RSC – Chem. Sci. latest articles- Atomic diffusion barriers and inter-element miscibility guide the development of unexplored crystal phases Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01754H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kenshi Matsumoto, Masaki Kudo, Yasutomi Tatetsu, Ryota Sato, Ryo Takahata, Toshiharu TeranishiZ3-Fe(Pd,In)3 ordered alloy nanoparticles containing alternating layers of an L10 (CuAu-type)-like PdFePd trilayer and a Pd–In ordered alloy monolayer are formed by […]Kenshi Matsumoto
- SpyTag/SpyCatcher-mediated protein ubiquitination to investigate 20S and 26S proteasomal degradation Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05440K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julia Kriegesmann, Shahar Levi, Mahdi Hasan, Eman Nassar, Michael H. Glickman, Ashraf BrikUbiquitination significantly influences human health and disease because it plays an essential role in many cellular signaling pathways. To investigate the […]Julia Kriegesmann
- Intrinsic Electrocatalytic Activity of Platinum Grain Boundaries: Correcting Measurement Artefacts in Scanning Electrochemical Cell Microscopy (SECCM) Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03829D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Harry B Swan, Lachlan F Gaudin, Alannah J Hunt, Cameron Luke BentleyDetailed understanding of the behaviour of an electrocatalyst is not only founded on the bulk properties of a given material, but must […]Harry B Swan
- Autonomous Optimisation of Biocatalytic Reactions: Enzymatic Synthesis of N-benzyl acetoacetamide in Continuous Flow Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04249F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew Takle, Sebastian C. Cosgrove, Adam D. ClaytonBiocatalysis represents an invaluable tool for developing more sustainable pharmaceutical manufacturing processes. However, the optimisation of these complex transformations remains challenging when using traditional methods. Recent […]Matthew Takle
- Unraveling the Photoredox Chemistry of a Molecular Ruby Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05170C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Guangjun Yang, Georgina Shillito, Phillip Seeber, Oliver S. Wenger, Stephan KupferIn contrast to well-studied 4d6 and 5d6 transition metal complexes such as the modern-day drosophila of photochemistry, Ru(II)-tris(bipyridine), which often feature a typical […]Guangjun Yang
- Intrinsic direct air capture Tháng 9 9, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC06099K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Austin McDannald, Daniel W. Siderius, Brian DeCost, Kamal Choudhary, Diana L. Ortiz-MontalvoHow can you tell if a sorbent material will be good for any gas separation process – without detailed simulations of the […]Austin McDannald
- Silver- and Gold-Catalyzed Divergent Cascade Cycloisomerization / [3 + 2] versus [2+2+1] Cycloaddition towards a Stereoselective Access to Heterohexacyclic Derivatives Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05338B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Emilie Gentilini, Anaïs Bouschon, Vincent Davenel, Fabien Fontaine-vive, Jean-Marie Fourquez, Véronique MicheletA divergent cascade cycloisomerization / [3 + 2] vs [2+2+1]-cycloaddition via gold or silver catalysis has been reported in 1,1,1,3,3,3-hexafluoroisopropan-2-ol (HFIP). The […]Emilie Gentilini
- pH Guided Pathways Trigger Tailoring of Chiral Luminescence in Enantiomeric Gold Cluster Assemblies Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04763C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Camelia Dutta, Jatish KumarThe modulation of chirality has been a subject of scientific research for past decades due to its broad and impactful applications in drug discovery, catalysis, and biotechnology. However, the control...The […]Camelia Dutta
- Boosting Planar Perovskite Solar Cell Performance via Peripheral End-Group Engineering of Phenoxazine-Core Hole Transport Materials Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04399A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Murali Ravi, Ziyang Xia, Kumar Divya, Cheng Chen, Haoxin Wang, Yi Tian, Balamurali Ravichandran, Ming ChengDeveloping novel, cost-effective hole-transporting materials (HTMs) with tailored chemical/electronic properties is critical for high-performance, stable planar perovskite solar […]Murali Ravi
- Chemoselective Cu-catalyzed acylsilylation of vinyl arenes using silylboronates and acyl fluorides Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05220C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhengyu Zhao, Jun Zhou, Seishu Ochiai, Sota Ikawa, Norio ShibataWe report the chemoselective copper-catalyzed acylsilylation of vinyl arenes using bench-stable silylboronates and acyl fluorides, which enables efficient access to β-silyl ketones under mild […]Zhengyu Zhao
