RSC – Dalton Trans. latest articles- Carbon dioxide hydrogenation with cobalt catalysts (Co-N-C) using organosilanes as hydrogen sources Tháng 3 3, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00082G, PaperYanin Álvarez-Briseño, Marco García-Corral, Hugo Carcaño-Morales, Paola Aguillón-Rodríguez, Lazaro Huerta, Carmen Ortiz CervantesCobalt-nitrogen-carbon (Co-N-C) catalysts were synthesized from cobalt(II) acetylacetonate and 5-amino-1,10phenanthroline using high-purity magnesium oxide as a removable support. The resulting materials contain subnanometric cobalt species dispersed within a nitrogen-doped carbon...The content of this RSS Feed (c) The […]Yanin Álvarez-Briseño
- Correction: An N-heterocyclic carbene-based pincer system of palladium and its versatile reactivity under oxidizing conditions Tháng 3 2, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT90035F, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Haobin Li, Bo Zhang, Rui Feng, Shuai GuoTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryHaobin Li
- Combining gold(I/III) complexes and ferrociphenol scaffold for the generation of bimetallic complexes with anticancer activity Tháng 3 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00049E, PaperMagda Křelinová, Jérémy Forté, Tom Lacoma, Giulia Annesi , Alessandra Folda, Maria Pia Rigobello, Michèle Salmain, Petr Štěpnička, Jiří Schulz, Benoît BertrandA series of eleven heterobimetallic Au/Fe complexes featuring [Au(I)-thioglucose tetraacetate], [Au(I)-NHC], [(C^N)Au(III)Cl], [(C^N^C)Au(III)] or [(C^C)Au(III)Cl] fragments and (diphenylphosphino)ferrociphenol or (diphenylphosphino)ferrocene ligands have been synthesized. The compounds were fully […]Magda Křelinová
- Solution-processable Homoleptic Aluminum(III) Catecholaldimine Complex as an Active Material for RRAM Switching Device Tháng 3 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02954F, PaperVivek Sharma, Anupam Chetia, Rishabh Raj Upadhyay, Purva Dua, Satyajit Sahu, Ramesh K. MetreIn this paper, we report the synthesis and structural characterization of a new mononuclear aluminum complex 1, containing redox-active hydrazine based catecholaldimine ligand (4,6-ditert-butyl-2,3-dihydroxybenzylidene)furan-2-carbohydrazide (LH 3 ). Complex 1 was...The content of this RSS Feed (c) […]Vivek Sharma
- Fixing CO2 from the air to assemble Dy8 zero-field single-molecule magnet and Gd8 magnetocaloric molecular material Tháng 3 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00214E, PaperCai-Ming Liu, Xiang HaoAssembling Ln(III) clusters by capturing and fixing CO2 from the air is a unique and eco-friendly approach to multinuclear single-molecule magnets and magnetocaloric molecular materialss. However, the conditions or factors...The content of this RSS Feed (c) The Royal Society of ChemistryCai-Ming Liu
- Modulation of the electrocatalytic performance of rGO/CoCuFe[Ni(CN) 4 ] pillared with pyridine derivatives in Zinc-air batteries Tháng 3 2, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02812D, PaperE. Arturo Quintanilla-Serrano, Prospero Acevedo-Peña, Edilso Reguera, Marlene M. GonzálezComposites consisting of cobalt, iron, and copper tetracyanonickelates, pillared with different organic ligands, were obtained via chemical precipitation and subsequently exfoliated in a rGO suspension. Exfoliation and the presence of...The content of this RSS Feed (c) The Royal Society of […]E. Arturo Quintanilla-Serrano
- Developing Ni3N/NiO Heterostructure Catalysts to Enhance Hydrogen Evolution Reaction in Alkaline Medium via a Surface-Dependent Mechanism Tháng 2 28, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00031B, PaperFangfang Liu, Shan Ji, Yongwei Li, Zhihao Fang, Vladimir Linkov, Yucheng Dong, Hui WangIn the construction of sustainable energy systems, the development of efficient and stable electrocatalysts for the hydrogen evolution reaction (HER) is of crucial significance. This study adopts an in-situ oxidation-nitridation...The content of this RSS Feed (c) […]Fangfang Liu
