RSC – Dalton Trans. latest articles- A water-soluble heterometallic iron(IV)–ruthenium(IV) μ-nitrido porphyrin complex: synthesis, structure and catalytic activity† Tháng 5 7, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00712G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rain Ng, Wai-Man Cheung, Cheuk-Pui Leung, Chun Kit Au, Yat-Ming So, Herman H-Y. Sung, Wan Chan, Ian Duncan Williams, Wa-Hung LeungA heterometallic Fe(IV)–Ru(IV) nitrido complex bearing a water-soluble porphyrin ligand has been synthesized, and […]Rain Ng
- Alkylzinc-Mediated Transmetallation of a Calcium Hydride Tháng 5 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00958H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kyle G. Pearce, Mary F Mahon, Michael HillThe dimeric β-diketiminato calcium hydride, [(BDI)CaH]2 (BDI = HC{(Me)CNDipp}2; Dipp = 2,6-i-Pr2C6H3), reacts with dialkylzinc reagents in a 1:2 ratio through sequential dialkyl(hydrido)zincate formation, calcium alkyl extrusion followed […]Kyle G. Pearce
- Recent developments in atomically precise metal nanocluster-based photocatalysts for hydrogen production Tháng 5 6, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00283D, PerspectiveRugma T. P., Michael N. Pillay, C. W. LiuThis review covers atomically precise metal nanocluster-based photocatalysts for hydrogen production, focusing on their unique structures, strong light harvesting abilities, and charge-transfer mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]Rugma T. P.
- Water Soluble Palladium Complexes Bearing NNN-Pincer Ligands: Synthesis, DFT Modeling, cT-DNA Interactions and In Vitro Cytotoxicity Studies Against Breast Cancer Cell Lines Tháng 5 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00224A, PaperHafiz Muhammad Rizwan Sarwar, Muhammad Jamshaid, Sara Masood, Gul-e-Saba Chaudhry, Sameen Fatima, Itrat Zahra, Arusa Akhtar, Muhammad Tahir, Ehsan Ullah Mughal, M. Naveed ZafarIn the pursuit of designing new anticancer pharmaceuticals and enhancing the therapeutic effectiveness of metal-containing compounds, two new Pd(II) pincer complexes, [Pd(o-LMe)Cl](OTf) (5) and [Pd(o-L′Me)Cl](OTf) (6), […]Hafiz Muhammad Rizwan Sarwar
- Reactivity of a dithorium oxo complex from adventitious water Tháng 5 6, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00855G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Pritam Mahawar, Steven P. Kelley, Justin R. WalenskyTreatment of [(C5Me5)2ThCl2] with degassed H2O forms a bridging oxo complex, [{(C5Me5)2ThCl}2(μ-O)], which is derivatized to its methyl analogue using MeMgCl. When treated with Me3SiCl and AlCl3, the title compound […]Pritam Mahawar
- Cadmium sulfide quantum dots functionalized with serine, proline, and aspartic acid homologs to study the influence of ligand size on the induced circular dichroism. Tháng 5 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00778J, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Milan Balaz, Yoonbin A. Joh, Krisztina VargaChirality, a fundamental property of molecules and materials, underlies numerous critical chemical, biochemical, and optical phenomena. Chiral organic molecules, termed capping ligands, have been shown to induce chirality […]Milan Balaz
- Catalytic Regioselective 3,4-Difunctionalization of 3-Iodo-o-Carborane via Pd Migration Tháng 5 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00981B, CommunicationXianren Jiang, Chang-Hua Ding, Zaozao Qiu, Zuowei XieA Pd-catalyzed one-pot regioselective difunctionalization of 3-iodo-o-carborane has been achieved for the synthesis of a wide variety of 3-alkyl-4-Nu-o-carboranes (Nu = aryl, alkyl, amino, or thio groups) in moderate to...The content of this RSS Feed (c) The Royal Society of ChemistryXianren Jiang
- Structural Insights and In Vitro and In Vivo Anticancer Evaluation of Dithiocarbamate-Based Metal Complexes against Murine Lymphoma Tháng 5 6, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00666J, PaperAnupam Singh, Riya Patel, Samrat Daripa, Manoj Kumar Bharty, R. J. Butcher, Sumit Kumar Hira, Lal Bahadur PrasadMetal-based chemotherapeutics have gained attention due to their ability to interfere with cellular functions. Dithiocarbamate ligands, known for their strong metal-binding properties, have been explored for their potential in anticancer...The content of […]Anupam Singh
- Retraction, republication and removal of expression of concern for ‘Synthesis and characterization of a novel copper carboxylate complex and a copper complex-coated polyether sulfone membrane for efficient degradation of methylene blue dye under UV irradiation: the single crystal X-ray structure of the copper carboxylate complex’ Tháng 5 6, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT90068A, Retraction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rupy Dhir, Bulle Shah, Narinder SinghTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryRupy Dhir
- Tungsten oxide as a universal source for the synthesis of complexes with different nuclearities in WO3/chalcogen/NaCN systems Tháng 5 5, 2025Dalton Trans., 2025, Advance ArticleDOI: 10.1039/D5DT00361J, PaperSpartak S. Yarovoy, Irina V. Mirzaeva, Taisiya S. Sukhikh, Yuri V. Mironov, Vadim Yanshole, Konstantin A. BrylevTungsten trioxide can be used as a readily available source in the one-step preparation of a variety of cyanide and chalcocyanide mononuclear and cluster complexes of tungsten.To cite this article before page numbers […]Spartak S. Yarovoy