- Insight of Interfacial Water & Key Intermediates at Cu95Co5 Aerogels for Electrocatalytic Nitrate-to-Ammonia Conversion Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04633E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ming Mu, Junjie Chen, Xiangxin Xue, Yumei Yang, Ruikai Qi, Yuezhu Wang, Di Liu, Lijia Shang, Wenji Jiang, Xinyi Shao, Zheng-Jie Chen, Bing Zhao, Wei SongElectrocatalytic nitrate reduction (NO3RR) to ammonia presents a […]Ming Mu
- Synthesis of Perhalogenated Silylboranes (X = Cl, I) and Their Application in Regiodivergent Alkene Silaboration Tháng 9 9, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06234A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jan Heller, Christoph D. Buch, Alexander Virovets, Eugenia V. Peresypkina, Hans-Wolfram Lerner, Felipe Fantuzzi, Matthias WagnerSilaboration of olefins is a synthetically valuable and atom-economic mode of functionalization; however, it typically requires transition-metal catalysis. […]Jan Heller
- Potential-driven dynamic strain in chemical bonds for urea electrosynthesis Tháng 9 8, 2025Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC04375A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Zhang, Hao Sun, Hai-Yan Zheng, Zhan Shi, Jian-Rong Zeng, Jing-Yao Liu, Chun-Yi Sun, Zhong-Min SuA dynamic catalytic system by controlling the elastic strain of Cu–O bonds in the Cu5-PPF electrocatalyst has been […]Xin Zhang
- Harnessing the copper surface for direct mechanocatalysis: A case study on mechanochemical sulfonylurea synthesis Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04099J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kathleen Rose Floyd, Lizette Mella, Ryan W Kwok, Mackenzie Gray, Edward Broker, Mateusz Marianski, Tomislav Friščić, James D BatteasDirect mechanocatalysis has arisen as a promising tool to achieve synthetic transformations by utilizing reaction […]Kathleen Rose Floyd
- Büchner-Type Ring Expansion of Aromatic Main-Group Biradicaloids Toward Phosphorus Radical-Derived NIR-II Photothermal Materials Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06158J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shihua Liu, Shunlin Zheng, Jieli Lin, Hansjörg Grützmacher, Cheng-Yong Su, Zhongshu LiThe Büchner reaction enables the construction of functionalized cycloheptatrienes and aromatic tropylium cations, and has recently been extended to the ring expansion […]Shihua Liu
- Color-tunable ultralong room temperature afterglow under wide excitation range from UV to visible light via doping Boric acid with polyaromatic hydrocarbons Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04627K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Siyu Yan, Yunze Huang, Weibo Zhang, Hongpu Xin, Jing Yang, Peng LiAbstract: The development of ultralong organic room temperature afterglow (UL-RTA) materials have inspired tremendous attention owing to their great potential applications in […]Siyu Yan
- Flexible Crystalline Persistent Fluorescence Waveguides: A Universal Strategy for Anti-Counterfeiting and Secure Communication Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04999G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shun Liu, Linfeng Lan, Hongyu ZhangThe development of flexible organic crystals (FOCs) with persistent emissions represents a groundbreaking advancement in optoelectronic materials, offering transformative applications in flexible displays, secure communication, and anti-counterfeiting. Despite […]Shun Liu
- Single-Molecule Graphene Quantum Dots: Enhancement of Optical Properties and Promotion of Photodynamic Efficacy Based on Precise Control of Electronic Structure Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03593G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jintao Chen, Bin Li, Daoyuan Liu, Shiru Yin, Ji Qi, Zhenming Lu, Yi Liu, Tian GaoGraphene quantum dots (GQDs) exhibit excellent optical properties, low toxicity, good biocompatibility, and high re-active oxygen species (ROS) […]Jintao Chen
- One-step synthesis of graphene containing topological defects Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC03699B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benedikt P Klein, Matthew A Stoodley, Joel Deyerling, Luke A Rochford, Dylan B Morgan, David G. Hopkinson, Sam Sullivan-Allsop, Henry Thake, Fulden Eratam, Lars Sattler, Sebastian Michael Weber, Gerhard Hilt, Alexander Generalov, Alexei […]Benedikt P Klein
- Lewis-Acid Induced Mechanochemical Degradation of Polyvinylidene Fluoride: Transformation into Valuable Products Tháng 9 8, 2025Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05783C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Thomas Braun, Minh Bui, Christian Heinekamp, Emil Fuhry, Steffen M. Weidner, Jörg Radnik, Mike Ahrens, Kannan Balasubramanian, Franziska EmmerlingPolyvinylidene fluoride (-[CH2CF2]n-, PVDF) waste poses significant environmental challenges due to its recalcitrant nature and […]Thomas Braun
- Atomic diffusion barriers and inter-element miscibility guide the development of unexplored crystal phases Tháng 9 9, 2025
