RSC – Dalton Trans. latest articles- Angle-robust and tunable mid-infrared absorption in a Ge grating/SrTiO3 /VO2 hybrid metastructure on a metallic substrate Tháng 8 26, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01725D, PaperXin Cui, Yangyang Dai, Fenglin Xian, Liming Qian, Gaige ZhengWe propose a dynamically tunable and angle-robust mid-infrared (mid-IR) absorber based on a hybrid metastructure composed of a top-layer Ge grating, an ultrathin SrTiO3 polar dielectric layer, a thermochromic VO2...The content of this RSS Feed (c) The Royal Society of […]Xin Cui
- Single-component white-light-emitting hybrid copper(I) halide constructed by supramolecular cation for WLED Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01801C, PaperRong-Yan Zhang, Ting Zhu, Jin Zhang, Dong-Sheng Shao, Ying-Zhao Ma, Guo Peng, Xiaoming RenSingle-component white-light-emitters ensure color stability while reducing device complexity, which are ideal candidates for white light-emitting diodes (WLEDs). However, the realization of single-component white-light emission with high efficiency and stability...The content of this RSS Feed (c) […]Rong-Yan Zhang
- Interplay between the morphology, crystal facets and silver modifications of titanium dioxide nanomaterials in the context of photocatalysis Tháng 8 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01597A, PaperNasir Shakeel, Ireneusz Piwoński, Aneta Kisielewska, Maciej Krzywiecki, Edyta Matyja, Magdalena Małecka, Tomasz Szmechtyk, Andrzej Kruk, Younas Sohail, Muhammad NaveedTitanium dioxide (TiO2) having the morphology of nanofibers (TNFs), nanorods (TNRs), and nanograss (TNGs) nanostructures was prepared.To cite this article before page numbers are assigned, use the DOI form of […]Nasir Shakeel
- 2D-Self-Assembly of Twisted Porphyrin Appended on Multiwalled Carbon Nanotubes for Oxygen Reduction Reaction Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01591J, PaperVarusha Bhardwaj, Varsha Singh, Vellaichamy Ganesan, Muniappan SankarThe spontaneous formation of an ordered array of twisted cobalt(II) porphyrin yielding a 2D self-assembled structure is wrapped around multiwalled carbon nanotubes (MWCNT) and characterized by different techniques. The approach...The content of this RSS Feed (c) The Royal Society of ChemistryVarusha Bhardwaj
- Constructing Ni(OH)2 nanosheets on nickel foam electrode for efficient electrocatalytic ethanol oxidation Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01777G, PaperShasha Ma, Di Chen, Zhaobin Ye, Yuanlong Wang, Jie Xu, Jianyong ZhangThe main bottleneck faced by traditional hydrogen production technology through water electrolysis lies in the high energy consumption of anodic oxygen evolution reaction (OER). Combining thermodynamically favorable ethanol oxidation reaction...The content of this RSS Feed (c) The Royal […]Shasha Ma
- Semiconductor-to-semimetal transition on Te doping in a new semiconducting material Ba2.75Pb1.1Sb4.1Se10 Tháng 8 25, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01185J, Paper Swati, Subhendu Jana, Sayani Barman, Sweta Yadav, Jai PrakashNew quaternary Ba2.75Pb1.1Sb4.1Se10 and its Te-substituted derivatives have been synthesized. Te substitution has significantly improved the electrical conductivity of the parent Ba2.75Pb1.1Sb4.1Se10, which has ultralow thermal conductivity.To cite this article before page numbers are assigned, use the DOI form of […]Swati
- Supramolecular Surface Modification of Ceria Nanoparticles for Enhanced Chemical Mechanical Planarization Performance in Shallow Trench Isolation Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01483B, PaperHaining Zhang, Chenyan Zhao, Xueli Sun, Chengrui Xin, Fangwei Lu, Shuming Wu, Xin-Ping Qu, Song Wang, Simin Li, Hui Shen, Fan ZhangChemical mechanical planarization (CMP) is an indispensable technique for achieving global planarization in shallow trench isolation (STI) structures, a critical component in modern integrated circuits. With the continuous […]Haining Zhang
