RSC – Chem. Sci. latest articles- Ionomers modulate the microenvironment in electrocatalytic CO2 reduction Tháng mười một 22, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07515G, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sunhong Ruan, Gangjun Tang, Zhiming Zhang, Qinghong Zhang, Ye Wang, Shunji XieThe global shift toward a low-carbon society has accelerated the development of electrocatalytic CO2 reduction reaction (CO2RR) technology, which shows great potential […]Sunhong Ruan
- Electronic and Energy descriptor for SACs as tri-functional catalysts towards urea formation and unveiling the C-N coupling Tháng mười một 21, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06657C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Narad Barman, Chiranjib Majumder, Ranjit ThapaSingle atom catalysts (SACs) have rapidly emerged as a cutting-edge trend in electro-catalysis for synthesizing nitrogen-based products such as ammonia, nitric acid and urea. In the present study, […]Narad Barman
- AI-enabled New Sensing Technology: Colorimetric Analysis of Exosomes for Precise Diagnosis of Breast Cancer Tháng mười một 21, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06650F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xinyu Qu, Bingqian Lu, Chengge Gao, Weizun Zhao, Yujing Zeng, Shuai Wu, Chenbo Ji, Genxi LiColorimetric sensors are widely utilized in biomedical detection owing to simple operation and intuitive visual results. However, their […]Xinyu Qu
- Photocatalytic Generation of Alkoxysulfonium Ions for Selective Oxidation of Benzylic/Allylic Halides to Carbonyls under Base-Free Conditions Tháng mười một 21, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07057K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuanzhen Mao, Xiaofang Zhang, Wei-Yu Shi, Hongyu Guo, Rong ZhouSelective oxidation of organic molecules to carbonyls is a highly desirable but still challenging transformation in both synthetic chemistry and pharmaceutical industry. Herein, we […]Yuanzhen Mao
- Development of a Glutamine-Responsive MRI Contrast Agent Tháng mười một 20, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05987A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Charles A Wilson, Austin T Bruchs, Saman Fatima, David G Boggs, Noah M Dietzen, Jennifer Bridwell-Rabb, Lisa OlshanskyMagnetic resonance imaging (MRI) is widely used to visualize disease, and image quality can be improved […]Charles A Wilson
- Inherently Chiral Homo-Heteracalixarenes: Design and Synthesis via Enantioselective Intramolecular Sonogashira Cross-coupling Reaction Tháng mười một 20, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05923B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi-Fan Shuo Jiang, Yue Zhang, Shuo Tong, Jieping Zhu, Mei-Xiang WangRecent research has seen a growing interest in synthesizing inherently chiral macrocycles, driven by their potential applications in chiral supramolecular chemistry. We present […]Yi-Fan Shuo Jiang
- Covalently grafted MOP-on-MOF hybrid ionic-porous composite for efficient adsorption and catalysis Tháng mười một 20, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC06370A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dipayan Ghosh, Sahel Fajal, Kishalay Biswas, Anirban Roy, Dipanjan Majumder, Sujit K. GhoshCovalently grafted MOP-on-MOF hybrid crystalline ionic-porous composite for efficient adsorption (selective adsorption of polyiodide species from aqueous phases) and catalysis (Lewis […]Dipayan Ghosh
- Permanently porous cycloparaphenylene nanohoops via supramolecular engineering Tháng mười một 20, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC07685D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ashlyn A. Kamin, Nathaniel J. Schuster, Haomiao Xie, Phuong H. Le, Kathleen M. Snook, Sebastian Krajewski, Werner Kaminsky, Omar K. Farha, Ramesh Jasti, Dianne J. XiaoIn this work, we establish carbon nanohoops as […]Ashlyn A. Kamin
- Charged two-dimensional nanochannels with high ion density enabling ultrafast monovalent and multivalent ion conductivity Tháng mười một 20, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC08076B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lingjie Zhang, ling Yunjia, Jianglin Yan, Zhenlei Wang, Yanhui Miao, Haoyu Bai, Tingting Zhang, Shaoxian Song, Mildred Quintana, Yunliang ZhaoIon conductors with fast ion transport and reliable stability are highly desired for energy […]Lingjie Zhang
- Phenothiazine-Based TADF Emitters with Dual Conformations for Single-Molecule White OLEDs Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04370K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pavithra V. Prabhu, Vibhu Darshan, Indira S Divya, Moumita Banerjee, Sunil Varughese, Anakuthil Anoop, K. N. Narayanan Unni, Joshy JosephDonor-π-acceptor (D-π-A) type phenothiazine derivatives, exhibiting quasi-axial and quasi-equatorial conformers with distinct photophysical properties, […]Pavithra V. Prabhu
