RSC – Chem. Sci. latest articles- 3-Component Reactions for Accessing Heterocycle-rich Topologies: Trapping of Pyrrole-stabilized Carbenes via Net Bimolecular C–H or N–H Insertion Tháng 10 14, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05345E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander L Guzman, Katharine B Toll, Thomas R HoyeThe intermolecular trapping of free carbenes derived from diazo precursors is well documented in the literature. We have recently reported on the generation of free […]Alexander L Guzman
- Heterologous expression of an in planta-upregulated gene cluster in the wheat pathogen Parastagonospora nodorum establishes the biosynthesis of methylene-bridged depsides Tháng 10 14, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05442G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hera Thao Nguyen, Nicolau Sbaraini, Joe Bracegirdle, Luke Smithers, Stephen A. Moggach, Daniel Vuong, Ernest Lacey, Peter S. Solomon, Joel Haywood, Andrew M Piggott, Yit-Heng ChooiDepsides are polyphenolic natural products commonly found in […]Hera Thao Nguyen
- Cation Gating-Breathing Synergetic Mechanism in K-MER Zeolite Enables Unprecedented Selective CO₂ Separation from Hydrocarbon Gas Streams Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03281D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Renhao Li, Chenxu Liu, Wenli Bao, Lin Li, Jingfeng Han, Xiaoxin Zou, Xiaowei Song, Donghai Mei, Zhiqiang LiangThe ubiquitous presence of CO2 impurity in industrial hydrocarbon streams underscores the critical need for developing […]Renhao Li
- The Optical Response of Aromatic Cyclocarbons Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05519A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simone Grillo, Olivia Pulci, Tommaso GiovanniniCyclo[n]carbons are a recently synthesized class of carbon allotropes that offer a unique platform to probe electron delocalization, quantum confinement, and strong correlation effects. Their peculiar electronic properties […]Simone Grillo
- Enhanced MOF performance in chromium (VI) removal from water using tailored MOF-polymer composites Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05812K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Timo Felder, Wei Shi, Daniel T Sun, Till Schertenleib, Emad Oveisi, Jordi Espín, Wendy Lee QueenFunctionalizing the internal and external surface of MOFs with polymers allows for tailor-made improvements in their performance for […]Timo Felder
- Room Temperature Dinitrogen Cleavage and Hydrogenation with Organometallic Complexes of Uranium Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07194A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Angus C Shephard, Lucie Pedussaut, Linda De Marchi, Luca Demonti, Thayalan Rajeshkumar, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Thomas Simler, Grégory NoctonThe conversion of dinitrogen into ammonia plays an important role in sustaining […]Angus C Shephard
- Brønsted acid-promoted ethylene dimerization to 1-butene over Ni-containing zeolite catalysts Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05078B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Landong Li, Yuchao Chai, Li Wang, Yuwen Ni, Jingyao Yang, Guangjun WuEthylene dimerization is a critical industrial process traditionally catalyzed by homogeneous systems employing cocatalysts or solvents. Although heterogeneous catalysts show potential to […]Landong Li
- Large-area thin-film synthesis of photoactive Cu3PS4 thiophosphate semiconductor with 0-14 pH stability range Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05882A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lena Angelika Mittmann, Javier Sanz Rodrigo, Eugène Bertin, Giulia Dalmonte, Jean Claude Grivel, Ivano E. Castelli, Andrea CrovettoThe vast and versatile group of phosphorus- and sulfur-based inorganic materials, phosphosulfides, has sparked growing interest […]Lena Angelika Mittmann
- Integrating a hydrogen-bonded complex as a secondary building unit to construct a multivariate framework for programmable drug delivery Tháng 10 13, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC04021C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xujiao Ma, Zhong Zhang, Xianghui Ruan, Jiarui Cao, Ye Yuan, Yajie Yang, Nan Gao, Guangshan ZhuPorous organic frameworks (POFs) consisting of organic building blocks through covalent bonds are novel functional solids.To cite this […]Xujiao Ma
- Solvent-Induced Oriented FAPbI3 Single Crystals towards Highly Efficient Self-Powered X-ray Detectors Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04089B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fang Liu, Yu Zou, Pengxiang Wang, Hu Wang, Jiahao Guo, Yugang Liang, Haifei Wang, Wenji Zhan, Zhengzheng Dang, Jixin Wu, Yanming Wang, Bowei Li, Yanfeng Miao, Yuetian Chen, Yao Wang, Yixin ZhaoPerovskites are […]Fang Liu