- Biological activities of metallic nanostructures functionalized with hexadeca-substituted copper (II) and cobalt (II) phthalocyanines Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01232E, PaperNazlı Farajzadeh Farajzadeh Öztürk, Sadin Özdemir, M. Serkan Yalçın, Zehra Altuntas Bayir, Makbule Burkut KoçakIn this study, a novel phthalonitrile derivative (a) containing three various groups (hexyl, aminated ester, phenoxy) was synthesized and then cyclotetramerized in the presence of the related metal chloride salts...The content of this RSS Feed […]Nazlı Farajzadeh Farajzadeh Öztürk
- Copper complex with thiazole-modified tridentate ligand: synthesis, structural characterization, and anticancer activity in B16-F10 melanoma cells Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01235J, PaperBishu Wang , Huishan Zhong, Jiawen Huo, Tao Wang , Fenglin Wu, Kejie Du, Tao Feng, Jin-Quan WangCopper serves as a crucial trace element in various biological systems. Copper ions form complexes with different ligands, amplifying reactive oxygen species (ROS) levels and promoting intracellular ROS accumulation in...The content of […]Bishu Wang
- Fluorescence spectroscopy: detection and sensing of SO2 and H2S using MOFs and other emerging porous materials Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01521A, Tutorial Review Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marco L. Martínez, Pablo Marín-Rosas, Valeria López-Cervantes, Ariel Guzman-Vargas, Ricardo A. Peralta, Diego Solis-Ibarra, Ilich A. IbarraIn this tutorial review we introduce the basic concepts on fluorescence spectroscopy as an analytical technique to […]Marco L. Martínez
- Synthesis of N-Alkylated Amines via Alcohol Dehydrogenation Catalyzed by a Bis-Azo-Diamido Coordinated Ruthenium(III) Complex Tháng 8 25, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01716E, PaperSupriyo Halder, Srijita Naskar, Sampad Malik, Dipika Roy, Kausikisankar PramanikAn interesting ruthenium(III) complex, trans-[Ru(H2L)Cl(PPh3)], has been synthesized using a redox-active tetradentate bis-azo diamine ligand (H4L). This complex represents the first example of a structurally robust, air- and moisture-stable coordination...The content of this RSS Feed (c) The Royal Society of […]Supriyo Halder
- Exploring the effect of copper on the bioactivity of 8-quinolines: an in vitro and in vivo study Tháng 8 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01396H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alessia Sambugaro, Riccardo Po, Martina Lorenzetto, Rebecca Ceolin, Giuditta Palmerston, Erik Murador, Laura Cifalinò, Giulia Annesi , VALERIA SCALCON, Chiara Nardon, Valentina OliveriCurrent anticancer therapy is challenged by the adaptability and resistance of tumor […]Alessia Sambugaro
- Trifluoroborate-Appended Cyclen Complexes of Paramagnetic Transition Metals (Ni2+, Co2+) as Fast-Relaxing 19F MRI Probes Tháng 8 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01834J, CommunicationCharline Sire, Francesca Garello, Noemie Lalaoui, Nathalie Saffon-Merceron, Nicolas Le Poul, Raphael Tripier, Lorenzo Tei, Thibault TroadecFor the first time, trifluoroborate groups (BF3s) have been investigated as sensitive probes for 19F Magnetic Resonance Imaging (MRI) in paramagnetic complexes. Using a macrocyclic BF3-appended cyclen ligand, complexes of...The content of this […]Charline Sire
