RSC – Org. Chem. Front. latest articles- Catalytic Haloallylation/Zr-Mediated Dienyne Cyclization/Isomerization Sequence for Tailored Cyclopentadiene Substitution Tháng Mười Một 27, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO02020K, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marko Gobin, Ivana Nikšić-Franjić, Nikola TopolovcanChemical properties and reactivity of cyclopentadienes (Cp) originate from the number and nature of attached functionalities. Even slight change in molecular architecture dramatically reflects their application in […]Marko Gobin
- TMEDA-enabled regioselective sulfenylation of unprotected N-heterocycles via electrochemical sulfinyl radical generation Tháng Mười Một 27, 2024Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01772B, Research ArticleQiang Zhong, Xinru Jiang, Hui Gao, Pei-Long Wang, Hongji LiAn electrochemical sulfenylation of unprotected N-heterocycles with a wide range of commercially available arylsulfonyl chlorides was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) […]Qiang Zhong
- A Catalyst- and Solvent-Free Visible-Light-Promoted Bromination and Chlorination of Tertiary C(sp3)-H Bond Tháng Mười Một 27, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01997K, Research ArticleQuanjin Rong, Zhe Zhang, Jingyu Meng, Fan Wang, Zhongquan LiuPrevious methods for selective halogenation of aliphatic C-H bonds generally required catalysts, additives, and the use of large amounts of solvents, leading to low atom economy and solvent pollution issues....The content of this RSS Feed (c) The Royal […]Quanjin Rong
- Axially Chiral Biaryls via Rhodium-Catalyzed Atroposelective C-H Sulfenylation and Selenylation Tháng Mười Một 27, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01905A, Research ArticleYishou Wang, Songjie Yu, Xingwei LiTransition metal-catalyzed atroposelective C-H activation has become an efficient approach for the rapid construction of functionalized axially chiral biaryls, but remains challenging in synthesis of chalcogenated axially chiral biaryls due...The content of this RSS Feed (c) The Royal Society of ChemistryYishou Wang
- Highly Regioselective Oxidative Csp2-H Amination for Indolosesquiterpene Alkaloids: Total Synthesis of (+)-Dioridamycin Tháng Mười Một 26, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01773K, Research ArticleRhituparna Nandi, Sovan Niyogi, Sourav Kundu, Ayan Mondal, Nanda Kishore Roy, Alakesh BisaiDimeric indolosesquiterpenoids drew significant interest in the synthetic community due to their higher potential of biological activity than their monomeric congeners. Biosynthetically it has been shown that xiamycin A (2a)...The content of this RSS Feed […]Rhituparna Nandi
- Modular Assembling of Chiral Multisubstituted Tetrahydropyrans through the Cascade Asymmetric Aldehyde Allylboration/oxa-Cyclization by a Chiral Phosphoric Acid Tháng Mười Một 26, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01851F, Research ArticleYiyong Huang, Yuhao Wang, Bojun He, Subarna Jyoti Kalita, Zhen-Ni Zhao , Yi-Chao Li, Dehua Zhang, Zi-Qi Yi, Uwe SchneiderConsidering the structural importance of 2,6-disubstituted and 2,2,6-trisubstituted tetrahydropyran motifs, two novel types of cascade reactions have been developed to address the challenges of synthetic efficiency, high stereoselectivity […]Yiyong Huang
- Practical heptafluoroisopropylation of nitrogen-containing (hetero)aromatics under visible light Tháng Mười Một 26, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01660B, Research ArticleXin Luo, Shao-Jie Lou, Yan-Biao Sun, Cheng-Cheng Jing, Xiang Fei, Xiaoxiao Zhang, Jing-Jing Zhai, Yifeng Wang, Dan-Qian XuA practical visible-light-driven heptafluoroisopropylation of substituted anilines and heterocyclic aromatics has been achieved. The key to the success of this facile transformation lies in the in-situ generation of a novel...The […]Xin Luo
- Carbamoylation of azaarenes and olefins with formamides through dual photoredox/HAT catalysis Tháng Mười Một 26, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO02040E, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jose C. Gonzalez-Gomez, Beatriz Quevedo-Flores, Irene Bosque, Loris Laze, Mario MartosA unique strategy for the photoinduced Minisci and Giese carbamoylation with readily available formamides is described. This approach avoids using less atom-efficient […]Jose C. Gonzalez-Gomez
- Artificial photoenzyme catalyzed aerobic oxidative cleavage of olefins in water Tháng Mười Một 26, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01724B, Research ArticleYu Fu, Xutong Ye, Yuanjie Sun, Zehui Wang, Yingru Xu, Yuzhou Wu, Shangxian Xie, Weining Zhao, Guojiao Wu, Fangrui ZhongAn efficient photocatalytic system based on an artificially engineered photoenzyme, BSA-TXO, has been developed for the oxidative cleavage of various alkenes into ketones. This catalytic system operates under […]Yu Fu
- Catalytic Asymmetric Synthesis and Synthetic Application of Heteroatom-substituted Axially Chiral Allenes Tháng Mười Một 25, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO02004A, Review ArticleLifei Gan, Xuanchen Wan, Yucheng Pang, Yuqi Zou, Yu-Hua Deng, Zhihui ShaoThe axially chiral allene framework has garnered significant attention from synthetic community, due to its wide applications in natural products, organic synthesis, pharmaceuticals, and materials science. Among the structurally diverse...The content of this RSS Feed (c) […]Lifei Gan