- Air-Water Interfacial Nitrogen Cycle Produces Irrigatable-Level Ammonium Nitrate Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05754J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaowei Song, Basheer Chanbasha, Jinheng Xu, Richard N. ZareWe report a sustainable, air-based strategy for synthesizing ammonium nitrate (NH4NO3) by harnessing the redox-active properties of microscale air–water interfaces. The process proceeds through two […]Xiaowei Song
- Trapping Carbon Suboxide with a Carbene and Isolation of the Carbene-stabilized Carbon Suboxide Dimer Tháng 10 13, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06444A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tanner George, Erin R. Johnson, Jason Douglas MasudaCarbon suboxide (C 3 O 2 ), the heavier cousin of carbon carbon monoxide, CO, and carbon dioxide, CO 2 , is an unstable gas at […]Tanner George
- Near-Unity and Narrow Green Emission from a Manganese(II) Bromide for Efficient WLEDs and 3D X-ray Imaging Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04721H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mengzhu Wang, Xiaolong Li, Siwen Zou, Haixia Cui, Yongjing Deng, Jiangang Li, Yi Jiang, Longlu Wang, Shu-Juan Liu, Qiang Zhao, Yun MaDeveloping efficient, narrow-band, and environmentally friendly emitters is crucial for advanced optoelectronics. […]Mengzhu Wang
- Leveraging an intelligent slug flow platform for self-optimization of reaction systems with categorical variables Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04715C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Florian Wagner, Gernot Neun, Thomas Tampone, Zhen Lei, Frederic Buono, Christopher A. Hone, C. Oliver KappeIn this work we describe the development of a chemistry-based encoding approach utilizing nucleophilicity to perform Bayesian optimization […]Florian Wagner
- Chromophore charge-state switching through copper-dependent homodimerisation of an engineered green fluorescent protein Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06589E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rochelle Ahmed, Danoo Vitsupakorn, Kieran D Hartwell, Karma Albalawi, Pierre Rizkallah, Peter Watson, D. Dafydd JonesHere, we have linked one of the most common protein-protein interaction events, homodimerisation, to an essential trace metal, […]Rochelle Ahmed
- Single atom-bridged Au nanozymes boost glucose oxidase-like activity in acidic media Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05430C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Luo, Feilong Tan, Zhenglong Mao, Yan Zhang, Yinjun Tang, Cang-Long Wang, Wenling Gu, Cao Li, Juewen Liu, Chengzhou ZhuAu nanozymes hold great promise as glucose oxidase (GOx) mimics; however, their catalytic activity […]Xin Luo
- Conjugated Microporous Polymer Electrodes for Supercapacitors: Recent Progress, Key Challenges, and Future Directions Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05384F, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mohammed G. Kotp, Mohamed Gamal Mohamed, Shiao-Wei KuoConjugated Microporous Polymers (CMPs) have shown great potential class of materials for supercapacitor electrodes, offering a distinctive blend of extensive surface area, tunable porosity, redox activity, […]Mohammed G. Kotp
- Design Principles of Spacer Cations for Suppressing Phase Segregation in 2D Halide Perovskites Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06511A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Junsang Cho, Seonhong Min, Manish Mukherjee, Gabor Gabor Szabo, Prashant V KamatSuppression of photoinduced halide segregation in mixed halide perovskites remains a significant challenge for their application as wide bandgap semiconductors in solar […]Junsang Cho
- A Diverse and Chemically Relevant Solvation Model Benchmark Set with Flexible Molecules and Conformer Ensembles Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06406F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lukas Wittmann, Christian Erik Selzer, Stefan GrimmeWe introduce FlexiSol - a flexible solvation benchmark set with molecule ensembles. FlexiSol is the first of its kind to combine structurally and functionally complex, highly flexible […]Lukas Wittmann
- Carboxylate Positional Isomerism in Metallacycles Governs Hierarchical Assembly Pathways Tháng 10 12, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05591A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.lingran Liu, Meilin Yu, Wei Tuo, Yue Zhao, Fengmin Zhang, Yan SunPositional isomerism plays a pivotal role in governing the assembly pathways of hierarchical architectures by modulating both the thermodynamic landscape and kinetic […]lingran Liu
- 3-Component Reactions for Accessing Heterocycle-rich Topologies: Trapping of Pyrrole-stabilized Carbenes via Net Bimolecular C–H or N–H Insertion Tháng 10 14, 2025