- A di-nuclear μ-oxido rhenium(VI) complex: from deep purple to catalytic applications Tháng 2 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00039H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tobias A. Doliner, Peter E. Hartmann, Gernot Oberwinkler, Ferdinand Belaj, Antoine Dupé, A. Daniel Boese, Jörg A. SchachnerFrom lab curiosity to a novel Re(VI) oxyanion reduction catalyst, we proudly present deep purple.To cite this […]Tobias A. Doliner
- Pendant-cation assisted spontaneous axial halide substitution in group 7 M(L)(CO)3X complexes Tháng 2 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02433A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wesley W. Kramer, Thomas R. Sheridan, Jorge Pérez-Vázquez, Christophe A. Boivin, Amanda M. Browne, Catherine G. Logan, Brian C. SandersThe presence of pendant cationic functional groups in group 7 fac-tricarbonyl complexes produces unusual axial-halide […]Wesley W. Kramer
- Structural transformation and redox chemistry of Pd/CeO 2 during SO2 -induced sulfurization: An in situ XAFS study Tháng 2 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00070C, PaperSaki Shigenobu, Takeharu Sugiyama, Hajime Hojo, Hisahiro EinagaIn situ X-ray absorption fine structure (XAFS) spectroscopy was employed to elucidate the structural evolution of Pd/CeO 2 catalysts during SO 2 -induced sulfurization. Linear combination fitting of Ce L...The content of this RSS Feed (c) The Royal Society of ChemistrySaki Shigenobu
- Fraternal twins: B2O2- or B2N2-doped polycyclic π systems and their formation mechanism via regiodivergent Au-versus amine catalyzed cycloadditions Tháng 2 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00412A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Simon M. Mittag, Jonas Klopf, Alexander Virovets, Eugenia V. Peresypkina, Hans-Wolfram Lerner, Holger Helten, Matthias WagnerBE-doped polycyclic aromatic hydrocarbons (PAHs; E = NR, O) often exhibit superior optoelectronic properties compared to their carbonaceous congeners. […]Simon M. Mittag
- Single-Site Hydrogen-Bond Modulation Enhances Catalytic Ester Hydrolysis in a Zn(II)–TPA Scaffold Tháng 2 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03058G, PaperHan Sol Kim, Soo Suk LeeZinc(II)-dependent metalloenzymes rely heavily on secondary-sphere interactions to modulate reactivity, inspiring the design of biomimetic Zn(II) catalysts that incorporate analogous features. Here, we introduce a hydroxymethyl-functionalized TPA ligand in which...The content of this RSS Feed (c) The Royal Society of ChemistryHan Sol Kim
- Green synthesis of biomass-derived graphene for supercapacitor application Tháng 2 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02322J, PaperAminata Fall, Martinson Addo Nartey, Daniel Nframah Ampong, Kwadwo Mensah-Darkwa, Ram K. GuptaGreen synthesis of biomass precursor into GO and rGO was achieved using hydrothermal carbonization. The synthesized material exhibited an enhanced specific capacitance of 552.48 F g−1 at 1 A g−1 with high redox activity.To cite this article […]Aminata Fall
- Rigidified cyclic diglycolamides: coordination and extraction of trivalent f-elements Tháng 2 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D6DT00275G, PaperMariia V. Evsiunina, Mikhail A. Kalinin, Paulina Kalle, Danila A. Iakovlev, Stepan N. Kalmykov, Petr I. Matveev, Nataliya E. BorisovaConformationally rigid cyclic diglycolamides were synthesized for the first time. La(III) coordination revealed 1 : 1 and 2 : 1 ligand-to-metal complexes.To cite this article before page numbers are assigned, use the DOI form […]Mariia V. Evsiunina
