RSC – Dalton Trans. latest articles
- MIL-101(Cr)/Aminoclay Nanocomposites for Conversion of CO2 into Cyclic Carbonates Tháng Năm 13, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00849A, Paperjyoti sharma, Sarita Kumari, Samiran Chakraborty, Prakash Kanoo, Vinod Kumar, Anindita ChakrabortyWe present the use of an amine functionalized two-dimensional clay i.e., aminoclay (AC), in the chemistry of a three-dimensional metal-organic framework (MOF) i.e., MIL-101(Cr), to prepare MIL-101(Cr)/AC composites, which are...The content of this RSS Feed (c) The Royal […]jyoti sharma
- Coordinating nature of M6L12 double-stranded macrocycles: co-ligand competition of perchlorate, water, and acetonitrile depending on metal(II) ions Tháng Năm 13, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00902A, PaperSeonghyeon An, Jihun Han, Dongwon Kim, Haeri Lee, Ok-Sang JungSelf-assembly of M(ClO4)2 (M(II) = Mn(II), Co(II), Ni(II), Cu(II), and Zn(II)) with dicyclopentyldi(pyridine-3-yl)silane (L) as a donor in the same mixture of acetonitrile and toluene produces crystals consisting of M6L12...The content of this RSS Feed (c) The Royal Society of […]Seonghyeon An
- Alpha-Metalated N,N-Dimethylbenzylamine Rare-Earth Metal Complexes and Their Catalytic Applications Tháng Năm 13, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00826J, PerspectiveYesmin Akter Rina, Joseph A SchmidtThis perspective summarizes our group’s extensive research in the realm of organometallic lanthanide complexes, while also placing the catalytic reactions supported by these species within the context of known lanthanide...The content of this RSS Feed (c) The Royal Society of ChemistryYesmin Akter Rina
- Coordination of azol(in)ium dithiocarboxylate ligands to Au(III): unexpected formation of a novel family of biscyclometallated Au(III) complexes, DFT calculations and catalytic studies. Tháng Năm 13, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01184H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paula Pérez-Ramos, María A. Mateo, David Elorriaga, Daniel García-Vivó, Raquel G. Soengas, Humberto Rodríguez-SollaA series of cyclometallated gold(III) complexes 21-27 of general formula [Au(dppta)(azdtc)Cl] (dppta = N,N-diisopropyl-P,P-diphenylphosphinothioic amide-2C,S; azdtc = azol(in)ium-2-dithiocarboxylate-1S) were prepared and […]Paula Pérez-Ramos
- Vitamin B1-based thiazol-2-ylidene–Ru(II) complexes: recyclable transfer hydrogenation catalysts in water Tháng Năm 13, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00445K, PaperRafet Kılınçarslan, Hayriye Tuncer, Namık Özdemir, Bekir ÇetinkayaIn order to develop recyclable catalyst in water, vitamin B1 based Ru(II)-NHC complexes (2–4) were synthesized and evaluated for transfer hydrogenation of ketones and aldehydes with an azeotropic mixture of HCOOH/Et3N in water. The complex,4 exhibited excellent catalytic activity and recyclability.To cite […]Rafet Kılınçarslan
- Promotional effects of In(PO3)3 on the high catalytic activity of CuOIn(PO3)3/C for CO2 reduction reaction Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00645C, PaperChengtao Ruan, Zhihui Zhao, Hui Wu, Jiaqian Liu, Yuande Shi, Lingxing Zeng, Zhongshui LiThe construction of Cu-In bi-component catalysts is an effective strategy to enhance the electrocatalytic properties towards CO2 reduction reaction (CO2RR). However, realizing the co-promotion of In and heteroatom P on...The content of this RSS Feed (c) […]Chengtao Ruan
- A Triazolium-Based Fluorophore Intercalated in Layered Double Hydroxides: from Simple Syntheses to Bright Solid-State Luminescence Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00573B, PaperGuillaume ZERBIB, Amélie Roux, Laurène Salat, Federico Cisnetti, Damien Boyer, Genevieve Chadeyron, Fabrice LerouxThis study presents the intercalation into Layered Double Hydroxides (LDHs) of two sulfonated organic molecules featuring the mesoionic triazolium scaffold. These sulfonated fluorophores exhibited excellent solubility in aqueous basic solutions,...The content of this RSS Feed (c) […]Guillaume ZERBIB
