RSC – Chem. Sci. latest articles- Hosting of [Cs(Crown ether)2]+ type Host-Guest Complexes by a Nano-Sized Molecular Cuboid Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03202D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Manaswini Ray, Shobhana Krishnaswamy, Dillip Kumar ChandEncapsulation of a guest by a host forming (G-in-H) type host-guest complexes is the central theme of supramolecular chemistry. Binding of typical hosts (Hin) in the cavity […]Manaswini Ray
- Interfacial Chemistry Regulation by Orbital Hybridization for Superior Kinetics of Hard Carbon in Ester-Based Electrolyte Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04111B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lu Liu, Jianhua Zhu, Guohui Chen, Zhuosen Wang, Liu Wang, Chengkun Guo, Yunfeng Chao, Xinwei Cui, Caiyun WangHard carbon is the most commercially viable anode materials for sodium-ion batteries (SIBs), yet its application […]Lu Liu
- Spin-coupling-dependent oxygen reduction mechanism in dual-atom-catalysts Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04842G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mingyuan Yu, Erjun Kan, Cheng ZhanThe role of electronic spin in electrocatalysis has led to the emerging field of "spin-dependent electrocatalysis." While spin effects in individual active sites have been well understood, spin […]Mingyuan Yu
- Maleic anhydride derived diphosphines: adaptable chelators for receptor-targeted 99mTc, 64Cu and 188Re radiotracers Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02110C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rachel E Nuttall, Ingebjorg Hungnes, Truc Pham, Oliver Carter, Alex Rigby, Natasha Patel, Zilin Yu, Julie Cleaver, Jennifer Denise Young, Gary Cook, Lefteris Livieratos, Jane K Sosabowski, Hong Hoi Ting, Nicholas Vetter, Paul […]Rachel E Nuttall
- Bidirectional interfacial engineering strategy for highly stable sodium metal batteries Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04722F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaomin Yang, Long Wang, Minghui Zhao, Lingxiao Peng, Yun Wu, Baohua Zhu, Le Chen, Jinliang LiSodium (Na) metal batteries (SMBs) are regarded as one of the most promising next-generation energy storage systems due […]Xiaomin Yang
- The Dichotomous Behavior of Allylsilanes in the Additions to Platinum α,β-Unsaturated Carbenes Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03784K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jeff P. Costello, Jacob P. Garber, Khoi Q. Huynh, Eric Matthew FerreiraThe observation of allylsilane dual reactivity with α,β-unsaturated platinum carbenes is described. The reaction pathways are controlled by the nature of the […]Jeff P. Costello
- Copper-Catalyzed Oxy-Alkylation of Styrenes Enabled by Halogen-Atom Transfer Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03774C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiujian Tan, Xiang Lyu, Yu Zhao, Huaquan Fang, Xianxiu Xu, Zhongyan HuHerein, we present a mechanistically distinct approach to the multicomponent difunctionalization of styrenes with alkyl halides and oxygen by integrating α-aminoalkyl radical-mediated […]Qiujian Tan
- Targeting the selectivity filter to drastically alter the activity and substrate spectrum of a promiscuous metal transporter Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03700J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuhan Jiang, Michael Nikolovski, Tianqi Wang, Keith MacRenaris, Thomas O'Halloran, Jian Hud-Block metal transporters are attractive engineering targets for selectively enriching or excluding metals in living organisms. However, systematic efforts to engineer these […]Yuhan Jiang
- Rigid Cationic Ligands Enable High-Efficiency NIR-II Photoluminescence in Copper(I) Iodide Hybrid Semiconductors Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04588F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jingwen Chen, Xueqian Wu, Minghui Zhang, Simon Teat, Guozhong Xu, Jingbai Li, Xiuze Hei, Jing LiNear-infrared (NIR) luminescent materials are pivotal for advanced optoelectronic and biomedical applications, yet attaining efficient emission in the […]Jingwen Chen
- Geminal Hyperconjugation as a Driving Force for C–C Bond Shortening in Heavy-Atom Tunneling Tháng 8 25, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02914G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Croix J. Laconsay, Ishika Jain, Tim Schleif, William Karney, Judy WuGeminal hyperconjugation can play an important role in heavy-atom tunnelling reactions that involve three-membered rings. We demonstrate this relationship in a case study […]Croix J. Laconsay
