RSC – Dalton Trans. latest articles- Facile Time-Controlled Synthesis of Two-Dimensional Zr-Perylenediimide MOF Nanosheets for Ultrasensitive DNA Fluorescent Biosensing Tháng 9 16, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01883H, CommunicationShiyang He, Yuhong Chen, Jiayi Wang, Xiaoyang Guo, Xiangrong Pan, Yumeng Su, Xiaoyan Lu, Zhan Zhou, Lufang MaThis study demonstrates a facile, surfactant-free strategy for synthesizing uniform two-dimensional (2D) rhombic Zr-PDI (perylenediimide) metal-organic framework (MOF) nanosheets (NSs) (~17 nm thick) by precisely controlling the solvothermal reaction time...The content of […]Shiyang He
- Proton-coupled electron transfer modulates the metal release of blood serum iron transferrin Tháng 9 16, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01803J, PaperMahesh Sundararajan, Lokpati Mishra, Naman K. Bharti, Swarna P. MantryA proton-coupled-electron transfer is the most probable pathway of iron release in physiological pH of serum transferrin.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal […]Mahesh Sundararajan
- Synthesis of Pd(II)–NHC complexes via C–H oxidative addition of triazolium salts to Pd(0) Tháng 9 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01695A, CommunicationAnes Kovacevic, Sean Parkin, Jay H. BaltisbergerAir-stable Pd(II)–NHC complexes are synthesized via direct oxidative addition of 1,2,4-triazolium salts to Pd2(dba)3. Both cis and trans isomers are observed and structurally characterized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS […]Anes Kovacevic
- Phosphinoamine coinage metal complexes with a coumarin fluorophore: synthesis, characterization, and in vitro (photo)cytotoxicity Tháng 9 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01532D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vanitha R. Naina, Shubham, Franziska Rönicke, Hans-Achim Wagenknecht, Peter W. RoeskyA coumarin-substituted phosphinoamine ligand was employed to synthesize Cu(I) and Au(II) complexes. The fluorophore in the ligand resulted in emissive complexes, which enabled cell […]Vanitha R. Naina
- Heteroleptic Tethered NHC Rare Earth Initiators for the Ring Opening Polymerisation of rac-Lactide Tháng 9 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01352F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joseph W. Walker, Tajrian Chowdhury, Georgina Rosair, Joy Farnaby, Stephen M Mansell, Ruaraidh D McIntoshThe importance of catalyst design is shown by the contrasting reactivity of tethered NHC and Tp ligands with rare-earth metal […]Joseph W. Walker
- Bulky Bis-Guanidine Ligand Based Neutral and Cationic Zinc Alkyl, Halide, and Hydride Complexes: Synthesis, Characterization, and Catalytic Application Tháng 9 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D4DT02907K, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rajata Kumar Sahoo, Sayantan Mukhopadhyay, Sagrika Rajput, Achintya Jana, Sharanappa NembennaThe tetra-aryl substituted bis-guanidine ligand L(3H) (L(3H) = {(ArHN)(ArNH)-C=N-C=(NAr)(NHAr)}; Ar=2,6-iPr2-C6H3), was used for the synthesis of mononuclear zinc(II) alkyls [L(2H)ZnR, R = Me (Zn-1), […]Rajata Kumar Sahoo
- Multimodal Synergistic Thermometry: Designing Wide-Range Optical Thermometers via Eu 3+ /Er 3+ Co-Doped YVO4 Tháng 9 15, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01830G, PaperZiyuan Li, Qiao Liang, Lu He, Xiaoli WuIn this paper, a five-mode synergistic thermometry system based on Eu3+/Er3+ co-doped YVO4 fluorescent material was developed. By utilizing the spectral properties of the phosphor, two luminescence intensity ratio (LIR)...The content of this RSS Feed (c) The Royal Society of ChemistryZiyuan Li
- Triggering the intrinsic catalytic activity of electrodeposited CoNiFe LDH via Pt decoration for an efficient hydrogen evolution reaction Tháng 9 15, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT01617G, PaperS. Vijaya, L. John KennedySchematic representation of (a) the preparation of CNF and Pt@CNF, and (b) a symmetric electrolyser using two identical hybrid Pt@CNF electrodes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]S. Vijaya
- Atomically Dispersed Co-Cu Dual Active Sites in Carbon Networks as Efficient Oxygen Electrocatalyst Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01807B, PaperNibedita Sinha, Chandni Das, Santanu Pal, Rajashri Urkude, Tanbir Ahmed, Biplab Ghosh, Poulomi RoySingle-atom metal-based electrocatalysts offer extended advantages by maximizing the utilization of active sites but often suffers from complex synthesis processes and low-density metal loading. The present work showcases a strategic...The content of this RSS Feed (c) […]Nibedita Sinha
- Oxygen Vacancy-Rich Co-Doped V2O5 as a High-Performance Cathode for Aqueous Zinc-Ion Batteries Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01909E, PaperWei Cao, Chenhan Xiong, Yanqiu Yu, Xiang Ji, Hao Xu, Yingge Guo, Ziwei Chen, Jun ChenDeveloping high-performance cathode materials is crucial for advancing aqueous zinc-ion batteries (AZIBs). In this work, we report a Co-doped V2O5 (CoVO) material engineered with abundant oxygen vacancies (Od -CoVO) via...The content of this RSS […]Wei Cao
