Chemical Science

RSC – Chem. Sci. latest articles

• Effect of size, charge, and spin state on Hückel and Baird aromaticity in [N]annulenes Tháng Hai 21, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08225G, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Louis Van Nyvel, Mercedes Alonso, Miquel SolàThe Hückel and Baird rules provide a framework to understand the aromaticity of monocyclic π-conjugated molecules in their singlet ground state and lowest-lying triplet state, respectively, particularly […]
  Louis Van Nyvel
• Facile Synthesis of Recyclable Polythioimidocarbonates via Aromatization-driven Alternating Copolymerization of para-Quinone Methide and Isothiocyanates Tháng Hai 21, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00050E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wen-Dao Chu, Si-Yu Dan, Jie Zhan, Bo Chen, Ji Xian, Chun-Mei Wang, Quanzhong Liu, Jincai Wu, Chun-An FanThe efficient and controllable alternating copolymerization of para-Quinone Methide (p-QM) is rare and challenging. The aromatization-driven […]
  Wen-Dao Chu
• Valence Activity of SO-Coupled Atomic Core Shells in Solid Compounds of Heavy Elements Tháng Hai 21, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08151J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shiru-ru Wei, Han-Shi Hu, W. H. Eugen Schwarz, Jun LiAn alert look reveals chemically relevant changes from light to heavy elements of the atomic orbital-energy patterns, relevant for both chemical theory and material […]
  Shiru-ru Wei
• Access to arynes from arenes via net dehydrogenation: scope, synthetic applications and mechanistic analysis Tháng Hai 20, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00054H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Riley A Roberts, Bryan Metze, Nicole Javali, Theresa M. McCormick, David Ross StuartArynes undergo a wide range of chemical transformations making them versatile reactive intermediates for organic synthesis. Access to arynes has long […]
  Riley A Roberts
• Modulating the spin–flip rates and emission energies through ligand design in chromium(III) molecular rubies Tháng Hai 20, 2025
  Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08021A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yating Ye, Maxime Poncet, Polina Yaltseva, Pablo Salcedo-Abraira, Antonio Rodríguez-Diéguez, Javier Heredia Martín, Laura Cuevas-Contreras, Carlos M. Cruz, Benjamin Doistau, Claude Piguet, Oliver S. Wenger, Juan Manuel Herrera, Juan-Ramón JiménezThree homoleptic spin–flip (SF) […]
  Yating Ye
• Multimeric, Multivalent Fusion Carrier Proteins for Site-Selective Glycoconjugate Vaccines Simultaneously Targeting Staphylococcus aureus and Pseudomonas aeruginosa Tháng Hai 20, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08622H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Charlotte Sorieul, Bartal Mikladal, Dung-Yeh Wu, Cinzia Giovani, Giusy Adamo, Giacomo Romagnoli, Filippo Carboni, Roberto Adamo, Barbara Brogioni, Immaculada Margarit, Jeroen D Codee, Maria Rosaria RomanoStaphylococcus aureus and Pseudomonas aeruginosa are major antimicrobial-resistant […]
  Charlotte Sorieul
• Reversible Redox 19F Magnetic Resonance Imaging Nanoprobes for Monitoring Redox State in Vivo Tháng Hai 20, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08297D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaoyao Xiong, Sijia Li, Yumin Li, Suying Xu, Chang Guo, Leyu WangRedox processes are indispensable for physiology, and dysregulated redox balance is critical in various metabolic diseases. The development of imaging diagnosis tools […]
  Xiaoyao Xiong
• Machine Learning-Driven Discovery of Highly Selective Antifungal Peptides Containing Non-Canonical β-Amino Acids Tháng Hai 20, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC06689H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Douglas H. Chang, Joshua D Richardson, Myung-Ryul Lee, David M. Lynn, Sean P. Palecek, Reid C Van LehnAntimicrobial peptides (AMPs) are promising compounds for the treatment and prevention of multidrug-resistant infections because of […]
  Douglas H. Chang
• An argument for abandoning the “allowed” and “forbidden” classification of electrocyclic reactions Tháng Hai 19, 2025
  Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08748H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Barry K. CarpenterThe energy gaps between “forbidden” and “allowed” mechanisms of routine electrocyclic reactions can be negligibly small.To cite this article before page numbers are assigned, use the DOI form of citation above.The […]
  Barry K. Carpenter
• A Photo- and Cobalt-Catalyzed Highly Selective and Divergent Hydrofunctionalization of 1,3-Dienes with Phenols Tháng Hai 19, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00438A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yue Wang, Junhao Miao, Honglin Dong, Dongliang Zhang, Bei Chen, Meihui Guan, Ge Zhang, Qian ZhangAn applicable cobalt-hydride mediated selective, divergent hydroetherification and sequential hydroetherification/hydroarylation of dienes with simple phenol feedstocks under photoredox […]
