RSC – Inorg. Chem. Front. latest articles
- Highly active superoxide dismutase mimic: pyridine-carboxamide based copper(II) complexes September 29, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI01687H, Research ArticleRóbert Diószegi, Andrea Guidetti, Norbert Ág, Ilenia Serra, Dóra Vargáné Szalóki, Dóra Bonczidai-Kelemen, Nóra May, Erzsébet Fekete, Levente Karaffa, István Fábián, Sabine Van Doorslaer, Norbert LihiPyridine-based ligands functionalized with one (PyHis) or two histidine (PydiHis) moieties have been synthesized, and their copper(II) complexes were studied as novel […]Róbert Diószegi
- Thermally Responsive Magnetic Bistability Through Solid-Liquid Phase Transitions in Alkylthio-Functionalized Dithiadiazolyl Radicals September 29, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI01391G, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Juho M Toivola, Ankita Naik, Manu Lahtinen, Oriol Gonzàlez-Prats, Andrea Perez Prieto, Itziar Oyarzabal, Aaron M. MailmanA series of p-alkylthio-substituted phenyl-1,2,3,5-dithiadiazolyl radicals, p-R-PhDTDA (R = SMe (2), SEt (3), S n Pr […]Juho M Toivola
- Realizing large birefringence via S-substitution and anisotropic arrangement optimization September 28, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01600B, Research ArticleZhiwei Sun, Bingbing Wu, Zihao Yu, Qingran Ding, Yuling Wang, Ming Zhong, Sangen Zhao, Junhua LuoThe substitution of sulfur (S) (from 1 to 2) and the optimized arrangement of functional groups (from 2 to 3) can effectively promote enhancement in birefringence.To cite this article before page numbers […]Zhiwei Sun
- Promotion of Acetylene Semi-Hydrogenation by Oxide-Oxide Interactions in FeOX/TiO2 Catalysts September 25, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI01502B, Research ArticleQianjun Zhang, Yuanjing Fan, Xinhui Zhang, Fan Zhang, Yingxue Qin, Feng Feng, Jia Zhao, Chunshan Lu, Qunfeng Zhang, Qingtao Wang, Xiaonian LiOxide catalysts have garnered significant attention in heterogeneous catalysis due to their excellent activity and cost-effectiveness. While metal-support interactions have been widely studied, the role of […]Qianjun Zhang
- Stabilization of Double Sandwich Structure of Mercury(II) Porphyrins: Hg•••Hg•••Hg Interactions and Structure-Function Correlation September 25, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI01593F, Research ArticleAnindya Sarkar, Dolly Chandel, Mirza Nasib Begg, Anjani Kumar Pandey, Nityananda Dutta, Chandrani Pal, Mohammad Usman, Anindya Datta, Sankar Prasad RathA series of stable trinuclear "double sandwich" complexes of mercury(II) porphyrins having linear Hg3 core have been stabilized successfully utilizing both flexible and rigid porphyrin dimer frameworks. […]Anindya Sarkar
- A bridging thiocarbyne ligand in diiron(I) complexes enables unconventional isomerization pathways and structural diversity leading to potent cytotoxicity September 25, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI01498K, Research ArticleLorenzo Biancalana, Ekatarina Mihajlovic, Gianluca Ciancaleoni, Marija Mojic, Sanja Jelača, Stefano Zacchini, Guido Pampaloni, Biljana Dojčinović, Danijela Maksimovic-Ivanic, Sanja Mijatović, Fabio MarchettiEight diiron(I) bis-cyclopentadienyl complexes with a bridging methylthiocarbyne ligand were prepared from the tris-carbonyl precursor [Fe2Cp2(CO)2(μ-CO)(μ-CSMe)]CF3SO3 (Cp = η5-C5H5) through the substitution of one or two […]Lorenzo Biancalana
- Reciprocating Thermal Behavior and Thermometry Studies of Tb3+ and Gd 3+ -Oxamato Single-Ion Magnets September 23, 2025Inorg. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D5QI01603G, Research ArticleCleber R Araujo Junior, Luana M Murad, Rafael V Perrella, Willian X. C. Oliveira, Carlos Basílio Pinheiro, Thais F Ramos, Patricia Patricio, Emerson F. Pedroso, Wallace C. Nunes, Pablo Rafael Trajano Ribeiro, Diego Muraca, Fernando Fabris, Marcelo Knobel, Fernando Aparecido Sigoli, Cynthia L. M. PereiraSingle-ion magnets (SIMs) […]Cleber R Araujo Junior
- Anion exchange in bismuth oxyhalides for electronic property control and isolation of BiON3 September 22, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01602A, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander E. Padilla II, Adam JaffeWe tune layered bismuth oxy(pseudo)halides through anion exchange and then show the first structure of BiON3 and its unique thermolysis.To cite this article before page numbers are […]Alexander E. Padilla II
- Mixed valence bimetallic Cu complexes with a urea-backboned tetradentate ligand September 22, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01792K, Research ArticleAnshu Singh, Samgyul Lee, Kang Mu Kwon, In Hyun Hwang, Jeongcheol Shin, Kyounghoon LeeTwo different mixed valence bimetallic Cu complexes, induced by coordination environments, were prepared and characterized using spectroscopic and computational methods.To cite this article before page numbers are assigned, use the DOI form of citation […]Anshu Singh
- Construction of π–d metal–organic frameworks featuring butterfly-inspired building blocks as efficient anodes for high-performance lithium-ion batteries September 21, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01815C, Research ArticleWenqian Zhou, Jinjian Li, Jie Li, Yiting Guo, Shujun Li, Chao Li, Kuaibing Wang, Cheng Zhang, Qichun ZhangA conjugated π–d copper-catecholate-based metal–organic framework was synthesized as a novel anode for lithium-ion batteries, exhibiting enhanced electrical conductivity, fast lithium-ion transport, and outstanding electrochemical performance.To cite this article before […]Wenqian Zhou