- Trinuclear Copper(I) Furanyl ortho-Diphosphine Halide Clusters: Structure, Photophysical and Photocatalytic Hydrogen Production Properties Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01864A, PaperXiang Chen, Li Liu, Xinxin Zhong, Hengjiang Cong, Fa-Bao Li, Fengyan Li, Yi ZhaoIn recent years, mono-and di-nuclear copper(I) ortho-diphosphine halide complexes have attracted much attention due to their excellent emissive properties. However, trinuclear copper(I) ortho-diphosphine halide clusters have not been reported so...The content of this RSS Feed (c) […]Xiang Chen
- Circular Polarized Luminescent Framework Materials: From Synthesis to Future Applications Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01773D, PerspectiveJialei Chai, Yan XiaCircularly polarized luminescent (CPL) materials have attracted much attention in recent years due to their simultaneous chirality and luminescence, which have a wide range of applications in the fields of...The content of this RSS Feed (c) The Royal Society of ChemistryJialei Chai
- Upconversion luminescence and temperature sensing of Dy3+ and Yb3+ codoped Bi2WO6 powder in aqueous environments Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01331C, PaperJiachen Shi, Linxiang Wang, Mengliang Jiang, Xin Feng, Yan Zhangx%Dy3+, y%Yb3+: Bi2WO6 (x=0.5, 1, 3, 5; y=1, 6, 10, 15) upconversion luminescent powders were prepared using a high-temperature solid-phase method. X-ray diffraction experiments revealed that moderate amounts of Dy3+...The content of this RSS Feed (c) The Royal Society of […]Jiachen Shi
- Zeolite encapsulated Cu(II)-salen complexes for catalytic Rhodamine B degradation Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01828E, PaperShuyu Li, Tiankun Guo, Zecui Hui, Han Wang, Kaili MaWe successfully synthesized two copper complexes (CuL1 and CuL2) with N₄-tetradentate salen-ligands and encapsulated them within zeolite frameworks. Comprehensive characterization of both free and encapsulated complexes was performed using multiple...The content of this RSS Feed (c) The Royal Society of […]Shuyu Li
- Random Metamaterials with Double Negative Electromagnetic Parameters in Dense CuCr2Se4-CoCr2Se4 Binary Spinels Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01531F, PaperJun Cao, Chengsheng Wang, Zechao Xu, Kelan Yan, Liming Shen, Zhen Huang, Lingjie Zhang, Runhua Fan, Ningzhong BaoMetamaterials exhibiting simultaneous negative permittivity (εJun Cao
- N-Heterocyclic Silylene Complexes of Nickel(0) Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01887K, PaperEduard Glok, Luis Werner, Udo RadiusReactivity studies on the nickel complex [Ni(Mes2NHSi)2(COD)] (1), ligated with the N-heterocyclic silylene 1,3-bis(2,6-dimesityl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene (= Mes2NHSi; COD = cyclooctadiene) are presented. Treatment of 1 with two equivalents of the phosphines...The content of this RSS Feed (c) The Royal Society of ChemistryEduard Glok
- Nanoporous CoSe2 Polyhedron Imbedded Graphene as a Highperformance Sodium-ion Battery Anode Material Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01923K, PaperShujie Liu, Haiguang Guo, Bohao Wang, Liang Qiao, Xiaoying Hu, Junzhi LiSodium-ion batteries (SIBs) emerge as a promising candidate with the virtue of abundant sodium resources and low costs of sodium salts. CoSe2 as the anode material has attracted much attention...The content of this RSS Feed (c) The Royal […]Shujie Liu
- In Situ Confinement of CsPbBr 3 Quantum Dots within COF for Enhanced Photocatalytic CO2 Reduction Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01826A, PaperWenjian Lv, Jiacheng Wu, Ren Ma, Zhengqiang Xia, Sanping Chen, Gang XieConfining quantum dots (QDs) within covalent organic frameworks (COFs) has emerged as a promising strategy to address their inherent limitations, particularly the aggregation and environmental instability of perovskite QDs, as...The content of this RSS Feed (c) The Royal […]Wenjian Lv
- Redox Transition and Property Modulation in Vanadium Oxide Nanourchins: From V2O5 to long hydrocarbon alkylammonium V7O162-. Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01489A, PaperTamara Bruna, Andres Ibañez, Daniel NavasUrchin-like vanadium oxide nanostructures (VOₓ–NUs) were synthesized using V⁵⁺ alkoxide precursors [VO(OCH(CH₃)₂)₃] and long-chain primary alkylamines (1 hexadecylamine and 1 octadecylamine) as structure-directing agents. The process involves intercalation-driven sol–gel assembly...The content of this RSS Feed (c) The Royal Society of ChemistryTamara Bruna
- Inkless Rewritable Paper Enabled by a Scalable Photochromic Membrane Tháng 9 14, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT01957E, PaperJunchao Liu, Chenfang Zhang, Tianyu Huang, Xusheng Guo, Zhenxin Kuang, Rong-Wei Kou, Yu Zhong, Pan Jia, Jingxia WangRewritable paper has attracted wide research attention in the field of environment-friendly information transmission owing to its potential possibility to promote a sustainable society development. Traditional organic dye-based rewritable paper...The content of […]Junchao Liu
- Facile Time-Controlled Synthesis of Two-Dimensional Zr-Perylenediimide MOF Nanosheets for Ultrasensitive DNA Fluorescent Biosensing Tháng 9 16, 2025