- Self-assembly of Ni(II) with a chiral ligand pair vs. mixture of the chiral ligand pair: structural features and recognition ability of Ni2L4 cages Tháng Năm 12, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00762J, PaperJihun Han, Hyo Jeong Back, Mohammad M. Hossain, Ok-Sang Jung, Young-A. LeeDiscrete chiral cages with two encapsulated chloride anions were useful for the recognition of chiral molecules. An achiral cage consisting of L-and D-chiral ligands was constructed and two chloride anions and two H2O molecules were encapsulated.To cite this […]Jihun Han
- Enhanced selectivity towards melanoma cells with zinc(II)-Schiff bases containing imidazole derivatives Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00733F, PaperIsabel Correia, Leonor Côrte-Real, Baris Sergi, Busra Yildirim, Raquel Colucas, Radosław Starosta, Xavier Fontrodona, Isabel Romero, Vania Andre, Ceyda AcilanZinc(II)-complexes with the general formula [Zn(L)2] containing 8-hydroxyquinoline Schiff bases functionalized with 1-(3-aminopropyl)imidazole or 1-(3-aminopropyl)-2- methyl-1H-imidazole on 2-position and their respective ligands (HL1 or HL2) were synthesized and characterized by...The […]Isabel Correia
- An Elastic Single Crystal Composed of One-dimensional Chiral Coordination Polymers Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01050G, CommunicationYan Zhang, Yu-Xia Li, Kaige Gao, Jia-Hui Zhang, Jie-Sheng Hu, Jun Tao, Zi-Shuo YaoA single crystal composed of one-dimensional coordinated polymers, [CdCl2(1-Methyl-2-pyridone)]n, has been synthesized and characterized. This compound exhibits outstanding elastic bending due to the molecular spring nature of the CdCl2 coordination...The content of this RSS Feed (c) […]Yan Zhang
- Step-Wise Changes in the Excited State Lifetime of [Eu(D2O)9]3+ and [Eu(DOTA)(D2O)]- as a Function of the Number of Inner-Sphere O-H Oscillators Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00744A, PaperNicolaj Kofod, Thomas Just SørensenLanthanide luminescence is dominated by quenching from high-energy oscillators in the chemical environment. The rate of non-radiative energy transfer to a single H2O molecule coordinated to a Eu3+ ion exceeds...The content of this RSS Feed (c) The Royal Society of ChemistryNicolaj Kofod
- 1,2,3-triazol-5-ylidene- vs 1,2,3-triazole-based tricarbonylrhenium(I) complexes: Influence of a mesoionic carbene ligand on the electronic and biological properties Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00922C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Corinne Vanucci-Bacqué, Mariusz Wolff, Beatrice Delavaux-Nicot, abanoub Mosaad Abdallah, Sonia Mallet-Ladeira, Charles-Louis Serpentini, Florence Bedos-Belval, Kar Wai Fong, Xiao Ying Ng, May Lee Low, Eric Benoist, Suzanne Fery-ForguesThe tricarbonylrhenium complexes that incorporate a mesoionic […]Corinne Vanucci-Bacqué
- Triptycene as a Scaffold in Metallocene Catalyzed Olefin Polymerization Tháng Năm 12, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01170H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pavel Sergeevich Kulyabin, Mikhail Sharikov, Dmitry Kononovich , Georgy Goryunov, Nikita V. Alexeev , Dmitry Uborsky, Antonio Vittoria, Giuseppe Antinucci, Christian Ehm, Petrus Henricus Maria Budzelaar, Roberta Cipullo, Vincenzo Busico, Alexander VoskoboynikovA set of […]Pavel Sergeevich Kulyabin
- Theoretical investigations of 2-vinylpyridine stereoselective polymerization catalyzed by cationic yttrium complexes with different ancillary ligands Tháng Năm 10, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00838C, PaperXin Wen, Zhenli Zhang, Kaipai Ren, Wenzhen Zhang, Guangli Zhou, Yi LuoThe polymerization mechanism of 2-vinylpyridine catalyzed by cationic yttrium complexes with diverse ancillary ligands, specifically Y-1, Y-2, and Y-3, was studied using density functional theory (DFT) calculations.To cite this article before page numbers are assigned, use the DOI […]Xin Wen
