery of supercapacitors (SCs), potassium ion hybrid capacitors (PIHCs) pave the way for […]Yize Wang
- A three-in-one strategy enables improved kinetics in an LLZTO solid electrolyte for Li-CO2 batteries with high energy efficiency May 6, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00659G, Research ArticleZesen Gao, Shijie Yang, Yan Yang, Futing Sun, Tianshuo Zhang, Yunluo Wang, Tianrui Zhou, Lang Tao, Hucheng Song, Haijie ChenVacuum-synthesized LLZTO@PVDF offers triple functions: high Li+ conductivity (1.92 mS cm−1), strength, and Li2CO3 decomposition sites. Ru@C-based Solid-state Li-CO2 cells with a molten salt layer achieve 3.0 V […]Zesen Gao
- Photochemical [2+2] reaction-tuned spin-crossover cooperativity in an Fe(II)-Ag(I) bimetallic Hofmann-type framework May 6, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00821B, Research ArticleLong-Fei Wang, Liang Wu, Guo-Zhang Huang, Si-Guo Wu, Ming-Liang TongPhoto-responsive spin-crossover (SCO) compounds are particularly appealing due to their adjustable wavelength/energy of light and the capability for remote switching. Herein, we introduce the 3-styrylpyridine (3-spy) ligand into a 2D...The content of this RSS Feed (c) The Royal […]Long-Fei Wang
- Profiting from Light-Induced Metal-to-Metal Intramolecular Electron Transfer: Towards Highly Efficient Heterodinuclear Photosensitizers for Photodynamic Therapy May 6, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00924C, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.JUAN SANZ-VILLAFRUELA, Lisa-Marie Servos, Nicolas Montesdeoca, José Vicente Cuevas-Vicario, Artur J. Moro, J. Carlos Lima, Marta Martínez-Alonso, Gustavo Espino, Johannes KargesPhotodynamic therapy is receiving increasing attention due to its versatile application in […]JUAN SANZ-VILLAFRUELA
- High-Entropy Alloys and Oxides as Catalysts for Water-Splitting: Synthesis, Characterization, Applications and Prospect May 5, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00538H, Review ArticleTong Wu, Xiaoyi Zhang, Ziyu Yang, Zhilin Chen, Yihao Long, Liang He, Changsong Dai, Jibing Chen, Hui TangHigh-entropy materials (HEMs), due to their exceptional physicochemical performance, which includes a unique electronic structure, outstanding catalytic performance, and remarkable electrochemical stability, are considered as promising catalysts for applications such...The […]Tong Wu
- Structural engineering of MXene frameworks with abundant surface functionalities for enhanced lithium–sulfur battery electrochemistry May 5, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00422E, Research ArticleYongjie Ye, Sisi Liu, Yongqian He, Wanqi Zhang, Ying Chen, Mengqing Wang, Xuewen Peng, Caixiang Wang, Qin Tang, Yan Luo, Bing Wu, Hongbo Shu, Ruizhi Yu, Manfang ChenTi3C2Tx with abundant surface functional groups effectively promotes the redox transformation of polysulfides.To cite this article before page numbers are […]Yongjie Ye
- Synergistic interplay between oxygen-vacancy and S-scheme charge transfer dynamics in an LaFeO3/FeOOH heterojunction towards sono-assisted photo-Fenton antibiotic degradation and water splitting May 5, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00648A, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Anshumika Mishra, Newmoon Priyadarshini, Kulamani ParidaThe study investigates synergism of S-scheme charge transfer dynamics, oxygen vacancies, and sono-photo-Fenton mechanisms in a novel LaFeO3/FeOOH heterojunction photocatalyst, showcasing enhanced activity for remediation of antibiotics […]Anshumika Mishra
- A Janus binder favors interfacial protection and mechanical stabilization for Li-rich layered oxide cathodes May 5, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00455A, Research ArticleWenhua Cheng, Qingcui Liu, Huan Zhou, Fengjuan Chen, Yudai Huang, Anqiang PanThe carrageenan binder eliminates residual alkalis and inhibits interfacial side reactions, and maintained 100% capacity over 550 cycles with a voltage decay of 0.598 mV per cycle at 2 C.To cite this article before page numbers […]Wenhua Cheng
- Engineering Active Site Reconstruction of Metal Hydroxide/Metal Molybdate Heterogeneous Interface Enhances the Electrochemical Water Oxidation Process May 5, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00418G, Research ArticleXuanyu Zhou, Junjun Zhang, Mengyuan Zhang, Xiaoqian Du, Weiwei Bao, Jie Han, Xiu Lin, Pengfei Zhang, Zheng-Hong LuoEfficient, stable and economical water electrolysis catalysts are of paramount importance in energy transition and storage systems. Although numerous single compounds exhibit certain electrocatalytic properties, their inherent limitations hinder optimal...The […]Xuanyu Zhou
- Tailoring the Catalytic Microenvironment of large-scale Cu foil with Polyaniline to Enhance CH4 Selectivity in CO2 Electroreduction May 3, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00566C, Research ArticleYu-Ting Wen, Wanfeng Xiong, Duan-Hui Si, Hongfang Li, Rong CaoElectrochemical conversion of CO2 into liquid fuels and value-added chemicals is a promising approach to close the carbon cycle. Copper (Cu) is considered as one of the most effective catalysts...The content of this RSS Feed (c) The Royal […]Yu-Ting Wen