- Nanoscale Ruthenium(III) Complexes with Bioactive Ligands: Structural, Colloidal, and Dual Antimicrobial–Cytotoxic Investigations Tháng 8 24, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01857A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rudi van Eldik, Olga Impert, Anna Katafias, Maciej Witwicki, Anna Kozakiewicz, Pawel Pomastowski, Oleksandra Pryshchepa, Michalina Ehlert, Barbara Kubiak, Yogeswara Rao Pateda, Erik Rakovský, Natalia Balinska, Natalia CzernieckaThis study comprehensively analyses two new ruthenium(III) […]Rudi van Eldik
- Hidden Spin State Accessed by Light Irradiation in Iron(III) High-Spin Complex Tháng 8 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01604E, CommunicationHikaru Zenno, Rui Hieda, Ryosuke Nakao, Yoshihiro Sekine, Shinya HayamiHigh-spin (HS) iron(III) complex, [Fe(qsal)2]Cl·MeOH·H2O, was synthesised, and its crystal structures and photo-induced magnetic properties were characterised. Upon photo-excitation, the HS state is converted into a low-spin (LS) state, revealing...The content of this RSS Feed (c) The Royal Society of […]Hikaru Zenno
- Cd5Te4O12X2 (X = Cl, Br, I): A New Oxyhalide Family with [CdO4X] Mixed Anionic Units and Adjustable Optical Properties Tháng 8 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01473E, PaperMaqsood Iqbal, Jiazheng Zhou, Hongshan Wang, Juanjuan Lu, Shilie Pan, Junjie LiThree novel tellurate halides Cd5Te4O12X2 (X = Cl, Br, I) were rationally designed by introducing planar [TeO3] into the binary anionic compounds, and synthesized by the flux method in sealed...The content of this RSS Feed (c) The Royal […]Maqsood Iqbal
- Mixed-anion chalcogenide-halide semiconductors A2BaTaS4Cl (A = K, Rb, Cs) and K2BaNbS4Cl Tháng 8 21, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01676B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Thomas S. Ie, Siddhartha S. Nathan, James M. Rondinelli, Mercouri G. KanatzidisThe synthesis and structural evolution of four novel mixed-anion compounds: K2BaTaS4Cl, Rb2BaTaS4Cl, Cs2BaTaS4Cl and K2BaNbS4Cl.To cite this article before page numbers are assigned, […]Thomas S. Ie
- Electrochemical water oxidation using single-site Cu(II) molecular complexes: A mechanism elucidated by computational studies Tháng 8 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01397F, PaperDev Raj, Koushik Makhal, Manaswini Raj, Aman Mishra, Rohan Mahapatra, Tanya Pattnaik, Bhabani S. Mallik, Sumanta Kumar PadhiIn this work, the penta-coordinated mononuclear Cu(II) complexes [Cu(QCl-Tpy)Cl2], [Cu1] (where QCl-Tpy = 3-([2,2':6',2''-terpyridin]-4'-yl)-2-chloroquinoline) and [Cu(8HQ-Tpy)Cl2], [Cu2] (where 8HQ-Tpy = 2-([2,2':6',2''-terpyridin]-4'-yl)quinolin-8-ol) had been utilized as an electrocatalyst for water oxidation...The content of […]Dev Raj
- Thermoreversible Hydrogel Containing Photoactivatable Tricarbonyl Mn(I) Terpyridine complexes for Therapeutic Carbon monoxide (CO) Release Tháng 8 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01527H, PaperAakshika Sree M, Amilan Jose DevadossCarbon monoxide (CO) is a well-established gasotransmitter known for its diverse physiological benefits. However, achieving controlled and targeted CO delivery remains challenging. To address this, light-activated carbon monoxide-releasing molecules (photoCORMs)...The content of this RSS Feed (c) The Royal Society of ChemistryAakshika Sree M
- Comparative Analysis of Metal-Binding Properties of C-Terminal FeoB Peptide Models from Selected Gram-Negative Bacteria Tháng 8 21, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01388G, PaperBartosz Orzel, Malgorzata Ostrowska, Slawomir Potocki, Henryk Kozlowski, Massimiliano Francesco Peana, Elzbieta Gumienna-KonteckaIn our previous work, we have analyzed the coordination chemistry of the peptidic model of the C-terminal part of E. coli FeoB protein, regarded as the most important Fe(II) bacterial...The content of this RSS Feed (c) The […]Bartosz Orzel
- Angle-robust and tunable mid-infrared absorption in a Ge grating/SrTiO3 /VO2 hybrid metastructure on a metallic substrate Tháng 8 26, 2025