- Highly luminescent divalent tin(II) imide complexes [ArNSn]2 September 21, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01134E, Research ArticleOlga A. Kushnerova, Vasily A. Ilichev, Roman V. Rumyantcev, Georgy K. Fukin, Nikolay V. Somov, Wenhua Xu, Yanxia Zhao, Vladimir A. DodonovNovel low-valent organotin imide complexes exhibit remarkable phosphorescent properties suitable for advanced luminescent applications.To cite this article before page numbers are assigned, use the DOI form […]Olga A. Kushnerova
- Mg/Ti co-doping induced P2/O3 biphasic modulation strategies enhancing structural stability for sodium-ion battery cathodes September 18, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01182E, Research ArticleZirun Chai, Huijun Li, Mingyang Gao, Weijie Yi, Xiaomin WangThe unique ratio of P2/O3 biphasic layered oxides undergoes a phase transition after long cycling with only a low content of the O3 phase structure.To cite this article before page numbers are assigned, use the DOI form of […]Zirun Chai
- Manipulating molecular alignment: organoselenium radical cations with tailored Π-stacking architectures September 17, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01615K, Research ArticleShan Li, Jiayao Yang, LinLin Yang, Tao Li, Wanxiang ZhaoOxidized Se-PAHs form radicals that counterion-control π-stacking, revealing assemblies with delocalized Se–Se π-bonding.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of […]Shan Li
- High-performance hybrid supercapacitors based on cobalt sulfide and iron sulfide nanoparticles supported by hollow nitrogen–sulfur co-doped carbon spheres September 17, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01452B, Research ArticleXiang Gao, Xiaoyuan Lu, Jiali Zhong, Xiaoqi Fu, Zixin Lin, Xiaoping Shen, Guoxing Zhu, Zhenyuan JiHollow nitrogen–sulfur co-doped carbon spheres decorated with sulfur-vacancy-rich CoS nanocrystals and Fe3S4/FeS2 nanoparticles were constructed. The assembled hybrid supercapacitor delivers a high energy density with long-term cycle life.To cite this article before […]Xiang Gao
- Triply chalcogenophenolato-bridged erbium-cyclooctatetraenyl complexes: syntheses and single-molecule magnetic properties September 16, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01733E, Research ArticleJia-Qi Huang, You-Song Ding, Zhiping ZhengThree dinuclear Er(III) SMMs with different chalcogenophenolato ligands are reported. Magneto-structural studies reveal that as bridging atoms change from O to S to Se, dipolar interactions decrease, while energy barriers increase accordingly.To cite this article before page numbers are assigned, use the […]Jia-Qi Huang
- Rare earth metal-based oxygen electrocatalysts: insights from mechanisms and designs to applications September 16, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01040C, Review ArticleHaiyan Wang, Yifan Xia, Ruiteng Sun, Xiaobin Liu, Jianping Lai, Jingqi Chi, Lei WangThis paper summarizes the research progress of rare earth metal-based oxygen electrocatalysts, and introduces their synthesis strategies, evaluation metrics, design strategies as well as application.To cite this article before page numbers are assigned, use […]Haiyan Wang
- Diversity of supramolecular assemblies based on photoactive Cu(I) trimetallic building blocks and N donor ditopic ligands: from 1D coordination polymers to metallacycles September 16, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01567G, Research ArticleAdrien Schlachter, Jaison Casas, Vincent Dorcet, Guillaume Calvez, Sylvie Ferlay, Christophe LescopCoordination-driven supramolecular assembly of a luminescent trimetallic Cu(I) precursor with various N-donors-based linkers demonstrate how linkers’ backbones can rationally influence structural and photophysical properties.To cite this article before page numbers are assigned, use the DOI form […]Adrien Schlachter
- Crystallographic site engineering of a single Bi3+-doped single-component Ca5Ga6O14:Bi3+ phosphor for full-spectrum white light emission and highly sensitive optical thermometry September 15, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01715G, Research ArticleXiangxiang Jing, Yaxin Xu, Jia Yang, Zien Cheng, Rihong Cong, Tao Yang, Pengfei JiangHigh-quality full-spectrum white emission and highly sensitive ratiometric thermometry are simultaneously achieved in a single Bi3+-doped, single-component phosphor, Ca5Ga6O14:Bi3+, through the implementation of crystallographic site engineering.To cite this article before page numbers are assigned, […]Xiangxiang Jing
- Nested NiPd nanocatalysts fabricated by reactive laser ablation in liquids: a breakthrough in selective nitroarene reduction to anilines September 15, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01093D, Research ArticleOndřej Havelka, Astrid Thomas, Miriam Rodenes, Martin Cvek, Dariusz Łukowiec, Iván Sorribes, Rafael Torres-MendietaThe presence of persistent pollutants in water poses a severe environmental threat, driving an urgent need for efficient and eco-friendly remediation strategies.To cite this article before page numbers are assigned, use the DOI form […]Ondřej Havelka
- Expanding NIR-IIc nanothermometry: architectural control of Tm3+-doped NaGdF4 core/shell nanoparticles September 14, 2025Inorg. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D5QI01571E, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nan Liu, Hana Mirmajidi, Lucas Crozier, Eva HemmerRational architectural design of Tm3+-based core/(multi)shell nanoparticles co-doped with either Er3+ or Ho3+ allows for high-sensitivity temperature sensing in the NIR-IIc spectral region between 1500 […]Nan Liu
- Highly active superoxide dismutase mimic: pyridine-carboxamide based copper(II) complexes September 29, 2025