- The agentic age of predictive chemical kinetics Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07692G, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alon Grinberg DanaPredictive chemical kinetic modeling is foundational to areas ranging from energy and environmental science to pharmaceuticals and advanced materials. While significant progress has been made in automating individual steps, the...The content of […]Alon Grinberg Dana
- Oxidative Rearrangement of Alkynes to chiral α-Arylalkanoic Esters Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07882B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rawiyah Alkahtani, Johannes Westphäling, Alexandra Gorecka, Rasool Babaahmadi, Hanaa Gieman, Maylis Finance, Jaime Lorente Martinez, Dhananjay Bhattacherjee, Rebecca Melen, Mu-Hyun Baik, Thomas WirthChiral α-arylalkanoic esters, valued as anti-inflammatory agents, are synthesised through an […]Rawiyah Alkahtani
- Measuring concentration and diffusivity within biomolecular condensates using calibration-free scanning fluorescence correlation spectroscopy Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05592J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stavros Stavrakis, Prerit Mathur, Marcell Papp, Katarzyna Makasewicz, Paolo Arosio, Andrew deMelloThere is a growing consensus that cells can regulate biochemical activity through membrane-less organelles, also known as biomolecular condensates. Unfortunately, the mechanisms […]Stavros Stavrakis
- High-valent sulfur fluorides as reactivity switches for PFAS-free benzene–azepine skeletal editing Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC08177G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chavakula Nagababu, Takuya Muramatsu, Muhamad Zulfaqar Bacho, Shiwei Wu, Seishu Ochiai, Jorge Escorihuela, Norio ShibataThe development of non-PFAS fluorinated heterocycles is a critical challenge in sustainable molecular design. Here we report a reactivity-switching […]Chavakula Nagababu
- Robust π-Conjugated Radical Cations Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06726J, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shilong Su, Qian Miaoπ-Conjugated radical cations, open-shell species carrying a positive charge, serve as charge carriers in p-type organic semiconductors, underpinning the operation of various organic electronic devices. Although they are traditionally perceived...The […]Shilong Su
- Gas Exclusion Zones in Type II Porous Liquids Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06588G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stuart James, José Luis Borioni, Émer M Rooney, Cathal Kelly, Sergio Fonrouge, Mario G Del Popolo, Travis Holman, Deborah CrawfordPorous liquids combine permanent porosity with fluidity and may ultimately find uses which are […]Stuart James
- Structural and Electronic Modulations of Lytic Polysaccharide Monooxygenase (LPMO) upon Chitin Binding: Insights from X-ray Spectroscopy Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07620J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chris Joseph, Ashish Tamhankar, Ole Golten, Kushal Sengupta, Sergio Augusto Venturinelli Jannuzzi, Morten Sørlie, Liqun Kang, Åsmund Kjendseth Røhr, Vincent G.H. Eijsink, Serena DeBeerLytic polysaccharide monooxygenases (LPMOs) play a critical role in the […]Chris Joseph
- Pressure-Induced Emission Enhancement through a Synergistic Effect between Suppression of Excimer Formation and Activation of Aggregation-Induced Emission Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07579C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xinqi Yang, Yuxiang Dai, Xiaoxiang Zhang, Daojie Yang, Ru Guo, Haile Yan, Lili Zhang, Kai Wang, Haichao Liu, Bing YangConventional organic π-systems usually suffer from pressure-induced emission quenching due to enhanced π–π stacking, […]Xinqi Yang
- Nickel-catalyzed decarbonylative addition of acylsilanes across alkynes via the cleavage of a carbon–silicon bond Tháng mười một 19, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07524F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yui Morimoto, Takahiro Ando, Tetsuya Inagaki, Hayato Fujimoto, Mamoru TobisuWhile hydrosilylation, the formal insertion of alkenes or alkynes into an H–Si bond, has been widely developed, analogous transformations involving inert C–Si bonds are […]Yui Morimoto
- Insights into the initial steps of the thiamin pyrimidine synthase (ThiC)-catalyzed reaction through EPR spectroscopic characterization of radical intermediates Tháng mười một 18, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04563K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Melissa Bollmeyer, Vishav Sharma, Dmytro Fedoseyenko, Yumeng Cao, Guodong Rao, Dean J Tantillo, Tadhg P. Begley, R. David BrittThiamin pyrimidine synthase (ThiC) is a noncanonical radical SAM enzyme that catalyzes the complex radical […]Melissa Bollmeyer
- Ionomers modulate the microenvironment in electrocatalytic CO2 reduction Tháng mười một 22, 2025