- Unravelling co-catalyst integration methods in Ti-based metal-organic gels for photocatalytic H2 production Tháng Năm 10, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00880D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maite Perfecto-Irigaray, Garikoitz Beobide, Oscar Castillo, Michael G. Allan, Moritz F Kühnel, Antonio Luque , Harishchandra Singh, Ashok Kumar Yadav, Sonia Pérez-YáñezThe synthesis, characterization and photocatalytic hydrogen evolution reaction (HER) performance of a series […]Maite Perfecto-Irigaray
- In-depth characterization of phosphate intercalated Mg Al Layered double hydroxides and study of the PO4 release properties Tháng Năm 9, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00601A, PaperAlexandra Jourdain, Christine Taviot-Gueho, Ulla Gro Nielsen, Vanessa Prévot, Claude ForanoSlow-release fertilizers (SRFs) form the core of innovative strategies in sustainable agriculture. Layered Double Hydroxides (LDH), known for their high capacity to sequester plant nutrients, especially phosphate, are emerging as...The content of this RSS Feed (c) The Royal Society […]Alexandra Jourdain
- Synthesis and characterization of a novel copper carboxylate complex and a copper complex-coated polyether sulfone membrane for the efficient degradation of methylene blue dye under UV irradiation: Single crystal X-ray structure of copper carboxylate complex Tháng Năm 9, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00871E, Paperrupy dhir, Bulle Shah, Narinder SinghSynthesis of a novel binuclear Cu (II) carboxylate complex under ambient laboratory conditions is presented. The complex possesses a paddle wheel structure in which the axial positions are occupied by...The content of this RSS Feed (c) The Royal Society of Chemistryrupy dhir
- Exploring the interaction between a fluorescent Ag(I)-biscarbene complex and non-canonical DNA structures: a multi-technique investigation Tháng Năm 9, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00851K, PaperFrancesca Binacchi, Ester Giorgi, Giacomo Salvadori, Damiano Cirri, Mariassunta Stifano, Aurora Donati, Linda Garzella, Natalia Busto, Begona Garcia, Alessandro Pratesi, Tarita BiverSilver compounds are studied mainly as antimicrobial but have anticancer properties, the latter being, in some cases, better than their gold counterparts. In this paper, we analyse the […]Francesca Binacchi
- A Ratiometric Substrate for Rapid Evaluation of Transfer Hydrogenation Efficiency in Solution Tháng Năm 9, 2024Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT00891J, CommunicationYen-An Young, Huong T. H. Nguyen, Hieu Dang Nguyen, Tuhin Ganguly, Yennie Nguyen, Loi H. DoA cyclometalated iridium(III) complex bearing a self-immolative quinolinium moiety was developed as a ratiometric substrate for transfer hydrogenation studies. This photoluminescent probe allowed the rapid screening of a variety of...The content of this RSS […]Yen-An Young
- Crystal-to-crystal polymerisation of monosubstituted [PW11O39Cu(H2O)]5− Keggin-type anions Tháng Năm 9, 2024Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT00690A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Estibaliz Ruiz-Bilbao, Aroa Pache, Unai Barrenechea, Santiago Reinoso, Leire San Felices, Maria dM. Vivanco, Luis Lezama, Beñat Artetxe, Juan M. Gutiérrez-ZorrillaCompound [C(NH2)3]10[{PW11O39Cu(H2O)}2{Cu(pic)2}]·10H2O (1, pic = picolinate) undergoes a thermally-triggered single-crystal-to-single-crystal transformation that involves an […]Estibaliz Ruiz-Bilbao
- MIL-101(Cr)/Aminoclay Nanocomposites for Conversion of CO2 into Cyclic Carbonates Tháng Năm 13, 2024