- Synthesis and Reactivity of a Benzo-Fused 1,2-Diborete Biradicaloid May 1, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00960J, Research ArticleAlena Häfner, Lukas Endres, Merle Arrowsmith, Cornelius Mihm, Sonja Fuchs, Samuel Nees, Krzysztof Radacki, Ivo Krummenacher, Rüdiger Bertermann, Felipe Fantuzzi, Holger BraunschweigThe synthesis of 1,2-(BCl2)2C6H4 (1) was optimised by performing a SiMe3-BCl2 metathesis reaction between 1-SiMe3-2-(BCl2)C6H4 with BCl3 in the dilute gas phase at 95 °C, with […]Alena Häfner
- Highly Stable and Reversible Birefringent Switching Triggered by Thermally Stimulated Phase Transition April 30, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00625B, Research ArticleCheng Chen, Yunjie Bai, Qi Shi, Mingye Han, Bingbing Zhang, Ying WangManipulating light polarization in birefringent crystals is central to photonic applications. However, controlling intrinsic optical anisotropy in a noninvasive manner remains challenging. Here, we discovered the polymorphism of inorganic birefringent...The content of this RSS Feed (c) […]Cheng Chen
- Hierarchically Porous Zeolite Featuring an Alveolus-Like Microsphere for Efficient Oxidative Desulfurization April 30, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI00664C, Research ArticleXing-Yu Yue, Yuan-Yuan Wang, Shen Yu, Chun-Mu Guo, Zhan Liu, Yi-Long Wang, Zhi-Yi Hu, Yu Li, Li-Hua Chen, Bao-Lian SuBio-inspired catalyst materials with diverse functions and excellent performance are highly demanding for efficient catalytic conversion. However, precisely imitating the natural structure to achieve optimized performance is still […]Xing-Yu Yue
- High entropy sulfide nanoparticles as redox catalysts for lithium–sulfur batteries April 29, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QI03229B, Research ArticleYiqian Li, Yuehan Hao, Usman Ali, Mingxin Sui, Qi Zhang, Lingyu Zhang, Lu Li, Bingqiu Liu, Chungang WangUltrafine HES NSs modified separators enhance Li–S batteries by exposing abundant active sites, acting as a dual-functional LiPSs barrier to suppress side reactions and accelerate polysulfide redox.To cite this article […]Yiqian Li
- Mutual restriction-driven anomalous multistage piezochromic behavior in copper(I) thiocyanate/isoquinoline coordination polymers April 28, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00685F, Research ArticleZhenxing Yang, Chunguang Zhai, Jianqi Shang, Lingyan Dang, Yuchen Shang, Jiangya Xu, Yupu Zheng, Xiaolu Qi, Rui Shi, Mingguang YaoHere, we report the multistage piezochromic behavior in copper(I) thiocyanate/isoquinoline coordination polymers by the competing effects of pressure-enhanced charge transfer efficiency and structural deformation.To cite this article before […]Zhenxing Yang
- Reverse quantum wells in gradient-doped CdS for photocatalytic H2O2 production April 28, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00742A, Research ArticleXiaoying Bo, Caijie Yang, Bolun Li, Yikang Fan, Jiaoyan Li, Hengming Huang, Jiahui Kou, Chunhua LuGradient Mn-doping in CdS forms reverse quantum wells and surface active sites, which enhance charge extraction and O2 activation. This achieves a H2O2 production rate of 1874 μmol g−1 h−1 and an apparent quantum efficiency of […]Xiaoying Bo
- Linker-Cluster Cooperativity in Confinement of Proline-Functionalized Zr-Based Metal-Organic Frameworks and its Effect on the Organocatalytic Aldol Reaction April 28, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QI02724H, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zarfishan Dilruba, Ardeshir Dadgar Yeganeh, Sofia Kolin, Sadia Noor, Hassan Shatla, Carl Wieland, Bo-Hung Yu, Katrin Gugeler, Anna Zens, Johannes Kästner, Deven Estes, Kristyna Pluhackova, Simon Krause, Sabine LaschatMetal organic frameworks (MOFs) […]Zarfishan Dilruba
- Microwave quasi-solid-state-constructed low-content Pt on CeO2 with strong electronic interactions for efficient electrocatalytic acidic overall water splitting April 28, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00536A, Research ArticleJing Li, Qihao Wang, Ruotong Guo, Yingxia Zong, Jun Xing, Weiping Xiao, Guangrui Xu, Dehong Chen, Lei Wang, Zexing WuPt-loaded CeO2 cubes were designed via a rapid and eco-friendly ultrafast microwave quasi-solid-state approach within 60 s, which exhibited a low overpotential of 10 mV to reach 10 […]Jing Li
- Deep-ultraviolet nonlinear-optical crystals LiBePO4 and BeP2O6 synthesized by ionic potential modulation towards uniform arrangement of PO4 groups April 27, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI00779H, Research ArticleXia Zhang, Jian-Qiang Shen, Hong-Xiao Lv, Peng-Hui Guo, Yi-Gang Chen, Chun-Li Hu, Xian-Ming ZhangDUV NLO crystals LiBePO4 and BeP2O6 adopting a Cs4LiBe4P7O24 structural model were synthesized using an ionic potential modulation strategy. The arrangement of PO4 groups exhibits uniform evolution, inducing increased SHG effects.To cite this article […]Xia Zhang
- Dual-State heptanuclear metal cluster-based MOF materials: Open Metal Sites Enhanced Acetylene/Ethylene Separation and Coordinated Water-Driven Propylene /Propane Kinetics May 6, 2025
