RSC – Inorg. Chem. Front. latest articles- Unusual solvent-regulated inversion of metal stereocenter in enantiopure Eu2L4 helicate: A new strategy for CPL inversion October 4, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02276A, Research ArticleQing Ma, Sen Yin, Ziye Song, Ting Gao, Pengfei Yan, Yanyan Zhou, Hongfeng LiDeveloping artificial metal helicates with stimuli-responsive helicity inversion is a significant challenge in functional supramolecular chemistry. However, most reported helicity inversions are based on the synchronous transformation of P/M conformation...The content of this RSS […]Qing Ma
- Multicolor Luminescence and Afterglow from Cs2NaScCl6: Sb3+, Mn2+ Crystals October 4, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02019G, Research ArticleXiaojia Wang, Wei Zheng, Xiangzhou Zhang, Xiangxiang Chen, Yuhai ZhangIn contrast to single-band emitting phosphors, dual-band emitting phosphors provided a versatile tool for ratio-metric color tuning, enabling a wide color gamut and ensuing applications in information encryption and anti-counterfeiting...The content of this RSS Feed (c) The Royal […]Xiaojia Wang
- Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening October 4, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02234C, Research Articlechenxu li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie PanAiming to discover short-wavelength ultraviolet (UV) excellent nonlinear optical (NLO) materials, we used the first-principles high-throughput screening pipeline for hydroxyborate NLO materials. We systematically assessed over 222 non-centrosymmetric (NCS) compounds...The content of this RSS Feed (c) […]chenxu li
- Highly defective and conductive Cu-doped 1T/2H-MoS2 nanosheets as high-capacity cathode materials toward enhanced magnesium ion storage October 3, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02064B, Research ArticleAo Xu, Yan Liu, Jiahui Wang, Yijing Wang, Fuyi Jiang, Yanli ZhouLimited by the poor electronic conductivity and strong interaction between Mg2+ and MoS2, the 2H phase of MoS2 as the cathode materials exhibits a low capacity along with poor rate...The content of this RSS Feed (c) […]Ao Xu
- Towards ultra-sensitive multimodal luminescent thermometers enabled by high crystal field strength of Lu2CaMg2Ge3O12:Yb3+,Nd3+,Er3+ phosphors October 3, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01767F, Research ArticleZhijiao Zhao, Mengmeng Dai, Kejie Li, Guiying Liang, Yanling Wei, Zuoling FuAn effective full-spectrum thermometer covering from the visible to NIR-II band was designed based on garnet Lu2CaMg2Ge3O12:Yb3+,Er3+/Nd3+ phosphors; meanwhile, Er3+ (4I13/2) split into four Stark sublevels due to high crystal field strength.To cite this article before […]Zhijiao Zhao
- Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds October 3, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02232G, Review ArticleHangwei Jia, Xueling Hou, Shilie PanThe calculated polarizability anisotropy, hyperpolarizability and HOMO–LUMO gap of optically active groups.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryHangwei Jia
- Long-Range Synergistic Effect between Ptn Cluster and Zn1 Single Atom for Efficient Selective Hydrogenations October 3, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02027H, Research ArticleHaisheng Wei, Jing Li, Xiaorui Yan, Tiantian Liu, Kairui Li, Dan Feng, Yujing RenSupported platinum group metals (PGMs) catalysts are extensively utilized in catalytic hydrogenations. However, the inherent scaling properties of adsorption energies on single PGM surfaces often lead to increased hydrogenation activity...The content of this RSS […]Haisheng Wei
- Photochromism-induced multi-mode optical modulations and fluorescent temperature sensing in Sr/Er-codoped (K0.5Na0.5)NbO3 ceramics October 3, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01804D, Research ArticleFangyuan Yu, Qifa Lin, Xiangfu Zeng, Ping Zhou, Xiao Wu, Cong Lin, Chunlin Zhao, Min Gao, Tengfei Lin, Xingan Jiang, Laihui Luo, Qiwei ZhangHigh-quality (K0.5Na0.5)NbO3 (KNN)-based transparent ceramics are ideal candidates for 3D optical information storage and information anti-counterfeiting encryption. However, conventional single-mode storage and convenient replicability […]Fangyuan Yu
- Governing efficiency and thermoresponsivity of luminescence in dirhenium(V) molecules by a highly tunable emission mechanism October 1, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01943A, Research ArticleMichal Liberka, Mikolaj Zychowicz, Laurine Vasseur, James Hooper, Szymon ChorazyThe search for strategies that can create photoluminescent (PL) materials linking high emission efficiency with sensitivity to external stimuli is important for applications in light-emitting devices and sensors. We report...The content of this RSS Feed (c) The Royal […]Michal Liberka
- Enhancing Blocking Temperatures in {Cr
III
2
Dy
III
2
} Butterfly SMMs: Deciphering the Role of Exchange Interactions and Developing Magneto-Structural Maps October 1, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01484G, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stuart K. Langley, Abinash Swain, Yasmin Whyatt, Daniel Wielechowski, Sophie L Benjamin, Keith S. Murray, Gopalan Rajaraman, Satheeshkumar MuthuA heterometallic butterfly-shaped complex with molecular formula; [CrIII2DyIII2(OMe)2(mdea)2(benz)4(NO3)2] (mdeaH2 = N-methyldiethanolamine, benz = benzoate) […]Stuart K. Langley