- Efficient synergistic photocatalysis of supported Ir/Pd dual metal catalysts based on flexible polymeric brushes Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00593K, CommunicationWenyan Tian, Yongyue Luo, Siwen Zhu, Yang Zhou, Chuangchuang He, Xuebing MaDual metal complexes, Pd(PPh3)4 and Ir(ppy)2(dtbbpy)PF6, are simultaneously anchored onto SiO2-grafted poly(4-vinyl benzyl chloride) (PVBC) brushes via Friedel-Crafts alkylation in one-pot, affording supported dual Pd/Ir complexes with good yields in...The content of this RSS Feed (c) The Royal […]Wenyan Tian
- Toward Enhancing the Electromagnetic Wave Absorption Performance of CeFe-PBA Derived Composites: Morphology Controlling Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00780A, PaperXuan Zhang, Xueling Wang, Hongbo Tai, Zhiliang LiuThe preparation of high-efficiency electromagnetic wave (EMW) absorption materials usually requires matching dielectric and magnetic components. However, simultaneously tuning the dielectric and magnetic properties of materials still faces a significant...The content of this RSS Feed (c) The Royal Society of ChemistryXuan Zhang
- (C7H3NO4)2Sb2F2.2H2O: a pyridine-based compound shows large optical anisotropy Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00698H, CommunicationYaoguo Shen, Jiajia Xiong, Yiman Yang, Zhifeng TangA new organic-inorganic hybrid compound (C7H3NO4)2Sb2F2·2H2O was synthesized. It has two-dimensional [C14H10F2N2O10Sb2]∞ parallel layers structure, which are further optimally aligned by π-π conjugation mode. Remarkably, this compound exhibits a large...The content of this RSS Feed (c) The Royal Society of ChemistryYaoguo Shen
- FLP-CO2 adducts: Convenient sources of frustrated Lewis pairs for stoichiometric and catalytic chemistry Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00942A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jordan Thomson, Marc-Andre Courtemanche, Rebecca Claire Neu, Douglas W. StephanThe compounds [tBu3PCO2B(C6F5)3] 1 and [TMPH][C5H6Me4NCO2B(C6F5)3] 7 are easily handled synthons releasing CO2 on warming generating the corresponding FLPs which can activate H2, disulfides, alkynes, […]Jordan Thomson
- Photo-release of acetonitrile in Ruthenium (II) complexes with various substituted terpyridine ligands Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00734H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Isabelle Malfant, Vladyslav Mudrak, Pascal G. Lacroix, Pablo Labra-Vázquez, Marine Tassé, Sonia Mallet-LadeiraThe photo-release of acetonitrile is investigated in a series of ruthenium (II) complexes of general formula [Ru(R-phtpy)(acac)(MeCN)](PF6) (phtpy stands for 4’phenyl-2,2′:6′,2″-terpyridine, and […]Isabelle Malfant
- Dissolution of Zero-valent Al and its Structural Transformation in Chloride Molten Salts Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00209E, PaperJunheng Yingsu, Yiyang Liu, Jianchao Sun, Hailong Huang, Ling Han, Min Ge, Xiaobin Fu, Yuan Qian, Hong-Tao LiuMolten salts are extensively used in aluminum production and recycling industries. In this study, we discovered that metallic Al can directly dissolve into molten salts as zero-valent, forming nanoclusters—an unusual...The content of […]Junheng Yingsu
- Phosphine-induced conversion from Au36 to Au32 for constructing high-performance CO2RR catalyst Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00604J, PaperJiansheng Ye, Yali Dai, Wenjun Liu, Jingrou Xu, Jialing Li, Meng Chen, Sha Yang, Qinzhen Li, Yuanxin Du, Jinsong Chai, Manzhou ZhuTaking the Au36(CHT)24 (Au36 for short) as a precursor, a Au32(CHT)20(TFP) (Au32 for short) nanocluster is obtained with the aid of a phosphine-mediated approach. Structural analysis shows that […]Jiansheng Ye
- Pnictogen-Functionalised Isocyanide Ligands Tháng 5 5, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00992H, PaperAnthony Hill, Ryan M. KirkThe reactions of a range of cyanometallate salts with ClAtBu2Bu2 (A = P, As, Sb, A ≠ Bi) afford the new phosphino, arsino and stibino-isonitrile complexes [M(CNAtBu2)(CO)5] (M = W,...The content of this RSS Feed (c) The Royal Society of ChemistryAnthony Hill
- Photoinduced Electron Transfer Cascade between Mo- and W-based Polyoxometalates Tháng 5 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00624D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Manu Sánchez, Ana Gonzalez, Emma Guerrero-Ortega, Vipul Bansal, Jose M. Dominguez-VeraThe Keggin-type polyoxometalates phosphotungstic acid (PTA, H₃PW₁₂O₄₀) and phosphomolybdic acid (PMA, H₃PMo₁₂O₄₀) can undergo reduction through chemical and photochemical methods. However, the higher electron […]Manu Sánchez
- Dithienylethene-based supramolecular chiroptical switch in phosphate-coordination-driven 2:2 duplexes Tháng 5 4, 2025Dalton Trans., 2025, Accepted ManuscriptDOI: 10.1039/D5DT00421G, PaperMengxue Lu, Xiaowen Sun, Ji Wang, Wei Zhao, Hongwei Ma, Xiao-Juan Yang, Biao WuChiral photoswitches based on dithienylethenes have attracted extensive attention due to their unique chirality and optical activities, endowing them with potential applications in a multitude of fields. Herein, we present...The content of this RSS Feed (c) […]Mengxue Lu
- A water-soluble heterometallic iron(IV)–ruthenium(IV) μ-nitrido porphyrin complex: synthesis, structure and catalytic activity† Tháng 5 7, 2025