- S-Alkylation of sulfinamides with Zn-carbenoids: expanding stereoselective sulfoximine synthesis beyond NH derivatives Tháng Mười Một 22, 2024Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO01931H, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Glebs Jersovs, Dzonatans Melgalvis, Artis Kinens, Pavel A. Donets, Edgars SunaA general entry to enantiopure N-substituted sulfoximines via direct stereospecific S-alkylation of sulfinamides with Zn-carbenoids is disclosed.To cite this article before page […]Glebs Jersovs
- Efficient synthesis of trisubstituted allenes via palladium-catalysed deaminative coupling of tertiary propargylamines with arylsiloxanes Tháng Mười Một 22, 2024Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO01780C, Research ArticleMingjie Liao, Ziqi Yi, Qingqing You, Chuang Liu, Huangdi Feng, Junhai HuangHighly regioselective and efficient synthesis of trisubstituted allenes with palladium catalysts via deaminative coupling reaction among tertiary propargylamines and arylsiloxanes which were activated in situ using Et3N·3HF has been developed.To cite this article before page numbers […]Mingjie Liao
- Recent advances in the photocatalytic cleavage of C–C and C–N bonds associated with amines and their derivatives Tháng Mười Một 22, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO02038C, Review ArticleQibo Ni, Yan Zhou, Lang Chen, Yunkui LiuThe cleavage of C-C and C-N bonds in ubiquitous amines and their derivatives serves as an important and useful protocol for the construction of valuable organic molecules. Recently, the visible-light-driven...The content of this RSS Feed (c) The Royal Society of […]Qibo Ni
- Water-enabled α-C(sp3)–H amination via [1,6]-hydride transfer: green access to diazepino[6,5,4-cd]indoles Tháng Mười Một 21, 2024Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01761G, Research ArticleYao-Bin Shen, Xiao-Lin Wang, Qian-Hao Zhuang, Xiao-De An, Bin Qiu, Houchen Wang, Tiesheng Shi, Jian XiaoWater-enabled α-C(sp3)–H amination of 4-dialkylamino-indole-3-carbaldehydes with primary amines was developed for green synthesis of diazepino[6,5,4-cd]indoles via cascade aldimine condensation/[1,6]-hydride transfer/cyclization.To cite this article before page numbers are assigned, use the DOI form […]Yao-Bin Shen
- Palladium-catalyzed NHC ligand-controlled regiodivergent allyl-fluoroallyl cross-couplings Tháng Mười Một 21, 2024Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO01800A, Research ArticleYangyang Ma, Boxia Xu, Hua Zhang, Zhiping LiThe palladium-catalyzed cross-coupling of (E)-2-fluoroallyl carbonates and allylboronates is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of ChemistryYangyang Ma
- Copper-catalyzed N–H bond chalcogenation of anilines Tháng Mười Một 21, 2024Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO01962H, Research ArticleMonak Patel, Rishukumar Panday, Bharatkumar Z. Dholakiya, Togati NaveenThe chalcogen–nitrogen bond (X–N, where X = S, Se) is a key chemical motif in many structures, including inorganic and organic materials, catalysts, protein mimics, and pharmaceuticals.To cite this article before page numbers are assigned, use the DOI form […]Monak Patel
- Synthesis, crystal growth, structure and photophysical properties of decafluoroanthracene and its co-crystals with polycyclic arenes Tháng Mười Một 21, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01825G, Research ArticleAlexandra Friedrich, Lisa Schraut-May, Florian Rauch, Pablo Durand, Johannes Krebs, Paul Niklas Niklas Ruth, Sebastian Hammer, Rüdiger Bertermann, Maik Finze, Stewart Clark, Jens Pflaum, Nicolas Leclerc, Todd B MarderA series of 1:1 co-crystals of decafluoroanthracene with naphthalene, anthracene, tetracene, pyrene, perylene and triphenylene were grown and characterised […]Alexandra Friedrich
- Photoinduced Ullmann-type cross-coupling reactions: mechanistic insights and emerging challenges Tháng Mười Một 20, 2024Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01814A, Review ArticleAhmed Th. Abdulghaffar, Haolong Zhang, Qiankun Zhang, Qian Tong, Ruirui Tian, Hao Xu, Jiawei Yang, Yuanqing XuThis review traces the evolution of Cu-catalyzed Ullmann mechanisms, highlighting the SET mechanism with extensive synthetic examples and mechanistic insights.To cite this article before page numbers are assigned, use the DOI […]Ahmed Th. Abdulghaffar
- (BO)2-doped tetrathia[7]helicenes: synthesis and properties-change induced by “BO bonds inversion” Tháng Mười Một 20, 2024Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01897D, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luigi Menduti, Clara CB Baldoli, Michael Bolte, Simone Manetto, Claudio Villani, Marta Penconi, Sara Grecchi, Serena ARNABOLDI, Giuseppe Mazzeo, Giovanna Longhi, Alexander Virovets, Hans-Wolfram Lerner, Matthias Wagner, Emanuela LicandroHelical distortion of polyaromatic […]Luigi Menduti
- Synthesis and derivatization of an isomer of an N-heterotriangulene bearing five-, six- and seven-membered rings around the central nitrogen atom Tháng Mười Một 20, 2024Org. Chem. Front., 2025, Advance ArticleDOI: 10.1039/D4QO02027H, Research ArticleXinxin Chen, Weifan Wang, Gang ZhangAn isomer of an N-heterotriangulene containing five-, six- and seven-membered rings around the central nitrogen atom was synthesized. It can be further functionalized by condensing with ortho-diamines to afford the π-extended derivatives.To cite this article before page numbers are assigned, use the […]Xinxin Chen
- Catalytic Haloallylation/Zr-Mediated Dienyne Cyclization/Isomerization Sequence for Tailored Cyclopentadiene Substitution Tháng Mười Một 27, 2024