- Pyridyl–triazole ligands enable in situ generation of a highly active dihydride iridium(III) complex for formic acid dehydrogenation October 1, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01818D, Research ArticleMiriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra[CpIr(CO)H2] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k2-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF […]Miriam Abán
- A General Strategy to In Situ Construct CoSe2-MSex@GA (M=Zn, Ni, Fe) Heterostructures for Effective Sodium Storage September 30, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01704H, Research ArticleZhengzheng Xu, Yanjiao Li, Shiqi Li, Yingying Chen, Majid Farahmandjou, Guoxiu Wang, Hongxun Yang, Hao TianEffective strategies for constructing micro/nanostructures with fast electrochemical reaction kinetics and superb structural integrity can promote the practical application of metal selenide-based anode materials in sodium ion batteries (SIBs). However,...The content of […]Zhengzheng Xu
- Tuning the phototherapeutic activity of Pt(IV) complexes for bladder cancer via modification of trans N-heterocyclic ligands September 30, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01765J, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Huayun Shi, Guy J. Clarkson, Peter J. SadlerThe photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, […]Huayun Shi
- Mesoscopic Spiral Nanoplates Formed by Porphyrin-Spaced Coordination Frameworks for Enhanced H2O2 Photosynthesis September 30, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01580K, Research ArticleLiang He, Er-Xia Chen, Ju-Qiang Xiang, Yu-Jun Guo, Jian Zhang, Qipu LinDespite extensive efforts to regulate the morphology of metal-organic frameworks (MOFs), achieving chirality at the morphological level in crystals of MOFs continues to be a substantial challenge. This study presents...The content of this RSS Feed (c) […]Liang He
- Equivalent cation-tuning to realize a new Ce(IV) fluoride with excellent comprehensive nonlinear optical performances September 29, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02088J, Research ArticleBei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wen-Long Liu, Ru-Ling Tang, Sheng-Ping GuoExploring nonlinear optical (NLO) halide materials have become a hot research field due to their diverse structures and excellent optical properties. In this paper, a new inorganic tetravalent cerium fluoride...The content of this RSS […]Bei-Bei Zhang
- Ammonia activation using a heteroleptic stannylene and lithium stannylenoid formation facilitated by hemilabile iminophosphorane-based ligands September 29, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI02202E, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Marc Jannik Krengel, Nico Graw, Regine Herbst-Irmer, Dietmar Stalke, Oliver Townrow, Malte FischerHeteroleptic stannylenes, featuring pendant hemilabile iminophosphorane functionalities and kinetically stabilizing terphenyl ligands, were synthesized straightforwardly through formal C–H activation. […]David Marc Jannik Krengel
- Insights into the role of iron coordination in the enhanced photoactivity of MAPbI3/iron oxide heterojunctions September 27, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02039A, Research ArticleWei JianIron oxide-based heterojunctions have garnered widespread interest in the field of photocatalysis due to their outstanding photoelectric properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryWei Jian
- Significant Adsorption Enhancements Driven by Pore Microenvironment Tuning for Efficient C2H2/C2H4 Separation in a Chemically Stable Ni7-Cluster-based framework September 27, 2024Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI01856G, Research ArticleYunli Wang, Rizhao Zhang, Xue Jinpeng, Yuqiao Chai , Bao Li, Jia LiIn the activation process of MOF materials, the formation of open metal sites (OMSs) generally enhances the binding force between the framework and C2H2/C2H4, while it can also lead to...The content of this RSS Feed […]Yunli Wang
- Rationally reconstructing the surface microstructure of a chemical bath deposited electron transport layer for efficient and stable perovskite solar cells September 26, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01808G, Research ArticleXinxuan Yang, Lexin Wang, Meihan Liu, Jiahui Jin, Lili Yang, Lin Fan, Maobin Wei, Huilian Liu, Haoran Chen, Jinghai Yang, Yulei Chang, Fengyou WangA reconstruction strategy is designed to manipulate the surface microstructure of a CBD SnO2 ETL, yielding PSCs with a high PCE >24%.To cite this […]Xinxuan Yang
- A high-entropy FeCoMnCuNi diselenide self-standing electrode with outstanding water-electrolysis performance in alkaline medium September 26, 2024Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01835D, Research ArticleXinxin Guo, Mengmeng Zhou, Ziwu Liu, Shiheng Mu, Kaijia Wang, Huanqiang Shi, Fang Wang, Shijian Lu, Zhonghai Ni, Guiqing LiuA self-standing high-entropy FeCoMnCuNiSe2 electrode exhibited superior HER activity and OWS performance due to high entropy, lattice distortion and tip-enhancement effects.To cite this article before page numbers are […]Xinxin Guo
- Unusual solvent-regulated inversion of metal stereocenter in enantiopure Eu2L4 helicate: A new strategy for CPL inversion October 4, 2024