- Zero valent iron and nickel coordination chemistry: metal atoms as direct approach to bis(benzene)chromium bridged N-heterocyclic silylene complexes Tháng 2 27, 2026Dalton Trans., 2026, Advance ArticleDOI: 10.1039/D5DT02957K, PaperJohannes M. Emmert, Jörg Rust, Christian W. Lehmann, Jörg J. SchneiderA bis(benzene) chromium bridged bidentate organometallic silylene pincer ligand is introduced for zerovalent iron and nickel. The pincer ligand and its Fe complex are accessible by a direct metal-atom route under extremely mild chimie douce conditions.To cite this article […]Johannes M. Emmert
- Deciphering Cation-Driven Structure-Property Correlations in 0D Hybrid Ruthenium Halide Perovskites Tháng 2 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02797G, PaperHimangshu Pratim Saikia, Ankita Likson, Khyati Anand, Bidyut Das, Abinash Tiwari, Sandeep Kumar Dey, Beatriz Gil-Hernández, Prashurya Pritam MudoiHybrid organic-inorganic halides have emerged as a structurally tunable class of materials that allows simultaneous modulation of optical properties and magnetic interactions. By varying the A-site cation with organic amines...The content […]Himangshu Pratim Saikia
- Homoleptic Complexes of Vanadium and N-Heterocycles Made via Oxidation of Vanadium Nanoparticles Tháng 2 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00230G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Claus Feldmann, Lena BaumgärtnerThe four homoleptic coordination compounds [NaV(cbz)4] (1), [V(bipy)3] (2), [V(phen)3] (3), and [V(Hai)3(ai)2]·0.5 tol (4) are prepared by reaction of vanadium metal (V(0)) nanoparticles (mean size: 1.6±0.3 nm) with the...The content […]Claus Feldmann
- Tailoring In-Gap States for Optimizing the Band Gap in Mixed-Valent Bromometallates, Towards Lead-Free Photovoltaics Tháng 2 27, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT02874D, PaperTatiana Alekseevna Shestimerova, Angelina P Klykova, Alexey Medved'ko, Victor N Khrustalev, Michael A. Bykov, Denis A. Pankratov, Igor A Presniakov, Alexey N. Kuznetsov, Sergey Z. Vatsadze, Andrei V ShevelkovMotivated by the task to replace toxic lead halide perovskites with lead-free environmentally benign light-harvesting materials for photovoltaics, we have synthesized […]Tatiana Alekseevna Shestimerova
- IPr*BndiNHC – Sterically-Adaptable Benzyl-Linked Dinuclear N-Heterocyclic Carbenes Tháng 2 26, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D6DT00096G, PaperKatarzyna Halikowska-Tarasek, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira BiszN-Heterocyclic carbenes (NHCs) represent one of the most important ligand classes in inorganic and organometallic chemistry due to their strong σ-donor properties and sterically-hindered environment around the metal centers. Recently,...The content of this RSS Feed (c) The Royal Society of […]Katarzyna Halikowska-Tarasek
- Dihalogen-substituted [MnIII(3,5-diHal-sal2323)]BPh4 salts: so similar but so different Tháng 2 26, 2026Dalton Trans., 2026, Accepted ManuscriptDOI: 10.1039/D5DT03065J, PaperDenis V. Korchagin, Gennady V. Shilov, Michael V. Zhidkov, Alexey I. Dmitriev, Andrei Palii, Eduard Borisovich Yagubskii, Sergey M. AldoshinThree novel tetraphenylborate salts of Mn(III) complexes with the Schiff base ligands 3,5-diHal-sal2323 are synthesized and structurally and magnetically characterized: [Mn(3,5-Br,F-sal2323)]BPh4 (1), [Mn(3,5-diI-sal2323)]BPh4 (2) and [Mn(3,5-Cl,Br-sal2323)]BPh4 (3). Complex 1 exhibits...The […]Denis V. Korchagin
- Carbon dioxide hydrogenation with cobalt catalysts (Co-N-C) using organosilanes as hydrogen sources Tháng 3 3, 2026