  Yue Wang
• Electrically conductive charge-segregated pseudo-polymorphs comprising highly planar expanded π-electronic cation Tháng Hai 19, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07576E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Haketa, Ryoya Nakajima, Yuto Maruyama, Hiroki Tanaka, Wookjin Choi, Shu Seki, Shunsuke Sato, Hitomi Baba, Yoshiki Ishii, Go Watanabe, Kirill Bulgarevich, Kazuo Takimiya, Kenzo Deguchi, Shinobu Ohki, Kenjiro Hashi, Takashi Nakanishi, Yukihide […]
  Yohei Haketa
• Adaptive Representation of Molecules and Materials in Bayesian Optimization Tháng Hai 19, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00200A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mahyar Rajabi Kochi, Negareh Mahboubi, Aseem Partap Singh Gill, Seyed Mohamad MoosaviBayesian optimization (BO) is increasingly used in molecular optimization and in guiding self-driving laboratories for automated materials discovery. A crucial aspect of […]
  Mahyar Rajabi Kochi
• Photocatalytic 1,3-Difluoroalkylcarboxylation of Alkenes by Triple Kinetic-Controlled Radical Self-Ordering Tháng Hai 19, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08607D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hong Fu, Zuo-Shuai Wang, Si-Jia Li, Lin-Yuan Zhu, Xiao-Jian Wang, Hong-Chen Wang, Bing HanA transition metal-free protocol for the unsymmetrical radical 1,3-difunctionalization of alkenes has been established for the first time in the […]
  Hong Fu
• Logic-gated approach for targeted delivery and site-selective activation of photothermal agents in precision cancer treatment Tháng Hai 19, 2025
  Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08228A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chang Jiang, Zhengxiang Zhao, Amanda K. East, Suritra Bandyopadhyay, Ziyi Jiang, Jefferson ChanLogic-gated strategies represent a promising approach to achieving highly selective cancer therapies.To cite this article before page numbers are assigned, use […]
  Chang Jiang
• A Switch-On Luminescent Europium(III) Probe for Selective and Time-Resolved Detection of Adenosine Diphosphate (ADP) Tháng Hai 19, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07188C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Samantha E Bodman, Patrycja Stachelek, Umatur Rehman, Felix Plasser, Robert Pal, Stephen Jonathan ButlerAdenosine diphosphate (ADP) is a key product of two essential classes of biological reactions, catalysed by ATPases and kinases. This […]
  Samantha E Bodman
• Unusually air-stable copper(I) complexes showing high selectivity for carbon monoxide Tháng Hai 19, 2025
  Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC00237K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Borna Saeednia, Aria M. Sragow, Yannan Lin, Colton J. Sheehan, Amy S. Metlay, Michael R. Gau, Samantha A. Dye, Sarah P. O'Konski, Thomas E. Mallouk, Ivan J. DmochowskiWe report two Cu(I)-tren host molecules […]
  Borna Saeednia
• Formation of polysulfides as a smart strategy to selectively detect H2S in a Bi(III)-based MOF material Tháng Hai 19, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07144A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Valeria B. López-Cervantes, Juan L. Obeso, J. Gabriel Flores, Aida Gutierrez-Alejandre, Raul A. Marquez, J. de los Reyes, Catalina V. Flores, N. S. Portillo-Vélez, Pablo Marín-Rosas, Christian A. Celaya, Eduardo González-Zamora, Diego Solis-Ibarra, […]
  Valeria B. López-Cervantes
• Operando evidence on the chirality-enhanced oxygen evolution reaction in intrinsically chiral electrocatalysts† Tháng Hai 18, 2025
  Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07927B, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Felipe Garcés-Pineda, Jiahao Yu, Camilo A. Mesa, Sergi Plana-Ruiz, Daniel Ruano, Yunchang Liang, Magalí Lingenfelder, Sixto Giménez Juliá, Jose Galan-MascarosElectrolytic hydrogen is identified as a crucial component in the desired decarbonisation of the […]
  Felipe Garcés-Pineda
• Polarizable potential window at soft molecular interfaces as a quantitative descriptor for the water content in organic solvents Tháng Hai 18, 2025
  Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC00527B, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Siqi Jin, Lifang Yang, Sijia He, Taoxiong Fang, Xiaohang Sun, Dandan Cai, Qiong Hu, Xinjian Huang, Haiqiang DengPPW width is dictated by different probabilities of ion-water finger complex encountering with water molecules in […]
  Siqi Jin
• Stereochemical expression of Bi 6s2 lone pairs mediates fluoride-ion (De)insertion in tunnel-structured Bi2PdO4 and Bi1.6Pb0.4PtO4 Tháng Hai 18, 2025
  Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08111K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.George Agbeworvi, Anindya Pakhira, Shruti Hariyani, Wasif Zaheer, Alice Giem, Jaime R. Ayala, John D. Ponis, Saul Perez-Beltran, Cherno Jaye, Conan Weiland, Daniel A. Fischer, Hassan S. Bazzi, Mohammed Al-Hashimi, Sarbajit BanerjeeAn energy […]
  George Agbeworvi