- Chemoenzymatic total synthesis of the antibiotic (−)-13-deoxytetrodecamycin using the Diels–Alderase TedJ Tháng 8 25, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC05480J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.S. Joe Russell, Catherine R. Back, Christopher Perry, Kaiman A. Cheung, Laurence Maschio, Sacha N. Charlton, Nicholas R. Lees, Monserrat Manzo-Ruiz, Martin A. Hayes, Marc W. van der Kamp, Paul R. Race, Christine […]S. Joe Russell
- A natural ultrasound-triggered nitric oxide booster for endothelial dysfunction therapy Tháng 8 25, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC04788A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuqiong Wang, Dong Meng, Yu Dong, Xiaoqing Huang, Liping Wang, Wen Gao, Bo TangThe ultrasound-responsive NO booster developed in this study synergistically addresses endothelial dysfunction through on-demand NO release, along with its anti-inflammatory […]Yuqiong Wang
- Photomediated C‒H Trifluoromethoxylations Enabled by Bis(trifluoromethyl)peroxide Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04945H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kamar Shakeri, Merlin Kleoff, Paul Golz, Thomas Drews, Manuela Weber, Sebastian Riedel, Mathias ChristmannWe describe a photomediated protocol for the trifluoromethoxylation of benzylic, aldehydic, and non-activated C‒H bonds, using bis(trifluoromethyl)peroxide (BTMP, (F3CO)2) as […]Kamar Shakeri
- Cyclization-Enhanced Photoactivatable Reversible Room-Temperature Phosphorescence for Efficient Real-Time Light Printing Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05008A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yonghui Sun, Yuqing Shu, Li Zheng, Yufei Song, Baotong Huang, Xiufang Xu, Haohua Chen, Junbiao Chang, Pengyang XinThe construction of polymer-based photoactivated room-temperature phosphorescence systems remains a prominent research focus, yet the development […]Yonghui Sun
- Regioselective Construction of Two Isomeric BN-Fused Aromatics Frameworks Enabling Ultralong Room-Temperature Phosphorescence Materials Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05061H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qiang Feng, Junxiong Yao, Qianxin Wu, Yang Qiu, Zicheng Wan , Xia Wang, Weilin Chen, Sibo Tong, Xiaohua Cao, Jianqi Sun, Qianqian Ye, Jianhua Liu, Dian Yuan Wang, Jianguo Wang, Huanan HuangBN-fused aromatic […]Qiang Feng
- Enantioselective Lactonization Catalyzed by Chiral N-Heterocyclic Carbenes Enables Access to Inherently Chiral Eight-Membered Lactones Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05037E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vojtěch Dočekal, Adam Kurčina, Ivana Císařová, Jan VeselyChiral saddle-shaped molecules are an emerging class of compounds with significant potential in both material science and medicinal chemistry. However, their broader application has been hindered […]Vojtěch Dočekal
- Molecular Functionalization of Ni(OH)2 Promotes Electrosynthesis of Adipic Acid Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05036G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rui Yang, Yuanhao Li, Haonan Xu, Qicheng Zhang, Shu-Fan He, Tao Shen, Xiaobin Fan, Tao Wu, Yifan SunAdipic acid is an essential platform molecule for polymer production, and is industrially manufactured by thermochemical […]Rui Yang
- Effect of Halogen/Chalcogen Substitution on the Dielectric Constant of Asymmetric Acceptor Alloys to Improve the Efficiency and Stability of Inverted Organic Photovoltaics Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04976H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yan-Bo Wang, Yung-Jing Xue, Chieh-Ming Hung, Kuo-Hsiu Huang, Bing-Huang Jiang, Chia-Lin Tsai, Yu-Chi Huang, Hong-Yi Chen, Shang-Da Yang, Su-Ying Chien, Chih-Ping Chen, Pi-Tai Chou, Yen-Ju ChengThe dielectric constant (εᵣ) of non-fullerene acceptors is […]Yan-Bo Wang
- Ultrastrong Circularly Polarized Electroluminescence Achieved by Chiral Co-Assembly of Liquid Crystal-Functionalized Carbazole Derivative Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05196G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hang Li, Dong Li, Zhenhao Jiang, Yuxiang Wang, Yixiang ChengCircularly polarized organic light-emitting diodes (CP-OLEDs) exhibiting circularly polarized electroluminescence (CP-EL) properties hold significant promise for future display technologies. However, enhancing the electroluminescence dissymmetry […]Hang Li
- Expanding the Fluorescent Toolkit: Molecular Design, Synthesis and Biological Application of Unnatural Amino Acids Tháng 8 24, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05745K, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Olivia Marshall, Andrew SutherlandFluorescent imaging has become an indispensable tool in modern biology, enabling the visualisation of dynamic molecular processes with spatial and temporal precision. Traditional strategies rely heavily on the conjugation of...The content […]Olivia Marshall
- Hosting of [Cs(Crown ether)2]+ type Host-Guest Complexes by a Nano-Sized Molecular Cuboid Tháng 8 25, 2025
